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Diphenyl Phosphate as an Efficient Acidic Organocatalyst for Controlled/Living Ring-Opening Polymerization of Trimethylene Carbonates Leading to Block, End-Functionalized, and Macrocyclic Polycarbonates
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
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Cationic ring-opening polymerization (CROP) major mechanistic phenomena
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New Paradigms for Organic Catalysts: The First Organocatalytic Living Polymerization
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Direct Organocatalytic Ring‐Opening Polymerizations of Lactones
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Organocatalysts for the Controlled “Immortal” Ring‐Opening Polymerization of Six‐Membered‐Ring Cyclic Carbonates: A Metal‐Free, Green Process
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Controllable ring‐opening polymerization of trimethylene carbonate catalyzed by aliphatic tertiary amines in the presence of benzyl alcohol or F127
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Phosphines: Nucleophilic organic catalysts for the controlled ring-opening polymerization of lactides
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Sugars‐grafted aliphatic biodegradable poly( L ‐lactide‐co‐carbonate)s by click reaction and their specific interaction with lectin molecules
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Synthesis of various end‐functionalized polyesters by controlled/living ring‐opening polymerization of lactones using pentafluorophenylbis(triflyl)methane
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Synthesis of end‐functionalized polyethers by phosphazene base‐catalyzed ring‐opening polymerization of 1,2‐butylene oxide and glycidyl ether
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Controlled/living ring-opening polymerization of ɛ-caprolactone catalyzed by phosphoric acid
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N-Heterocyclic carbenes: Effective organic catalysts for living polymerization
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Synthesis of functionalized polylactide by cationic activated monomer polymerization
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Selective pyrolysis of bifunctional compounds: gas-phase elimination of carbonate–ester functionalities
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Organocatalytic Ring Opening Polymerization of Trimethylene Carbonate
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Organocatalytic Ring-Opening Polymerization
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First Example of N-Heterocyclic Carbenes as Catalysts for Living Polymerization: Organocatalytic Ring-Opening Polymerization of Cyclic Esters
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In Situ Generation of Carbenes: A General and Versatile Platform for Organocatalytic Living Polymerization
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Activity-Based Protein Profiling in Vivo Using a Copper(I)-Catalyzed Azide-Alkyne [3 + 2] Cycloaddition
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Thiourea-Based Bifunctional Organocatalysis: Supramolecular Recognition for Living Polymerization
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An Efficient Route to Well-Defined Macrocyclic Polymers via “Click” Cyclization
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Triazabicyclodecene: A Simple Bifunctional Organocatalyst for Acyl Transfer and Ring-Opening Polymerization of Cyclic Esters
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Organocatalytic Stereoselective Ring-Opening Polymerization of Lactide with Dimeric Phosphazene Bases
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Star Polymer Synthesis from ε-Caprolactone Utilizing Polyol/Protonic Acid Initiator
