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Dual Nickel/Photoredox-Catalyzed Asymmetric Carbosulfonylation of Alkenes

https://doi.org/10.1021/jacs.3c00744
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trans‐Selective Aryldifluoroalkylation of Endocyclic Enecarbamates and Enamides by Nickel Catalysis
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Transition‐Metal‐Catalyzed Three‐Component Difunctionalizations of Alkenes
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Chiral Imidazoline Ligands and Their Applications in Metal‐Catalyzed Asymmetric Synthesis†
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Recent Advances in Radical Difunctionalization of Simple Alkenes
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Transition Metal‐Catalyzed Dicarbofunctionalization of Unactivated Olefins
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Recent Advances in the Intermolecular Oxidative Difunctionalization of Alkenes
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Renin Inhibition in Hypertension
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inferredcites →https://doi.org/10.1021/acscatal.5b00072openalex-snapshot
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inferredcites →https://doi.org/10.1021/jacs.1c13482openalex-snapshot
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inferredcites →https://doi.org/10.1021/jacs.2c06636openalex-snapshot
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NiH-catalyzed asymmetric hydroarylation of N-acyl enamines to chiral benzylamines
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Catalytic asymmetric reductive hydroalkylation of enamides and enecarbamates to chiral aliphatic amines
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Enantioselective access to chiral aliphatic amines and alcohols via Ni-catalyzed hydroalkylations
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Catalytic enantioconvergent coupling of secondary and tertiary electrophiles with olefins
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inferredcites →https://doi.org/10.1039/c9cc09866fopenalex-snapshot
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inferredcites →https://doi.org/10.1039/c9cs00681hopenalex-snapshot
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inferredcites →https://doi.org/10.1039/c9sc06006eopenalex-snapshot
Recent developments in nickel-catalyzed intermolecular dicarbofunctionalization of alkenes
inferredcites →https://doi.org/10.1039/d0sc00712aopenalex-snapshot
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inferredcites →https://doi.org/10.1039/d0sc02054kopenalex-snapshot
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inferredcites →https://doi.org/10.1039/d1cs00223fopenalex-snapshot
Electrocatalysis as an enabling technology for organic synthesis
inferredcites →https://doi.org/10.1039/d1cs00399bopenalex-snapshot
Catalytic three-component dicarbofunctionalization reactions involving radical capture by nickel
inferredcites →https://doi.org/10.1055/a-1320-6946openalex-snapshot
Borates as a Traceless Activation Group for Intermolecular Alkylarylation of Ethylene through Photoredox/Nickel Dual Catalysis
inferredcites →https://doi.org/10.1126/science.aaf6123openalex-snapshot
A general alkyl-alkyl cross-coupling enabled by redox-active esters and alkylzinc reagents
inferredcites →https://doi.org/10.3389/fphar.2018.01048openalex-snapshot
Phosphodiesterase-4 Inhibitors for the Treatment of Inflammatory Diseases
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Adamantane in Drug Delivery Systems and Surface Recognition

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Photoredox/Nickel Dual-Catalysis-Enabled Regioselective Cyclization of Alkenes with Alkyl Chlorides
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Electrochemical Three‐Component Reaction to Construct N ‐( α ‐alkoxyalkyl)benzotriazoles
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Recent Advances in Transition‐Metal‐Catalyzed Thiolation and Sulfonylation of Alkenes
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Electron Donor–Acceptor Mediated Hydrosulfonylation of Olefins From N ‐Hydroxymethylphthalimide Sulfones
