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B(C6f5)3-Catalyzed Regio- and Stereoselective Cyanation of Isatogens and Their Derivatives

https://doi.org/10.2139/ssrn.4647549
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Highly enantioselective cyanosilylation of aldehydes catalyzed by a Lewis acid–Lewis base bifunctional catalyst
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Catalytic enantioselective cyanosilylation of ketones: improvement of enantioselectivity and catalyst turn-over by ligand tuning
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Austamide, a new toxic metabolite from
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Effects of brevianamide A, its photolysis product brevianamide D, and ochratoxin A from two Penicillium strains on the insect pests Spodoptera frugiperda and Heliothis virescens
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Electrochemical Oxidative Addition of Nucleophiles on 2-Arylindoles: Synthesis of C2-Heteroquaternary Indolin-3-ones
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Boron-Catalyzed Silylative Reduction of Nitriles in Accessing Primary Amines and Imines
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Selective Synthesis of 2-Indolyl-3-oxoindolines or 2-(2-Aminophenyl)quinolines through Cu(II)- or Bi(III)-Catalyzed Tunable Dimerizations of 2-Alkynylanilines
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Total Synthesis of Hinckdentine A
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Regioselective Cross-Coupling of Isatogens with Boronic Acids to Construct 2,2-Disubstituted Indolin-3-one Derivatives
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B(C 6 F 5 ) 3 -Catalyzed Reductive Denitrogenation of Benzonitrile Derivatives
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Expedited Total Synthesis of (±)-Brevianamide A via the Strategic Use of Gold(I) Catalysis
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Ru-Catalyzed Redox-Neutral Cleavage of the N–O Bond in Isoxazolidines: Isatogens to Pseudoindoxyls via a One-Pot [3 + 2]-Cycloaddition/N–O Cleavage
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Total Synthesis of (±)-Grandilodine B
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Catalytic Activation of 1-Cyano-3,3-dimethyl-3-(1 H )-1,2-benziodoxole with B(C 6 F 5 ) 3 Enabling the Electrophilic Cyanation of Silyl Enol Ethers
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Catalytic Asymmetric Mukaiyama–Mannich Reaction of Cyclic C-Acylimines with Difluoroenoxysilanes: Access to Difluoroalkylated Indolin-3-ones
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One-Pot Au[III]-/Lewis Acid Catalyzed Cycloisomerization of Nitroalkynes and [3 + 3]Cycloaddition with Donor–Acceptor Cyclopropanes
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Boron-Catalyzed Double Hydrofunctionalization Reactions of Unactivated Alkynes
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Asymmetric, stereocontrolled total synthesis of (-)-brevianamide B
inferredcites →https://doi.org/10.1021/ja001643hopenalex-extracted
Catalytic Enantioselective Cyanosilylation of Ketones
inferredcites →https://doi.org/10.1021/ja021380mopenalex-extracted
Synthesis of 8-Desbromohinckdentine A1
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Total Synthesis of (±)-Trigonoliimine C via Oxidative Rearrangement of an Unsymmetrical Bis-Tryptamine
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Rapid Access to 2,2-Disubstituted Indolines via Dearomative Indolic-Claisen Rearrangement: Concise, Enantioselective Total Synthesis of (+)-Hinckdentine A
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Activation of TMSCN by N-Heterocyclic Carbenes for Facile Cyanosilylation of Carbonyl Compounds
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Total Synthesis of (−)-Isatisine A
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Indole Alkaloids from Cephalanceropsis gracilis
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Three New Indole Alkaloids from Trigonostemon lii
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A Concise Total Synthesis of (±)-Trigonoliimine B
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Synthesis of 2-Spiropseudoindoxyls via an Intramolecular Nitroalkyne Redox–Dipolar Cycloaddition Cascade
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2-Iodoisatogens: Versatile Intermediates for the Synthesis of Nitrogen Heterocycles
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Isatisine A, a Novel Alkaloid with an Unprecedented Skeleton from Leaves of Isatis indigotica
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Stereoselective Oxidative Rearrangement of 2-Aryl Tryptamine Derivatives
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First Total Synthesis of Hinckdentine A
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Total synthesis of brevianamide A
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A modular total synthesis of (±)-trigonoliimine C
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Applications of pentafluorophenyl boron reagents in the synthesis of heterocyclic and aromatic compounds
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A unified survey of Si–H and H–H bond activation catalysed by electron-deficient boranes
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Facile access to 2,2-disubstituted indolin-3-ones via a cascade Fischer indolization/Claisen rearrangement reaction
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Chiral phosphoric acid-catalyzed direct asymmetric mannich reaction of cyclic C -acylimines with simple ketones: facile access to C2-quaternary indolin-3-ones
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C–H alkenylation/cyclization and sulfamidation of 2-phenylisatogens using N -oxide as a directing group
inferredcites →https://doi.org/10.1039/c9ob01710kopenalex-extracted
B(C 6 F 5 ) 3 -catalyzed divergent cyanosilylations of chromones dependent on temperature
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Catalytic asymmetric formal [3+2] cycloaddition of isatogens with azlactones to construct indolin-3-one derivatives
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Isolation and Structure of a Novel Biindole Pigment Substituted with an Ethyl Group from a Metagenomic Library Derived from the Marine Sponge Halichondria okadai
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Two New Cytotoxic Indole Alkaloids from a Deep-Sea Sediment Derived Metagenomic Clone
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