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Origin of and a Solution for Uneven Efficiency by Cinchona Alkaloid-Derived, Pseudoenantiomeric Catalysts for Asymmetric Reactions

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/adsc.201100447openalex-snapshot

Cinchona Alkaloid‐Catalyzed Enantioselective Amination of α,β‐Unsaturated Ketones: An Asymmetric Approach to Δ2‐Pyrazolines

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In the Golden Age of Organocatalysis

inferredcites →https://doi.org/10.1002/anie.201105536openalex-snapshot

Structural Study‐Guided Development of Versatile Phase‐Transfer Catalysts for Asymmetric Conjugate Additions of Cyanide

inferredcites →https://doi.org/10.1002/anie.201109036openalex-snapshot

Cinchona‐based Primary Amine Catalysis in the Asymmetric Functionalization of Carbonyl Compounds

inferredcites →https://doi.org/10.1002/anie.201206835openalex-snapshot

Recent Developments in Asymmetric Phase‐Transfer Reactions

inferredcites →https://doi.org/10.1002/anie.201710915openalex-snapshot

Catalytic Asymmetric Synthesis of Trifluoromethylated γ‐Amino Acids through the Umpolung Addition of Trifluoromethyl Imines to Carboxylic Acid Derivatives

inferredcites →https://doi.org/10.1002/chem.200600993openalex-snapshot

Highly Enantioselective Epoxidation of 2‐Methylnaphthoquinone (Vitamin K3) Mediated by New Cinchona Alkaloid Phase‐Transfer Catalysts

inferredcites →https://doi.org/10.1002/chem.201601917openalex-snapshot

Synthetic and Organocatalytic Studies of Quinidine Analogues with Ring‐Size Modifications in the Quinuclidine Moiety

inferredcites →https://doi.org/10.1002/hlca.19850680329openalex-snapshot

Isomérisation cis‐trans en Série Alkyl‐4‐vinyl‐3‐pipéridine par Sigmatropie [3.3]. Synthèse des Epivinyl Isomères des Alcaloïdes du Quinquina

inferredcites →https://doi.org/10.1016/j.tetasy.2010.04.046openalex-snapshot

Synthesis of quinine and quinidine using sulfur ylide-mediated asymmetric epoxidation as a key step

inferredcites →https://doi.org/10.1016/j.tetlet.2004.03.085openalex-snapshot

Stereocontrolled synthesis of quinine and quinidine

inferredcites →https://doi.org/10.1016/s0040-4039(97)10293-3openalex-snapshot

A new class of asymmetric phase-transfer catalysts derived from Cinchona alkaloids — Application in the enantioselective synthesis of α-amino acids

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Contemporary Asymmetric Phase Transfer Catalysis: Large-Scale Industrial Applications

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Enantioselective α-Benzoyloxylation of Malonic Diesters by Phase-Transfer Catalysis

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Virtual Issue Posts on Organocatalysis: Design, Applications, and Diversity

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Cinchona-Based Primary Amine Catalyzed a Proximal Functionalization of Dienamines: Asymmetric α-Fluorination of α-Branched Enals

inferredcites →https://doi.org/10.1021/ar030048sopenalex-snapshot

Asymmetric Organic Catalysis with Modified Cinchona Alkaloids

inferredcites →https://doi.org/10.1021/ar0300625openalex-snapshot

The Enantioselective Synthesis of α-Amino Acids by Phase-Transfer Catalysis with Achiral Schiff Base Esters

inferredcites →https://doi.org/10.1021/cs200304gopenalex-snapshot

Asymmetric Alkylation of Malonic Diester Under Phase-Transfer Conditions

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A Highly Enantioselective Catalytic Desymmetrization of Cyclic Anhydrides with Modified Cinchona Alkaloids

inferredcites →https://doi.org/10.1021/ja00188a089openalex-snapshot

The stereoselective synthesis of .alpha.-amino acids by phase-transfer catalysis

inferredcites →https://doi.org/10.1021/ja039550yopenalex-snapshot

Catalytic Asymmetric Total Syntheses of Quinine and Quinidine

inferredcites →https://doi.org/10.1021/ja067289qopenalex-snapshot

Organocatalytic Asymmetric Direct α-Alkynylation of Cyclic β-Ketoesters

inferredcites →https://doi.org/10.1021/ja0707097openalex-snapshot

Organocatalytic Asymmetric 1,6-Additions of β-Ketoesters and Glycine Imine

inferredcites →https://doi.org/10.1021/ja071509yopenalex-snapshot

Cinchona Alkaloid-Catalyzed Enantioselective Monofluoromethylation Reaction Based on Fluorobis(phenylsulfonyl)methane Chemistry Combined with a Mannich-type Reaction

inferredcites →https://doi.org/10.1021/ja100173wopenalex-snapshot

Enantioselective Bromolactonization of Conjugated (Z)-Enynes

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Asymmetric Synthesis of Trifluoromethylated Amines via Catalytic Enantioselective Isomerization of Imines

