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Intramolecular C(sp2)−H Bond Activation in 6,6′-Dimethoxy-2,2′-Bipyridine with Gold(III). Crystal and Molecular Structure of the First N′,C(3) “Rollover” Cycloaurated Derivative

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inferred← citeshttps://doi.org/10.2139/ssrn.4475968openalex-extracted
A Study Toward Synthesis of Triaryl(Fluorinated)-Gallium, Their Rollover and Classic Cyclometallated Species and Aryl-Ga Clusters
inferred← citeshttps://doi.org/10.1002/ange.201607225openalex-snapshot
Cyclometallierte AuIII‐Komplexe: Synthese, Reaktivität und physikalisch‐chemische Eigenschaften
inferred← citeshttps://doi.org/10.1002/anie.201607225openalex-snapshot
Cyclometalated Gold(III) Complexes: Synthesis, Reactivity, and Physicochemical Properties
inferred← citeshttps://doi.org/10.1002/chem.201406543openalex-snapshot
Gold–Acetonyl Complexes: From Side‐Products to Valuable Synthons
inferred← citeshttps://doi.org/10.1002/slct.201703079openalex-snapshot
Rollover Cyclopalladation via Remote C‐H Bond Activation of Br‐Pyridinbenzothiazole: An Experimental Study
inferred← citeshttps://doi.org/10.1007/978-4-431-54604-7_7openalex-snapshot
Applications of Cyclometalation Reactions and Five-Membered Ring Products for Synthetic Purposes
inferred← citeshttps://doi.org/10.1016/bs.adomc.2018.03.001openalex-snapshot
Organometallic Fluorophores of d 8 Metals (Pd, Pt, Au)
inferred← citeshttps://doi.org/10.1016/j.ccr.2017.06.006openalex-snapshot
More hydra than Janus – Non-classical coordination modes in complexes of oligopyridine ligands
inferred← citeshttps://doi.org/10.1016/j.ccr.2017.10.018openalex-snapshot
Weiss’ Reagents: A synthetically useful class of iodine(III) coordination compounds
inferred← citeshttps://doi.org/10.1016/j.chemphys.2014.03.005openalex-snapshot
Excited-state dynamics of a ruthenium(II) catalyst studied by transient photofragmentation in gas phase and transient absorption in solution
inferred← citeshttps://doi.org/10.1016/j.ica.2012.12.002openalex-snapshot
Examination of a dicationic rhodium methyl aquo complex
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2016.06.023openalex-snapshot
Platinum(II), palladium(II) and gold(III) adducts and cyclometalated derivatives of 6-methoxy-2,2′-bipyridine: A comparative study
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2016.07.007openalex-snapshot
Newly designed luminescent di- and tetra-nuclear double rollover cycloplatinated(II) complexes
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2018.03.022openalex-snapshot
Roll-over cyclometalation: A versatile tool to enhance the catalytic activity of transition metal complexes
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2023.122853openalex-snapshot
Diaryl(fluorinated)-mercury species as potential precursors of triaryl(fluorinated)-gallium to be used in the synthesis of cyclometallated Ga compounds and unexpected formation of aryl-Ga clusters
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2026.124058openalex-snapshot
Unexpected C-H bond activation mediated by gold(III) acetate
inferred← citeshttps://doi.org/10.1016/j.mcat.2021.111979openalex-snapshot
CO2 Conversion to formates catalyzed by iridium(III) catalysts precursors with proton responsive OH and NH electron-rich tetrazole ligands
inferred← citeshttps://doi.org/10.1016/j.poly.2015.03.016openalex-snapshot
Forty years on – Covalent hydration of transition metal complexes revisited
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5b03000openalex-snapshot
Mass Spectrometry Uncovers Molecular Reactivities of Coordination and Organometallic Gold(III) Drug Candidates in Competitive Experiments That Correlate with Their Biological Effects
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6c00762openalex-snapshot
Two-Dimensional Hybrid Framework Based on Weakley-Type POM as a Heterogeneous Catalyst for Glycolysis of PET and Various Polyesters
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.7b03210openalex-snapshot
Rollover Cyclometalated Bipyridine Platinum Complexes as Potent Anticancer Agents: Impact of the Ancillary Ligands on the Mode of Action
inferred← citeshttps://doi.org/10.1021/acs.joc.7b00444openalex-snapshot
Palladium-Catalyzed Directed Halogenation of Bipyridine N-Oxides
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00156openalex-snapshot
Osmium- and Iridium-Promoted C–H Bond Activation of 2,2′-Bipyridines and Related Heterocycles: Kinetic and Thermodynamic Preferences
inferred← citeshttps://doi.org/10.1021/acs.organomet.6b00806openalex-snapshot
Iridium and Ruthenium Complexes of N -Heterocyclic Carbene- and Pyridinol-Derived Chelates as Catalysts for Aqueous Carbon Dioxide Hydrogenation and Formic Acid Dehydrogenation: The Role of the Alkali Metal
inferred← citeshttps://doi.org/10.1021/acsomega.6c05687openalex-snapshot