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Photoinduced Sulfinate‐Mediated Decarboxylative Heteroarylation of α‐Amino Acid Derivatives
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Advancing Sulfono Functionalization: Integrating Classic and Contemporary Approaches to Drive Innovation in Synthetic Chemistry
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Photochemical Oximesulfonylation of Alkenes Using Sulfonyl‐Oxime‐Ethers as Bifunctional Reagents
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Photocatalytic Enantioselective Hydrosulfonylation of α,β‐Unsaturated Carbonyls with Sulfonyl Chlorides
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A General Copper‐Box System for the Asymmetric Arylative Functionalization of Benzylic, Propargylic or Allenylic Radicals
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Photochemical Oximesulfonylation of Alkenes Using Sulfonyl‐Oxime‐Ethers as Bifunctional Reagents
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Photocatalytic Enantioselective Hydrosulfonylation of α,β‐Unsaturated Carbonyls with Sulfonyl Chlorides
inferred← citeshttps://doi.org/10.1002/anie.202411469openalex-snapshot
A General Copper‐Box System for the Asymmetric Arylative Functionalization of Benzylic, Propargylic or Allenylic Radicals
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Recent progress in visible light‐driven halogenation: Chlorination, bromination, and iodination
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Visible‐Light Mediated Nickel‐Catalyzed Asymmetric Difunctionalizations of Alkenes
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Visible‐Light‐Induced Radical Sulfonylative‐Cyclization Cascade of 1,6‐Enynol Derivatives with Sulfinic Acids: A Sustainable Approach for the Synthesis of 2,3‐Disubstituted Benzoheteroles
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Recent Advances in Photochemical Asymmetric Three‐Component Reactions
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SO2-Insertion induced enantioselective oxysulfonylation to access β-chiral sulfones with quaternary carbon stereocenters
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Photoinduced radical sulfur dioxide insertion with asymmetric cyclization of alkenes: accessing β-chiral sulfones bearing S-stereocentric cyclic sulfinamides
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Photochemical difunctionalization of gem-difluoroalkenes with sulfenamides: divergent synthesis of β-difluorosulfenamides and β-difluoroiminothiolates
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Deboronative cross-coupling enabled by nickel metallaphotoredox catalysis
inferred← citeshttps://doi.org/10.1016/j.checat.2023.100819openalex-snapshot
Ni-catalyzed reductive alkylgermylation of activated alkenes: Modular access to polyfunctionalized alkyl germanes
inferred← citeshttps://doi.org/10.1016/j.checat.2024.100915openalex-snapshot
Recent progress in stereoselective transformations enabled by thermally activated delayed fluorescence photocatalysts
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CO2-promoted photoredox-catalyzed cascade cyclization of N-propargylindoles with sulfinates
inferred← citeshttps://doi.org/10.1016/j.gresc.2025.10.002openalex-snapshot
TBADT/nickel co-catalyzed three-component radical acylarylation of alkenes with aldehydes and aryl iodides
inferred← citeshttps://doi.org/10.1016/j.gresc.2025.11.007openalex-snapshot
Visible-light-induced cascade radical sulfonation/annulation/isomerization reactions of propargyl chalcones with sodium sulfinates: Regioselective synthesis of sulfonyl 2H-chromene and 2H-quinoline derivatives
inferred← citeshttps://doi.org/10.1016/j.mcat.2023.113806openalex-snapshot
Photoredox/nickel dual-catalysis-enabled synthesis of N-heterocycles from alkyl chlorides and alkenes
inferred← citeshttps://doi.org/10.1016/j.scib.2023.11.048openalex-snapshot
Photo-induced versatile aliphatic C–H functionalization via electron donor–acceptor complex
inferred← citeshttps://doi.org/10.1016/j.tet.2025.134733openalex-snapshot