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Living Cationic Polymerization of δ-Valerolactone and Synthesis of High Molecular Weight Homopolymer and Asymmetric Telechelic and Block Copolymer
inferredcites →https://doi.org/10.1021/ma025872vopenalex-snapshot
Polycarbonate and Poly(carbonate−ester)s Synthesized from Biocompatible Building Blocks of Glycerol and Lactic Acid
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Selective Organocatalytic Ring-Opening Polymerization: A Versatile Route to Carbohydrate-Functionalized Poly(ε-caprolactones)
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Controlled Cationic Polymerization of Lactide
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Exploration, Optimization, and Application of Supramolecular Thiourea−Amine Catalysts for the Synthesis of Lactide (Co)polymers
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Guanidine and Amidine Organocatalysts for Ring-Opening Polymerization of Cyclic Esters
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Phosphazene Bases: A New Category of Organocatalysts for the Living Ring-Opening Polymerization of Cyclic Esters
inferredcites →https://doi.org/10.1021/ma100798uopenalex-snapshot
Controlled/Living Ring-Opening Polymerization of δ-Valerolactone Using Triflylimide as an Efficient Cationic Organocatalyst
inferredcites →https://doi.org/10.1021/ma101461yopenalex-snapshot
Ring-Opening Polymerization of Trimethylene Carbonate Catalyzed by Methanesulfonic Acid: Activated Monomer versus Active Chain End Mechanisms
inferredcites →https://doi.org/10.1021/ma101688dopenalex-snapshot
Ring-Opening Polymerization of l -Lactide Catalyzed by an Organocatalytic System Combining Acidic and Basic Sites
inferredcites →https://doi.org/10.1021/ma102588kopenalex-snapshot
Well-Defined Amphiphilic Biodegradable Comb-Like Graft Copolymers: Their Unique Architecture-Determined LCST and UCST Thermoresponsivity
inferredcites →https://doi.org/10.1021/ma102882vopenalex-snapshot
Organocatalytic Synthesis and Postpolymerization Functionalization of Allyl-Functional Poly(carbonate)s
inferredcites →https://doi.org/10.1021/ma200043xopenalex-snapshot
Diphenyl Phosphate as an Efficient Cationic Organocatalyst for Controlled/Living Ring-Opening Polymerization of δ-Valerolactone and ε-Caprolactone
inferredcites →https://doi.org/10.1021/ma200137aopenalex-snapshot
Preparation of Azido Polycarbonates and Their Functionalization via Click Chemistry
inferredcites →https://doi.org/10.1021/ma702291kopenalex-snapshot
Degradable Cross-Linkers and Strippable Imaging Materials for Step-and-Flash Imprint Lithography
inferredcites →https://doi.org/10.1021/ma800626qopenalex-snapshot
Organo-Catalyzed ROP of ϵ-Caprolactone: Methanesulfonic Acid Competes with Trifluoromethanesulfonic Acid
inferredcites →https://doi.org/10.1021/ma802618hopenalex-snapshot
N-Heterocyclic Carbenes for the Organocatalytic Ring-Opening Polymerization of ε-Caprolactone
inferredcites →https://doi.org/10.1021/ma900712popenalex-snapshot
Synthesis of Well-Defined Macrocyclic Poly(δ-valerolactone) by “Click Cyclization”
inferredcites →https://doi.org/10.1021/ma901776xopenalex-snapshot
Acyclic Guanidines as Organic Catalysts for Living Polymerization of Lactide
inferredcites →https://doi.org/10.1021/ma9025948openalex-snapshot
Organocatalysis: Opportunities and Challenges for Polymer Synthesis
inferredcites →https://doi.org/10.1021/ma902597popenalex-snapshot
Strategy for Rapid and High-Purity Monocyclic Polymers by CuAAC “Click” Reactions
inferredcites →https://doi.org/10.1021/ma992138bopenalex-snapshot
Activated Monomer Cationic Polymerization of Lactones and the Application to Well-Defined Block Copolymer Synthesis with Seven-Membered Cyclic Carbonate
inferredcites →https://doi.org/10.1021/mz3005956openalex-snapshot
Organic Catalysis for Ring-Opening Polymerization
inferredcites →https://doi.org/10.1039/b713925jopenalex-snapshot
Tagging alcohols with cyclic carbonate: a versatile equivalent of (meth)acrylate for ring-opening polymerization
