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Late-Stage C(sp3)–H Methylation of Drug Molecules
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
inferredcites →https://doi.org/10.1002/anie.201303207openalex-snapshot
Profound Methyl Effects in Drug Discovery and a Call for New CH Methylation Reactions
inferredcites →https://doi.org/10.1002/anie.202002674openalex-snapshot
Catalytic Synthesis of 8‐Membered Ring Compounds via Cobalt(III)‐Carbene Radicals
inferredcites →https://doi.org/10.1002/cmdc.201200025openalex-snapshot
Discovery of [(2R,5R)‐5‐{[(5‐Fluoropyridin‐2‐yl)oxy]methyl}‐2‐methylpiperidin‐1‐yl][5‐methyl‐2‐(pyrimidin‐2‐yl)phenyl]methanone (MK‐6096): A Dual Orexin Receptor Antagonist with Potent Sleep‐Promoting Properties
inferredcites →https://doi.org/10.1002/cmdc.201800119openalex-snapshot
The Current Status of O‐Heterocycles: A Synthetic and Medicinal Overview
inferredcites →https://doi.org/10.1016/j.cbpa.2013.05.032openalex-snapshot
Radical SAM-mediated methylation reactions
inferredcites →https://doi.org/10.1016/j.chempr.2020.07.007openalex-snapshot
Late-Stage Functionalization
inferredcites →https://doi.org/10.1016/j.molcata.2006.08.092openalex-snapshot
Mechanism of decatungstate photocatalyzed oxygenation of aromatic alcoholsPart I. Continuous photolysis and laser flash photolysis studies
inferredcites →https://doi.org/10.1021/acs.jmedchem.0c02008openalex-snapshot
Discovery of GLPG1972/S201086, a Potent, Selective, and Orally Bioavailable ADAMTS-5 Inhibitor for the Treatment of Osteoarthritis
inferredcites →https://doi.org/10.1021/acs.jmedchem.2c00473openalex-snapshot
Rings in Clinical Trials and Drugs: Present and Future
inferredcites →https://doi.org/10.1021/acs.jmedchem.7b00408openalex-snapshot
4-Methyl-6,7-dihydro-4H-triazolo[4,5-c]pyridine-Based P2X7 Receptor Antagonists: Optimization of Pharmacokinetic Properties Leading to the Identification of a Clinical Candidate
inferredcites →https://doi.org/10.1021/acs.jmedchem.7b01515openalex-snapshot
Identification of Morpholino-2H-pyrido[3,2-b][1,4]oxazin-3(4H)-ones as Nonsteroidal Mineralocorticoid Antagonists
inferredcites →https://doi.org/10.1021/acs.jmedchem.8b01187openalex-snapshot
Discovery and Characterization of AZD6738, a Potent Inhibitor of Ataxia Telangiectasia Mutated and Rad3 Related (ATR) Kinase with Application as an Anticancer Agent
inferredcites →https://doi.org/10.1021/acs.jmedchem.9b01720openalex-snapshot
Structure-Based Design and Pharmacokinetic Optimization of Covalent Allosteric Inhibitors of the Mutant GTPase KRASG12C
inferredcites →https://doi.org/10.1021/acs.organomet.2c00533openalex-snapshot
Structural Evidence for Aromatic Heterocycle N–O Bond Activation via Oxidative Addition
inferredcites →https://doi.org/10.1021/acscatal.0c02105openalex-snapshot
Direct C–H Arylation of Aldehydes by Merging Photocatalyzed Hydrogen Atom Transfer with Palladium Catalysis
inferredcites →https://doi.org/10.1021/acscatal.6b01984openalex-snapshot
Unraveling the Key Features of the Reactive State of Decatungstate Anion in Hydrogen Atom Transfer (HAT) Photocatalysis
inferredcites →https://doi.org/10.1021/acscatal.7b03354openalex-snapshot
Site-Selective C–H Functionalization by Decatungstate Anion Photocatalysis: Synergistic Control by Polar and Steric Effects Expands the Reaction Scope
inferredcites →https://doi.org/10.1021/ar200202copenalex-snapshot
Radical-Mediated Enzymatic Methylation: A Tale of Two SAMS
inferredcites →https://doi.org/10.1021/cr00102a004openalex-snapshot
Transition metal-hydrogen and metal-carbon bond strengths: the keys to catalysis
inferredcites →https://doi.org/10.1021/cr200060gopenalex-snapshot
The Methylation Effect in Medicinal Chemistry
inferredcites →https://doi.org/10.1021/cr4004709openalex-snapshot
RadicalS-Adenosylmethionine Enzymes
inferredcites →https://doi.org/10.1021/ic00122a021openalex-snapshot
Early-Time Dynamics and Reactivity of Polyoxometalate Excited States. Identification of a Short-Lived LMCT Excited State and a Reactive Long-Lived Charge-Transfer Intermediate following Picosecond Flash Excitation of [W10O32]4- in Acetonitrile
inferredcites →https://doi.org/10.1021/ja00234a047openalex-snapshot
