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A unified survey of Si–H and H–H bond activation catalysed by electron-deficient boranes

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Metal‐Free Deoxygenation of Carbohydrates
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Metal‐Free Hydrogenation of Unsaturated Hydrocarbons Employing Molecular Hydrogen
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The Highly Lewis Acidic Dicationic Phosphonium Salt: [(SIMes)PFPh2][B(C6F5)4]2
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Metal‐Free Hydrogenation Catalyzed by an Air‐Stable Borane: Use of Solvent as a Frustrated Lewis Base
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B(C6F5)3‐Catalyzed Hydrogenation of Oxime Ethers without Cleavage of the NO Bond
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A Highly cis‐Selective and Enantioselective Metal‐Free Hydrogenation of 2,3‐Disubstituted Quinoxalines
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Enantioselective Metal‐Free Hydrogenation Catalyzed by Chiral Frustrated Lewis Pairs
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Borohydrides from Organic Hydrides: Reactions of Hantzsch’s Esters with B(C6F5)3
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Catalytic Hydrogenation with Frustrated Lewis Pairs: Selectivity Achieved by Size‐Exclusion Design of Lewis Acids
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Enantioselective Hydrosilylation with Chiral Frustrated Lewis Pairs
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Illuminating the Mechanism of the Borane‐Catalyzed Hydrosilylation of Imines with Both an Axially Chiral Borane and Silane
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Metal‐Free Polymerization of Phenylsilane: Tris(pentafluorophenyl)borane‐Catalyzed Synthesis of Branched Polysilanes at Elevated Temperatures
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On the Mechanism of Hydrogen Activation by Frustrated Lewis Pairs
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Ab Initio Molecular Dynamics Study of Hydrogen Cleavage by a Lewis Base [tBu3P] and a Lewis Acid [B(C6F5)3] at the Mesoscopic Level—Dynamics in the Solute–Solvent Molecular Clusters
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2‐Hydroxybenzocyclobutenone Ethylene Dithioacetals as Precursors of Highly Substituted 1,4‐Dihydronaphthalenes
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Influence of Lewis Acid and Solvent in the Hydrosilylation of Aldehydes and Ketones with Et3SiH; Tris(pentafluorophenyl)borane B(C6F5)3 versus Metal Triflates [M(OTf)3; M = Sc, Bi, Ga, and Al] – Mechanistic Implications
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B(C6F5)3‐Catalyzed Reduction of Ketones and Imines Using Silicon‐Stereogenic Silanes: Stereoinduction by Single‐Point Binding
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Salt‐Free Preparation of Trimethylsilyl Ethers by B(C6F5)3‐Catalyzed Transfer Silylation by Using a Me3SiH Surrogate
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Copolycondensation of Regular Functional Silane and Siloxane in Aqueous Emulsion Using B(C6F5)3 as a Catalyst
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Extension of the Application of Piers‐Rubinsztajn Conditions to Produce Triarylamine Pendant Dimethylsiloxane Copolymers
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B(C6F5)3 catalyzed dehydrocarbon polycondensation of PhSiH3 with (MeO)4Si as model polyfunctional comonomers in new route to hydrophobic silicone TQ resins
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Oligo(ethylene glycol)-functionalized disiloxanes as electrolytes for lithium-ion batteries
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Anhydrous formation of foamed silicone elastomers using the Piers–Rubinsztajn reaction
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Reductive etherification of carbonyl compounds with alkyl trimethylsilylethers using polymethylhydrosiloxane (PMHS) and catalytic B(C 6 F 5 ) 3
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Total synthesis of (±)-heliannuol C and E via aromatic Claisen rearrangement
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Synthesis of trisubstituted alkenes by reductive dehydroxylation of Baylis–Hillman adducts using polymethylhydrosiloxane (PMHS) and catalytic B(C6F5)3
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A novel reduction reaction for the conversion of aldehydes, ketones and primary, secondary and tertiary alcohols into their corresponding alkanes
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An efficient metal-free reduction using diphenylsilane with (tris–perfluorophenyl)borane as catalyst
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B(C6F5)3: an efficient catalyst for reductive alkylation of alkoxy benzenes and for synthesis of triarylmethanes using aldehydes
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Metal-free asymmetric hydrogenation and hydrosilylation catalyzed by frustrated Lewis pairs
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Perfluorophenyl derivatives of the elements
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Perfluorophenyl derivatives of the elements
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Silane reductions in acidic media
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Lewis acid catalyzed stereoselective hydrosilylation of ketones under the control of σ–π chelation
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B(C 6 F 5 ) 3 catalyzed hydrosilation of enones and silyl enol ethers
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B(C6F5)3-catalyzed silylation versus reduction of phosphonic and phosphinic esters with hydrosilanes
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A novel reduction of alcohols and ethers with a HSiEt3catalytic B(C6F5)3 system
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The Chemistry of Perfluoroaryl Boranes
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Frustrated Lewis Pairs: From Concept to Catalysis
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Synthesis and Ionic Conductivity of Cyclosiloxanes with Ethyleneoxy-Containing Substituents
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Cocatalysts for Metal-Catalyzed Olefin Polymerization: Activators, Activation Processes, and Structure−Activity Relationships
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Mechanistic Aspects of Bond Activation with Perfluoroarylboranes
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Metal-Free Catalytic Hydrogenation of Polar Substrates by Frustrated Lewis Pairs
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Unusual Concerted Lewis Acid−Lewis Base Mechanism for Hydrogen Activation by a Phosphine−Borane Compound
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Cation-like homogeneous olefin polymerization catalysts based upon zirconocene alkyls and tris(pentafluorophenyl)borane
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Cationic Zirconocene Olefin Polymerization Catalysts Based on the Organo-Lewis Acid Tris(pentafluorophenyl)borane. A Synthetic,Structural, Solution Dynamic, and Polymerization Catalytic Study
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Facile Heterolytic Cleavage of Dihydrogen by Phosphines and Boranes
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Rapid Assembly of Complex 3D Siloxane Architectures
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Metal-Free Aromatic Hydrogenation: Aniline to Cyclohexyl-amine Derivatives
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Improved Performance of Protected Catecholic Polysiloxanes for Bioinspired Wet Adhesion to Surface Oxides
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Reactivity Models of Hydrogen Activation by Frustrated Lewis Pairs: Synergistic Electron Transfers or Polarization by Electric Field?
