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Direct Catalytic Desaturation of Lactams Enabled by Soft Enolization

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Chiral Nanoparticles/Lewis Acids as Cooperative Catalysts for Asymmetric 1,4‐Addition of Arylboronic Acids to α,β‐Unsaturated Amides

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Chemical Assembly Systems: Layered Control for Divergent, Continuous, Multistep Syntheses of Active Pharmaceutical Ingredients

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Chiral Nanoparticles/Lewis Acids as Cooperative Catalysts for Asymmetric 1,4‐Addition of Arylboronic Acids to α,β‐Unsaturated Amides

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Palladium(II)‐Catalyzed Dehydroboration via Generation of Boron Enolates

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Hydroxylation of substituted diatomic phenols and their derivatives

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7.06 Oxidation Adjacent to CX Bonds by Dehydrogenation

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One-pot dehydrogenation of carboxylic acid derivatives to α,β-unsaturated carbonyl compounds under mild conditions

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Catalytic CC bond forming transformations via direct β-CH functionalization of carbonyl compounds

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Verbesserte variante der knoevenagel-kondensation mit TiCl4/THF/pyridin(I). Alkyliden- und Arylidenmalonester bei 0–25°C.

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Palladium-Catalyzed Aerobic Dehydrogenation of Cyclic Hydrocarbons for the Synthesis of Substituted Aromatics and Other Unsaturated Products

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Boron Enolate Chemistry

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Rhodium-Catalyzed Asymmetric 1,4-Addition and Its Related Asymmetric Reactions

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Silylation-mediated oxidation of 4-aza-3-ketosteroids with DDQ proceeds via DDQ-substrate adducts

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Enantioselective aldol condensations. 2. Erythro-selective chiral aldol condensations via boron enolates

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New synthetic reactions. Sulfenylations and dehydrosulfenylations of esters and ketones

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Electrophilic and nucleophilic organoselenium reagents. New routes to .alpha.,.beta.-unsaturated carbonyl compounds

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Some Reactions of N-Acetylphthalimides

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Catalytic Four-Component Assembly Based on Allenylboronate Platform: New Access to Privileged Allylic Amine Structures

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Aerobic Dehydrogenation of Cyclohexanone to Cyclohexenone Catalyzed by Pd(DMSO) 2 (TFA) 2 : Evidence for Ligand-Controlled Chemoselectivity

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Catalytic Direct β-Arylation of Simple Ketones with Aryl Iodides

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Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl- and Alkenylboronic Acids to Enones

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Palladium-Catalyzed α,β-Dehydrogenation of Esters and Nitriles

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Amide α,β-Dehydrogenation Using Allyl-Palladium Catalysis and a Hindered Monodentate Anilide

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Frustrated Lewis Acid/Brønsted Base Catalysts for Direct Enantioselective α-Amination of Carbonyl Compounds

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Structure-activity relationship of quinazolinedione inhibitors of calcium-independent phosphodiesterase

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Iodotrimethylsilane-mediated 2-monohalogenation of 4-aza-5.alpha.-androstan-3-one steroids

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Synthesis of .alpha.,.beta.-unsaturated carbonyl compounds by palladium(II)-catalyzed dehydrosilylation of silyl enol ethers

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Preparation of .alpha.,.beta.-unsaturated carbonyl compunds

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Rhodium-Catalyzed Asymmetric 1,4-Addition of Organoboron Reagents to 5,6-Dihydro-2(1H)-pyridinones. Asymmetric Synthesis of 4-Aryl-2-piperidinones

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Synthesis of 4-Aryl-2-pyrrolidones and β-Aryl-γ-amino-butyric Acid (GABA) Analogues by Heck Arylation of 3-Pyrrolines with Arenediazonium Tetrafluoroborates. Synthesis of (±)-Rolipram on a Multigram Scale and Chromatographic Resolution by Semipreparative Chiral Simulated Moving Bed Chromatography

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Copper-Catalyzed Asymmetric Conjugate Addition of Alkenyl- and Alkylalanes to α,β-Unsaturated Lactams

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Multistep continuous-flow synthesis of (R)- and (S)-rolipram using heterogeneous catalysts

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Tau-driven 26S proteasome impairment and cognitive dysfunction can be prevented early in disease by activating cAMP-PKA signaling

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Unprecedented copper-catalyzed asymmetric conjugate addition of organometallic reagents to α,β-unsaturated lactams

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Direct aerobic α,β-dehydrogenation of aldehydes and ketones with a Pd(TFA) 2 /4,5-diazafluorenone catalyst

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Biologically active γ-lactams: synthesis and natural sources

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Synthesis of the Novel Antidepressant (R)-(-)-Rolipram

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NEW CROSS-ALDOL REACTION Via VINYLOXYBORANES

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Direct Dehydrogenation for the Synthesis of α,β‐Unsaturated Carbonyl Compounds

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Recent Advances for the Desaturation of Amides

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Platinum‐Catalyzed Desaturation of Lactams, Ketones, and Lactones

