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ent-Kaurane-based regio- and stereoselective inverse electron demand hetero-Diels–Alder reactions: synthesis of dihydropyran-fused diterpenoids

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Pharmacognosy, Phytochemistry, Medicinal Plants

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Highly Enantio- and Diastereoselective Hetero-Diels-Alder Reactions Catalyzed by New Chiral Tridentate Chromium(III) Catalysts

inferredcites →https://doi.org/10.1002/anie.200250652openalex-snapshot

The First Organocatalytic Enantioselective Inverse‐Electron‐Demand Hetero‐Diels–Alder Reaction

inferredcites →https://doi.org/10.1002/chin.200513203openalex-snapshot

Maoecrystal V, Cytotoxic Diterpenoid with a Novel C19 Skeleton from Isodon eriocalyx (Dunn.) Hara.

inferredcites →https://doi.org/10.1002/cjoc.20020200915openalex-snapshot

A Novel Asymmetric ent‐Kauranoid Dimer from Isodon enanderianus

inferredcites →https://doi.org/10.1002/cmdc.201200559openalex-snapshot

Library Construction and Biological Evaluation of Enmein‐Type Diterpenoid Analogues as Potential Anticancer Agents

inferredcites →https://doi.org/10.1007/bf00807566openalex-snapshot

Hetero-Diels-Alder reaction of 3-aryl-2-benzoyl-2-propenenitriles with enol ethers. Synthesis of 2-alkoxy-3,4-dihydro-2H-pyran-5-carbonitriles

inferredcites →https://doi.org/10.1007/bf01937766openalex-snapshot

Antitumor activity of the isodon diterpenoids: Structural requirements for the activity

inferredcites →https://doi.org/10.1007/s10637-006-6452-1openalex-snapshot

A multi-center phase II study of sequential paclitaxel and bryostatin-1 (NSC 339555) in patients with untreated, advanced gastric or gastroesophageal junction adenocarcinoma

inferredcites →https://doi.org/10.1007/s11178-005-0118-xopenalex-snapshot

Conformational Mobility of Substituted 2-Methoxychalcones under the Action of Lanthanide Shift Reagents

inferredcites →https://doi.org/10.1016/0040-4020(95)00980-9openalex-snapshot

Exclusively endo-selective lewis acid-vatalyzed hetero diels-alder reactions of (E)-1-phenylsuifonyl-3-alken-2-ones with vinyl ethers

inferredcites →https://doi.org/10.1016/j.abb.2009.08.011openalex-snapshot

Oridonin induces G2/M arrest and apoptosis via activating ERK–p53 apoptotic pathway and inhibiting PTK–Ras–Raf–JNK survival pathway in murine fibrosarcoma L929 cells

inferredcites →https://doi.org/10.1016/j.bbrc.2005.09.040openalex-snapshot

Differential control of growth, cell cycle progression, and expression of NF-κB in human breast cancer cells MCF-7, MCF-10A, and MDA-MB-231 by ponicidin and oridonin, diterpenoids from the chinese herb Rabdosia rubescens

inferredcites →https://doi.org/10.1016/j.biocel.2011.01.020openalex-snapshot

Oridonin: An active diterpenoid targeting cell cycle arrest, apoptotic and autophagic pathways for cancer therapeutics

inferredcites →https://doi.org/10.1016/j.bmcl.2008.06.097openalex-snapshot

Synthesis and biological evaluation of novel 1-O- and 14-O-derivatives of oridonin as potential anticancer drug candidates

inferredcites →https://doi.org/10.1016/j.ejmech.2012.03.024openalex-snapshot

The conversion of oridonin to spirolactone-type or enmein-type diterpenoid: Synthesis and biological evaluation of ent-6,7-seco-oridonin derivatives as novel potential anticancer agents

inferredcites →https://doi.org/10.1016/j.ejmech.2013.04.012openalex-snapshot

Enmein-type diterpenoid analogs from natural kaurene-type oridonin: Synthesis and their antitumor biological evaluation

inferredcites →https://doi.org/10.1016/j.jss.2014.03.036openalex-snapshot

Oridonin inhibits hepatic stellate cell proliferation and fibrogenesis

inferredcites →https://doi.org/10.1016/j.tet.2009.01.068openalex-snapshot

Asymmetric hetero-Diels–Alder reactions of carbonyl compounds

inferredcites →https://doi.org/10.1016/j.tetlet.2004.02.051openalex-snapshot

Novel ent-kaurane dimers from Isodon rubescens var. rubescens

inferredcites →https://doi.org/10.1016/j.tetlet.2005.06.004openalex-snapshot

An asymmetric ent-kauranoid dimer from Isodon rubescens var. lushanensis

inferredcites →https://doi.org/10.1016/s0031-9422(00)90595-8openalex-snapshot

Maoecrystal M: A naturally occurring symmetric ent-kaurane dimer from Rabdosia eriocalyx