Recent advances in photoredox/transition metal-catalyzed sulfonylation using sodium sulfinates
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Sulfonyl radicals generation via β-scission
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Enantioselective multicomponent 1,2-arylaminoalkylation of acrylates by photoredox/nickel dual catalysis
inferred← citeshttps://doi.org/10.1016/s1872-2067(24)60190-7openalex-snapshot
Modular three-component radical fluoroalkyl-sulfuration of unactivated alkenes
inferred← citeshttps://doi.org/10.1021/acs.accounts.4c00638openalex-snapshot
Photocatalysis Meets Copper Catalysis: A New Opportunity for Asymmetric Multicomponent Radical Cross-Coupling Reactions
inferred← citeshttps://doi.org/10.1021/acs.accounts.4c00656openalex-snapshot
Recent Advances in Asymmetric Organometallic Electrochemical Synthesis (AOES)
inferred← citeshttps://doi.org/10.1021/acs.joc.5c02867openalex-snapshot
Visible-Light-Promoted Direct Synthesis of α-Arylthioacetyloximes from Alkenes and Thiophenols
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c00139openalex-snapshot
Photoredox/Nickel Dual Catalysis-Enabled Aryl Formylation with 2,2-Dimethoxy-N,N-dimethylethan-1-amine as CO Source
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Nickel–Photoredox-Catalyzed Stereoconvergent Coupling of Alkenyl Halides and Nitrogen-Containing Heterocycles
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c01258openalex-snapshot
Dual Nickel/Photoredox-Catalyzed Arylsulfonylation of Allenes
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c01380openalex-snapshot
Catalytic Enantioselective Electrophilic Difunctionalization of Unsaturated Sulfones
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c02700openalex-snapshot
Carbosulfonylation of Alkynes: A Direct Conversion of sp-C to sp 3 -C through Visible Light-Mediated 3-Component Reaction
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Visible-Light-Mediated Ni-Catalyzed Gas-Free Carboxylation: Stereodivergent Synthesis of E- and Z-Acrylic Acids
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Catalyst-Free Radical Carbosulfonylation of Enamides with Indoles, Aryldiazonium Tetrafluoroborates, and DABCO·(SO2)2
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Enantioselective Synthesis of Benzylic Boronic Esters via Photoredox/Nickel-Catalyzed Multicomponent Cross-Couplings
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Modular Access to Chiral Benzylamines via Ni/Photoredox-Catalyzed Multicomponent Cross-Electrophile Coupling
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c00237openalex-snapshot
Enantioselective Photoredox- and Cu-Catalyzed Cyanoalkylation of Styrenes via Deoxygenation of Alkoxyl Radicals with Organophosphorus Compounds(III)
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c01171openalex-snapshot
Iron-Catalyzed Alkylative Aminosulfonylation of Alkenes and Alkynes via Radical-Anion Relay
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c01230openalex-snapshot
Nickel/Photoredox Dual-Catalyzed, Regioselective 1,2-Carboacylation of Alkenes via Synergistic Alkyl and Benzoyl Radical Coupling
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Dual-Co/Ni-Catalyzed Radical Hydroarylation of 1,3-Enynes: Selective Access to Tetrasubstituted Allenes
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c04202openalex-snapshot
Regioselective Markovnikov Hydroalkylation of Unactivated Alkenes Enabled by Photoredox/Nickel Dual Catalysis
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Three-Component Carbosulfonylation of Alkenes via Single-Atom Nickel Photocatalysis
inferred← citeshttps://doi.org/10.1021/acs.orglett.6c02021openalex-snapshot
Dual Nickel/Photoredox-Catalyzed Radical Phosphonylacylation of Terminal Alkenes with Aroyl Chlorides and H -Phosphine Oxides
inferred← citeshttps://doi.org/10.1021/acs.orglett.6c02471openalex-snapshot
Photoinduced Alkene Carbothiolation via Fe/Ni Dual Catalysis
inferred← citeshttps://doi.org/10.1021/acscatal.4c04277openalex-snapshot
Artificial Intelligence-Driven Development of Nickel-Catalyzed Enantioselective Cross-Coupling Reactions