A new and practical method of decarboxylation: photosensitized decarboxylation of N-acyloxyphthalimides via electron-transfer mechanism
inferredcites →https://doi.org/10.1021/jacs.1c04655openalex-snapshot
Asymmetric Radical Process for General Synthesis of Chiral Heteroaryl Cyclopropanes
inferredcites →https://doi.org/10.1021/jacs.1c04968openalex-snapshot
New Catalytic Radical Process Involving 1,4-Hydrogen Atom Abstraction: Asymmetric Construction of Cyclobutanones
inferredcites →https://doi.org/10.1021/jacs.1c09412openalex-snapshot
Exploring Electrochemical C(sp 3 )–H Oxidation for the Late-Stage Methylation of Complex Molecules
inferredcites →https://doi.org/10.1021/jacs.2c02062openalex-snapshot
Nontraditional Fragment Couplings of Alcohols and Carboxylic Acids: C( sp 3 )–C( sp 3 ) Cross-Coupling via Radical Sorting
inferredcites →https://doi.org/10.1021/jacs.2c08989openalex-snapshot
Nickel Catalysis via S H 2 Homolytic Substitution: The Double Decarboxylative Cross-Coupling of Aliphatic Acids
inferredcites →https://doi.org/10.1021/jacs.8b01662openalex-snapshot
Enantioselective Radical Cyclization for Construction of 5-Membered Ring Structures by Metalloradical C–H Alkylation
inferredcites →https://doi.org/10.1021/jacs.9b02411openalex-snapshot
Connecting Organometallic Ni(III) and Ni(IV): Reactions of Carbon-Centered Radicals with High-Valent Organonickel Complexes
inferredcites →https://doi.org/10.1021/jacs.9b06454openalex-snapshot
Mechanistic Studies on CysS – A Vitamin B 12 -Dependent Radical SAM Methyltransferase Involved in the Biosynthesis of the tert -Butyl Group of Cystobactamid
inferredcites →https://doi.org/10.1021/jacs.9b12554openalex-snapshot
Nickel/Photo-Cocatalyzed Asymmetric Acyl-Carbamoylation of Alkenes
inferredcites →https://doi.org/10.1021/jm100541copenalex-snapshot
Discovery of the Dual Orexin Receptor Antagonist [(7 R )-4-(5-Chloro-1,3-benzoxazol-2-yl)-7-methyl-1,4-diazepan-1-yl][5-methyl-2-(2 H -1,2,3-triazol-2-yl)phenyl]methanone (MK-4305) for the Treatment of Insomnia
inferredcites →https://doi.org/10.1021/jm501100bopenalex-snapshot
Analysis of the Structural Diversity, Substitution Patterns, and Frequency of Nitrogen Heterocycles among U.S. FDA Approved Pharmaceuticals
inferredcites →https://doi.org/10.1021/jp980723topenalex-snapshot
Early Events in Decatungstate Photocatalyzed Oxidations: A Nanosecond Laser Transient Absorbance Reinvestigation
inferredcites →https://doi.org/10.1038/nature22813openalex-snapshot
Selective sp3 C–H alkylation via polarity-match-based cross-coupling
inferredcites →https://doi.org/10.1038/ncomms10093openalex-snapshot
Acceptorless dehydrogenation of small molecules through cooperative base metal catalysis
inferredcites →https://doi.org/10.1038/nrd.2018.116openalex-snapshot
Expanding the medicinal chemistry synthetic toolbox
inferredcites →https://doi.org/10.1038/s41557-020-0436-1openalex-snapshot
The merger of decatungstate and copper catalysis to enable aliphatic C(sp3)–H trifluoromethylation
inferredcites →https://doi.org/10.1038/s41570-021-00300-6openalex-snapshot
Late-stage C–H functionalization offers new opportunities in drug discovery
inferredcites →https://doi.org/10.1038/s41586-018-0366-xopenalex-snapshot
Direct arylation of strong aliphatic C–H bonds
inferredcites →https://doi.org/10.1038/s41586-020-2137-8openalex-snapshot
Late-stage oxidative C(sp3)–H methylation
inferredcites →https://doi.org/10.1039/a908588bopenalex-snapshot
Reactivity of the charge transfer excited state of sodium decatungstate at the nanosecond time scale
inferredcites →https://doi.org/10.1039/b812100copenalex-snapshot
Decatungstate as an efficient photocatalyst in organic chemistry
inferredcites →https://doi.org/10.1039/c2cp43950fopenalex-snapshot
Electronic and EPR spectra of the species involved in [W10O32]4− photocatalysis. A relativistic DFT investigation
inferredcites →https://doi.org/10.1039/c5cs00628gopenalex-snapshot
The medicinal chemist's toolbox for late stage functionalization of drug-like molecules
inferredcites →https://doi.org/10.1039/d0cs00973copenalex-snapshot
Installing the “magic methyl” – C–H methylation in synthesis
inferredcites →https://doi.org/10.1039/d0gc01035aopenalex-snapshot
Photocatalytic hydrogen atom transfer: the philosopher's stone for late-stage functionalization?