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Phosphoric and phosphoramidic acids as bifunctional catalysts for the ring-opening polymerization of ε-caprolactone: a combined experimental and theoretical study
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Recent advances in metallo/organo-catalyzed immortal ring-opening polymerization of cyclic carbonates
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Organocatalytic synthesis and post-polymerization functionalization of propargyl-functional poly(carbonate)s
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inferred← citeshttps://doi.org/10.1021/acs.macromol.6c00038openalex-snapshot
A Broadly Applicable Zwitterionic Organocatalyst for Controlled Polyester Synthesis
inferred← citeshttps://doi.org/10.1021/acs.macromol.6c00358openalex-snapshot
Metal-Free Synthesis of Tough PLLA- b -PCVL- b -PLLA Triblock Polyester Thermoplastic Elastomers from Mixed Monomers
inferred← citeshttps://doi.org/10.1021/acs.macromol.6c00668openalex-snapshot
Aluminum-Catalyzed Ring-Opening Polymerization of Trimethylene Carbonate: A Route to Molecular-Weight-Controllable Cyclic Poly(trimethylene carbonate)
inferred← citeshttps://doi.org/10.1021/acs.macromol.7b01784openalex-snapshot
Dual Switching in Both RAFT and ROP for Generation of Asymmetric A2A1B1B2 Type Tetrablock Quaterpolymers
inferred← citeshttps://doi.org/10.1021/acs.macromol.8b00456openalex-snapshot
Functional Polyesters with Pendant Double Bonds Prepared by Coordination–Insertion and Cationic Ring-Opening Copolymerizations of ε-Caprolactone with Renewable Tulipalin A
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b02750openalex-snapshot
Electrostatically Enhanced Phosphoric Acids: A Tool in Brønsted Acid Catalysis
inferred← citeshttps://doi.org/10.1021/acsami.7b17718openalex-snapshot
Hyaluronic Acid-Shelled Disulfide-Cross-Linked Nanopolymersomes for Ultrahigh-Efficiency Reactive Encapsulation and CD44-Targeted Delivery of Mertansine Toxin
inferred← citeshttps://doi.org/10.1021/acscatal.3c05712openalex-snapshot
Al(III)/K(I) Heterodinuclear Polymerization Catalysts Showing Fast Rates and High Selectivity for Polyester Polyols
inferred← citeshttps://doi.org/10.1021/acsmacrolett.0c00813openalex-snapshot
Advances, Challenges, and Opportunities of Poly(γ-butyrolactone)-Based Recyclable Polymers
inferred← citeshttps://doi.org/10.1021/acsmacrolett.3c00720openalex-snapshot
Chemically Recyclable Unnatural (1→6)-Polysaccharides from Cellulose-Derived Levoglucosenone and Dihydrolevoglucosenone
inferred← citeshttps://doi.org/10.1021/acsmacrolett.9b00229openalex-snapshot
Hyper-Cross-Linked Polymer on the Hollow Conjugated Microporous Polymer Platform: A Heterogeneous Catalytic System for Poly(caprolactone) Synthesis
inferred← citeshttps://doi.org/10.1021/acsomega.1c04486openalex-snapshot
Toughening Poly( l -lactide) Blends: Effectiveness of Sequence-Controlled Six-Arm Star-Branched Block Copolymers of Poly( l -lactide) and Poly(ε-caprolactone)
inferred← citeshttps://doi.org/10.1021/acssuschemeng.9b00884openalex-snapshot
Trimethyl Glycine as an Environmentally Benign and Biocompatible Organocatalyst for Ring-Opening Polymerization of Cyclic Carbonate
inferred← citeshttps://doi.org/10.1021/ja408641gopenalex-snapshot
Organic Acid-Catalyzed Polyurethane Formation via a Dual-Activated Mechanism: Unexpected Preference of N-Activation over O-Activation of Isocyanates
inferred← citeshttps://doi.org/10.1021/ma400916kopenalex-snapshot
Mild and Efficient Preparation of Block and Gradient Copolymers by Methanesulfonic Acid Catalyzed Ring-Opening Polymerization of Caprolactone and Trimethylene Carbonate
inferred← citeshttps://doi.org/10.1021/ma500830vopenalex-snapshot
A “Catalyst Switch” Strategy for the Sequential Metal-Free Polymerization of Epoxides and Cyclic Esters/Carbonate
inferred← citeshttps://doi.org/10.1038/pj.2016.126openalex-snapshot
Synthesis and properties of poly(L-lactide-co-glycolide)-b-Poly(ɛ-caprolactone) multiblock copolymers formed by self-polycondensation of diblock macromonomers