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Chiral Dienes as “Ligands” for Borane-Catalyzed Metal-Free Asymmetric Hydrogenation of Imines
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Metal-Free Borane-Catalyzed Highly Stereoselective Hydrogenation of Pyridines
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Experimental Analysis of the Catalytic Cycle of the Borane-Promoted Imine Reduction with Hydrosilanes: Spectroscopic Detection of Unexpected Intermediates and a Refined Mechanism
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Olefin Isomerization and Hydrosilylation Catalysis by Lewis Acidic Organofluorophosphonium Salts
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Surface Functionalization of Silica by Si–H Activation of Hydrosilanes
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Enabling Catalytic Ketone Hydrogenation by Frustrated Lewis Pairs
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Nonmetal Catalyzed Hydrogenation of Carbonyl Compounds
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Boron-Catalyzed Silylative Reduction of Quinolines: Selective sp 3 C–Si Bond Formation
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Molecular Tweezers for Hydrogen: Synthesis, Characterization, and Reactivity
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On the Mechanism of B(C6F5)3-Catalyzed Direct Hydrogenation of Imines: Inherent and Thermally Induced Frustration
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Tris(pentafluorophenyl)boron-Catalyzed Hydrosilation of Aromatic Aldehydes, Ketones, and Esters
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Organo-Lewis Acids As Cocatalysts in Cationic Metallocene Polymerization Catalysis. Unusual Characteristics of Sterically Encumbered Tris(perfluorobiphenyl)borane
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A Novel B(C6F5)3-Catalyzed Reduction of Alcohols and Cleavage of Aryl and Alkyl Ethers with Hydrosilanes
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A Direct Reduction of Aliphatic Aldehyde, Acyl Chloride, Ester, and Carboxylic Functions into a Methyl Group
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Synthesis of (−)-Astrogorgiadiol
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Reduction of aldehydes and ketones to alcohols and hydrocarbons through use of the organosilane-boron trifluoride system
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Highly Efficient B(C 6 F 5 ) 3 -Catalyzed Hydrosilylation of Olefins
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Synthesis of (−)-Calicoferol B
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Rapid Defunctionalization of Carbonyl Group to Methylene with Polymethylhydrosiloxane−B(C6F5)3
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Liquid Triarylamines: The Scope and Limitations of Piers–Rubinsztajn Conditions for Obtaining Triarylamine–Siloxane Hybrid Materials
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Quantum Chemical Study of B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Group
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Metal-Free Reduction of Secondary and Tertiary N-Phenyl Amides by Tris(pentafluorophenyl)boron-Catalyzed Hydrosilylation
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B(C 6 F 5 ) 3 -Catalyzed Silation of Alcohols: A Mild, General Method for Synthesis of Silyl Ethers
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Studies on the Mechanism of B(C 6 F 5 ) 3 -Catalyzed Hydrosilation of Carbonyl Functions
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Analysis of the Activation and Heterolytic Dissociation of H2by Frustrated Lewis Pairs: NH3/BX3(X = H, F, and Cl)
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A New Polycondensation Process for the Preparation of Polysiloxane Copolymers
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Tris(pentafluorophenyl)borane as a Superior Catalyst in the Synthesis of Optically Active SiO-Containing Polymers
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Oligomerization of Hydrosiloxanes in the Presence of Tris(pentafluorophenyl)borane
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The Use of Piers–Rubinsztajn Conditions for the Placement of Triarylamines Pendant to Silicone Polymers
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Hydride Transfer Ring-Opening Polymerization of a Cyclic Oligomethylhydrosiloxane. Route to a Polymer of Closed Multicyclic Structure
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Preparation of Polyaryloxysilanes and Polyaryloxysiloxanes by B(C6F5)3 Catalyzed Polyetherification of Dihydrosilanes and Bis-Phenols
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Synthesis of Highly Branched Alkoxysiloxane−Dimethylsiloxane Copolymers by Nonhydrolytic Dehydrocarbon Polycondensation Catalyzed by Tris(pentafluorophenyl)borane
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Polysiloxanes with Periodically Distributed Isomeric Double-Decker Silsesquioxane in the Main Chain
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Endowing Single-Chain Polymer Nanoparticles with Enzyme-Mimetic Activity
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B(C6F5)3-Catalyzed Hydrosilation of Imines via Silyliminium Intermediates
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B(C6F5)3-Promoted Tandem Silylation and Intramolecular Hydrosilylation: Diastereoselective Synthesis of Oxasilinanes and Oxasilepanes
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Siloxane−Triarylamine Hybrids: Discrete Room Temperature Liquid Triarylamines via the Piers−Rubinsztajn Reaction
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Amphiphilic Silicone Architectures via Anaerobic Thiol–Ene Chemistry
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Selective Reduction of Carboxylic Acids to Aldehydes Catalyzed by B(C 6 F 5 ) 3
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Silane-Controlled Diastereoselectivity in the Tris(pentafluorophenyl)borane-Catalyzed Reduction of α-Diketones to Silyl-Protected 1,2-Diols
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Synthesis and Characterization of (Perfluoroaryl)borane-Functionalized Carbosilane Dendrimers and Their Use as Lewis Acid Catalysts for the Hydrosilation of Acetophenone
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Borane-Catalyzed Hydrosilylation of Thiobenzophenone: A New Route to Silicon−Sulfur Bond Formation
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Mechanism of the B(C6F5)3-Catalyzed Reaction of Silyl Hydrides with Alkoxysilanes. Kinetic and Spectroscopic Studies
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Metal-Free Transfer Hydrogenation Catalysis by B(C6F5)3
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Activation of Alkyl C–F Bonds by B(C6F5)3: Stoichiometric and Catalytic Transformations
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Borane-Catalyzed Si–H Activation Routes to Polysilanes Containing Thiolato Side Chains
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Metal-Free Hydrogenation of N-Based Heterocycles
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Reactivity of a Titanocene Pendant Si–H Group toward Alcohols. Unexpected Formation of Siloxanes from the Reaction of Hydrosilanes and Ph3COH Catalyzed by B(C6F5)3
inferredcites →https://doi.org/10.1021/om400970jopenalex-snapshot
Structure and Solution Reactivity of (Triethylsilylium)triethylsilane Cations
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Tris(5,6,7,8-tetrafluoronaphthalen-2-yl)borane, a Partially Fluorinated Boron Lewis Acid with Fluorination Distal to the Boron Atom
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B(C 6 F 5 ) 3 -Catalyzed Synthesis of Benzofused-Siloles
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Quantum Chemical Study of the Reaction of 3-(Trimethylsilyl)cyclohexa-1,4-dienes with B(C 6 F 5 ) 3
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Direct and Transfer Hydrosilylation Reactions Catalyzed by Fully or Partially Fluorinated Triarylboranes: A Systematic Study
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Metal-Free Frustrated Lewis Pair Catalyzed 1,4-Hydrogenation of Conjugated Metallocene Dienamines
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Synthesis, Properties, and Hydroboration Activity of the Highly Electrophilic Borane Bis(pentafluorophenyl)borane, HB(C6F5)21
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Improving the Industrial Feasibility of Metal-Free Hydrogenation Catalysts Using Chemical Scavengers
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Hydrogenation by Frustrated Lewis Pairs: Main Group Alternatives to Transition Metal Catalysts?
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Direct observation of a borane–silane complex involved in frustrated Lewis-pair-mediated hydrosilylations
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Hydrostannation of C–C multiple bonds with Bu3SnH prepared in situ from Bu3SnCl and Et3SiH in the presence of Lewis acid catalysts
inferredcites →https://doi.org/10.1039/b503688gopenalex-snapshot
Tris(pentafluorophenyl)borane: a special boron Lewis acid for special reactions
inferredcites →https://doi.org/10.1039/b511344jopenalex-snapshot
Novel weak coordination to silylium ions: formation of nearly linear Si–H–Si bonds
inferredcites →https://doi.org/10.1039/b603610bopenalex-snapshot
A facile and chemoselective conjugate reduction using polymethylhydrosiloxane (PMHS) and catalytic B(C6F5)3
inferredcites →https://doi.org/10.1039/b710475hopenalex-snapshot
Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane–borane adduct
inferredcites →https://doi.org/10.1039/b718598gopenalex-snapshot
Lewis acid-catalyzed hydrogenation: B(C6F5)3-mediated reduction of imines and nitriles with H2
inferredcites →https://doi.org/10.1039/b801806eopenalex-snapshot
Metal-free catalytic hydrogenation of imines with tris(perfluorophenyl)borane
inferredcites →https://doi.org/10.1039/b802575bopenalex-snapshot
“Frustrated Lewis pairs”: a concept for new reactivity and catalysis
inferredcites →https://doi.org/10.1039/b806270fopenalex-snapshot
Toward selective functionalisation of oligosilanes: borane-catalysed dehydrogenative coupling of silanes with thiols
inferredcites →https://doi.org/10.1039/b813286kopenalex-snapshot
Heterolytic dihydrogen activation with the 1,8-bis(diphenylphosphino)naphthalene/B(C6F5)3 pair and its application for metal-free catalytic hydrogenation of silyl enol ethers
inferredcites →https://doi.org/10.1039/b819621dopenalex-snapshot
Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis
inferredcites →https://doi.org/10.1039/b905137fopenalex-snapshot
On the possibility of catalytic reduction of carbonyl moieties with tris(pentafluorophenyl)borane and H2: a computational study
inferredcites →https://doi.org/10.1039/b909620eopenalex-snapshot
Metal-free hydrogen activation and hydrogenation of imines by 1,8-bis(dipentafluorophenylboryl)naphthalene
inferredcites →https://doi.org/10.1039/c0cc00369gopenalex-snapshot
Testing the functional tolerance of the Piers–Rubinsztajn reaction: a new strategy for functional silicones
inferredcites →https://doi.org/10.1039/c0cc00719fopenalex-snapshot
Metal-free reductions of N-heterocycles via Lewis acid catalyzed hydrogenation
inferredcites →https://doi.org/10.1039/c0cc02569kopenalex-snapshot
Electric field induced activation of H2—Can DFT do the job?
