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Cyclopalladation of 6-Substituted-2,2‘-bipyridines. Metalation of Unactivated Methyl Groups vs Aromatic C−H Activation
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
inferredcites →https://doi.org/10.1016/0020-1693(95)04724-7openalex-snapshot
Aliphatic cyclopalladation. Crystal structure of
inferredcites →https://doi.org/10.1016/0022-328x(85)88104-3openalex-snapshot
Metallation of aliphatic carbon atoms
inferredcites →https://doi.org/10.1016/0022-328x(86)80181-4openalex-snapshot
Palladium(II) and platinum(II) derivatives with chiral 2,2′-bipyridines. X-ray structure of C18H15ClN2Pd; C- and N-intramolecular coordination in a six-membered metallacycle
inferredcites →https://doi.org/10.1016/0022-328x(86)80489-2openalex-snapshot
Six-membered cyclometallated compounds of methylbenzalazines with PdC(aliphatic)bonds
inferredcites →https://doi.org/10.1016/0022-328x(92)83234-9openalex-snapshot
Metallation of aliphatic carbon atoms
inferredcites →https://doi.org/10.1016/0022-328x(93)80172-8openalex-snapshot
Cyclometallated derivatives of palladium(II) and platinum(II) derived from 6-t-butyl-2,2′-bipyridine
inferredcites →https://doi.org/10.1016/0022-328x(94)85026-7openalex-snapshot
Six-membered cyclometallated derivatives of platinum(II) derived from 2-benzylpyridines. Crystal and molecular structure of [Pt(L)(Ph3P)Cl] (HL = 2-(1-methylbenzyl)pyridine)
inferredcites →https://doi.org/10.1016/0022-328x(95)00519-vopenalex-snapshot
Optically active organometallic compounds (a personal account from the inside)
inferredcites →https://doi.org/10.1016/0277-5387(96)00105-2openalex-snapshot
Cyclopalladation of N-(p-thiotoluoyl)pyrrolidine and -piperidine
inferredcites →https://doi.org/10.1016/s0020-1693(00)89380-9openalex-snapshot
Crystal and molecular structure of trans-PtCl(CH2CN)(PPh3)2
inferredcites →https://doi.org/10.1016/s0022-328x(00)80688-9openalex-snapshot
Formation of a chiral carbon centre by direct metallation into a methylene group
inferredcites →https://doi.org/10.1016/s0022-328x(00)82943-5openalex-snapshot
Palladation behaviour of 8-methyl-, 8-ethyl-, and 8-isopropyl-quinolines and some of their 2-substituted derivatives
inferredcites →https://doi.org/10.1016/s0022-328x(00)83942-xopenalex-snapshot
Asymmetric cyclopalladation of dimethylaminomethylferrocene
inferredcites →https://doi.org/10.1016/s0022-328x(00)99687-6openalex-snapshot
Optically active nitrogen ligans
inferredcites →https://doi.org/10.1016/s0022-328x(96)06800-3openalex-snapshot
Cyclometallated complexes of palladium(II) with a C, N, N′ terdentate Schiff base donor ligand. Oxidative addition of an arylchlorine bond to palladium(O)
inferredcites →https://doi.org/10.1016/s0040-4020(01)96448-8openalex-snapshot
Functionalisation of unactivated methyl groups through cyclopalladation reactions
inferredcites →https://doi.org/10.1021/cr00068a002openalex-snapshot
The organometallic chemistry of alkanes
inferredcites →https://doi.org/10.1021/ic00069a022openalex-snapshot
Reactivity of palladium complex [Pd(CN)(C6F5)(NCMe)] [CN = ((dimethylamino)methyl)phenyl-C2,N, 8-quinolylmethyl-C,N] toward 2,2'-bipyridine or 1,10-phenanthroline. Synthesis and structures of [{Pd(8-mq)(C6F5)}2(.mu.-bpy)] and [(C6F5)(8-mq)Pd(.mu.-8-mq)Pd(C6F5)(phen)], dinuclear complexes…
inferredcites →https://doi.org/10.1021/ic00165a013openalex-snapshot
A carbon-bonded tris(2,2'-bipyridine)iridium(III) complex: (2,2'-bipyridinyl-C3,N')bis(2,2'-bipyridine-N,N')iridium(III) perchlorate-water (3/1)
inferredcites →https://doi.org/10.1021/ic00168a047openalex-snapshot
Analysis of the proton and carbon-13 NMR spectra of [Ir(Hbpy-C3,N')(bpy-N,N')2]3+: evidence for a carbon-bonded structure
inferredcites →https://doi.org/10.1021/ic00189a032openalex-snapshot
Solution structure and properties of the [(2,2'-bipyridinyl-C3,N')bis(2,2'-bipyridine-N,N')iridium(III)](2+) hydrate ion, "pseudo-[Ir(bpy)3(OH)]2+"
inferredcites →https://doi.org/10.1021/ja00262a055openalex-snapshot
Geometrical characteristics from experiment and theory of isostructural complexes involving palladium and platinum-methyl bonds
inferredcites →https://doi.org/10.1021/om00006a021openalex-snapshot