inferred← citeshttps://doi.org/10.1038/s41428-019-0264-6openalex-snapshot
Facile synthesis of poly(trimethylene carbonate) by alkali metal carboxylate-catalyzed ring-opening polymerization
inferred← citeshttps://doi.org/10.1038/s41428-021-00484-0openalex-snapshot
Synthesis of polyarylates and aliphatic polyesters by divalent acyl-1,2,4-triazole: a route to metal-free synthesis at low temperature
inferred← citeshttps://doi.org/10.1038/s41598-018-22171-6openalex-snapshot
Organocatalyzed chemoselective ring-opening polymerizations
inferred← citeshttps://doi.org/10.1039/9781788015738-00037openalex-snapshot
Ring-opening Polymerization Promoted by Brønsted Acid Catalysts
inferred← citeshttps://doi.org/10.1039/c3dt53513dopenalex-snapshot
Magnesium complexes containing biphenyl-based tridentate imino-phenolate ligands for ring-opening polymerization of rac-lactide and α-methyltrimethylene carbonate
inferred← citeshttps://doi.org/10.1039/c3gc41806eopenalex-snapshot
Hydrogen-bonding organocatalysts for ring-opening polymerization
inferred← citeshttps://doi.org/10.1039/c3py00667kopenalex-snapshot
Imidodiphosphoric acid as a bifunctional catalyst for the controlled ring-opening polymerization of δ-valerolactone and ε-caprolactone
inferred← citeshttps://doi.org/10.1039/c3py00935aopenalex-snapshot
Selective O -acyl ring-opening of β-butyrolactone catalyzed by trifluoromethane sulfonic acid: application to the preparation of well-defined block copolymers
inferred← citeshttps://doi.org/10.1039/c3py01613gopenalex-snapshot
o -Benzenedisulfonimide as a recyclable cationic organocatalyst for the controlled/living ring-opening polymerization of δ-valerolactone and ε-caprolactone
inferred← citeshttps://doi.org/10.1039/c4cc00215fopenalex-snapshot
Binaphthol-derived phosphoric acids as efficient chiral organocatalysts for the enantiomer-selective polymerization of rac-lactide
inferred← citeshttps://doi.org/10.1039/c4py00342jopenalex-snapshot
Metal-free controlled ring-opening polymerization of ε-caprolactone in bulk using tris(pentafluorophenyl)borane as a catalyst
inferred← citeshttps://doi.org/10.1039/c4py00773eopenalex-snapshot
A base–conjugate-acid pair for living/controlled ring-opening polymerization of trimethylene carbonate through hydrogen-bonding bifunctional synergistic catalysis
inferred← citeshttps://doi.org/10.1039/c4ra01239aopenalex-snapshot
Controlled bulk polymerization of l-lactide and lactones by dual activation with organo-catalytic systems
inferred← citeshttps://doi.org/10.1039/c4ra09579kopenalex-snapshot
2,4-Dinitrobenzenesulfonic acid in an efficient Brønsted acid-catalyzed controlled/living ring-opening polymerization of ε-caprolactone
inferred← citeshttps://doi.org/10.1039/c4ra12417kopenalex-snapshot
Four-component α-bromo-β-phosphoalkoxylation of aromatic α,β-unsaturated carbonyl compounds
inferred← citeshttps://doi.org/10.1039/c5dt00158gopenalex-snapshot
Ring-opening polymerization of rac-lactide and α-methyltrimethylene carbonate catalyzed by magnesium and zinc complexes derived from binaphthyl-based iminophenolate ligands
inferred← citeshttps://doi.org/10.1039/c5py00533gopenalex-snapshot
Organophosphate-catalyzed bulk ring-opening polymerization as an environmentally benign route leading to block copolyesters, end-functionalized polyesters, and polyester-based polyurethane
inferred← citeshttps://doi.org/10.1039/c5py01843aopenalex-snapshot
Synthesis of high-molecular-weight aliphatic polycarbonates by organo-catalysis
inferred← citeshttps://doi.org/10.1039/c5py01846copenalex-snapshot
Development of polycarbonate-containing block copolymers for thin film self-assembly applications
inferred← citeshttps://doi.org/10.1039/c6py01107aopenalex-snapshot
Traceless switch organocatalysis enables multiblock ring-opening copolymerizations of lactones, carbonates, and lactides: by a one plus one approach in one pot
inferred← citeshttps://doi.org/10.1039/c6py01210hopenalex-snapshot