inferredcites →https://doi.org/10.1039/c0cc03313hopenalex-snapshot
Activation of dihydrogen by non-metal systems
inferredcites →https://doi.org/10.1039/c0dt00400fopenalex-snapshot
Rapid assembly of explicit, functional silicones
inferredcites →https://doi.org/10.1039/c1cc10438aopenalex-snapshot
Metal-free diastereoselective catalytic hydrogenations of imines using B(C6F5)3
inferredcites →https://doi.org/10.1039/c1sc00124hopenalex-snapshot
Intramolecular frustrated N/B lewis pairs by enamine hydroboration
inferredcites →https://doi.org/10.1039/c2cc33551dopenalex-snapshot
Synthesis of allylic and homoallylic alcohols from unsaturated cyclic ethers using a mild and selective C–O reduction approach
inferredcites →https://doi.org/10.1039/c2dt30370aopenalex-snapshot
Association of frustrated phosphine–borane pairs in toluene: molecular dynamics simulations
inferredcites →https://doi.org/10.1039/c2dt30926bopenalex-snapshot
Hydrogen activation by 2-boryl-N,N-dialkylanilines: a revision of Piers’ ansa-aminoborane
inferredcites →https://doi.org/10.1039/c2ob25339aopenalex-snapshot
“Frustrated Lewis pair” hydrogenations
inferredcites →https://doi.org/10.1039/c3cc45889jopenalex-snapshot
Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]–H⋯H–[TMP]
inferredcites →https://doi.org/10.1039/c3cc47372dopenalex-snapshot
E–H (E = R 3 Si or H) bond activation by B(C 6 F 5 ) 3 and heteroarenes; competitive dehydrosilylation, hydrosilylation and hydrogenation
inferredcites →https://doi.org/10.1039/c3cc47655copenalex-snapshot
Unprecedented organocatalytic reduction of lignin model compounds to phenols and primary alcohols using hydrosilanes
inferredcites →https://doi.org/10.1039/c3cc48796bopenalex-snapshot
Hydrogen activation with perfluorinated organoboranes: 1,2,3-tris(pentafluorophenyl)-4,5,6,7-tetrafluoro-1-boraindene
inferredcites →https://doi.org/10.1039/c3cc49558bopenalex-snapshot
Catalytic metal-free Si–N cross-dehydrocoupling
inferredcites →https://doi.org/10.1039/c4cc02894eopenalex-snapshot
Efficient metal-free hydrosilylation of tertiary, secondary and primary amides to amines
inferredcites →https://doi.org/10.1039/c4cy00339jopenalex-snapshot
Catalytic hydrosilylation of oxalic acid: chemoselective formation of functionalized C 2 -products
inferredcites →https://doi.org/10.1039/c4ob02419bopenalex-snapshot
A chiral borane catalyzed asymmetric hydrosilylation of imines
inferredcites →https://doi.org/10.1039/c4py00680aopenalex-snapshot
Silicone dendrons and dendrimers from orthogonal SiH coupling reactions
inferredcites →https://doi.org/10.1039/c4sc00395kopenalex-snapshot
Frustrated Lewis pair chemistry of carbon, nitrogen and sulfur oxides
inferredcites →https://doi.org/10.1039/cs9972600345openalex-snapshot
Pentafluorophenylboranes: from obscurity to applications
inferredcites →https://doi.org/10.1055/s-0032-1318312openalex-snapshot
Frustrated Lewis Pair Catalyzed Hydrogenations
inferredcites →https://doi.org/10.1055/s-0033-1339130openalex-snapshot
Frustrated Lewis Pairs: An Elegant Concept for Catalysis
inferredcites →https://doi.org/10.1080/00397911.2013.853798openalex-snapshot
Unexpected Reduction of Indole Double Bond in Mitragynine Using n-Butylsilane and Catalytic Tris(pentaflorophenyl)borane
inferredcites →https://doi.org/10.1126/science.1134230openalex-snapshot
Reversible, Metal-Free Hydrogen Activation
inferredcites →https://doi.org/10.1295/polymj.pj2006171openalex-snapshot
Precise Synthesis of Poly(silphenylenesiloxane)s with Epoxy Side Functional Groups by Tris(pentafluorophenyl)borane as a Catalyst
inferredcites →https://doi.org/10.6023/a14040344openalex-snapshot
Frustrated Lewis Pair Catalyzed Asymmetric Hydrogenation

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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B(C6f5)3-Catalyzed Regio- and Stereoselective Cyanation of Isatogens and Their Derivatives
inferred← citeshttps://doi.org/10.1002/047084289x.rn01910openalex-snapshot
3-(Trimethylsilyl)-1,4-cyclohexadiene
inferred← citeshttps://doi.org/10.1002/047084289x.rn02098openalex-snapshot
Tri(cyclohexa-2,5-dien-1-yl)silane
inferred← citeshttps://doi.org/10.1002/9783527814787.ch2openalex-snapshot
Si ─ H Bond Activation by Main‐Group L ewis Acids
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Selective Synthesis of Silacycles by Borane‐Catalyzed Domino Hydrosilylation of Proximal Unsaturated Bonds: Tunable Approach to 1,n‐Diols
inferred← citeshttps://doi.org/10.1002/adsc.201801389openalex-snapshot
Boron‐Catalyzed C−C Functionalization of Allyl Alcohols
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Transition‐Metal‐Free Reduction of α ‐Keto Thioesters with Hydrosilanes at Room Temperature: Divergent Synthesis through Reagent‐Controlled Chemoselectivities
inferred← citeshttps://doi.org/10.1002/adsc.201901419openalex-snapshot
B(C6F5)3‐Catalyzed α‐Deuteration of Bioactive Carbonyl Compounds with D2O
inferred← citeshttps://doi.org/10.1002/adsc.202000425openalex-snapshot
Hydroalkylation of Aryl Alkenes with Organohalides Catalyzed by Molybdenum Oxido Based Lewis Pairs
inferred← citeshttps://doi.org/10.1002/adsc.202000961openalex-snapshot
Recent Advances in Asymmetric Organomulticatalysis
inferred← citeshttps://doi.org/10.1002/adsc.202001269openalex-snapshot
Boron‐Catalyzed Dehydrative Friedel‐Crafts Alkylation of Arenes Using β‐Hydroxyl Ketone as MVK Precursor
inferred← citeshttps://doi.org/10.1002/adsc.202100022openalex-snapshot
Electrochemical‐Induced Hydrogenation of Electron‐Deficient Internal Olefins and Alkynes with CH3OH as Hydrogen Donor
inferred← citeshttps://doi.org/10.1002/adsc.202100590openalex-snapshot
B(C6F5)3‐Catalyzed Hydroarylation of Terminal Alkynes with Phenols
inferred← citeshttps://doi.org/10.1002/adsc.202100819openalex-snapshot
Application of Mutualism in Organic Synthetic Chemistry: Mutually Promoted C−H Functionalization of Indole and Reduction of Quinoline
inferred← citeshttps://doi.org/10.1002/adsc.202101249openalex-snapshot
Advances in Electrochemical Hydrogenation Since 2010
inferred← citeshttps://doi.org/10.1002/adsc.202200476openalex-snapshot
Conjugate Addition of α‐Substituted Acyl Imidazoles to Nitroalkenes Catalyzed by Nickel Bisoxazoline and B(C6F5)3
inferred← citeshttps://doi.org/10.1002/adsc.202300040openalex-snapshot