Stability in Solution of (Chloromethyl)palladium(II) Complexes: X-ray Structures of trans-Bis(triphenylphosphine)chloro(chloromethyl)palladium(II) and -platinum(II) and Comparison of the Relative Stabilities of Analogous Palladium and Platinum Chloromethyl Complexes Containing Phosphine Ligands
inferredcites →https://doi.org/10.1021/om00015a022openalex-snapshot
Aliphatic Palladation of Ketone N,N-Dimethylhydrazones
inferredcites →https://doi.org/10.1021/om00029a045openalex-snapshot
Rigid five- and six-membered C,N,N'-bound aryl-, benzyl-, and alkylorganopalladium complexes: sp2 vs. sp3 carbon-hydrogen activation during cyclopalladation and palladium(IV) intermediates in oxidative addition reactions with dihalogens and alkyl halides
inferredcites →https://doi.org/10.1021/om00040a025openalex-snapshot
Cyclopalladation of N-mesitylbenzylideneamines. Aromatic versus aliphatic carbon-hydrogen bond activation
inferredcites →https://doi.org/10.1021/om00115a033openalex-snapshot
Synthetic routes to methylpalladium(II) and dimethylpalladium(II) chemistry and the synthesis of new nitrogen donor ligand systems
inferredcites →https://doi.org/10.1021/om00137a018openalex-snapshot
Reaction of diazomethane with platinum(II) chloride complexes of chelating olefins. Crystal structure analyses of a-chloro-b-(chloromethyl)-cd-(2,2,N,N-tetramethyl-3-buten-1-amine)platinum(II), a-chloro-b-(chloromethyl)-dc-(2,2,N,N-tetramethyl-3-buten-1-amine)platinum(II),…
inferredcites →https://doi.org/10.1021/om00141a018openalex-snapshot
A comparative study of isostructural palladium and platinum methyl complexes. The structures of cis-dimethylbis(diphenylmethylphosphine)palladium(II) and cis-dimethylbis(diphenylmethylphosphine)platinum(II)
inferredcites →https://doi.org/10.1021/om00143a034openalex-snapshot
Competitive metalation reactions between aliphatic and aromatic carbon atoms in N-benzylideneamines. X-ray molecular structure of [Pd[1-CH2-2-(HC:NPh)-3,5-(CH3)2C6H2]BrPPh3]
inferredcites →https://doi.org/10.1021/om981043fopenalex-snapshot
Multidonor Ligands. 3. Cyclopalladation of py{SCH2C(O)R}-2 (py-2 = 2-pyridyl, R = Ph, Me, OMe) through a C(sp3)−H Bond Activation
inferredcites →https://doi.org/10.1021/om990125gopenalex-snapshot
Divergent Behavior of Palladium(II) and Platinum(II) in the Metalation of 1,3-Di(2-pyridyl)benzene
inferredcites →https://doi.org/10.1039/a903614hopenalex-snapshot
Cyclometallated derivatives of rhodium(III). Activation of C(sp3)–H vs. C(sp2)–H bonds
inferredcites →https://doi.org/10.1039/c39850000609openalex-snapshot
‘Roll-over’ 3-metallation of co-ordinated 2,2′-bipyridyl in the thermal rearrangement of diary(bipyridyl)platinum( II ) complexes: molecular structure of (µ-bidyl)[PtPh(Bu t py)] 2
inferredcites →https://doi.org/10.1039/c39900000513openalex-snapshot
Cyclopalladated and cycloplatinated complexes of 6-phenyl-2,2′-bipyridine: platinum-platinum interactions in the solid state
inferredcites →https://doi.org/10.1039/dt9800001992openalex-snapshot
Transition-metal–carbon bonds. Part 45. Attempts to cyclopalladate some aliphatic oximes, NN-dimethylhydrazones, ketazines, and oxime O-allyl ethers. Crystal structures of [Pd 2 {CH 2 C(CH 3 ) 2 C(NOH)CH 3 } 2 Cl 2 ] and [Pd{CH 2 C(NNMe 2 )C(CH 3 ) 3 }(acac)]
inferredcites →https://doi.org/10.1039/dt9810000205openalex-snapshot
Cyclopalladation of 1-tetralone (3,4-dihydronaphthalen-1-one) oximes
inferredcites →https://doi.org/10.1039/dt9820001699openalex-snapshot
Light-induced reactions of trans-chloro(cyanomethyl)bis(triphenylphosphine) palladium(II) and the crystal and molecular structures of its acetone, acetonitrile, and benzene solvates
inferredcites →https://doi.org/10.1039/dt9830000897openalex-snapshot
Metallation of aliphatic carbon atoms. Part 1. Synthesis and characterization of the cyclopalladated complexes of 2-neopentylpyridine
inferredcites →https://doi.org/10.1039/dt9880000785openalex-snapshot
Metallation of aliphatic carbon atoms. Part 5. Synthesis and characterization of the cyclopalladated complexes of 2-(trimethylsilyl)pyridine and their dynamic behaviour observed by proton nuclear magnetic resonance spectroscopy
inferredcites →https://doi.org/10.1039/dt9930001973openalex-snapshot
Molecular structures of mixed-ligand palladium(II) and platinum(II) alkyl complexes, including three isomorphous compounds