inferred← citeshttps://doi.org/10.1021/acscatal.5c00858openalex-snapshot
Photoredox-Neutral Ni-Catalyzed Decarboxylative Fluoroalkylation via Radical Sorting Cross-Coupling
inferred← citeshttps://doi.org/10.1021/acscatal.5c01514openalex-snapshot
Nickel-Catalyzed Enantioselective Three-Component 1,2-Alkylarylation of Alkenes with Arylboronic Acids as Arylation Reagents
inferred← citeshttps://doi.org/10.1021/acscatal.5c07508openalex-snapshot
In Situ Generated Triazine Co-Catalyst Unlocks Amidine Arylation under Dual Nickel/Photoredox Catalysis: A Platform for Mild C–N Bond Formation
inferred← citeshttps://doi.org/10.1021/jacs.3c07919openalex-snapshot
NiH-Catalyzed Regio- and Enantioselective Hydroalkylation for the Synthesis of β- or γ‑Branched Chiral Aromatic N‑Heterocycles
inferred← citeshttps://doi.org/10.1021/jacs.3c10109openalex-snapshot
Enantioselective Reductive Cross-Couplings of Olefins by Merging Electrochemistry with Nickel Catalysis
inferred← citeshttps://doi.org/10.1021/jacs.4c13682openalex-snapshot
General Alkene 1,2-syn-Cyano-Hydroxylation Procedure Via Electrochemical Activation of Isoxazoline Cycloadducts
inferred← citeshttps://doi.org/10.1021/jacs.5c15392openalex-snapshot
Enantioselective Radical Sulfonylation of 2-Naphthols and β-Ketoamides with Sodium Sulfinates
inferred← citeshttps://doi.org/10.1021/jacs.6c05474openalex-snapshot
Asymmetric Radical Allylic Cyanation of Electron-Deficient Alkenes with a Low Copper Catalyst Loading: Development and Mechanism
inferred← citeshttps://doi.org/10.1021/jacs.6c15694openalex-snapshot
Enantioselective Cross-Coupling of an Unbiased Carbon Radical Enabled by Perfluoroaryl Semicorrin Ligands
inferred← citeshttps://doi.org/10.1021/jacs.6c15886openalex-snapshot
Regio- and Enantioselective Functionalization of Gaseous Alkanes via Nickel-Catalyzed Alkene Dicarbofunctionalization
inferred← citeshttps://doi.org/10.1021/jacsau.6c00241openalex-snapshot
Remote 1,5-Difunctionalization of Alkenes via a Sulfinyl-Smiles Rearrangement and Vinylcyclopropane Ring-Opening Cascade
inferred← citeshttps://doi.org/10.1038/s41467-023-43748-4openalex-snapshot
Nickel/photoredox dual catalyzed arylalkylation of nonactivated alkenes
inferred← citeshttps://doi.org/10.1038/s41467-024-46713-xopenalex-snapshot
Ni-catalyzed enantioconvergent deoxygenative reductive cross-coupling of unactivated alkyl alcohols and aryl bromides
inferred← citeshttps://doi.org/10.1038/s41467-024-49514-4openalex-snapshot
Red-light-mediated copper-catalyzed photoredox catalysis promotes regioselectivity switch in the difunctionalization of alkenes
inferred← citeshttps://doi.org/10.1038/s41467-024-54597-0openalex-snapshot
Enantioselective construction of C-B axially chiral alkenylborons by nickel-catalyzed radical relayed reductive coupling
inferred← citeshttps://doi.org/10.1038/s41467-025-56377-wopenalex-snapshot
Enantioselective reductive cross-couplings to forge C(sp2)–C(sp3) bonds by merging electrochemistry with nickel catalysis
inferred← citeshttps://doi.org/10.1038/s41467-025-58438-6openalex-snapshot
Nickel catalyzed C-N coupling of haloarenes with B2N4 reagents
inferred← citeshttps://doi.org/10.1038/s41467-025-61363-3openalex-snapshot
Vinyl cyclopropanes as a unifying platform for enantioselective remote difunctionalization of alkenes
inferred← citeshttps://doi.org/10.1038/s41467-026-69838-7openalex-snapshot
Stereoselective vicinal C(sp³)–C bond formation via metallaphotoredox 1,2-difunctionalization of internal alkenes
inferred← citeshttps://doi.org/10.1038/s41557-025-01775-2openalex-snapshot
Biomimetic 1,2-amino migration via photoredox catalysis
inferred← citeshttps://doi.org/10.1038/s41929-024-01153-0openalex-snapshot
Nickel-catalysed enantioselective alkene dicarbofunctionalization enabled by photochemical aliphatic C–H bond activation
inferred← citeshttps://doi.org/10.1039/d3sc05700copenalex-snapshot
Strain-enabled radical spirocyclization cascades: rapid access to spirocyclobutyl lactones and – lactams
inferred← citeshttps://doi.org/10.1039/d4cc00802bopenalex-snapshot