Sulfonamide as Photoinduced Hydrogen Atom Transfer Catalyst for Organophotoredox Hydrosilylation and Hydrogermylation of Activated Alkenes
inferred← citeshttps://doi.org/10.1002/adsc.202300343openalex-snapshot
Electrochemical Hydrosilylation of Electron‐Withdrawing Alkenes
inferred← citeshttps://doi.org/10.1002/adsc.202300817openalex-snapshot
B(C 6 F 5 ) 3 ‐Catalyzed One‐Pot Tandem Diastereoselective Synthesis of cis ‐2,3‐Disubstituted 1,2,3,4‐Tetrahydroquinoxalines and cis ‐2,4‐Disubstituted 2,3,4,5‐Tetrahydro‐1 H ‐1,5‐benzodiazepines
inferred← citeshttps://doi.org/10.1002/adsc.202301169openalex-snapshot
Catalytic Deoxygenative Reduction of Hydrazides to Hydrazines via B(C6F5)3‐Catalyzed Hydrosilylation
inferred← citeshttps://doi.org/10.1002/adsc.202301347openalex-snapshot
B(C6F5)3‐Catalyzed N‐Allylation of Hydrazines with Allylic Alcohols
inferred← citeshttps://doi.org/10.1002/adsc.202401077openalex-snapshot
Borane‐Catalyzed Selective Transformation of Levulinic Acid and Hydrazines into Hexahydropyridazines and Tetrahydropyridazin‐3(2 H )‐ones Using Hydrosilane
inferred← citeshttps://doi.org/10.1002/adsc.70004openalex-snapshot
Facile Access to 2‐Substituted‐1,2,3,4‐Tetrahydroquinoxalines via Borane‐Catalyzed One‐Pot Tandem Cyclization/Hydrosilylation
inferred← citeshttps://doi.org/10.1002/adsc.70649openalex-snapshot
Tuning the Basicity/Nucleophilicity of Phenolate Anions Modulates Ion Pair Organocatalysis in the Reductive Functionalization of CO 2
inferred← citeshttps://doi.org/10.1002/adsc.70752openalex-snapshot
Metal‐Free and Scalable Borane‐Catalyzed Dehydrative C–N Coupling of Allylic Alcohols and Sulfonamides
inferred← citeshttps://doi.org/10.1002/agt2.149openalex-snapshot
Controlling the aggregation and assembly of boron‐containing molecular and polymeric materials
inferred← citeshttps://doi.org/10.1002/ajoc.202000584openalex-snapshot
Transition‐Metal‐Free C−H Silylation: An Emerging Strategy
inferred← citeshttps://doi.org/10.1002/ajoc.202100188openalex-snapshot
Chemo‐ and Site‐Selective Fischer Esterification Catalyzed by B(C6F5)3
inferred← citeshttps://doi.org/10.1002/ajoc.202300098openalex-snapshot
Metal‐Free Catalytic Reduction of Amides: Recent Progress
inferred← citeshttps://doi.org/10.1002/ajoc.202300198openalex-snapshot
α‐Alkylation of Mono‐Carbonyl Compounds with N‐Allylamines through Cooperative Actions of Lewis Acids and a Brønsted Base
inferred← citeshttps://doi.org/10.1002/ajoc.202400051openalex-snapshot
Palladium Catalyzed Selective 1,4‐Dihydrosilylation of Alkynones
inferred← citeshttps://doi.org/10.1002/ajoc.70480openalex-snapshot
Synthesis of Arylsilanes by Catalytic Silylation of C(sp 2 )─X Bonds: A Review From the Silicon Perspective
inferred← citeshttps://doi.org/10.1002/ange.201500750openalex-snapshot
Eine Mischung deuteriummarkierter Silane als einfache mechanistische Sonde, die ohne Bestimmung von absoluten Konfigurationen auskommt
inferred← citeshttps://doi.org/10.1002/ange.201502400openalex-snapshot
Elusive Silane–Alane Complex [SiH⋅⋅⋅Al]: Isolation, Characterization, and Multifaceted Frustrated Lewis Pair Type Catalysis
inferred← citeshttps://doi.org/10.1002/ange.201502579openalex-snapshot
Catalytic Ketone Hydrodeoxygenation Mediated by Highly Electrophilic Phosphonium Cations
inferred← citeshttps://doi.org/10.1002/ange.201503172openalex-snapshot
Bor‐katalysierte regioselektive Desoxygenierung von terminalen 1,2‐Diolen zu 2‐Alkanolen durch die strategische Bildung eines cyclischen Siloxan‐Intermediates
inferred← citeshttps://doi.org/10.1002/ange.201504941openalex-snapshot
B(C6F5)3‐katalysierter Diwasserstofftransfer von einem ungesättigten Kohlenwasserstoff auf einen anderen
inferred← citeshttps://doi.org/10.1002/ange.201507863openalex-snapshot
Metal‐Free Hydrosilylation Polymerization by Borane Catalyst
inferred← citeshttps://doi.org/10.1002/ange.201508669openalex-snapshot
Borane‐Catalyzed Reductive α‐Silylation of Conjugated Esters and Amides Leaving Carbonyl Groups Intact
inferred← citeshttps://doi.org/10.1002/ange.201508879openalex-snapshot
Transferhydrosilylierung
inferred← citeshttps://doi.org/10.1002/ange.201605198openalex-snapshot
Elektrophile Aktivierung von Silicium‐Wasserstoff‐ Bindungen in katalytischen Hydrosilierungen
inferred← citeshttps://doi.org/10.1002/ange.201606177openalex-snapshot
Tris(pentafluorophenyl)borane‐Catalyzed Acceptorless Dehydrogenation of N‐Heterocycles
inferred← citeshttps://doi.org/10.1002/ange.201608470openalex-snapshot
Elektrophile aromatische Substitution mit Siliciumelektrophilen: die katalytische Friedel‐Crafts‐C‐H‐Silylierung
inferred← citeshttps://doi.org/10.1002/ange.201608583openalex-snapshot
Direct Mannich‐Type Reactions Promoted by Frustrated Lewis Acid/Brønsted Base Catalysts
inferred← citeshttps://doi.org/10.1002/ange.201608937openalex-snapshot
(C6F5)3B Catalyzed Chemoselective and ortho‐Selective Substitution of Phenols with α‐Aryl α‐Diazoesters
inferred← citeshttps://doi.org/10.1002/ange.201611623openalex-snapshot
By‐Product‐Free Siloxane‐Bond Formation and Programmed One‐Pot Oligosiloxane Synthesis
inferred← citeshttps://doi.org/10.1002/ange.201611813openalex-snapshot
B(C6F5)3‐katalysierte chemoselektive Defunktionalisierung von etherhaltigen primären Alkyltosylaten mit Hydrosilanen
inferred← citeshttps://doi.org/10.1002/ange.201702304openalex-snapshot
B(C6F5)3‐Catalyzed Cascade Reduction of Pyridines
inferred← citeshttps://doi.org/10.1002/ange.201704789openalex-snapshot
Stöchiometrische und katalytische C‐C‐ und C‐H‐Bindungsbildung mit B(C6F5)3 über kationische Zwischenstufen
inferred← citeshttps://doi.org/10.1002/ange.201704936openalex-snapshot
Catalytic Reductive Pinacol‐Type Rearrangement of Unactivated 1,2‐Diols through a Concerted, Stereoinvertive Mechanism
inferred← citeshttps://doi.org/10.1002/ange.201708103openalex-snapshot
Enantioselective Direct Mannich‐Type Reactions Catalyzed by Frustrated Lewis Acid/Brønsted Base Complexes
inferred← citeshttps://doi.org/10.1002/ange.201708109openalex-snapshot
Selective C−O Bond Cleavage of Sugars with Hydrosilanes Catalyzed by Piers’ Borane Generated In Situ
inferred← citeshttps://doi.org/10.1002/ange.201710782openalex-snapshot
Die Schöne (WCA) und das (kationische) Biest: Neues aus der Chemie von und mit schwach koordinierenden Anionen
inferred← citeshttps://doi.org/10.1002/ange.201711250openalex-snapshot