inferredcites →https://doi.org/10.1039/dt9950000777openalex-snapshot
Cyclometallated derivatives of platinum( II ) derived from 6-(tert-butyl)-2,2′-bipyridine (HL). Crystal and molecular structure of [Pt(L)CI]
inferredcites →https://doi.org/10.1039/dt9950002865openalex-snapshot
Synthesis and characterization of gold(III) adducts and cyclometallated derivatives with 2-substituted pyridines. Crystal structure of [Au{NC5H4(CMe2C6H4)-2}Cl2]
inferredcites →https://doi.org/10.1039/dt9960004217openalex-snapshot
Synthesis and characterization of gold( III ) adducts and cyclometallated derivatives with 6-benzyl- and 6-alkyl-2,2′-bipyridines
inferredcites →https://doi.org/10.1063/1.4822724openalex-snapshot
Computers and Crystallography: Joint Progress
inferredcites →https://doi.org/10.1107/s0108270184010465openalex-snapshot
a-Chloro-b-chloromethyl-dc-(3-4-η-2,2,N,N-tetramethyl-3-butenylamine-N)palladium(II), C9H19Cl2NPd
inferredcites →https://doi.org/10.1107/s0567739468000707openalex-snapshot
A semi-empirical method of absorption correction
inferredcites →https://doi.org/10.1107/s0567740876006080openalex-snapshot
International Tables for X-ray Crystallography
inferredcites →https://doi.org/10.1139/v82-129openalex-snapshot
Synthesis and vibrational study of a 1:1 stoichiometric complex of hydronium tetrafluoroborate and 1,4,7,10,13,16-hexaoxacyclooctadecane (18-crown-6)
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Incoming claims: where this work appears in other papers’ reference lists and arguments.
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Combination of Lacunary Polyoxometalates and High‐Nuclear Transition Metal Clusters under Hydrothermal Conditions: IX. A Series of Novel Polyoxotungstates Sandwiched by Octa‐Copper Clusters
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A Theoretical Assessment of the Thermodynamic Preferences in the Cyclopalladation of Amines
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C–H Bond Activation of Palladium Complexes That Feature Pendant Benzamidinate Ligands and Their Catalytic Behaviours
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Rollover Cyclopalladation via Remote C‐H Bond Activation of Br‐Pyridinbenzothiazole: An Experimental Study
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Applications of Cyclometalation Reactions and Five-Membered Ring Products for Synthetic Purposes
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Synthesis, Structure and Reactivity of Cyclometalated Nickel(II) Complexes: A Review and Perspective
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Cyclopalladated complexes containing an (sp3)C–Pd bond
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Examination of a dicationic rhodium methyl aquo complex
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Coordination chemistry to palladium(II) of pyridylbenzamidine ligands and the related reactivity with ethylene
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Effect of 5-Me substituent(s) on the catalytic activity of palladium(II) 2,2′-bipyridine complexes in CO/4-tert-butylstyrene copolymerization
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Substituent effect on cyclopalladation of arylimines
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Study of the reactivity of palladacycles containing [C(sp2, ferrocene),N,S]− or [C(sp3),N,S]− terdentate ligands with symmetric alkynes
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Iridium mediated methyl and phenyl C–H activation of 2-(arylazo)phenols. Synthesis, structure, and spectral and electrochemical properties of some organoiridium complexes
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Dinuclear platinum(II) complexes with bridging twofold deprotonated 2,2′:6′,2″-terpyridine. New molecules with a 3,5-diplatinated-pyridyl inner core: [Pt2(terpy-2H)(Me)2(L)2], [Pt2(terpy-2H)(X)2(L)2] and [Pt2(terpy-2H)(H)2(L)2] (L = neutral ligand; X = halide) – Crystal and molecular structure of…
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Cyclometallated imine complexes with oxygen-functionalised side-chains: Effect of the nature of the functional group, chain length and charge on coordination of the oxygen