inferredcites →https://doi.org/10.1039/dt9880000183openalex-snapshot
Photocatalytic dimerization of olefins by decatungstate( VI ), [W 10 O 32 ] 4– , in acetonitrile and magnetic resonance studies of photoreduced species
inferredcites →https://doi.org/10.1074/jbc.r114.607044openalex-snapshot
Mechanistic Diversity of Radical S-Adenosylmethionine (SAM)-dependent Methylation
inferredcites →https://doi.org/10.1126/science.2857503openalex-snapshot
Mechanisms of Coenzyme B 12 -Dependent Rearrangements
inferredcites →https://doi.org/10.1126/science.abh2623openalex-snapshot
C(sp 3 )–H methylation enabled by peroxide photosensitization and Ni-mediated radical coupling
inferredcites →https://doi.org/10.1126/science.abl4322openalex-snapshot
A biomimetic S H 2 cross-coupling mechanism for quaternary sp 3 -carbon formation
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
inferred← citeshttps://doi.org/10.2139/ssrn.4662834openalex-extracted
Photoredox/Nickel Dual-Catalysis-Enabled Regioselective Cyclization of Alkenes with Alkyl Chlorides
inferred← citeshttps://doi.org/10.1002/adsc.70498openalex-snapshot
Photo‐/Electrochemical Site‐Selective Radical α‐C(sp 3 )–H Functionalization of Amines: Four Green Strategies for Applications, Challenges, and Opportunities
inferred← citeshttps://doi.org/10.1002/advs.202305471openalex-snapshot
Photodriven Methane Conversion on Transition Metal Oxide Catalyst: Recent Progress and Prospects
inferred← citeshttps://doi.org/10.1002/advs.202415936openalex-snapshot
C(sp3)─S Bond Formation via the Synergy of Oxidative With Reductive Photocatalysts Through Photoredox and Dual Hydrogen Atom Transfer Processes
inferred← citeshttps://doi.org/10.1002/ange.202313247openalex-snapshot
Alicyclic‐Amine‐Derived Imine‐BF3 Complexes: Easy‐to‐Make Building Blocks for the Synthesis of Valuable α‐Functionalized Azacycles
inferred← citeshttps://doi.org/10.1002/ange.202403119openalex-snapshot
Cross‐selective Deoxygenative Coupling of Aliphatic Alcohols: Installation of Methyl Groups including Isotopic Labels by Nickel Catalysis
inferred← citeshttps://doi.org/10.1002/ange.202408697openalex-snapshot
Molecular Engineering of Methylated Sulfone‐Based Covalent Organic Frameworks for Back‐Reaction Inhibited Photocatalytic Overall Water Splitting
inferred← citeshttps://doi.org/10.1002/ange.202412418openalex-snapshot
Cyclic Sulfoximines as Methyl and Perdeuteromethyl Transfer Agents and Their Applications in Photoredox Catalysis
inferred← citeshttps://doi.org/10.1002/ange.202421256openalex-snapshot
Heterocoupling Two Similar Benzyl Radicals by Dual Photoredox/Cobalt Catalysis
inferred← citeshttps://doi.org/10.1002/ange.202423795openalex-snapshot
Alcohol Activation by Benzodithiolylium for Deoxygenative Alkylation Driven by Photocatalytic Energy Transfer
inferred← citeshttps://doi.org/10.1002/ange.202506883openalex-snapshot
Acyclic Quaternary Stereocenters via Catalytic Asymmetric Cross‐Couplings with Unactivated Alkyl N ‐Hydroxyphthalimide Esters
inferred← citeshttps://doi.org/10.1002/ange.202507632openalex-snapshot
S H 2 Decarboxylative Monofluoromethylation of Aliphatic Carboxylic Acids Enabled by Nickel/Photoredox Dual Catalysis
inferred← citeshttps://doi.org/10.1002/ange.3306470openalex-snapshot
Cooperative Fe–LMCT and Ni–S H 2 Catalysis for Native Carboxylic Acid Methyl Editing
inferred← citeshttps://doi.org/10.1002/ange.8014515openalex-snapshot
Data‐Driven Approach to Understanding Tetrabutylammonium Decatungstate‐Catalyzed C(sp 3 )–H Functionalization Selectivity
inferred← citeshttps://doi.org/10.1002/anie.202313247openalex-snapshot
Alicyclic‐Amine‐Derived Imine‐BF3 Complexes: Easy‐to‐Make Building Blocks for the Synthesis of Valuable α‐Functionalized Azacycles
inferred← citeshttps://doi.org/10.1002/anie.202403119openalex-snapshot
Cross‐selective Deoxygenative Coupling of Aliphatic Alcohols: Installation of Methyl Groups including Isotopic Labels by Nickel Catalysis