Visible‐Light‐Mediated Metal‐Free Hydrosilylation of Alkenes through Selective Hydrogen Atom Transfer for Si−H Activation
inferred← citeshttps://doi.org/10.1002/ange.201711658openalex-snapshot
Cleavage of Unstrained C−C Bonds in Acenes by Boron and Light: Transformation of Naphthalene into Benzoborepin
inferred← citeshttps://doi.org/10.1002/ange.201712155openalex-snapshot
Bis(perchlorocatecholato)silan – eine neutrale Silicium‐Lewis‐Supersäure
inferred← citeshttps://doi.org/10.1002/ange.201800483openalex-snapshot
Access to Enantioenriched Organosilanes from Enals and β‐Silyl Enones: Carbene Organocatalysis
inferred← citeshttps://doi.org/10.1002/ange.201801031openalex-snapshot
One‐Pot Sequence‐Controlled Synthesis of Oligosiloxanes
inferred← citeshttps://doi.org/10.1002/ange.201803797openalex-snapshot
Katalytische, isofunktionelle Reaktionen – Erweiterung des Repertoires an Shuttle‐ und Metathesereaktionen
inferred← citeshttps://doi.org/10.1002/ange.201808289openalex-snapshot
C2‐Symmetric Bicyclic Bisborane Catalysts: Kinetic or Thermodynamic Products of a Reversible Hydroboration of Dienes
inferred← citeshttps://doi.org/10.1002/ange.201809275openalex-snapshot
Reduktion von Phosphanoxiden mit Oxalylchlorid und Wasserstoff, vermittelt durch ein elektrophiles Phosphoniumkation
inferred← citeshttps://doi.org/10.1002/ange.201809533openalex-snapshot
B(C6F5)3/Amine‐Catalyzed C(sp)−H Silylation of Terminal Alkynes with Hydrosilanes: Experimental and Theoretical Studies
inferred← citeshttps://doi.org/10.1002/ange.201811574openalex-snapshot
Borane‐Catalyzed Cross‐Metathesis Strategy for Facile Transformation of Cyclic (Alkyl)(Amino)Germylenes
inferred← citeshttps://doi.org/10.1002/ange.201811729openalex-snapshot
Chemoselective Borane‐Catalyzed Hydroarylation of 1,3‐Dienes with Phenols
inferred← citeshttps://doi.org/10.1002/ange.201900907openalex-snapshot
Spiro‐Bicyclic Bisborane Catalysts for Metal‐Free Chemoselective and Enantioselective Hydrogenation of Quinolines
inferred← citeshttps://doi.org/10.1002/ange.201902499openalex-snapshot
Sequential C−H Borylation and N‐Demethylation of 1,1′‐Biphenylamines: Alternative Route to Polycyclic BN‐Heteroarenes
inferred← citeshttps://doi.org/10.1002/ange.201909852openalex-snapshot
Lewis Säure‐katalysierte Transferhydromethallylierung für den Aufbau quartärer Kohlenstoffzentren
inferred← citeshttps://doi.org/10.1002/ange.201914568openalex-snapshot
Asymmetric Hydrogenation of Ketones and Enones with Chiral Lewis Base Derived Frustrated Lewis Pairs
inferred← citeshttps://doi.org/10.1002/ange.202004651openalex-snapshot
Reduktive Desaminierung mit Hydrosilanen katalysiert durch B(C6F5)3
inferred← citeshttps://doi.org/10.1002/ange.202005925openalex-snapshot
Shedding Light on the Diverse Reactivity of NacNacAl with N‐Heterocycles
inferred← citeshttps://doi.org/10.1002/ange.202007176openalex-snapshot
Triarylboran‐katalysierte Alkenylierungen von Arylestern mit Diazoverbindungen
inferred← citeshttps://doi.org/10.1002/ange.202007352openalex-snapshot
Borane‐Catalyzed Chemoselective and Enantioselective Reduction of 2‐Vinyl‐Substituted Pyridines
inferred← citeshttps://doi.org/10.1002/ange.202007415openalex-snapshot
Modulating Electrostatic Interactions in Ion Pair Intermediates To Alter Site Selectivity in the C−O Deoxygenation of Sugars
inferred← citeshttps://doi.org/10.1002/ange.202011372openalex-snapshot
Reversible Silylium Transfer between P‐H and Si‐H Donors
inferred← citeshttps://doi.org/10.1002/ange.202012287openalex-snapshot
Towards Naked Zinc(II) in the Condensed Phase: A Highly Lewis Acidic ZnII Dication Stabilized by Weakly Coordinating Carborate Anions
inferred← citeshttps://doi.org/10.1002/ange.202106168openalex-snapshot
Bifunctional Borane Catalysis of a Hydride Transfer/Enantioselective [2+2] Cycloaddition Cascade
inferred← citeshttps://doi.org/10.1002/ange.202109744openalex-snapshot
Tris(pentafluorphenyl)boran‐katalysierte Erzeugung von Carbenium‐Ionen und autokatalytische Pyrazol‐Synthese – eine theoretische und experimentelle Studie
inferred← citeshttps://doi.org/10.1002/ange.202200100openalex-snapshot
Asymmetric Intramolecular Hydroalkoxylation of 2‐Vinylbenzyl Alcohols with Chiral Boro‐Phosphates
inferred← citeshttps://doi.org/10.1002/ange.202216959openalex-snapshot
Bor‐Zentrierte Lewis‐Supersäuren durch Redoxaktive Liganden: Anwendung in der C‐F‐ und S‐F‐Bindungsaktivierung
inferred← citeshttps://doi.org/10.1002/ange.202305449openalex-snapshot
Borane‐Catalyzed Tandem Cyclization/Hydrosilylation Towards Enantio‐ and Diastereoselective Construction of trans‐2,3‐Disubstituted‐1,2,3,4‐Tetrahydroquinoxalines
inferred← citeshttps://doi.org/10.1002/ange.202313957openalex-snapshot
Stereoselective Hydrosilylation of 1,2‐Diketones Catalyzed by Chiral Frustrated Lewis Pairs
inferred← citeshttps://doi.org/10.1002/ange.202504676openalex-snapshot
Merging Photocatalysis with Chiral Lewis Acid Catalysis for Enantioselective Hydrosilylation/Hydrogermylation of Electron‐Deficient Alkenes
inferred← citeshttps://doi.org/10.1002/ange.202506266openalex-snapshot
Stable Mg 2+ Dication Weakly Stabilized/Coordinated in Solution: Synthesis, Structure, Reactivity, and Use in Catalysis
inferred← citeshttps://doi.org/10.1002/anie.201500750openalex-snapshot
A Constellation of Deuterium‐Labeled Silanes as a Simple Mechanistic Probe not Requiring Absolute Configuration Determination
inferred← citeshttps://doi.org/10.1002/anie.201502400openalex-snapshot
Elusive Silane–Alane Complex [SiH⋅⋅⋅Al]: Isolation, Characterization, and Multifaceted Frustrated Lewis Pair Type Catalysis
inferred← citeshttps://doi.org/10.1002/anie.201502579openalex-snapshot
Catalytic Ketone Hydrodeoxygenation Mediated by Highly Electrophilic Phosphonium Cations
inferred← citeshttps://doi.org/10.1002/anie.201503172openalex-snapshot
Boron‐Catalyzed Regioselective Deoxygenation of Terminal 1,2‐Diols to 2‐Alkanols Enabled by the Strategic Formation of a Cyclic Siloxane Intermediate
inferred← citeshttps://doi.org/10.1002/anie.201504941openalex-snapshot
B(C6F5)3‐Catalyzed Transfer of Dihydrogen from One Unsaturated Hydrocarbon to Another
inferred← citeshttps://doi.org/10.1002/anie.201507863openalex-snapshot
Metal‐Free Hydrosilylation Polymerization by Borane Catalyst
inferred← citeshttps://doi.org/10.1002/anie.201508669openalex-snapshot