Polymerization of trimethylene carbonates using organic phosphoric acids
inferred← citeshttps://doi.org/10.1039/c7py01411bopenalex-snapshot
Design, synthesis and ring-opening polymerization of a new iodinated carbonate monomer: a universal route towards ultrahigh radiopaque aliphatic polycarbonates
inferred← citeshttps://doi.org/10.1039/c7py01671aopenalex-snapshot
Squaramide and amine binary H-bond organocatalysis in polymerizations of cyclic carbonates, lactones, and lactides
inferred← citeshttps://doi.org/10.1039/c7py02086dopenalex-snapshot
Metallic organophosphate catalyzed bulk ring-opening polymerization
inferred← citeshttps://doi.org/10.1039/c8cc08405jopenalex-snapshot
Ring-opening polymerization of trimethylene carbonate to poly(trimethylene carbonate) diol over a heterogeneous high-temperature calcined CeO 2 catalyst
inferred← citeshttps://doi.org/10.1039/c8gc01909fopenalex-snapshot
Development of a H 3 PW 12 O 40 /CeO 2 catalyst for bulk ring-opening polymerization of a cyclic carbonate
inferred← citeshttps://doi.org/10.1039/c8py00835copenalex-snapshot
Hybrid block copolymers of polyesters/polycarbonates and polypeptides synthesized via one-pot sequential ring-opening polymerization
inferred← citeshttps://doi.org/10.1039/c8py01357hopenalex-snapshot
Synthesis of well-defined PCL- b -PnBA- b -PMMA ABC-type triblock copolymers: toward the construction of nanostructures in epoxy thermosets
inferred← citeshttps://doi.org/10.1039/c9py00018fopenalex-snapshot
N-Heterocyclic olefins and thioureas as an efficient cooperative catalyst system for ring-opening polymerization of δ-valerolactone
inferred← citeshttps://doi.org/10.1039/c9py01777aopenalex-snapshot
Organocatalyzed ring opening polymerization of regio-isomeric lactones: reactivity and thermodynamics considerations
inferred← citeshttps://doi.org/10.1039/d0cc02906hopenalex-snapshot
Organocatalytic sequential ring-opening polymerization of a cyclic ester and anionic polymerization of a vinyl monomer
inferred← citeshttps://doi.org/10.1039/d0py00031kopenalex-snapshot
Facile preparation of long-chain aliphatic polycarbonates containing block copolycarbonates via one-pot sequential organic catalyzed polymerization of macrocyclic carbonates and trimethylene carbonates
inferred← citeshttps://doi.org/10.1039/d0py01534bopenalex-snapshot
Strategies for the synthesis of block copolymers with biodegradable polyester segments
inferred← citeshttps://doi.org/10.1039/d0ra04251jopenalex-snapshot
Phosphorus pentoxide as a cost-effective, metal-free catalyst for ring opening polymerization of ε-caprolactone
inferred← citeshttps://doi.org/10.1039/d0ra08087jopenalex-snapshot
Poly(trimethylene carbonate- co -valerolactone) copolymers are materials with tailorable properties: from soft to thermoplastic elastomers
inferred← citeshttps://doi.org/10.1039/d1cc01092aopenalex-snapshot
Changing the structural and physical properties of 3-arm star poly(δ-valerolactone)s by a branch-point design
inferred← citeshttps://doi.org/10.1039/d1py01289dopenalex-snapshot
Diphenyl phosphate/ethyl diphenylphosphinite as an efficient organocatalytic system for ring-opening polymerization of ε-caprolactone and δ-valerolactone
inferred← citeshttps://doi.org/10.1039/d2py00215aopenalex-snapshot
Ring opening copolymerization of δ-valerolactone with 2-methyl-1,3-dioxane-4-one towards poly(3-hydroxypropionate- co -5-hydroxyvalerate) copolyesters
inferred← citeshttps://doi.org/10.1039/d2py00339bopenalex-snapshot
Sequentially bridging anionic addition and ring-opening polymerization by cooperative organocatalysis: well-defined block copolymers from methacrylates and cyclic esters
inferred← citeshttps://doi.org/10.1039/d2py01128jopenalex-snapshot
Polyurethanes based on lignin-derived metabolic intermediate with strong adhesion to metals
inferred← citeshttps://doi.org/10.1039/d3py00195dopenalex-snapshot
One-pot catalyst-switching synthesis of thermoresponsive amphiphilic diblock copolymers consisting of poly( N , N -diethylacrylamide) and biodegradable polyesters