inferredcites →https://doi.org/10.1021/ja402058vopenalex-snapshot

The Cinchona Primary Amine-Catalyzed Asymmetric Epoxidation and Hydroperoxidation of α,β-Unsaturated Carbonyl Compounds with Hydrogen Peroxide

inferredcites →https://doi.org/10.1021/ja9100276openalex-snapshot

Practical and Highly Selective Sulfur Ylide Mediated Asymmetric Epoxidations and Aziridinations Using an Inexpensive, Readily Available Chiral Sulfide. Applications to the Synthesis of Quinine and Quinidine

inferredcites →https://doi.org/10.1021/ja973174yopenalex-snapshot

A Rational Approach to Catalytic Enantioselective Enolate Alkylation Using a Structurally Rigidified and Defined Chiral Quaternary Ammonium Salt under Phase Transfer Conditions

inferredcites →https://doi.org/10.1021/ja9835739openalex-snapshot

Highly Enantioselective Phase Transfer Catalyzed Alkylation of a 3-Oxygenated Propionic Ester Equivalent; Applications and Mechanism

inferredcites →https://doi.org/10.1021/jacs.5b03243openalex-snapshot

Photo-organocatalytic Enantioselective Perfluoroalkylation of β-Ketoesters

inferredcites →https://doi.org/10.1021/jacs.6b07229openalex-snapshot

Enantioselective Total Synthesis of (+)-Psiguadial B

inferredcites →https://doi.org/10.1021/jacs.6b08727openalex-snapshot

Cinchonium Betaines as Efficient Catalysts for Asymmetric Proton Transfer Catalysis: The Development of a Practical Enantioselective Isomerization of Trifluoromethyl Imines

inferredcites →https://doi.org/10.1021/jacs.6b09754openalex-snapshot

Catalytic Asymmetric Synthesis of Chiral γ-Amino Ketones via Umpolung Reactions of Imines

inferredcites →https://doi.org/10.1021/jo2011522openalex-snapshot

Asymmetric Organocatalytic Allylic Substitution of Morita–Baylis–Hillman Carbonates with Allylamines for the Synthesis of 2,5-Dihydropyrroles

inferredcites →https://doi.org/10.1021/jo401585vopenalex-snapshot

Cinchona Alkaloid Squaramide Catalyzed Enantioselective Hydrazination/Cyclization Cascade Reaction of α-Isocyanoacetates and Azodicarboxylates: Synthesis of Optically Active 1,2,4-Triazolines

inferredcites →https://doi.org/10.1021/ol050275popenalex-snapshot

Catalytic Enantioselective Sulfinyl Transfer Using Cinchona Alkaloid Catalysts

inferredcites →https://doi.org/10.1021/ol061524sopenalex-snapshot

Synthetic Studies on Quinine: Quinuclidine Construction via a Ketone Enolate Regio- and Diastereoselective Pd-Mediated Allylic Alkylation

inferredcites →https://doi.org/10.1021/ol203170xopenalex-snapshot

Highly Enantioselective Nitro-Mannich Reaction Catalyzed by Cinchona Alkaloids and N-Benzotriazole Derived Ammonium Salts

inferredcites →https://doi.org/10.1021/ol503264nopenalex-snapshot

Asymmetric Phase-Transfer Catalysts Bearing Multiple Hydrogen-Bonding Donors: Highly Efficient Catalysts for Enantio- and Diastereoselective Nitro-Mannich Reaction of Amidosulfones

inferredcites →https://doi.org/10.1021/ol701791ropenalex-snapshot

Cinchona Alkaloids/TMAF Combination-Catalyzed Nucleophilic Enantioselective Trifluoromethylation of Aryl Ketones

inferredcites →https://doi.org/10.1038/nature14617openalex-snapshot

Catalytic asymmetric umpolung reactions of imines

inferredcites →https://doi.org/10.1039/b914028jopenalex-snapshot

Cinchona-based phase-transfer catalysts for asymmetric synthesis

inferredcites →https://doi.org/10.1039/c1ob06319gopenalex-snapshot

Enantioselective synthesis of α-deuterium labelled chiral α-amino acids via dynamic kinetic resolution of racemic azlactones

inferredcites →https://doi.org/10.1039/c2cs35380fopenalex-snapshot

Applications of asymmetric organocatalysis in medicinal chemistry

inferredcites →https://doi.org/10.1055/s-0029-1218699openalex-snapshot

Cinchona Alkaloids in Asymmetric Organocatalysis

inferredcites →https://doi.org/10.1073/pnas.1718474115openalex-snapshot

Control of chemoselectivity in asymmetric tandem reactions: Direct synthesis of chiral amines bearing nonadjacent stereocenters

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Asymmetric Phase‐Transfer Catalysis – From Classical Applications to New Concepts

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Mechanistic Insights into Annulation of Arylidene‐Δ2‐Pyrrolin‐4‐Ones by Cinchona Squaramide‐Based Organocatalysts

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Tertiary Amides as Directing Groups for Enantioselective C−H Amination using Ion‐Paired Rhodium Complexes