Borane‐Catalyzed Reductive α‐Silylation of Conjugated Esters and Amides Leaving Carbonyl Groups Intact
inferred← citeshttps://doi.org/10.1002/anie.201508879openalex-snapshot
Transfer Hydrosilylation
inferred← citeshttps://doi.org/10.1002/anie.201605198openalex-snapshot
Electrophilic Activation of Silicon–Hydrogen Bonds in Catalytic Hydrosilations
inferred← citeshttps://doi.org/10.1002/anie.201606177openalex-snapshot
Tris(pentafluorophenyl)borane‐Catalyzed Acceptorless Dehydrogenation of N‐Heterocycles
inferred← citeshttps://doi.org/10.1002/anie.201608470openalex-snapshot
Electrophilic Aromatic Substitution with Silicon Electrophiles: Catalytic Friedel–Crafts C−H Silylation
inferred← citeshttps://doi.org/10.1002/anie.201608583openalex-snapshot
Direct Mannich‐Type Reactions Promoted by Frustrated Lewis Acid/Brønsted Base Catalysts
inferred← citeshttps://doi.org/10.1002/anie.201608937openalex-snapshot
(C6F5)3B Catalyzed Chemoselective and ortho‐Selective Substitution of Phenols with α‐Aryl α‐Diazoesters
inferred← citeshttps://doi.org/10.1002/anie.201611623openalex-snapshot
By‐Product‐Free Siloxane‐Bond Formation and Programmed One‐Pot Oligosiloxane Synthesis
inferred← citeshttps://doi.org/10.1002/anie.201611813openalex-snapshot
B(C 6 F 5 ) 3 ‐Catalyzed Chemoselective Defunctionalization of Ether‐Containing Primary Alkyl Tosylates with Hydrosilanes
inferred← citeshttps://doi.org/10.1002/anie.201702304openalex-snapshot
B(C 6 F 5 ) 3 ‐Catalyzed Cascade Reduction of Pyridines
inferred← citeshttps://doi.org/10.1002/anie.201704789openalex-snapshot
Stoichiometric and Catalytic C−C and C−H Bond Formation with B(C6F5)3 via Cationic Intermediates
inferred← citeshttps://doi.org/10.1002/anie.201704936openalex-snapshot
Catalytic Reductive Pinacol‐Type Rearrangement of Unactivated 1,2‐Diols through a Concerted, Stereoinvertive Mechanism
inferred← citeshttps://doi.org/10.1002/anie.201708103openalex-snapshot
Enantioselective Direct Mannich‐Type Reactions Catalyzed by Frustrated Lewis Acid/Brønsted Base Complexes
inferred← citeshttps://doi.org/10.1002/anie.201708109openalex-snapshot
Selective C−O Bond Cleavage of Sugars with Hydrosilanes Catalyzed by Piers’ Borane Generated In Situ
inferred← citeshttps://doi.org/10.1002/anie.201710782openalex-snapshot
Taming the Cationic Beast: Novel Developments in the Synthesis and Application of Weakly Coordinating Anions
inferred← citeshttps://doi.org/10.1002/anie.201711250openalex-snapshot
Visible‐Light‐Mediated Metal‐Free Hydrosilylation of Alkenes through Selective Hydrogen Atom Transfer for Si−H Activation
inferred← citeshttps://doi.org/10.1002/anie.201711658openalex-snapshot
Cleavage of Unstrained C−C Bonds in Acenes by Boron and Light: Transformation of Naphthalene into Benzoborepin
inferred← citeshttps://doi.org/10.1002/anie.201712155openalex-snapshot
Bis(perchlorocatecholato)silane—A Neutral Silicon Lewis Super Acid
inferred← citeshttps://doi.org/10.1002/anie.201800483openalex-snapshot
Access to Enantioenriched Organosilanes from Enals and β‐Silyl Enones: Carbene Organocatalysis
inferred← citeshttps://doi.org/10.1002/anie.201801031openalex-snapshot
One‐Pot Sequence‐Controlled Synthesis of Oligosiloxanes
inferred← citeshttps://doi.org/10.1002/anie.201803797openalex-snapshot
Catalytic Isofunctional Reactions—Expanding the Repertoire of Shuttle and Metathesis Reactions
inferred← citeshttps://doi.org/10.1002/anie.201808289openalex-snapshot
C2‐Symmetric Bicyclic Bisborane Catalysts: Kinetic or Thermodynamic Products of a Reversible Hydroboration of Dienes
inferred← citeshttps://doi.org/10.1002/anie.201809275openalex-snapshot
Electrophilic Phosphonium Cation‐Mediated Phosphane Oxide Reduction Using Oxalyl Chloride and Hydrogen
inferred← citeshttps://doi.org/10.1002/anie.201809533openalex-snapshot
B(C 6 F 5 ) 3 /Amine‐Catalyzed C(sp)−H Silylation of Terminal Alkynes with Hydrosilanes: Experimental and Theoretical Studies
inferred← citeshttps://doi.org/10.1002/anie.201811574openalex-snapshot
Borane‐Catalyzed Cross‐Metathesis Strategy for Facile Transformation of Cyclic (Alkyl)(Amino)Germylenes
inferred← citeshttps://doi.org/10.1002/anie.201811729openalex-snapshot
Chemoselective Borane‐Catalyzed Hydroarylation of 1,3‐Dienes with Phenols
inferred← citeshttps://doi.org/10.1002/anie.201900907openalex-snapshot
Spiro‐Bicyclic Bisborane Catalysts for Metal‐Free Chemoselective and Enantioselective Hydrogenation of Quinolines
inferred← citeshttps://doi.org/10.1002/anie.201902499openalex-snapshot
Sequential C−H Borylation and N‐Demethylation of 1,1′‐Biphenylamines: Alternative Route to Polycyclic BN‐Heteroarenes
inferred← citeshttps://doi.org/10.1002/anie.201909852openalex-snapshot
Lewis Acid Catalyzed Transfer Hydromethallylation for the Construction of Quaternary Carbon Centers
inferred← citeshttps://doi.org/10.1002/anie.201914568openalex-snapshot
Asymmetric Hydrogenation of Ketones and Enones with Chiral Lewis Base Derived Frustrated Lewis Pairs
inferred← citeshttps://doi.org/10.1002/anie.202004651openalex-snapshot
Reductive Deamination with Hydrosilanes Catalyzed by B(C 6 F 5 ) 3
inferred← citeshttps://doi.org/10.1002/anie.202005925openalex-snapshot
Shedding Light on the Diverse Reactivity of NacNacAl with N‐Heterocycles
inferred← citeshttps://doi.org/10.1002/anie.202007176openalex-snapshot
Triarylborane‐Catalyzed Alkenylation Reactions of Aryl Esters with Diazo Compounds
inferred← citeshttps://doi.org/10.1002/anie.202007352openalex-snapshot
Borane‐Catalyzed Chemoselective and Enantioselective Reduction of 2‐Vinyl‐Substituted Pyridines
inferred← citeshttps://doi.org/10.1002/anie.202007415openalex-snapshot
Modulating Electrostatic Interactions in Ion Pair Intermediates To Alter Site Selectivity in the C−O Deoxygenation of Sugars
inferred← citeshttps://doi.org/10.1002/anie.202011372openalex-snapshot
Reversible Silylium Transfer between P‐H and Si‐H Donors
inferred← citeshttps://doi.org/10.1002/anie.202012287openalex-snapshot
Towards Naked Zinc(II) in the Condensed Phase: A Highly Lewis Acidic ZnII Dication Stabilized by Weakly Coordinating Carborate Anions
inferred← citeshttps://doi.org/10.1002/anie.202106168openalex-snapshot
Bifunctional Borane Catalysis of a Hydride Transfer/Enantioselective [2+2] Cycloaddition Cascade