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Platinum‐Catalyzed α,β‐Desaturation of Cyclic Ketones through Direct Metal–Enolate Formation

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1,2‐Aryl Migration Induced by Amide C−N Bond‐Formation: Reaction of Alkyl Aryl Ketones with Primary Amines Towards α,α‐Diaryl β,γ‐Unsaturated γ‐Lactams

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Palladium‐Catalyzed Cascade Carbonylation to α,β‐Unsaturated Piperidones via Selective Cleavage of Carbon–Carbon Triple Bonds

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Accessing Z‐Enynes via Cobalt‐Catalyzed Propargylic Dehydrogenation

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EDA Complex‐Driven Desaturation of Heterocyclic Carbonyl Compounds Enabled by HFIP

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Direct Palladium‐Catalyzed β‐Arylation of Lactams

inferred← citeshttps://doi.org/10.1002/anie.201808794openalex-snapshot

Chemoselective α,β‐Dehydrogenation of Saturated Amides

inferred← citeshttps://doi.org/10.1002/anie.201811197openalex-snapshot

Platinum‐Catalyzed Desaturation of Lactams, Ketones, and Lactones

inferred← citeshttps://doi.org/10.1002/anie.201907523openalex-snapshot

Enantioselective Total Syntheses of Pallambins A–D

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Enantioselective Total Synthesis and Absolute Configuration Assignment of (+)‐Tronocarpine Enabled by an Asymmetric Michael/Aldol Reaction

inferred← citeshttps://doi.org/10.1002/anie.202008242openalex-snapshot

A Divergent Enantioselective Total Synthesis of Post‐Iboga Indole Alkaloids

inferred← citeshttps://doi.org/10.1002/anie.202013628openalex-snapshot

Platinum‐Catalyzed α,β‐Desaturation of Cyclic Ketones through Direct Metal–Enolate Formation

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1,2‐Aryl Migration Induced by Amide C−N Bond‐Formation: Reaction of Alkyl Aryl Ketones with Primary Amines Towards α,α‐Diaryl β,γ‐Unsaturated γ‐Lactams

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Palladium‐Catalyzed Cascade Carbonylation to α,β‐Unsaturated Piperidones via Selective Cleavage of Carbon–Carbon Triple Bonds

inferred← citeshttps://doi.org/10.1002/anie.202402638openalex-snapshot

Accessing Z‐Enynes via Cobalt‐Catalyzed Propargylic Dehydrogenation

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EDA Complex‐Driven Desaturation of Heterocyclic Carbonyl Compounds Enabled by HFIP

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Transition‐Metal‐Free Multiple Functionalization of Piperidines to 4‐Substituted and 3,4‐Disubstituted 2‐Piperidinones

inferred← citeshttps://doi.org/10.1002/cjoc.202100001openalex-snapshot

Protecting‐Group‐Free Total Synthesis of (–)‐Pallambins A—D

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Transition‐Metal‐Catalyzed α,β‐Dehydrogenation of Carbonyl Compounds

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Oxidative Dehydrogenation of Alkanes through Homogeneous Base Metal Catalysis

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Reactions of 3-pyrrolin-2-ones

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Palladium-catalyzed α,β-dehydrogenation of acyclic ester equivalents promoted by a novel electron deficient phosphinooxazoline ligand

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Dehydrogenative Pd and Ni Catalysis for Total Synthesis

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Manganese(I) Catalyzed α-Alkenylation of Amides Using Alcohols with Liberation of Hydrogen and Water

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Comprehensive Mechanistic Analysis of Palladium- and Nickel-Catalyzed α,β-Dehydrogenation of Carbonyls via Organozinc Intermediates

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Chemoselective Dehydrogenation and Hetero-Arylation of Amides via Radical Translocation Enabled by Photoexcited Triplet Ketone Catalysis

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Dehydrogenation of Aromatic Alcohols, Aldehydes, and Ketones Catalyzed by Cu(I) Complexes

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Iodine-Catalyzed Carbonyl Desaturation: A One-Pot Synthesis of Flavones

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Radical α,β-Dehydrogenation of Saturated Amides via α-Oxidation with TEMPO under Transition Metal-Free Conditions

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Photoinduced Desaturation of Amides by Palladium Catalysis

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Iron-Catalyzed Aerobic α,β-Dehydrogenation

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Synthesis of Dienamides via Palladium-catalyzed Oxidative N-α,β-Dehydrogenation of Amides

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Copper-Catalyzed Dehydrogenative Diels–Alder Reaction

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Catalytic β-Functionalization of Carbonyl Compounds Enabled by α,β-Desaturation

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Carbonyl Desaturation: Where Does Catalysis Stand?

