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Photoredox/Nickel Dual-Catalysis-Enabled Regioselective Cyclization of Alkenes with Alkyl Chlorides

https://doi.org/10.2139/ssrn.4662834
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Nickel‐Catalyzed C‐Heteroatom Cross‐Coupling Reactions under Mild Conditions via Facilitated Reductive Elimination
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Divergent Aminocarbonylations of Alkynes Enabled by Photoredox/Nickel Dual Catalysis
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Catalytic Desymmetric Dicarbofunctionalization of Unactivated Alkenes
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Nickel‐Catalyzed Dicarbofunctionalization of Alkenes†
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Photoinduced Regioselective Perfluoroalkylation/Cyclization Cascade of 3‐Aza‐1,5‐Dienes: Access to Pentasubstituted 3‐Perfluoroalkyl‐1,3‐Dihydropyrrol‐2‐Ones
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Visible Light Induced Three‐Component 1,2‐Dicarbofunctionalization of Alkenes and Alkynes
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Visible-light-driven three-component reductive 1,2-diarylation of alkenes
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Developments in Photoredox/Nickel Dual-Catalyzed 1,2-Difunctionalizations
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Synthetic and Mechanistic Implications of Chlorine Photoelimination in Nickel/Photoredox C(sp 3 )–H Cross-Coupling
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Transition Metal (Ni, Cu, Pd)-Catalyzed Alkene Dicarbofunctionalization Reactions
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Visible Light-Induced Transition Metal Catalysis
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Redox Condensations of o-Nitrobenzaldehydes with Amines under Mild Conditions: Total Synthesis of the Vasicinone Family
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Cooperative Photoredox- and Nickel-Catalyzed Alkylative Cyclization Reactions of Alkynes with 4-Alkyl-1,4-dihydropyridines
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Tandem Oxidative Ritter Reaction/Hydration/Aldol Condensation of α-Arylketones with Propiolonitriles for the Construction of 3-Acyl-3-pyrrolin-2-ones
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Copper-Catalyzed Annulation of Oxime Acetates with α-Amino Acid Ester Derivatives: Synthesis of 3-Sulfonamido/Imino 4-Pyrrolin-2-ones
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Synthesis of 3-Alkoxy-4-Pyrrolin-2-ones via Rhodium(II)-Catalyzed Denitrogenative Transannulation of 1H-1,2,3-Triazoles with Diazo Esters
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Nickel-Catalyzed Three-Component Alkylacylation of Alkenes Enabled by a Photoactive Electron Donor–Acceptor Complex
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Dicarbofunctionalizations of an Unactivated Alkene via Photoredox/Nickel Dual Catalysis
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Photoinitiated Cascade for Rapid Access to Pyrroloquinazolinone Core of Vasicinone, Luotonins, and Related Alkaloids
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Stereo- and Enantioselective Benzylic C–H Alkenylation via Photoredox/Nickel Dual Catalysis
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Selective Three-Component Reductive Alkylalkenylation of Unbiased Alkenes via Carbonyl-Directed Nickel Catalysis
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Photoredox Nickel-Catalyzed C–S Cross-Coupling: Mechanism, Kinetics, and Generalization
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Nickel Catalysis via S H 2 Homolytic Substitution: The Double Decarboxylative Cross-Coupling of Aliphatic Acids
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Rapid Access to 2-Substituted Bicyclo[1.1.1]pentanes
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Late-Stage C(sp3)–H Methylation of Drug Molecules
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Dual Nickel/Photoredox-Catalyzed Asymmetric Carbosulfonylation of Alkenes
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Expedient Access to Underexplored Chemical Space: Deoxygenative C(sp 3 )–C(sp 3 ) Cross-Coupling
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Asymmetric [3 + 2] Photocycloaddition of β-Keto Esters and Vinyl Azides by Dual Photoredox/Nickel Catalysis
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Nickel/Photoredox Dual-Catalyzed Regiodivergent Aminoalkylation of Unactivated Alkyl Halides
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Synthetic exploration of sulfinyl radicals using sulfinyl sulfones
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Mechanistic insights into photochemical nickel-catalyzed cross-couplings enabled by energy transfer
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Asymmetric, visible light-mediated radical sulfinyl-Smiles rearrangement to access all-carbon quaternary stereocentres
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Energy-transfer-induced [3+2] cycloadditions of N–N pyridinium ylides
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Radical cascade reactions triggered by single electron transfer
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Catalytic three-component dicarbofunctionalization reactions involving radical capture by nickel
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DFT insight into asymmetric alkyl–alkyl bond formation via nickel-catalysed enantioconvergent reductive coupling of racemic electrophiles with olefins
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Photo/Ni dual-catalyzed radical defluorinative sulfonylation to synthesize gem -difluoro allylsulfones
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Visible light-induced Ni-catalyzed C–heteroatom cross-coupling of aryl halides via LMCT with DBU to access a Ni( i )/Ni( iii ) cycle
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Exploring the regioselectivity of the cyanoalkylation of 3-aza-1,5-dienes: photoinduced synthesis of 3-cyanoalkyl-4-pyrrolin-2-ones
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Three-component reductive conjugate addition/aldol tandem reaction enabled by nickel/photoredox dual catalysis
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Copper-catalyzed [3+2] annulation of O -acyl ketoximes with 2-aryl malonates for the synthesis of 3-aryl-4-pyrrolin-2-ones
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Catalytic asymmetric de novo construction of 4-pyrrolin-2-ones via intermolecular formal [3+2] cycloaddition of azoalkenes with azlactones
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Electrophotocatalytic tri- or difluoromethylative cyclization of alkenes
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Photosensitized, energy transfer-mediated organometallic catalysis through electronically excited nickel(II)
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Recent Advances in Photoredox-Catalyzed Difunctionalization of Alkenes
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Transition-metal-catalyzed domino reactions of strained bicyclic alkenes
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