inferred← citeshttps://doi.org/10.1002/anie.202408697openalex-snapshot
Molecular Engineering of Methylated Sulfone‐Based Covalent Organic Frameworks for Back‐Reaction Inhibited Photocatalytic Overall Water Splitting
inferred← citeshttps://doi.org/10.1002/anie.202412418openalex-snapshot
Cyclic Sulfoximines as Methyl and Perdeuteromethyl Transfer Agents and Their Applications in Photoredox Catalysis
inferred← citeshttps://doi.org/10.1002/anie.202421256openalex-snapshot
Heterocoupling Two Similar Benzyl Radicals by Dual Photoredox/Cobalt Catalysis
inferred← citeshttps://doi.org/10.1002/anie.202423795openalex-snapshot
Alcohol Activation by Benzodithiolylium for Deoxygenative Alkylation Driven by Photocatalytic Energy Transfer
inferred← citeshttps://doi.org/10.1002/anie.202506883openalex-snapshot
Acyclic Quaternary Stereocenters via Catalytic Asymmetric Cross‐Couplings with Unactivated Alkyl N ‐Hydroxyphthalimide Esters
inferred← citeshttps://doi.org/10.1002/anie.202507632openalex-snapshot
S H 2 Decarboxylative Monofluoromethylation of Aliphatic Carboxylic Acids Enabled by Nickel/Photoredox Dual Catalysis
inferred← citeshttps://doi.org/10.1002/anie.3306470openalex-snapshot
Cooperative Fe–LMCT and Ni–S H 2 Catalysis for Native Carboxylic Acid Methyl Editing
inferred← citeshttps://doi.org/10.1002/anie.8014515openalex-snapshot
Data‐Driven Approach to Understanding Tetrabutylammonium Decatungstate‐Catalyzed C(sp 3 )–H Functionalization Selectivity
inferred← citeshttps://doi.org/10.1002/cctc.202300042openalex-snapshot
Decatungstate‐Photocatalyzed Functionalization of α‐Imino Esters for the Preparation of Unnatural α‐Amino Acid Derivatives
inferred← citeshttps://doi.org/10.1002/cctc.202400955openalex-snapshot
Bimolecular Homolytic Substitution (SH2) at a Transition Metal
inferred← citeshttps://doi.org/10.1002/cctc.202401613openalex-snapshot
Mechanochemical Ball Milling Approach to C(sp3)‐H Functionalization of 8‐Methylquinolines
inferred← citeshttps://doi.org/10.1002/cctc.202501714openalex-snapshot
Development of a Continuous, Uncoupled Fluorescence‐based Assay for Monitoring Methyltransferase Activity: Methylation Going Sour
inferred← citeshttps://doi.org/10.1002/ceur.70299openalex-snapshot
meta ‐Methylation of Aniline and Anisole Derivatives via Palladium/S, O‐Ligand/Norbornene Cooperative Catalysis
inferred← citeshttps://doi.org/10.1002/chem.202302542openalex-snapshot
Photo‐Induced C−H Methylation Reactions
inferred← citeshttps://doi.org/10.1002/chem.71191openalex-snapshot
Nickel‐Catalyzed Radical‐Radical Cross‐Coupling Reactions
inferred← citeshttps://doi.org/10.1002/ejoc.70835openalex-snapshot
Counterion Effects in Decatungstate Photocatalysis
inferred← citeshttps://doi.org/10.1002/slct.202302732openalex-snapshot
Visible‐Light Photoredox Catalysis in the Late‐Stage Functionalization of Anticancer Agents
inferred← citeshttps://doi.org/10.1007/s11426-025-2651-2openalex-snapshot
Deoxygenative radical reactions of alcohols: a review
inferred← citeshttps://doi.org/10.1016/b978-0-323-96025-0.00088-0openalex-snapshot
Oxidation Adjacent to Nitrogen
inferred← citeshttps://doi.org/10.1016/b978-0-323-96025-0.00155-1openalex-snapshot
Photoredox Catalysis
inferred← citeshttps://doi.org/10.1016/b978-0-443-29808-0.00048-0openalex-snapshot
Late-stage functionalization in drug discovery
inferred← citeshttps://doi.org/10.1016/j.cclet.2026.112653openalex-snapshot
Machine learning-enabled prediction of reactivity in metallaphotoredox SH2-mediated C(sp3)–C(sp3) coupling
inferred← citeshttps://doi.org/10.1016/j.cclet.2026.112871openalex-snapshot
Stereoselective synthesis of classical/nonclassical C-alkyl glycosides via SH2 strategy
inferred← citeshttps://doi.org/10.1016/j.ccr.2026.218464openalex-snapshot
