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A comparative study of olefin or acetylene insertion into Ru–H or Os–H of MHCl(CO)(phosphine)2

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/cber.19891221109openalex-snapshot
Fünf‐ und sechsfach koordinierte Vinylruthenium‐ und ‐osmium‐Komplexe durch Alkin‐Insertion in Hydridometall‐Vorstufen
inferredcites →https://doi.org/10.1016/0009-2614(93)89068-sopenalex-snapshot
A set of d-polarization functions for pseudo-potential basis sets of the main group elements AlBi and f-type polarization functions for Zn, Cd, Hg
inferredcites →https://doi.org/10.1016/0020-1693(94)04244-popenalex-snapshot
Hindered rotation about single bonds in RuHX(CO)(PtBu2Me)2 and IrHCl2(PtBu2Me)2
inferredcites →https://doi.org/10.1016/0022-328x(86)80134-6openalex-snapshot
Five- and six-coordinate hydrido(carbonyl)-ruthenium(II) and -osmium(II) complexes containing triisopropylphosphine as ligand
inferredcites →https://doi.org/10.1021/ja00018a005openalex-snapshot
Ab initio calculations of the relative strengths of the .pi. bonds in acetylene and ethylene and of their effect on the relative energies of .pi.-bond addition reactions
inferredcites →https://doi.org/10.1021/ja00097a017openalex-snapshot
Acetylene .pi.-Coordination, Slippage to .sigma.-Coordination, and 1,2-Hydrogen Migration Taking Place on a Transition Metal. The case of a Ru(II) Complex as Studied by Experiment and ab Initio Molecular Orbital Simulations
inferredcites →https://doi.org/10.1021/ja00201a024openalex-snapshot
Kinetic and mechanistic investigation of the sequential hydrogenation of phenylacetylene catalyzed by OsHCl(CO)(PR3)2 [PR3 = PMe-tert-Bu2 and P-i-Pr3]
inferredcites →https://doi.org/10.1021/ja962732qopenalex-snapshot
An ab Initio MO Study on the Transformation of Acetylene to Vinylidene in the Coordination Sphere of Rhodium(I). The Intra- and Intermolecular Proton Transfer Mechanism
inferredcites →https://doi.org/10.1021/om00010a036openalex-snapshot
Selective protonation of the styryl ligand of RuMe{(E)-CH:CHPh}(CO)2(PiPr3)2 and migratory CO insertion in the methyl group of [RuMe(CO)2(PiPr3)2]BF4
inferredcites →https://doi.org/10.1021/om00046a040openalex-snapshot
Hydrogenation of benzylideneacetone catalyzed by OsHCl(CO)(PR3)2 (PR3 = P-iso-Pr3, PMe-tert-Bu2): new roles of dihydrogen complexes in homogeneous catalytic hydrogenation
inferredcites →https://doi.org/10.1021/om960124dopenalex-snapshot
Five-Coordinate Complex [RuHCl(CO)(PPri3)2] as a Precursor for the Preparation of New Cyclopentadienylruthenium Compounds Containing Unsaturated η1-Carbon Ligands
inferredcites →https://doi.org/10.1021/om970081gopenalex-snapshot
Carbon−Carbon Coupling of Two Alkenyl Fragments on a Saturated Compound
inferredcites →https://doi.org/10.1021/om970139ropenalex-snapshot
Stable Osmium Hydrido−Carbene Complexes with CH2 and Secondary Carbenes CHR as Ligands
inferredcites →https://doi.org/10.1021/om970961vopenalex-snapshot
CO-Induced C(sp 2 )/C(sp) Coupling on Ru and Os: A Comparative Study
inferredcites →https://doi.org/10.1021/om971109ropenalex-snapshot
Hydride Is Not a Spectator Ligand in the Formation of Hydrido Vinylidene from Terminal Alkyne and Ruthenium and Osmium Hydrides: Mechanistic Differences
inferredcites →https://doi.org/10.1021/om9711382openalex-snapshot
Osmium Converts Terminal Olefins to Carbynes: α-Hydrogen Migration Redox Isomers with Reversed Stability for Ruthenium and for Osmium
inferredcites →https://doi.org/10.1021/om980137mopenalex-snapshot
Mechanism of the Acetylene−Vinylidene Rearrangement in the Coordination Sphere of a Transition Metal1
inferredcites →https://doi.org/10.1021/om990493kopenalex-snapshot
Homogeneous Hydrogenation of Alkenes Catalyzed by the Ruthenium−Hydride Complex (PCy3)2(CO)(Cl)RuH: Spectroscopic Observation of the Ruthenium−Ethyl and Ruthenium−Ethylene−Hydride Intermediate Species
inferredcites →https://doi.org/10.1021/om990957eopenalex-snapshot
Facile Synthesis of Alkynyl− and Vinylidene−Niobocene Complexes. Unexpected η1-Vinylidene−η2-Alkyne Isomerization
inferredcites →https://doi.org/10.1039/a803432jopenalex-snapshot
Mechanistic and thermodynamic aspects of methylene transfer from CH2N2 to MHCl(CO)L2 (M=Ru, Os; L=tertiary phosphine): non-least motion behavior and extreme dependence on phosphine identity
inferredcites →https://doi.org/10.1039/a809997iopenalex-snapshot
18-Electron Os(X)(CHR)(Cl)(CO)L2 (X=H, Cl): not octahedral and metastable?