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A Unified Catalytic Asymmetric (4+1) and (5+1) Annulation Strategy to Access Chiral Spirooxindole‐Fused Oxacycles

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Tertiary Amides as Directing Groups for Enantioselective C−H Amination using Ion‐Paired Rhodium Complexes

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Enantioselective S‐Alkylation of Sulfenamides by Phase‐Transfer Catalysis

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Chemoselective Catalytic Asymmetric Synthesis of Functionalized Aminals Through the Umpolung Organocascade Reaction of α‐Imino Amides

inferred← citeshttps://doi.org/10.1002/cctc.70727openalex-snapshot

Computational Insights Into Enantioselectivity Differences in Pseudoenantiomeric Cinchona Alkaloid‐Catalyzed Imine Umpolung Michael Additions

inferred← citeshttps://doi.org/10.1002/chem.202004117openalex-snapshot

Insights on the Pseudo‐Enantiomeric Properties of Bifunctional Cinchona Alkaloid Squaramide‐Derived Organocatalyst

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Late‐Stage Dehydroxyazidation of Alcohols Promoted by Trifunctional Hypervalent Azido‐Iodine(III) Reagents

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PdII/Novel Chiral Cinchona Alkaloid Oxazoline‐Catalyzed Enantioselective Oxidative Cyclization of Aromatic Alkenyl Amides

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A Novel Dendrobine‐Derived Phase‐Transfer Catalyst

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Carbon–Carbon Bond Formation Reactions Using Chiral Phase-Transfer Catalysts

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Catalytic asymmetric umpolung reaction of imines to synthesize isoindolinones and tetrahydroisoquinolines

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Synthesis and pharmacological evaluation of fluoro/chloro-substituted acetyl and benzoyl esters of quinine as antimalarial agents

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Organocatalytic enantioselective sulfa-Michael addition of thiocarboxylic acids to β-trifluoromethyl-α,β-unsaturated ketones for the construction of stereogenic carbon center bearing a sulfur atom and a trifluoromethyl group

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Direct synthesis of regioselective α-allyl α-selanyl ketones and selanyl tetra-hydrofurans

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Organocatalytic asymmetric umpolung reaction of cyanoketimines with 2-(bromomethyl)acrylate

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Biomacromolecule-Assisted Screening for Reaction Discovery and Catalyst Optimization

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The Regiocontrollable Enantioselective Synthesis of Chiral Trifluoromethyl-Containing Spiro-Pyrrolidine-Pyrazolone Compounds via Amino-Regulated 1,3-Proton Migration Reaction

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The Ir-Catalyzed Asymmetric Hydrogenation of α-Halogenated Ketones Utilizing Cinchona-Alkaloid-Derived NNP Ligand to Produce (R)- and (S)-Halohydrins

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Direct Catalytic Asymmetric Synthesis of Trifluoromethylated γ-Amino Esters/Lactones via Umpolung Strategy

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Synthesis of Quinolines and Isoquinolines via Site-Selective, Domino Benzannulation of 2- and 3-Chloropyridyl Ynones with Nitromethane

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Chemo- and Regioselective Asymmetric Synthesis of Cyclic Enamides through the Catalytic Umpolung Organocascade Reaction of α-Imino Amides

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Enantio- and Diastereoselective Synthesis of Homoallylic α-Trifluoromethyl Amines by Catalytic Hydroalkylation of Dienes

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Catalytic Asymmetric Synthesis of Vicinal Tetrasubstituted Diamines via Umpolung Cross-Mannich Reaction of Cyclic Ketimines

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Regio- and Enantioselective Palladium-Catalyzed Asymmetric Allylation of N-Fluorenyl Trifluoromethyl Imine

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Organocatalytic Kinetic Resolution of N-Boc-Isoxazolidine-5-ones

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Cinchona-Alkaloid-Derived NNP Ligand for Iridium-Catalyzed Asymmetric Hydrogenation of Ketones

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Phase-Transfer-Catalyzed Asymmetric Annulations of Alkyl Dihalides with Oxindoles: Unified Access to Chiral Spirocarbocyclic Oxindoles

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Copper-Catalyzed Umpolung of N ‑2,2,2-Trifluoroethylisatin Ketimines for the Enantioselective 1,3-Dipolar Cycloaddition with Benzo[ b ]thiophene Sulfones

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Organocatalytic asymmetric α-C–H functionalization of alkyl amines

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Separation and detection of cyproconazole enantiomers and its stereospecific recognition with chiral stationary phase by high-performance liquid chromatography

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Construction of fully substituted carbon centers containing a heteroatom and a CF 3 group via in situ generated p -quinone methides

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Catalytic asymmetric umpolung reactions of imines via 2-azaallyl anion intermediates

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Enantioselectivity switch in asymmetric Michael addition reactions using phosphonium salts

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Palladium-catalyzed enantioselective umpolung allylation of amido-tethered allylic carbonates with isatin-derived ketimines

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Pyramidal Stereogenic Nitrogen Centers (SNCs)

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FIGURE 1 in A new Hemigrammus Gill from upper rio Paraná system, Southeastern Brazil (Characiformes: Characidae)

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