Machine learning-derived decatungstate photocatalytic CH functionalization: from machine learning to predictive modeling
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Microbial biodegradation of abacavir: Isolation of Pseudomonas sp. A1 and elucidation of novel degradation pathways
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Chinese herbal medicine-derived self-assembled bioactive materials: A promising strategy for hemostasis and wound repair
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Drugs from drugs: New chemical insights into a mature concept
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Nickel-catalyzed construction of C(sp3)-C(sp3) bonds with alkyl halides and diazo compounds for accessing all-carbon quaternary centers
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Photoredox/nickel dual-catalysis-enabled synthesis of N-heterocycles from alkyl chlorides and alkenes
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Taming radicals for stereoselective iron-catalyzed carbon–carbon bond formations
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Regioselective and enantioselective acylative ring opening of aziridines via cooperative nickel photocatalysis
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Strategies and Mechanisms of First-Row Transition Metal-Regulated Radical C–H Functionalization
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Earth-Abundant 3d Transition Metal-Catalyzed Enantioselective C–H Functionalization
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Mechanistic and Experimental Insights into Ligand-Class and Radical-Identity Effects on S H 2-Mediated Radical Sorting in Nickel Catalysis
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Ru(II)-Catalyzed Sustainable C–H Methylation of Indolines with Organoboranes in Ethanol
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Sustainable C–H Methylation Employing Dimethyl Carbonate
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Intramolecular/Intermolecular Sequential Cyclization Accompanied by Double C–F Bond Cleavage: Access to Tricyclic Fluorine-Containing Pyrano[3,2-c]chromenes
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Visible-Light-Induced C(sp3)-H Activation for Minisci Alkylation of Pyrimidines Using CHCl3 as Radical Source and Oxidant
inferred← citeshttps://doi.org/10.1021/acs.joc.5c00793openalex-snapshot
Photoinduced Nickel-Mediated Radical Coupling Reaction of Sodium Sulfinates with N-Hydroxyphthalimide Esters
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Activation Strategies for Alkyl Precursors in Achieving C(sp3)–C(sp3) Cross-Coupling via Metallaphotoredox Catalysis
inferred← citeshttps://doi.org/10.1021/acs.organomet.4c00102openalex-snapshot
A σ-Poor, π-Rich Pyridonate Pincer Ligand Designed To Enhance C–H Oxidative Addition at Platinum Group Metals: Experimental and Computational Studies
inferred← citeshttps://doi.org/10.1021/acs.orglett.3c03669openalex-snapshot
Nickel/Photo-Cocatalyzed Three-Component Alkyl-Acylation of Aryl-Activated Alkenes
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c00567openalex-snapshot
C(sp3)–C(sp3) Coupling of Cycloalkanes and Alkyl Halides via Dual Photocatalytic Hydrogen Atom Transfer and Nickel Catalysis
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c00755openalex-snapshot
Gold-Catalyzed C(sp 3 )–C(sp 2 ) Suzuki–Miyaura Coupling Reaction
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c01370openalex-snapshot
Cobalt/Photoredox Dual-Catalyzed Cross-Radical Coupling of Alkenes via Hydrogen Atom Transfer and Homolytic Substitution
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c04141openalex-snapshot
Electrochemical Desaturation and β-Thiocyanation of Cyclic Amides
inferred← citeshttps://doi.org/10.1021/acs.orglett.6c01471openalex-snapshot
Photocatalytic Regioselective Alkylation of 4-Alkenylpyridines via Delocalized Pyridinyl Radicals