inferredcites →https://doi.org/10.1039/b103815jopenalex-snapshot
A comprehensive view of M–H addition across the RCCH bond: frustration culminating in ultimate union
inferredcites →https://doi.org/10.1063/1.1677527openalex-snapshot
Self—Consistent Molecular Orbital Methods. XII. Further Extensions of Gaussian—Type Basis Sets for Use in Molecular Orbital Studies of Organic Molecules
inferredcites →https://doi.org/10.1063/1.448800openalex-snapshot
Ab initio effective core potentials for molecular calculations. Potentials for main group elements Na to Bi
inferredcites →https://doi.org/10.1063/1.448975openalex-snapshot
Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals
inferredcites →https://doi.org/10.1063/1.464913openalex-snapshot
Density-functional thermochemistry. III. The role of exact exchange

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4772835openalex-extracted
The Influence of Phosphine Ligands on the Redox Properties of 1,4-Divinylanthrylene-Bridged Diruthenium Complexes and a Derived Macrocyclic Analog
inferred← citeshttps://doi.org/10.1002/chem.201501843openalex-snapshot
Ruthenium(II) and Osmium(II) Vinyl Complexes as Highly Sensitive and Selective Chromogenic and Fluorogenic Probes for the Sensing of Carbon Monoxide in Air
inferred← citeshttps://doi.org/10.1002/chem.201601384openalex-snapshot
Redox‐Active Tetraruthenium Macrocycles Built from 1,4‐Divinylphenylene‐Bridged Diruthenium Complexes
inferred← citeshttps://doi.org/10.1002/ejic.200600241openalex-snapshot
Spectroscopic, Structural and Theoretical Investigation of Alkenyl Ruthenium Complexes Supported by Sulfur–Nitrogen Mixed‐Donor Ligands
inferred← citeshttps://doi.org/10.1002/ejic.201301504openalex-snapshot
The Pentynoate Ligand as a Building Block for Multimetallic Systems
inferred← citeshttps://doi.org/10.1002/ejic.201600776openalex-snapshot
Oxidized Styrylruthenium–Ferrocene Conjugates: From Valence Localization to Valence Tautomerism
inferred← citeshttps://doi.org/10.1016/b0-08-045047-4/00092-3openalex-snapshot
Mononuclear Ru/Os Compounds with Hydrocarbon Ligands: Compounds with η1-Ligands
inferred← citeshttps://doi.org/10.1016/b0-08-045047-4/00093-5openalex-snapshot
Mononuclear Ru/Os Compounds with Hydrocarbon Ligands: Compounds with η2–η4 Ligands
inferred← citeshttps://doi.org/10.1016/j.aqrep.2021.100697openalex-snapshot
A mini review of Yu-Ping-Feng polysaccharides: Their biological activities and potential applications in aquaculture
inferred← citeshttps://doi.org/10.1016/j.ccr.2010.02.020openalex-snapshot
Quantum chemical interpretation of redox properties of ruthenium complexes with vinyl and TCNX type non-innocent ligands
inferred← citeshttps://doi.org/10.1016/j.ica.2005.04.036openalex-snapshot
Ruthenium hydride and vinyl complexes supported by nitrogen–oxygen mixed-donor ligands
inferred← citeshttps://doi.org/10.1016/j.ica.2011.03.071openalex-snapshot
Vinyl-ruthenium entities as markers for intramolecular electron transfer processes
inferred← citeshttps://doi.org/10.1016/j.jcat.2004.01.028openalex-snapshot
OsHCl(CO)(PiPr3)2 as catalyst for ring-opening metathesis polymerization (ROMP) and tandem ROMP–hydrogenation of norbornene and 2,5-norbornadiene
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2016.02.031openalex-snapshot
Homo- and heterobimetallic 1,4-divinylphenylene- and naphthalene-1,8-divinyl-bridged diruthenium, diosmium and ruthenium osmium complexes
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2017.05.010openalex-snapshot
Polyelectrochromism and electronic coupling in vinylruthenium-modified carbazoles
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2024.123185openalex-snapshot
The influence of phosphine ligands on the redox properties of 1,4-divinylanthrylene-bridged diruthenium complexes and a derived macrocyclic analog
inferred← citeshttps://doi.org/10.1016/j.molcata.2014.09.040openalex-snapshot