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Iridium-Catalyzed Oxidant-Free Transfer Dehydrogenation of Carboxylic Acids

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Selective Synthesis of Primary Anilines from Cyclohexanone Oximes by the Concerted Catalysis of a Mg–Al Layered Double Hydroxide Supported Pd Catalyst

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Chemoselective Intermolecular Cross-Enolate-Type Coupling of Amides

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General, Mild, and Selective Method for Desaturation of Aliphatic Amines

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Palladium-Catalyzed Enantioselective Relay Heck Arylation of Enelactams: Accessing α,β-Unsaturated δ-Lactams

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Direct β-Alkylation of Ketones and Aldehydes via Pd-Catalyzed Redox Cascade

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Allyl-Nickel Catalysis Enables Carbonyl Dehydrogenation and Oxidative Cycloalkenylation of Ketones

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Copper-Catalyzed Desaturation of Lactones, Lactams, and Ketones under pH-Neutral Conditions

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Site-Selective Benzylic Dehydrogenation of Alkylindoles

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Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates

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Differentiation between enamines and tautomerizable imines in the oxidation reaction with TEMPO

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Copper-catalyzed dehydrogenative γ-C(sp3)-H amination of saturated ketones for synthesis of polysubstituted anilines

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A facile synthesis of α,β-unsaturated imines via palladium-catalyzed dehydrogenation

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Tandem dehydrogenation-olefination-decarboxylation of cycloalkyl carboxylic acids via multifold C–H activation

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Electrochemically driven desaturation of carbonyl compounds

inferred← citeshttps://doi.org/10.1039/c9sc05970aopenalex-snapshot

A borane-mediated palladium-catalyzed reductive allylic alkylation of α,β-unsaturated carbonyl compounds

inferred← citeshttps://doi.org/10.1039/d0dt04311gopenalex-snapshot

Unexpected binuclear O–O cleavage and radical C–H activation mechanism for Cu-catalyzed desaturation of lactone

inferred← citeshttps://doi.org/10.1039/d2sc02210aopenalex-snapshot

Selective desaturation of amides: a direct approach to enamides

inferred← citeshttps://doi.org/10.1039/d2sc02291eopenalex-snapshot

Cobalt-catalyzed chemoselective dehydrogenation through radical translocation under visible light

inferred← citeshttps://doi.org/10.1039/d2sc05370eopenalex-snapshot

Multiple remote C(sp 3 )–H functionalizations of aliphatic ketones via bimetallic Cu–Pd catalyzed successive dehydrogenation

inferred← citeshttps://doi.org/10.1039/d3cc01960hopenalex-snapshot

Direct synthesis of alkylated 4-hydroxycoumarin derivatives via a cascade Cu-catalyzed dehydrogenation/conjugate addition sequence

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Pd( ii )-Catalyzed tandem selective dehydrogenative [4+2] annulation of 2-methyl-1,3-cycloalkanediones with olefins

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Straightforward α-allylation of carbonyl compounds with alkenes via α-carbonyl radical intermediates

inferred← citeshttps://doi.org/10.1039/d4cc02609hopenalex-snapshot

Versatile dehydrogenation of carbonyls enabled by an iodine( iii ) reagent

inferred← citeshttps://doi.org/10.1039/d4sc04419copenalex-snapshot

Catalytic dehydrogenative synthesis of α,β-unsaturated secondary amides without external oxidants

inferred← citeshttps://doi.org/10.1039/d6ob00514dopenalex-snapshot

Base-promoted synthesis of α,β-unsaturated amides via C–N bond formation using α,β-unsaturated acids and isothiocyanates

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A Photochemical Strategy for the Synthesis of Caprolactams via Dearomative Ring Expansion of Nitroarenes

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47.1.4.11 Synthesis of Alkenes by α,β-Dehydrogenation

inferred← citeshttps://doi.org/10.1126/science.abl3939openalex-snapshot

Ligand-controlled divergent dehydrogenative reactions of carboxylic acids via C–H activation

inferred← citeshttps://doi.org/10.15227/orgsyn.098.0194openalex-snapshot

Enantioselective Michael-Proton Transfer-Lactamization for Pyroglutamic Acid Derivatives: Synthesis of Dimethyl-(S,E)-5-oxo-3-styryl-1-tosylpyrrolidine-2,2-dicarboxylate

inferred← citeshttps://doi.org/10.21203/rs.3.rs-3260796/v1openalex-snapshot

Hydrogen Atom Transfer (HAT)-Mediated Remote Desaturation Enabled by Fe/Cr-H Cooperative Catalysis

inferred← citeshttps://doi.org/10.26434/chemrxiv-2022-0t55gopenalex-snapshot

A Comparative Mechanistic Analysis of Palladium- and Nickel-Catalyzed α,β-Dehydrogenation of Carbonyls via Organozinc Intermediates

inferred← citeshttps://doi.org/10.26434/chemrxiv-2022-0t55g-v2openalex-snapshot

A Comprehensive Mechanistic Analysis of Palladium- and Nickel-Catalyzed α,β-Dehydrogenation of Carbonyls via Organozinc Intermediates

inferred← citeshttps://doi.org/10.5757/asct.2022.31.3.63openalex-snapshot

Recent Advances in the Low-Temperature Chemical Vapor Deposition Growth of Graphene

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