inferredcites →https://doi.org/10.1016/s0031-9422(01)00252-7openalex-snapshot

Semisynthetic derivatives of ent-kauranes and their antifeedant activity

inferredcites →https://doi.org/10.1016/s0040-4039(99)02187-5openalex-snapshot

Synthetic studies towards phorboxazole A. Stereoselective synthesis of the C3–C19 bis-oxane oxazole portion of the phorboxazole macrolide

inferredcites →https://doi.org/10.1021/ar700234ropenalex-snapshot

Evolution of the Petasis−Ferrier Union/Rearrangement Tactic: Construction of Architecturally Complex Natural Products Possessing the Ubiquitous cis-2,6-Substituted Tetrahydropyran Structural Element

inferredcites →https://doi.org/10.1021/ja00221a043openalex-snapshot

Total synthesis of zincophorin

inferredcites →https://doi.org/10.1021/ja0105055openalex-snapshot

Total Synthesis of (+)-Phorboxazole A

inferredcites →https://doi.org/10.1021/ja011867fopenalex-snapshot

Total Synthesis of (+)-Ambruticin S

inferredcites →https://doi.org/10.1021/ja064783lopenalex-snapshot

Racemization in Prins Cyclization Reactions

inferredcites →https://doi.org/10.1021/ja305464sopenalex-snapshot

Biomimetic Syntheses of (−)-Gochnatiolides A–C and (−)-Ainsliadimer B

inferredcites →https://doi.org/10.1021/jm400367nopenalex-snapshot

Novel Nitrogen-Enriched Oridonin Analogues with Thiazole-Fused A-Ring: Protecting Group-Free Synthesis, Enhanced Anticancer Profile, and Improved Aqueous Solubility

inferredcites →https://doi.org/10.1021/jm401248xopenalex-snapshot

Oridonin Ring A-Based Diverse Constructions of Enone Functionality: Identification of Novel Dienone Analogues Effective for Highly Aggressive Breast Cancer by Inducing Apoptosis

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A Short Olefin Metathesis-Based Route to Enantiomerically Pure Arylated Dihydropyrans and α,β-Unsaturated δ-Valero Lactones

inferredcites →https://doi.org/10.1021/jo048351+openalex-snapshot

Elaboration of d -(−)-Ribose into a Tricyclic, Natural Product-like Scaffold

inferredcites →https://doi.org/10.1021/ol0481535openalex-snapshot

Maoecrystal V, Cytotoxic Diterpenoid with a Novel C19 Skeleton from Isodon eriocalyx (Dunn.) Hara

inferredcites →https://doi.org/10.1021/ol0531379openalex-snapshot

Bisrubescensins A−C: Three New Dimeric ent-Kauranoids Isolated from Isodon rubescens

inferredcites →https://doi.org/10.1021/ol101705jopenalex-snapshot

A Biomimetic Total Synthesis of (+)-Ainsliadimer A

inferredcites →https://doi.org/10.1021/ol102296topenalex-snapshot

Synthesis of the Spirochroman Core of Dihypoestoxide and Stereochemical Proposal for the Natural Product

inferredcites →https://doi.org/10.1021/ol4015865openalex-snapshot

Overcoming Synthetic Challenges of Oridonin A-Ring Structural Diversification: Regio- and Stereoselective Installation of Azides and 1,2,3-Triazoles at the C-1, C-2, or C-3 Position

inferredcites →https://doi.org/10.1021/ol701669bopenalex-snapshot

Enantioselective Formal [3+3] Annulation for the Direct Construction of Bicyclic Skeletons with Four Stereogenic Centers

inferredcites →https://doi.org/10.1021/ol901065eopenalex-snapshot

Hetero-Diels−Alder Reactions of Cyclic Ketone Derived Enamide. A New and Efficient Concept for the Asymmetric Robinson Annulation

inferredcites →https://doi.org/10.1021/ol991326jopenalex-snapshot

First Asymmetric Synthesis of a 6-Alkoxy-5,6-dihydro-1,3-oxazine: A Promising Enantioselective Route to β-Amido Aldehydes

inferredcites →https://doi.org/10.1023/b:cohc.0000046686.33312.e6openalex-snapshot