inferred← citeshttps://doi.org/10.1021/acscatal.3c04049openalex-snapshot
Visible-Light-Mediated Two Transient C(sp3) Radical-Selective Cross-Coupling via Nickel Catalyst Continuous Capture: Synthesis of Pyrroline Derivatives
inferred← citeshttps://doi.org/10.1021/acscatal.3c05467openalex-snapshot
Direct Synthesis of β-Amino Boronates via Amide α-C–H Bond Activation and C(sp3)–C(sp3) Coupling under Dual Ni/Photoredox Catalysis
inferred← citeshttps://doi.org/10.1021/acscatal.4c01160openalex-snapshot
B(C6F5)3-Catalyzed C(sp3)–H Alkylation of Tertiary Amines with Electron-Deficient Olefins: Determinants of Site Selectivity
inferred← citeshttps://doi.org/10.1021/acscatal.4c04897openalex-snapshot
Acridine/Lewis Acid Complexes as Powerful Photocatalysts: A Combined Experimental and Mechanistic Study
inferred← citeshttps://doi.org/10.1021/acscatal.5c05860openalex-snapshot
Decarboxylative and Deformylative Alkyl–Alkyl Cross-Coupling Enabled by Nickel/Photoredox Catalysis
inferred← citeshttps://doi.org/10.1021/acscentsci.5c00468openalex-snapshot
Late-Stage Heteroarene Alkylation via Minisci Reaction with Gaseous Alkanes Enabled by Hydrogen Atom Transfer in Flow
inferred← citeshttps://doi.org/10.1021/acschembio.4c00825openalex-snapshot
Synthesis of Differentially Halogenated Lissoclimide Analogues To Probe Ribosome E-Site Binding
inferred← citeshttps://doi.org/10.1021/acsmaterialslett.3c00740openalex-snapshot
The Structure Determination of Organic Molecules by Co-crystallization of Anthracene-Based Crystallization Chaperone
inferred← citeshttps://doi.org/10.1021/acsnano.5c11814openalex-snapshot
W 10 Single-Cluster-Mediated Syngas Electrosynthesis in Single-Sandwich-Layer ZnAl-Layered Double Hydroxide Catalysts
inferred← citeshttps://doi.org/10.1021/jacs.3c06532openalex-snapshot
Oxidative Cross Dehydrogenative Coupling of N -Heterocycles with Aldehydes through C( sp 3 )–H Functionalization
inferred← citeshttps://doi.org/10.1021/jacs.4c01842openalex-snapshot
Enantioselective Construction of Quaternary Stereocenters via Cooperative Photoredox/Fe/Chiral Primary Amine Triple Catalysis
inferred← citeshttps://doi.org/10.1021/jacs.4c02284openalex-snapshot
A Bimolecular Homolytic Substitution-Enabled Platform for Multicomponent Cross-Coupling of Unactivated Alkenes
inferred← citeshttps://doi.org/10.1021/jacs.4c02316openalex-snapshot
Engaging Alkenes in Metallaphotoredox: A Triple Catalytic, Radical Sorting Approach to Olefin-Alcohol Cross-Coupling
inferred← citeshttps://doi.org/10.1021/jacs.4c05744openalex-snapshot
Triple Radical Sorting: Aryl-Alkylation of Alkenes
inferred← citeshttps://doi.org/10.1021/jacs.4c14104openalex-snapshot
Spectroscopic and Computational Interrogation of a High-Valent Nickel-Dialkyl Complex Indicates Electronic Structure Asymmetry Drives C–C Bond Formation Reactivity
inferred← citeshttps://doi.org/10.1021/jacs.4c14942openalex-snapshot
Iron-Catalyzed Cross-Electrophile Coupling for the Formation of All-Carbon Quaternary Centers
inferred← citeshttps://doi.org/10.1021/jacs.4c15275openalex-snapshot
Enantioselective Alkyl–Acyl Radical Cross-Coupling Enabled by Metallaphotoredox Catalysis
inferred← citeshttps://doi.org/10.1021/jacs.4c17267openalex-snapshot
Enantioselective β-C(sp 3 )–H Nucleophilic Tosylation of Native Amides: A Synthetic Platform for Chiral Methyl Stereocenters
inferred← citeshttps://doi.org/10.1021/jacs.5c03711openalex-snapshot
Synergistic LMCT and Ni Catalysis for Methylative Cross-Coupling Using tert-Butanol: Modulating Radical Pathways via Selective Bond Homolysis
inferred← citeshttps://doi.org/10.1021/jacs.5c03770openalex-snapshot
Photochemistry of Ni(II) Tolyl Chlorides Supported by Bidentate Ligand Frameworks
inferred← citeshttps://doi.org/10.1021/jacs.5c07367openalex-snapshot
Radical Sorting Catalysis via Bimolecular Homolytic Substitution (S H 2): Opportunities for C(sp 3 )–C(sp 3 ) Cross-Coupling Reactions