Mechanism of co-dimerization of vinylboronates with terminal alkynes catalyzed by ruthenium-hydride complex
inferred← citeshttps://doi.org/10.1016/s0010-8545(02)00276-xopenalex-snapshot
The chemistry of the carbon-transition metal double and triple bond: annual survey covering the year 2001
inferred← citeshttps://doi.org/10.1016/s0022-328x(03)00210-9openalex-snapshot
Ligand influences on hydrogen migration in transition metal hydrido–carbyne complexes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.7b02186openalex-snapshot
Manipulation and Assessment of Charge and Spin Delocalization in Mixed-Valent Triarylamine–Vinylruthenium Conjugates
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.8b03253openalex-snapshot
Mixed-Valent Ruthenocene–Vinylruthenium Conjugates: Valence Delocalization Despite Chemically Different Redox Sites
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00116openalex-snapshot
Self-Assembled Redox-Active Tetraruthenium Macrocycles with Large Intracyclic Cavities
inferred← citeshttps://doi.org/10.1021/acs.organomet.1c00619openalex-snapshot
Charge and Spin Delocalization in Mixed-Valent Vinylruthenium–Triarylamine-Conjugates with Planarized Triarylamines
inferred← citeshttps://doi.org/10.1021/acs.organomet.5b00401openalex-snapshot
Ruthenium Styryl Complexes with Ligands Derived from 2-Hydroxy- and 2-Mercaptopyridine and 2-Hydroxy- and 2-Mercaptoquinoline
inferred← citeshttps://doi.org/10.1021/ic400335yopenalex-snapshot
Multimetallic Complexes and Functionalized Nanoparticles Based on Oxygen- and Nitrogen-Donor Combinations
inferred← citeshttps://doi.org/10.1021/om1002123openalex-snapshot
Multifunctional Dithiocarbamates: Synthesis and Ring-Closing Metathesis of Diallyldithiocarbamate Complexes
inferred← citeshttps://doi.org/10.1021/om5011269openalex-snapshot
Multimetallic Alkenyl Complexes Bearing Macrocyclic Dithiocarbamate Ligands
inferred← citeshttps://doi.org/10.1021/om7002915openalex-snapshot
α-Substituted Alkenyl and α-Disubstituted Alkylidene Complexes with the OsCl(CO)(PiPr3)2 Skeleton
inferred← citeshttps://doi.org/10.1021/om800686fopenalex-snapshot
Multimetallic Arrays: Symmetrical and Unsymmetrical Bi-, Tri-, and Tetrametallic Organometallic Complexes of Ruthenium(II) and Osmium(II)
inferred← citeshttps://doi.org/10.1021/om900459xopenalex-snapshot
From Alkynes to Carbenes Mediated by [Re(Br)(H)(NO)(PR3)2] (R = Cy, iPr) Complexes
inferred← citeshttps://doi.org/10.1021/om900541ropenalex-snapshot
Ethylene Coordination and Acetylene Dimerization at Tp′IrIII Centers
inferred← citeshttps://doi.org/10.1039/b109666bopenalex-snapshot
20 Organometallic chemistry of monometallic species
inferred← citeshttps://doi.org/10.1039/b212025aopenalex-snapshot
Evaluation of energies of isomeric SO2 complexesElectronic supplementary information (ESI) available: DFT geometry optimized structures of isomeric RuCl(CO)(PMe3)2HSO2. See http://www.rsc.org/suppdata/nj/b2/b212025a/
inferred← citeshttps://doi.org/10.1039/b501906kopenalex-snapshot
σ-Organyl complexes of ruthenium and osmium supported by a mixed-donor ligand
inferred← citeshttps://doi.org/10.1039/b901822kopenalex-snapshot
Bimetallic complexes based on carboxylate and xanthate ligands: Synthesis and electrochemical investigations
inferred← citeshttps://doi.org/10.1039/c1dt10048copenalex-snapshot
Dithiocarboxylate complexes of ruthenium(ii) and osmium(ii)
inferred← citeshttps://doi.org/10.1039/c1ra00973gopenalex-snapshot
Synthesis and reactivity of dialkyldithiophosphate complexes of ruthenium( ii )
inferred← citeshttps://doi.org/10.1039/d5qo00563aopenalex-snapshot
Selective deuteration of terminal olefins with D 2 O by catalysis of osmium-hydride complexes
inferred← citeshttps://doi.org/10.1515/irm-2012-0005openalex-snapshot
Vinylruthenium-triarylamine conjugates as electroswitchable polyelectrochromic NIR dyes
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