Pt(II) Rollover Complexes with Poor-Donor Bipyridines: Synthesis, Reactivity, and Preliminary Antimicrobial Evaluation
inferred← citeshttps://doi.org/10.1021/ic500811nopenalex-snapshot
C–H Activation of Pyrazolyl Ligands by Ru(II)
inferred← citeshttps://doi.org/10.1021/ja5078365openalex-snapshot
Gold-Catalyzed Oxidative Cross-Coupling of Terminal Alkynes: Selective Synthesis of Unsymmetrical 1,3-Diynes
inferred← citeshttps://doi.org/10.1021/jacsau.0c00104openalex-snapshot
Rollover Cyclometalation vs Nitrogen Coordination in Tetrapyridyl Anticancer Gold(III) Complexes: Effect on Protein Interaction and Toxicity
inferred← citeshttps://doi.org/10.1021/om100757eopenalex-snapshot
Mechanistic Study on the Gas-Phase Generation of “Rollover”-Cyclometalated [M(bipy − H)]+(M = Ni, Pd, Pt)
inferred← citeshttps://doi.org/10.1021/om200172hopenalex-snapshot
Platinum(II)-Cyclometalated “Roll-over” Complexes with a Chiral Pinene-Derived 2,2′-Bipyridine
inferred← citeshttps://doi.org/10.1021/om200327aopenalex-snapshot
Synthesis of a Coordinatively Labile Gold(III) Methyl Complex
inferred← citeshttps://doi.org/10.1021/om200660aopenalex-snapshot
Heterobimetallic Rollover Derivatives
inferred← citeshttps://doi.org/10.1021/om300495uopenalex-snapshot
Facile Synthesis of Gold(III) Aryl–Carbene Metallacycles
inferred← citeshttps://doi.org/10.1021/om300537aopenalex-snapshot
Versatile Methods for Preparation of New Cyclometalated Gold(III) Complexes
inferred← citeshttps://doi.org/10.1021/om300594copenalex-snapshot
Rock ‘n’ Roll With Gold: Synthesis, Structure, and Dynamics of a (bipyridine)AuCl3 Complex
inferred← citeshttps://doi.org/10.1021/om300666jopenalex-snapshot
Selective Au–C Cleavage in (C ∧ N ∧ C)Au(III) Aryl and Alkyl Pincer Complexes
inferred← citeshttps://doi.org/10.1021/om300824dopenalex-snapshot
Mesoionic Complexes of Platinum(II) Derived from “Rollover” Cyclometalation: A Delicate Balance between Pt–C(sp3) and Pt–C(sp2) Bond Cleavage as a Result of Different Reaction Conditions
inferred← citeshttps://doi.org/10.1021/om5003057openalex-snapshot
Synthesis and Characterization of Palladium(II) and Platinum(II) Adducts and Cyclometalated Complexes of 6,6′-Dimethoxy-2,2′-bipyridine: C(sp3)–H and C(sp2)–H Bond Activations
inferred← citeshttps://doi.org/10.1038/s41565-026-02147-8openalex-snapshot
Versatile heavy metal ion separation via biological ion-channel-inspired membranes
inferred← citeshttps://doi.org/10.1039/9781849734868-00091openalex-snapshot
Alkali/coinage metals – organolithium, organocuprate chemistry
inferred← citeshttps://doi.org/10.1039/c1sc00651gopenalex-snapshot
“Rollover” cyclometalation – early history, recent developments, mechanistic insights and application aspects
inferred← citeshttps://doi.org/10.1039/c2cy20255gopenalex-snapshot
Gold(iii)–oxo complexes as catalysts in intramolecular hydroamination
inferred← citeshttps://doi.org/10.1039/c2sc00947aopenalex-snapshot
Quest for an intermolecular Au( iii )⋯Au( iii ) interaction between cyclometalated gold( iii ) cations
inferred← citeshttps://doi.org/10.1039/c4dt02279copenalex-snapshot
Synthesis, structures and stability of amido gold( iii ) complexes with 2,2′:6′,2′′-terpyridine
inferred← citeshttps://doi.org/10.1039/c4dt03424dopenalex-snapshot
“Aggregation induced phosphorescence” active “rollover” iridium( iii ) complex as a multi-stimuli-responsive luminescence material
inferred← citeshttps://doi.org/10.1039/c6sc03699fopenalex-snapshot
Au( iii )-aryl intermediates in oxidant-free C–N and C–O cross-coupling catalysis
inferred← citeshttps://doi.org/10.1039/c7dt04675hopenalex-snapshot
Direct formation of Au( iii ) acetyl, alkoxyl and alkynyl functionalities via halide free tricationic Au( iii ) precursors
inferred← citeshttps://doi.org/10.1039/c7nj03817hopenalex-snapshot
Simple tuning of the luminescence properties of the double rollover cycloplatinated( ii ) structure by halide ligands
inferred← citeshttps://doi.org/10.1039/d2dt00371fopenalex-snapshot
Synthesis of substituted (N,C) and (N,C,C) Au( iii ) complexes: the influence of sterics and electronics on cyclometalation reactions
inferred← citeshttps://doi.org/10.1055/a-2039-5521openalex-snapshot
Gold-Catalyzed Cyclization of Alkynyl Heteroarenes with a Norbornene Bridge
inferred← citeshttps://doi.org/10.1515/ncrs-2024-0311openalex-snapshot
The crystal structure of (μ4-oxo)-tri(μ4-2,2′-bipyridine-6,6′-bis(olato)-κ5 O,O′:N:N′:O″)tetrazinc(II) – methylformamide (1/1), C33H25N7O8Zn4
inferred← citeshttps://doi.org/10.1515/ncrs-2025-0396openalex-snapshot
Crystal structure of poly[( μ 3 -2,2′-bipyridine-6,6′-bi(olato)- κ 4 - N , N ′: O : O ′)lead(II)], C 10 H 6 N 2 O 2 Pb
inferred← citeshttps://doi.org/10.3390/molecules26020328openalex-snapshot
Rollover Cyclometalation as a Valuable Tool for Regioselective C–H Bond Activation and Functionalization
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