inferred← citeshttps://doi.org/10.1002/anie.202109744openalex-snapshot
Tris(pentafluorophenyl)borane‐Catalyzed Carbenium Ion Generation and Autocatalytic Pyrazole Synthesis—A Computational and Experimental Study
inferred← citeshttps://doi.org/10.1002/anie.202200100openalex-snapshot
Asymmetric Intramolecular Hydroalkoxylation of 2‐Vinylbenzyl Alcohols with Chiral Boro‐Phosphates
inferred← citeshttps://doi.org/10.1002/anie.202216959openalex-snapshot
Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation
inferred← citeshttps://doi.org/10.1002/anie.202305449openalex-snapshot
Borane‐Catalyzed Tandem Cyclization/Hydrosilylation Towards Enantio‐ and Diastereoselective Construction of trans‐2,3‐Disubstituted‐1,2,3,4‐Tetrahydroquinoxalines
inferred← citeshttps://doi.org/10.1002/anie.202313957openalex-snapshot
Stereoselective Hydrosilylation of 1,2‐Diketones Catalyzed by Chiral Frustrated Lewis Pairs
inferred← citeshttps://doi.org/10.1002/anie.202504676openalex-snapshot
Merging Photocatalysis with Chiral Lewis Acid Catalysis for Enantioselective Hydrosilylation/Hydrogermylation of Electron‐Deficient Alkenes
inferred← citeshttps://doi.org/10.1002/anie.202506266openalex-snapshot
Stable Mg 2+ Dication Weakly Stabilized/Coordinated in Solution: Synthesis, Structure, Reactivity, and Use in Catalysis
inferred← citeshttps://doi.org/10.1002/aoc.4442openalex-snapshot
B(C6F5)3 catalysis accelerates the hydrosilane chlorination by Ph3CCl
inferred← citeshttps://doi.org/10.1002/asia.201701796openalex-snapshot
Boron‐Based Catalysts for C−C Bond‐Formation Reactions
inferred← citeshttps://doi.org/10.1002/asia.201801156openalex-snapshot
Comprehensive Insight into the Hydrogen Bonding of Silanes
inferred← citeshttps://doi.org/10.1002/asia.201900330openalex-snapshot
Catalytic Reduction of Cyclic Ethers with Hydrosilanes
inferred← citeshttps://doi.org/10.1002/asia.202400208openalex-snapshot
Homogeneous and Heterogeneous Frustrated Lewis Pairs for the Activation and Transformation of CO2
inferred← citeshttps://doi.org/10.1002/asia.202401840openalex-snapshot
Mechanistic Insights Into the B(C 6 F 5 ) 3 ‐catalyzed Wolff Rearrangement/[2 + 2] and [4 + 2] Cascade Cyclization of α‐Diazoketones With Imines
inferred← citeshttps://doi.org/10.1002/cctc.201500348openalex-snapshot
An Iron Catalyst for Asymmetric Alkene Hydrosilylation
inferred← citeshttps://doi.org/10.1002/cctc.201700400openalex-snapshot
Efficient and Selective Hydrosilylation of Secondary and Tertiary Amides Catalyzed by an Iridium(III) Metallacycle: Development and Mechanistic Investigation
inferred← citeshttps://doi.org/10.1002/cctc.201800077openalex-snapshot
Benzoimidazole‐Pyridylamido Zirconium and Hafnium Alkyl Complexes as Homogeneous Catalysts for Tandem Carbon Dioxide Hydrosilylation to Methane
inferred← citeshttps://doi.org/10.1002/cctc.201900172openalex-snapshot
Radical‐Initiated Dismutation of Hydrosiloxanes by Catalytic Potassium‐Graphite
inferred← citeshttps://doi.org/10.1002/cctc.202100651openalex-snapshot
Expedient Hydrofunctionalisation of Carbonyls and Imines Initiated by Phosphacyclohexadienyl Anions
inferred← citeshttps://doi.org/10.1002/cctc.202301472openalex-snapshot
Design and Synthesis of Heterogeneous Frustrated Lewis Pairs for Hydrogenation: From Molecular Immobilization to Defects Engineering
inferred← citeshttps://doi.org/10.1002/cctc.202401179openalex-snapshot
Convenient Partial Reduction of CO2 to a Useful C1 Building Block: Efficient Access to 13C‐Labelled N‐Heterocyclic Carbenes
inferred← citeshttps://doi.org/10.1002/ceur.202500327openalex-snapshot
Ring‐opening metathesis polymerization‐Derived Organoborane Polymers as Strong Lewis Acids and Luminescent Materials
inferred← citeshttps://doi.org/10.1002/chem.201503509openalex-snapshot
Extending the Scope of the B(C6F5)3‐Catalyzed CN Bond Reduction: Hydrogenation of Oxime Ethers and Hydrazones
inferred← citeshttps://doi.org/10.1002/chem.201504791openalex-snapshot
A Highly Reactive Geminal P/B Frustrated Lewis Pair: Expanding the Scope to C−X (X=Cl, Br) Bond Activation
inferred← citeshttps://doi.org/10.1002/chem.201602719openalex-snapshot
The Propargyl Rearrangement to Functionalised Allyl‐Boron and Borocation Compounds
inferred← citeshttps://doi.org/10.1002/chem.201603466openalex-snapshot
Boron Lewis Acid‐Catalyzed Hydroboration of Alkenes with Pinacolborane: BArF3 Does What B(C6F5)3 Cannot Do!
inferred← citeshttps://doi.org/10.1002/chem.201603704openalex-snapshot
Investigation of N‐Heterocyclic Carbene‐Supported Group 12 Triflates as Pre‐catalysts for Hydrosilylation/Borylation
inferred← citeshttps://doi.org/10.1002/chem.201604397openalex-snapshot
3‐ tert ‐Butyl‐Substituted Cyclohexa‐1,4‐dienes as Isobutane Equivalents in the B(C 6 F 5 ) 3 ‐Catalyzed Transfer Hydro‐ tert ‐Butylation of Alkenes
inferred← citeshttps://doi.org/10.1002/chem.201604613openalex-snapshot
N‐Methyl‐Benzothiazolium Salts as Carbon Lewis Acids for Si−H σ‐Bond Activation and Catalytic (De)hydrosilylation
inferred← citeshttps://doi.org/10.1002/chem.201604630openalex-snapshot
Cooperative Activation of Isocyanates by Al–N‐Based Active Lewis Pairs and the Generation of a C5 Chain by Simultaneous Formation of Two C–C Bonds
inferred← citeshttps://doi.org/10.1002/chem.201605466openalex-snapshot
Expanding Water/Base Tolerant Frustrated Lewis Pair Chemistry to Alkylamines Enables Broad Scope Reductive Aminations
inferred← citeshttps://doi.org/10.1002/chem.201701944openalex-snapshot
β‐Hydroxy‐tetrahydroquinolines from Quinolines Using Chloroborane: Synthesis of the Peptidomimetic FISLE‐412
inferred← citeshttps://doi.org/10.1002/chem.201703644openalex-snapshot
N‐Phosphine Oxide‐Substituted Imidazolylidenes (PoxIms): Multifunctional Multipurpose Carbenes
inferred← citeshttps://doi.org/10.1002/chem.201703798openalex-snapshot
Transition‐Metal‐Free Cleavage of CO
inferred← citeshttps://doi.org/10.1002/chem.201704382openalex-snapshot
Accessing Two‐Coordinate ZnII Organocations by NHC Coordination: Synthesis, Structure, and Use as π‐Lewis Acids in Alkene, Alkyne, and CO2 Hydrosilylation
inferred← citeshttps://doi.org/10.1002/chem.201800123openalex-snapshot
New Control Over Silicone Synthesis using SiH Chemistry: The Piers–Rubinsztajn Reaction
inferred← citeshttps://doi.org/10.1002/chem.201800226openalex-snapshot
Heterolytic Si−H Bond Cleavage at a Molybdenum‐Oxido‐Based Lewis Pair