Features of the Reaction of Heterocyclic Analogs of 2'-Alkoxychalcones with Lanthanide Shift Reagents

inferredcites →https://doi.org/10.1038/aps.2012.53openalex-snapshot

Oridonin induces apoptosis and autophagy in murine fibrosarcoma L929 cells partly via NO-ERK-p53 positive-feedback loop signaling pathway

inferredcites →https://doi.org/10.1038/sj.cdd.4401996openalex-snapshot

Eriocalyxin B induces apoptosis of t(8;21) leukemia cells through NF-κB and MAPK signaling pathways and triggers degradation of AML1-ETO oncoprotein in a caspase-3-dependent manner

inferredcites →https://doi.org/10.1039/a704463aopenalex-snapshot

Effects of lanthanide complexes on the facial reactivity of 2-(2′,3′,4′,6′-tetra-O-acetyl-β-D-glucopyranosyloxy)benzaldehyde in hetero-Diels–Alder reactions and a model to account for such effects

inferredcites →https://doi.org/10.1039/a800103kopenalex-snapshot

Facial selectivity in the cycloaddition of heterodienes to carbohydrate cyclic ketene acetals. A novel synthesis of disaccharide derivatives

inferredcites →https://doi.org/10.1039/b416247aopenalex-snapshot

Revisiting the Maitland–Japp reaction. Concise construction of highly functionalised tetrahydropyran-4-ones

inferredcites →https://doi.org/10.1039/b604174dopenalex-snapshot

Diterpenoids from Isodon species and their biological activities

inferredcites →https://doi.org/10.1039/c1ob05611eopenalex-snapshot

Synthesis and revision of stereochemistry of rubescensin S

inferredcites →https://doi.org/10.1055/s-1977-24523openalex-snapshot

The Prins Reaction

inferredcites →https://doi.org/10.1055/s-2005-871234openalex-snapshot

An Anti-Inflammatoryent-Kaurane from the Stems ofAnnona squamosathat Inhibits Various Human Neutrophil Functions

inferredcites →https://doi.org/10.1097/jto.0b013e31823f43caopenalex-snapshot

A Phase II Study of Halichondrin B Analog Eribulin Mesylate (E7389) in Patients with Advanced Non-small Cell Lung Cancer Previously Treated with a Taxane: A California Cancer Consortium Trial

inferredcites →https://doi.org/10.1111/j.1742-4658.2008.06864.xopenalex-snapshot

Autophagy inhibits reactive oxygen species‐mediated apoptosis via activating p38‐nuclear factor‐kappa B survival pathways in oridonin‐treated murine fibrosarcoma L929 cells

inferredcites →https://doi.org/10.1111/j.1745-7254.2006.00440.xopenalex-snapshot

Pharmacokinetic behaviors and oral bioavailability of oridonin in rat plasma

inferredcites →https://doi.org/10.1111/j.1745-7254.2007.00667.xopenalex-snapshot

Oridonin induces apoptosis via PI3K/Akt pathway in cervical carcinoma HeLa cell line

inferredcites →https://doi.org/10.1158/1535-7163.mct-04-0277openalex-snapshot

Oridonin, a diterpenoid purified fromRabdosia rubescens, inhibits the proliferation of cells from lymphoid malignancies in association with blockade of the NF-κB signal pathways

inferredcites →https://doi.org/10.1158/1535-7163.mct-12-0066openalex-snapshot

Triggering Fbw7-Mediated Proteasomal Degradation of c-Myc by Oridonin Induces Cell Growth Inhibition and Apoptosis

inferredcites →https://doi.org/10.1182/blood-2006-06-032250openalex-snapshot

Oridonin, a diterpenoid extracted from medicinal herbs, targets AML1-ETO fusion protein and shows potent antitumor activity with low adverse effects on t(8;21) leukemia in vitro and in vivo

inferredcites →https://doi.org/10.1246/cl.1994.145openalex-snapshot

(E)-2-Oxo-1-sulfonyl-3-alkenes as Reactive Hetero 1,3-Dienes. Absolutely endo-Selective Hetero Diels-Alder Reactions with Vinyl Ethers in the Presence of a Lewis Acid Catalyst

inferredcites →https://doi.org/10.1248/cpb.24.2118openalex-snapshot

The antitumor and antibacterial activity of the Isodon diterpenoids.

inferredcites →https://doi.org/10.2174/1385272802666220128214243openalex-snapshot

Diels-Aider Type Natural Products - Structures and Biosynthesis

inferredcites →https://doi.org/10.3390/12030455openalex-snapshot

Occurrence, Biological Activities and Synthesis of Kaurane Diterpenes and their Glycosides

inferredcites →https://doi.org/10.3724/sp.j.1009.2011.00194openalex-snapshot

Synthesis and Anti-tumor Activity of 14-O-Derivatives of Natural Oridonin

inferredcites →https://doi.org/10.3892/ijo.26.3.579openalex-snapshot

The cytostatic and cytotoxic effects of oridonin (Rubescenin), a diterpenoid from Rabdosia rubescens, on tumor cells of different lineage

inferredcites →https://doi.org/10.4161/cbt.6.2.3621openalex-snapshot

Oridonin induced apoptosis through Akt and MAPKs signaling pathways in human osteosarcoma cells