inferred← citeshttps://doi.org/10.1021/jacs.5c10906openalex-snapshot
Development, Application, and Mechanistic Interrogation of a Dual Ni Catalysis Approach to Photoredox-Based C(sp 3 )–C(sp 3 ) Cross-Coupling
inferred← citeshttps://doi.org/10.1021/jacs.5c10963openalex-snapshot
Enantioselective Radical–Radical Cross-Couplings of β-Hydroxy Amides and N-Hydroxyphthalimide Esters via Ni/Photoredox Catalysis
inferred← citeshttps://doi.org/10.1021/jacs.6c05065openalex-snapshot
Quaternary Carbons from Amines and Acids
inferred← citeshttps://doi.org/10.1021/jacs.6c09101openalex-snapshot
Methyl-Selective Radical Sorting for the Regio- and Stereoselective Dialkylation of Activated Alkenes
inferred← citeshttps://doi.org/10.1021/jacsau.5c00884openalex-snapshot
Modular Synthesis of Substituted Lactams via a Deoxygenative Photochemical Alkylation–Cyclization Cascade of Secondary Amides in Flow
inferred← citeshttps://doi.org/10.1021/prechem.5c00388openalex-snapshot
A Dual Photoredox/Cobalt Catalytic System Enables Markovnikov-Selective Hydroaminoalkylation of Alkenes
inferred← citeshttps://doi.org/10.1038/d41586-024-00735-zopenalex-snapshot
Trio of radicals choreographed for versatile chemical reaction
inferred← citeshttps://doi.org/10.1038/s41467-024-52245-1openalex-snapshot
Catalytic undirected methylation of unactivated C(sp3)−H bonds suitable for complex molecules
inferred← citeshttps://doi.org/10.1038/s41467-025-62460-zopenalex-snapshot
Iron-catalyzed alkyne alkylzincation affected by counterions
inferred← citeshttps://doi.org/10.1038/s41467-026-69467-0openalex-snapshot
Formaldehyde hydrazone as a methyl reagent for nickel-catalyzed cross-coupling methylation of aryl and heteroaryl electrophiles
inferred← citeshttps://doi.org/10.1038/s41467-026-70619-5openalex-snapshot
Cross-ketone deacylative coupling via oxidative SH2 homolytic substitution
inferred← citeshttps://doi.org/10.1038/s41586-024-07165-xopenalex-snapshot
Alkene dialkylation by triple radical sorting
inferred← citeshttps://doi.org/10.1038/s41929-024-01192-7openalex-snapshot
Enantioselective alkylation of α-amino C(sp3)−H bonds via photoredox and nickel catalysis
inferred← citeshttps://doi.org/10.1038/s41929-024-01208-2openalex-snapshot
Radical control for enantioselective Csp3–Csp3 cross-coupling
inferred← citeshttps://doi.org/10.1038/s41929-026-01539-2openalex-snapshot
Neutral photogenerated N-centred radicals as a general, catalytic direct hydrogen atom transfer platform for aliphatic C–H functionalization
inferred← citeshttps://doi.org/10.1038/s44160-026-01162-wopenalex-snapshot
Photoelectrochemical C(sp3)–C(sp3) cross-coupling using native functional groups
inferred← citeshttps://doi.org/10.1039/d2cs00960aopenalex-snapshot
The mechanism of visible light-induced C–C cross-coupling by C sp 3 –H bond activation
inferred← citeshttps://doi.org/10.1039/d3ob01920aopenalex-snapshot
Non-enzymatic synthesis of C -methylated fluostatins: discovery and reaction mechanism
inferred← citeshttps://doi.org/10.1039/d3qo00914aopenalex-snapshot
Selective N -α-C–H alkylation of cyclic tertiary amides via visible-light-mediated 1,5-hydrogen atom transfer
inferred← citeshttps://doi.org/10.1039/d3qo01059gopenalex-snapshot
A photocatalytic traceless C–N bond formation/cleavage strategy enabling the use of (α-chiral) alkyl aldehydes as deoxygenative (chiral) alkyl radical equivalents
inferred← citeshttps://doi.org/10.1039/d3qo01231jopenalex-snapshot
Visible-light-induced dehydrogenative β-trifluoromethylthiolation of tertiary amines and direct β-trifluoromethylthiolation of enamides
inferred← citeshttps://doi.org/10.1039/d3sc01945dopenalex-snapshot
Asymmetric imino-acylation of alkenes enabled by HAT-photo/nickel cocatalysis
inferred← citeshttps://doi.org/10.1039/d4gc00848kopenalex-snapshot