inferred← citeshttps://doi.org/10.1039/d3py00535fopenalex-snapshot
Chemical recycling to monomer: thermodynamic and kinetic control of the ring-closing depolymerization of aliphatic polyesters and polycarbonates
inferred← citeshttps://doi.org/10.1039/d3py00657copenalex-snapshot
Sourcing, thermodynamics, and ring-opening (co)polymerization of substituted δ-lactones: a review
inferred← citeshttps://doi.org/10.1039/d4gc04411hopenalex-snapshot
Green synthesis of poly ε-caprolactone using a metal-free catalyst via non-covalent interactions
inferred← citeshttps://doi.org/10.1039/d6nj00201copenalex-snapshot
Polycarbonate synthesis via ring-opening polymerization: catalysts, mechanisms, and sustainable strategies
inferred← citeshttps://doi.org/10.1039/d6py00271dopenalex-snapshot
Controlled cationic ring-opening polymerization of cyclic esters toward metal-free polyesters with high-performance using a Meerwein-type ion pair initiator
inferred← citeshttps://doi.org/10.1080/15583724.2026.2670279openalex-snapshot
Ring-Opening Copolymerization of Lactide with Cyclic Ethers Using Different Catalytic Systems
inferred← citeshttps://doi.org/10.1080/15685551.2018.1550288openalex-snapshot
Organocatalyzed ring-opening copolymerization of α-bromo-γ-butyrolactone with ε-caprolactone for the synthesis of functional aliphatic polyesters – pre-polymers for graft copolymerization
inferred← citeshttps://doi.org/10.3390/polym11122078openalex-snapshot
DFT Modeling of Organocatalytic Ring-Opening Polymerization of Cyclic Esters: A Crucial Role of Proton Exchange and Hydrogen Bonding
inferred← citeshttps://doi.org/10.3390/polym14102031openalex-snapshot
Overview: Polycarbonates via Ring-Opening Polymerization, Differences between Six- and Five-Membered Cyclic Carbonates: Inspiration for Green Alternatives
inferred← citeshttps://doi.org/10.5059/yukigoseikyokaishi.71.706openalex-snapshot
Organocatalytic Ring-Opening Polymerization of Cyclic Esters, Cyclic Carbonates, and Epoxides
inferred← citeshttps://doi.org/10.5301/ijao.5000543openalex-snapshot
Triblock Copolymers Based on ε-Caprolactone and Trimethylene Carbonate for the 3D Printing of Tissue Engineering Scaffolds
inferred← citeshttps://doi.org/10.70675/23773083za3d6z4313zba39zf79b709667d0openalex-snapshot
Synthesis and Properties modulation of novel functional degradable polymers by means of fine tuning of their structure
inferred← citeshttps://doi.org/10.70675/2a463aa8z9d55z4840z8621z38308325a92dopenalex-snapshot
Catalyseurs organiques photolatents pour la polymérisation par ouverture de cycles différée
inferred← citeshttps://doi.org/10.70675/34759a3azc801z4ab2z8ce6z59605e4274cbopenalex-snapshot
Elaboration de nanoparticules fonctionnelles à base de dérivés du poly(acide diméthylmalique) pour la vectorisation ciblée de principes actifs
inferred← citeshttps://doi.org/10.70675/83ab0e6azba83z4631zb20az577f78a9f5e0openalex-snapshot
Copolymères en peigne à greffons éthers et carbonates : du design macromoléculaire à leur utilisation comme électrolyte de batterie au lithium
inferred← citeshttps://doi.org/10.70675/9261d953z2a49z486dzb566zc8b79d47625eopenalex-snapshot
Ingénierie macromoléculaire par ROP organocatalysée : application à l'étude de la nanostructuration de nouveaux copolymères à blocs biodégradables
inferred← citeshttps://doi.org/10.70675/a5ad76afz65ddz433bz87cbz8557eff4e7c2openalex-snapshot
Organopolymérisations du méthacrylate de méthyle induites par les carbène N-hétérocycliques et par des paires de Lewis organiques
inferred← citeshttps://doi.org/10.70675/b64899c0zd17ez4161zb39ez4aca7a594041openalex-snapshot
Les acides gras comme source de matériaux polycarbonates aliphatiques originaux
inferred← citeshttps://doi.org/10.70675/fb02d936zd560z40b0zade1z5c8b7f7cb2d6openalex-snapshot
Exploring the potential of ring-opening polymerization of biobased lactones as a substitute for non-biodegradable polymers
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