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Step by step palladium mediated syntheses of new 2-(pyridin-2-yl)-6-R-nicotinic acids and esters
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Interaction of 2-(2′,6′-dialkylphenylazo)-4-methylphenols with iridium. C–H activation and migration of alkyl group
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Reactivity of C(sp2)-Pd and C(sp3)-Pd bonded palladacycles with diphosphines. Crystal and molecular structure of the novel A-frame complex [{Pd[2,5-Me2C6H2C(H) N(2,4,6-Me3C6H2)-C6]}2(μ-Ph2PCH2PPh2)2(μ-Cl)][PF6]
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The cyclometalated nickel complex [(Phbpy)NiBr] (Phbpy− = 2,2′-bipyridine-6-phen-2-yl) – Synthesis, spectroscopic and electrochemical studies
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Platinum(II), palladium(II) and gold(III) adducts and cyclometalated derivatives of 6-methoxy-2,2′-bipyridine: A comparative study
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Newly designed luminescent di- and tetra-nuclear double rollover cycloplatinated(II) complexes
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Roll-over cyclometalation: A versatile tool to enhance the catalytic activity of transition metal complexes
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Diaryl(fluorinated)-mercury species as potential precursors of triaryl(fluorinated)-gallium to be used in the synthesis of cyclometallated Ga compounds and unexpected formation of aryl-Ga clusters
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Hydridobipyridine rhodium complexes as a result of the C–H bond activation in coordinated ligand, NMR studies
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Palladium complexes of unsymmetrical 1,3-bis(aryliminio)isoindoline (BAI) ligands: A novel class of complexes exhibiting unusual structural features
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Forty years on – Covalent hydration of transition metal complexes revisited
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Heterodimetallic palladium(II) compounds containing terdentate [Csp2(ferrocene),N,N′]− ferrocenyl ligands
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New complexes of palladium(II) with chelating heterocyclic nitrogen ligands.
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Reactivity of 6-(2-tolyl)- and 6-(2,6-xylyl)-2,2′-bipyridines with palladium(II) derivatives. Selective C(sp3)H vs. C(sp2)H activation
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Chapter 2 Organometallic Complexes of Polypyridine Ligands IV
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Unexpected Formation of Neutral Alkyl-Ni(II) Complexes Bearing Unsymmetrical C , N , N ’-Pincer Iminopyrrolyl Ligands via Intramolecular C–H Bond Activation: A Distinct Type of Single-Component Ethylene Polymerization Catalysts
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Two-Dimensional Hybrid Framework Based on Weakley-Type POM as a Heterogeneous Catalyst for Glycolysis of PET and Various Polyesters
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Osmium- and Iridium-Promoted C–H Bond Activation of 2,2′-Bipyridines and Related Heterocycles: Kinetic and Thermodynamic Preferences
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Role of the X Coligands in Cyclometalated [Ni(Phbpy)X] Complexes (HPhbpy = 6-Phenyl-2,2′-bipyridine)
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Computational and Experimental Study on Selective sp2/sp3 or Vinylic/Aryl Carbon–Hydrogen Bond Activation by Platinum(II): Geometries and Relative Stability of Isomeric Cycloplatinated Compounds
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C–H Activation of Pyrazolyl Ligands by Ru(II)
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Dinuclear C,N,C Cyclometalated Platinum Derivatives with Bridging Delocalized Ligands. Fourfold Deprotonation of 6,6‘-Diphenyl-2,2‘-bipyridine, H4L, Promoted by “Pt(R)2” Fragments (R = Me, Ph). Crystal Structures of [Pt2(L)(3,5-Me2py)2] and {Pt2(L)(dppe)}2(dppe = 1,2-Bis(diphenylphosphino)ethane).…
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Palladium Chemistry of 2-Ferrocenyl-1,10-phenanthroline Ligand