Demystifying the recent photochemical and electrochemical strategies in installing the magic methyl group: a comprehensive overview
inferred← citeshttps://doi.org/10.1039/d4ob00213jopenalex-snapshot
Recent advances of decatungstate photocatalyst in HAT process
inferred← citeshttps://doi.org/10.1039/d4qi01039fopenalex-snapshot
Atomically precise nanocluster-catalyzed coupling reactions
inferred← citeshttps://doi.org/10.1039/d4qo00887aopenalex-snapshot
Recent advancements in Ni/photoredox dual catalysis for Csp 3 –Csp 3 cross-coupling reactions
inferred← citeshttps://doi.org/10.1039/d4qo01179aopenalex-snapshot
Visible-light induced direct C(sp 3 )–H functionalization: recent advances and future prospects
inferred← citeshttps://doi.org/10.1039/d4qo02168aopenalex-snapshot
Computational study on Pd-catalyzed ipso , meta -dimethylation of ortho -substituted iodoarenes: mechanisms and the role of the base
inferred← citeshttps://doi.org/10.1039/d5gc05263gopenalex-snapshot
Minute-level alkylation of heteroarenes via a photo-Fenton mechanism in continuous flow
inferred← citeshttps://doi.org/10.1039/d5qo00399gopenalex-snapshot
Beyond HAT: harnessing TBADT for photocatalyzed Giese-type C(sp 3 )–C(sp 3 ) bond formation through reductive decarboxylation
inferred← citeshttps://doi.org/10.1039/d5ra05071eopenalex-snapshot
Tetrabutylammonium decatungstate-catalyzed hydroalkylation/alkoxylation of 3-methyleneisoindolin-1-ones with alcohols/ethers through hydrogen atom transfer process
inferred← citeshttps://doi.org/10.1039/d5sc01006copenalex-snapshot
Visible-light-mediated site-selective C(sp 2 )–H alkylation of tropones facilitates semi-synthesis of cephafortunoids A and B
inferred← citeshttps://doi.org/10.1039/d5sc06966aopenalex-snapshot
Navigating the next frontier in biomedicine: breakthroughs and insights in nucleic acid therapeutics
inferred← citeshttps://doi.org/10.1039/d6ob01155aopenalex-snapshot
Alkyl bromide-promoted photo-methylation of benzaldehydes with DMSO as the methyl source
inferred← citeshttps://doi.org/10.1039/d6qo00813eopenalex-snapshot
Benzophenone-mediated deconstructive cross-coupling of secondary alcohols with data-driven mechanistic insights
inferred← citeshttps://doi.org/10.1055/a-2352-4902openalex-snapshot
A Homolytic Substitution Approach for Directing Group-Free Nickel-Catalyzed Dialkylation of Unactivated Alkenes
inferred← citeshttps://doi.org/10.1055/a-2377-0629openalex-snapshot
Introduction of Fluorinated Groups via Photoredox-Catalyzed C–H Functionalization of (Hetero-)Arenes
inferred← citeshttps://doi.org/10.1055/s-0042-1752436openalex-snapshot
Installation of the Magic Methyl Group onto Heterocycles by Dual Decatungstate Photo-/Nickel Catalysis
inferred← citeshttps://doi.org/10.1055/s-0043-1775377openalex-snapshot
Recent Advances in Saturated N-Heterocycle C–H Bond Functionalization for Alkylated N-Heterocycle Synthesis
inferred← citeshttps://doi.org/10.1126/science.adi4758openalex-snapshot
Aminodealkenylation: Ozonolysis and copper catalysis convert C(sp 3 )–C(sp 2 ) bonds to C(sp 3 )–N bonds
inferred← citeshttps://doi.org/10.26434/chemrxiv-2023-jgr4jopenalex-snapshot
Dewar Pyridines: Conformationally Programmable Piperidine Isosteres
inferred← citeshttps://doi.org/10.3762/bjoc.21.86openalex-snapshot
Salen–scandium(III) complex-catalyzed asymmetric (3 + 2) annulation of aziridines and aldehydes
inferred← citeshttps://doi.org/10.5059/yukigoseikyokaishi.84.804openalex-snapshot
Development of Photo-Driven Dehydrogenative Coupling with H2 Evolution
inferred← citeshttps://doi.org/10.6023/cjoc202406036openalex-snapshot
Selective Functionalization of C(sp3)—H Bonds via Photoredox/ Nickel Dual Catalysis
inferred← citeshttps://doi.org/10.6023/cjoc202503010openalex-snapshot
Recent Advances in Selective C—H Bond Functionalization of Amines Through Hydrogen Atom Transfer (HAT) Process
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