Enantioselective sulfonylation to construct 3-sulfonylated oxindoles
inferred← citeshttps://doi.org/10.1039/d4cc02914copenalex-snapshot
Recent advances in dual photoredox/nickel catalyzed alkene carbofunctionalised reactions
inferred← citeshttps://doi.org/10.1039/d4dt02567aopenalex-snapshot
Theoretical study on the concerted catalysis of Ir/Ni for amino radical transfer for C(sp 2 )–C(sp 3 ) bond formation
inferred← citeshttps://doi.org/10.1039/d4ob00060aopenalex-snapshot
A visible-light-catalyzed sulfonylation reaction of an aryl selenonium salt via an electron donor–acceptor complex
inferred← citeshttps://doi.org/10.1039/d4sc04561kopenalex-snapshot
Ni-catalyzed enantioselective three-component reductive alkylacylation of alkenes: modular access to structurally complex α-amino ketones
inferred← citeshttps://doi.org/10.1039/d4sc07728hopenalex-snapshot
Ni-catalyzed regioselective and site-divergent reductive arylalkylations of allylic amines
inferred← citeshttps://doi.org/10.1039/d5cc06209hopenalex-snapshot
1,4-Difunctionalization of 1,3-enynes: new opportunities for the synthesis of allenes via photochemistry and electrochemistry
inferred← citeshttps://doi.org/10.1039/d5cs00670hopenalex-snapshot
Intermolecular 1,2-difunctionalization of alkenes
inferred← citeshttps://doi.org/10.1039/d5np00030kopenalex-snapshot
Photo-/electro-chemical catalysis: a promising toolkit for late-stage functionalization of alkene-containing natural products
inferred← citeshttps://doi.org/10.1039/d5ob00402kopenalex-snapshot
Construction of multi-functionalized carbon chains by Ni-catalyzed carbosulfonylation of butadiene
inferred← citeshttps://doi.org/10.1039/d5ob01229eopenalex-snapshot
Photochemical carbosulfonylative cross-coupling of alkenes
inferred← citeshttps://doi.org/10.1039/d5ob01408eopenalex-snapshot
Palladium-catalyzed asymmetric propargylic sulfonylation of propargyl esters with sulfonyl hydrazides
inferred← citeshttps://doi.org/10.1039/d5qo00214aopenalex-snapshot
Radical-mediated sulfonylation relay of alkyl alkynes/alkenes and electron-deficient alkenes to access vinyl and alkyl sulfones
inferred← citeshttps://doi.org/10.1039/d5qo00888copenalex-snapshot
Inorganic reagents in photochemical reactions
inferred← citeshttps://doi.org/10.1039/d6sc00382fopenalex-snapshot
Photocatalytic multicomponent alkene dicarbofunctionalization via PCET/nickel dual catalysis
inferred← citeshttps://doi.org/10.1055/a-2875-7326openalex-snapshot
Synthesis of Enol Ethers by Coupling Reaction of Alkenyl Halides with Alcohols
inferred← citeshttps://doi.org/10.1055/s-0043-1773495openalex-snapshot
Coupling Reaction of Aryl Halides with Orthoformate Ester
inferred← citeshttps://doi.org/10.1093/chemle/upae088openalex-snapshot
Ni-photoredox-catalyzed amide arylation reaction using amidyl radical formation via PCET
inferred← citeshttps://doi.org/10.1093/chemle/upae111openalex-snapshot
Nickel-photoredox-catalyzed E - and Z -stereoconvergent coupling of alkenyl halides and phenols
inferred← citeshttps://doi.org/10.20517/cs.2024.140openalex-snapshot
Three-component cross-coupling reactions involving alkenes enabled by visible-light and earth-abundant-metal-catalysis
inferred← citeshttps://doi.org/10.2139/ssrn.7197009openalex-snapshot
Stepwise Control of Regio- and Enantioselectivity in RhIII-Catalyzed Carboamination of (Homo)allylic Sulfides: A DFT Decoding of the Chiral CpX Ligand’s Role
inferred← citeshttps://doi.org/10.26434/chemrxiv-2024-f1rrcopenalex-snapshot
A General Copper-Box System for the Asymmetric Ary-lative Functionalization of Benzylic, Propargylic or Allenylic Radicals
inferred← citeshttps://doi.org/10.26434/chemrxiv-2024-rf0jnopenalex-snapshot
Ni-Catalyzed Enantioselective Three-Component Reductive Alkylacylation of Enamides
inferred← citeshttps://doi.org/10.3389/fchem.2024.1398397openalex-snapshot
Recent advances in catalytic asymmetric synthesis
inferred← citeshttps://doi.org/10.3390/catal16030284openalex-snapshot
The Merger of Transition Metal and Photocatalysis: Recent Advances and Prospects in Asymmetric Intermolecular 1,2-Difunctionalization of Alkenes
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