inferred← citeshttps://doi.org/10.1002/chem.201800609openalex-snapshot
Three‐Coordinate Boron(III) and Diboron(II) Dications
inferred← citeshttps://doi.org/10.1002/chem.201800958openalex-snapshot
Silylative Reductive Amination of α,β‐Unsaturated Aldehydes: A Convenient Synthetic Route to β‐Silylated Secondary Amines
inferred← citeshttps://doi.org/10.1002/chem.201803370openalex-snapshot
Cationic Complexes of Boron and Aluminum: An Early 21st Century Viewpoint
inferred← citeshttps://doi.org/10.1002/chem.201803565openalex-snapshot
Sequence‐Controlled Catalytic One‐Pot Synthesis of Siloxane Oligomers
inferred← citeshttps://doi.org/10.1002/chem.201803921openalex-snapshot
Lewis Base Catalyzed Selective Chlorination of Monosilanes
inferred← citeshttps://doi.org/10.1002/chem.201805208openalex-snapshot
Size‐Exclusion Borane‐Catalyzed Domino 1,3‐Allylic/Reductive Ireland–Claisen Rearrangements: Impact of the Electronic and Structural Parameters on the 1,3‐Allylic Shift Aptitude
inferred← citeshttps://doi.org/10.1002/chem.201900961openalex-snapshot
Cyclic(Alkyl)(Amino)Carbene (CAAC)‐Supported Zn Alkyls: Synthesis, Structure and Reactivity in Hydrosilylation Catalysis
inferred← citeshttps://doi.org/10.1002/chem.201902082openalex-snapshot
Bioinspired Metal‐Free Formal Decarbonylation of α‐Branched Aliphatic Aldehydes at Ambient Temperature
inferred← citeshttps://doi.org/10.1002/chem.201904084openalex-snapshot
Frustrated Lewis Pair Chemistry Enables N2 Borylation by Formal 1,3‐Addition of a B−H Bond in the Coordination Sphere of Tungsten
inferred← citeshttps://doi.org/10.1002/chem.202003319openalex-snapshot
Methylene Bridging Effect on the Structures, Lewis Acidities and Optical Properties of Semi‐planar Triarylboranes
inferred← citeshttps://doi.org/10.1002/chem.202004408openalex-snapshot
Partnering a Three‐Coordinate Gallium Cation with a Hydroborate Counter‐Ion for the Catalytic Hydrosilylation of CO2
inferred← citeshttps://doi.org/10.1002/chem.202100877openalex-snapshot
Metal‐Free Hydrosilylation of Ketenes with Silicon Electrophiles: Access to Fully Substituted Aldehyde‐Derived Silyl Enol Ethers
inferred← citeshttps://doi.org/10.1002/chem.202104318openalex-snapshot
Hydrogen‐Bridged Oligosilanylsilyl Mono‐ and Oligosilanylsilyl Dications
inferred← citeshttps://doi.org/10.1002/chem.202104464openalex-snapshot
Competition for Hydride Between Silicon and Boron: Synthesis and Characterization of a Hydroborane‐Stabilized Silylium Ion
inferred← citeshttps://doi.org/10.1002/chem.202201867openalex-snapshot
Molybdenum(VI) Bis(imido) Complexes: From Frustrated Lewis Pairs to Weakly Coordinating Cations
inferred← citeshttps://doi.org/10.1002/chem.202201920openalex-snapshot
Bonding Situation of σ‐E−H Complexes in Transition Metal and Main Group Compounds
inferred← citeshttps://doi.org/10.1002/chem.202202608openalex-snapshot
Access to Enantiomerically Pure P‐Stereogenic Primary Aminophosphine Sulfides under Reductive Conditions
inferred← citeshttps://doi.org/10.1002/chem.202300798openalex-snapshot
Highly Chemoselective Zn +2 ‐Catalyzed Hydrosilylation of Alkynes
inferred← citeshttps://doi.org/10.1002/chem.202402051openalex-snapshot
Radical‐Chain Hydrosilylation of Alkenes Enabled by Triplet Energy Transfer
inferred← citeshttps://doi.org/10.1002/chem.202403496openalex-snapshot
Redox Cycling with Tellurium. Si−H Bond Activation by a Lewis Superacidic Tellurenyl Cation
inferred← citeshttps://doi.org/10.1002/chem.202500738openalex-snapshot
Unlocking the Potential of Tris(Pentafluorophenyl)Borane in Reductive Desulfurization of Thioamides With Silane
inferred← citeshttps://doi.org/10.1002/chem.71612openalex-snapshot
Hydrogen Release From Silicon─Hydrogen Systems: From Surface Chemistry to Higher‐Coordinate Molecular Mechanisms
inferred← citeshttps://doi.org/10.1002/chem.71728openalex-snapshot
Exploring the Catalytic Activity of Ge(II) and Sn(II) Cationic Crown Ether Complexes: Hydrosilylation
inferred← citeshttps://doi.org/10.1002/chin.201527278openalex-snapshot
ChemInform Abstract: A Unified Survey of Si—H and H—H Bond Activation Catalyzed by Electron‐Deficient Boranes
inferred← citeshttps://doi.org/10.1002/cjoc.201500418openalex-snapshot
Synthesis, Structural Characterization and Reactivity of a Bis(phosphine)(silyl) Platinum(II) Complex
inferred← citeshttps://doi.org/10.1002/cjoc.201600666openalex-snapshot
Synthesis, Structural Studies and Reactivity of Two cis‐Bis(phosphine)bis(silyl) Palladium( II ) Complexes
inferred← citeshttps://doi.org/10.1002/cjoc.201900121openalex-snapshot
Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of Ketones
inferred← citeshttps://doi.org/10.1002/cjoc.201900240openalex-snapshot
B(C 6 F 5 ) 3 ‐Catalyzed sp 3 C—Si Bond Forming Consecutive Reactions
inferred← citeshttps://doi.org/10.1002/cjoc.202000489openalex-snapshot
B( C 6 F 5 ) 3 ‐Catalyzed Hydroboration of Alkenes with N ‐Heterocyclic Carbene Boranes via B—H Bond Activation
inferred← citeshttps://doi.org/10.1002/cjoc.202100854openalex-snapshot
Chiral Dienes: From Ligands to FLP Catalysts
inferred← citeshttps://doi.org/10.1002/cjoc.202300675openalex-snapshot
Asymmetric Partial Hydrosilylation of 2, 2‐Difluoro ‐1,3‐diketones with Chiral Frustrated Lewis Pairs
inferred← citeshttps://doi.org/10.1002/cjoc.70245openalex-snapshot
A Novel Photocatalytic Ring Opening Reaction of Silacyclobutanes with Alkenes
inferred← citeshttps://doi.org/10.1002/cphc.202100332openalex-snapshot
Diboron Bonds Between BX3 (X=H, F, CH3) and BYZ2 (Y=H, F; Z=CO, N2, CNH)
inferred← citeshttps://doi.org/10.1002/cptc.201800110openalex-snapshot
Recent Developments in the Photo‐Mediated Generation of Silyl Radicals and Their Application in Organic Synthesis
inferred← citeshttps://doi.org/10.1002/cssc.201901764openalex-snapshot
Diverse Catalytic Systems and Mechanistic Pathways for Hydrosilylative Reduction of CO2
inferred← citeshttps://doi.org/10.1002/cssc.70600openalex-snapshot
Room‐Temperature Degradation of Lignin from Wasted Seed Coats for the Production of Pyrocatechol/Gallol Derivatives
inferred← citeshttps://doi.org/10.1002/ejic.201600764openalex-snapshot
σ‐Bond Activation in Aluminium‐Functionalized Alkynylchlorogermanes: Facile Insertion of Isocyanate and Azide into Al–C and Ge–Cl Bonds
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