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Platinum(II)-Cyclometalated “Roll-over” Complexes with a Chiral Pinene-Derived 2,2′-Bipyridine
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Heterobimetallic Rollover Derivatives
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Mesoionic Complexes of Platinum(II) Derived from “Rollover” Cyclometalation: A Delicate Balance between Pt–C(sp3) and Pt–C(sp2) Bond Cleavage as a Result of Different Reaction Conditions
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Reaction of N-Isopropyl-N-phenyl-2,2′-bipyridin-6-amine with K2PtCl4: Selective C–H Bond Activation, C–N Bond Cleavage, and Selective Acylation
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Synthesis and Characterization of Palladium(II) and Platinum(II) Adducts and Cyclometalated Complexes of 6,6′-Dimethoxy-2,2′-bipyridine: C(sp3)–H and C(sp2)–H Bond Activations
inferred← citeshttps://doi.org/10.1021/om500681uopenalex-snapshot
Electronic and Steric Effects in Rollover C–H Bond Activation
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New bulky phosphinopyridine ligands. P∼N∼C Tridentates in palladium complexes
inferred← citeshttps://doi.org/10.1039/b411432aopenalex-snapshot
Cyclometallated Pd( ii ) azido complexes containing 6-phenyl-2,2′-bipyridyl or 2-phenylpyridyl derivatives: synthesis and reactivity toward organic isocyanides and isothiocyanates
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Kinetico–mechanistic studies of C–H bond activation on new Pd complexes containing N,N′-chelating ligands
inferred← citeshttps://doi.org/10.1039/b802185fopenalex-snapshot
Facile intramolecular C(sp3)–H bond activation with PdII
inferred← citeshttps://doi.org/10.1039/c1sc00651gopenalex-snapshot
“Rollover” cyclometalation – early history, recent developments, mechanistic insights and application aspects
inferred← citeshttps://doi.org/10.1039/c3dt50176kopenalex-snapshot
From discrete monomeric complexes to hydrogen-bonded dimeric assemblies based on sterically encumbered square planar palladium(ii) ONN-pincers
inferred← citeshttps://doi.org/10.1039/c5dt02483hopenalex-snapshot
Chiral cyclometalation of 6-(1-phenylbenzyl)-2,2′-bipyridine
inferred← citeshttps://doi.org/10.1039/c7nj03817hopenalex-snapshot
Simple tuning of the luminescence properties of the double rollover cycloplatinated( ii ) structure by halide ligands
inferred← citeshttps://doi.org/10.1039/d0ra03824eopenalex-snapshot
The shiny side of copper: bringing copper( i ) light-emitting electrochemical cells closer to application
inferred← citeshttps://doi.org/10.1039/d1dt00389eopenalex-snapshot
Modulation of N^N′-bidentate chelating pyridyl–pyridylidene amide ligands offers mechanistic insights into Pd-catalysed ethylene/methyl acrylate copolymerisation
inferred← citeshttps://doi.org/10.1039/d1dt00546dopenalex-snapshot
Synthesis and characterization of new Pd( ii ) and Pt( ii ) complexes with 3-substituted 1-(2-pyridyl)imidazo[1,5- a ]pyridine ligands
inferred← citeshttps://doi.org/10.1039/d3qi02597gopenalex-snapshot
meso -Aryl substituents modify the electrochemical profile and palladium( ii ) coordination of redox-active tripyrrin ligands
inferred← citeshttps://doi.org/10.1039/d4ra02173hopenalex-snapshot
LED-induced Ru-photoredox Pd-catalyzed C–H arylation of (6-phenylpyridin-2-yl)pyrimidines and heteroaryl counterparts
inferred← citeshttps://doi.org/10.1139/v08-084openalex-snapshot
Synthesis of platinum(II) cyclometallated compounds derived from imines containing pyridyl or pyrimidyl groups
inferred← citeshttps://doi.org/10.3390/app10196665openalex-snapshot
Pt(II) Derivatives with Rollover-Coordinated 6-substituted 2,2′-bipyridines: Ligands with Multiple Personalities
inferred← citeshttps://doi.org/10.3390/ecsoc-25-11663openalex-snapshot
Palladacycles as Functionalized Metal-Ligand Precursors, Contain Tridentate [Csp2, N, S] Ligands
inferred← citeshttps://doi.org/10.3390/molecules26010210openalex-snapshot
The Exchange of Cyclometalated Ligands
inferred← citeshttps://doi.org/10.3390/molecules26020328openalex-snapshot
Rollover Cyclometalation as a Valuable Tool for Regioselective C–H Bond Activation and Functionalization
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