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Dimeric and esterified sesquiterpenes from the liverwort Chiastocaulon caledonicum

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Dihydropyrans by Cycloadditions of Oxadienes

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Asymmetric Total Synthesis of (−)‐Maoecrystal V

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Domino Thermal Rearrangement/[4+2] Addition Reactions of an exo‐Methylene Spirocyclopropane Isoxazolidine

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Knoevenagel‐Cyclization Cascade Reactions of Substituted 5,6‐Dihydro‐2H‐Pyran Derivatives

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Direct cellular targets and anticancer mechanisms of the natural product oridonin

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Recent progress of oridonin and its derivatives for cancer therapy and drug resistance

inferred← citeshttps://doi.org/10.1007/s11010-015-2562-4openalex-snapshot

Enhanced anti-fibrogenic effects of novel oridonin derivative CYD0692 in hepatic stellate cells

inferred← citeshttps://doi.org/10.1007/s12272-016-0867-9openalex-snapshot

Lasiokaurin derivatives: synthesis, antimicrobial and antitumor biological evaluation, and apoptosis-inducing effects

inferred← citeshttps://doi.org/10.1016/b978-0-12-824021-2.00004-2openalex-snapshot

Applications of Diels–Alder cycloaddition reaction in total synthesis of alkaloids

inferred← citeshttps://doi.org/10.1016/b978-0-444-63929-5.00005-xopenalex-snapshot

Chemistry and Bioactivity of ent -Kaurene Diterpenoids

inferred← citeshttps://doi.org/10.1016/j.bmc.2022.116977openalex-snapshot

Spirolactone-type and enmein-type derivatives as potential anti-cancer agents derived from oridonin

inferred← citeshttps://doi.org/10.1016/j.bmcl.2016.04.068openalex-snapshot

Novel anticancer oridonin derivatives possessing a diazen-1-ium-1,2-diolate nitric oxide donor moiety: Design, synthesis, biological evaluation and nitric oxide release studies

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Targeting the NRF-2/RHOA/ROCK signaling pathway with a novel aziridonin, YD0514, to suppress breast cancer progression and lung metastasis

inferred← citeshttps://doi.org/10.1016/j.ejmech.2015.01.031openalex-snapshot

Evolution in medicinal chemistry of ursolic acid derivatives as anticancer agents

inferred← citeshttps://doi.org/10.1016/j.ejmech.2016.06.015openalex-snapshot

Discovery and development of natural product oridonin-inspired anticancer agents

inferred← citeshttps://doi.org/10.1016/j.ejmech.2018.07.052openalex-snapshot

Diterpenoid lead stevioside and its hydrolysis products steviol and isosteviol: Biological activity and structural modification

inferred← citeshttps://doi.org/10.1016/j.ejmech.2019.06.006openalex-snapshot

Oridonin derivatives as potential anticancer drug candidates triggering apoptosis through mitochondrial pathway in the liver cancer cells

inferred← citeshttps://doi.org/10.1016/j.ejmech.2022.114155openalex-snapshot

Identification of new potent anticancer derivatives through simplifying the core structure and modification on their 14- hydroxyl group from oridonin

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Oridonin and its derivatives for cancer treatment and overcoming therapeutic resistance

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Enhanced effects of novel oridonin analog CYD0682 for hepatic fibrosis

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Discovery of oridonin as a novel agonist for BRS-3

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Probing the Anticancer Action of Oridonin with Fluorescent Analogues: Visualizing Subcellular Localization to Mitochondria

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Regio- and Stereospecific Synthesis of Oridonin D-Ring Aziridinated Analogues for the Treatment of Triple-Negative Breast Cancer via Mediated Irreversible Covalent Warheads

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Total Synthesis of Nominal ent-Chlorabietol B

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Spiro ent-Clerodane Dimers: Discovery and Green Approaches for a Scalable Biomimetic Synthesis

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Enantioselective Type II Cycloaddition of Alkynes via C–C Activation of Cyclobutanones: Rapid and Asymmetric Construction of [3.3.1] Bridged Bicycles

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Unified, Asymmetric Total Synthesis of the Asnovolins and Related Spiromeroterpenoids: A Fragment Coupling Approach

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Structural modification of oridonin via DAST induced rearrangement

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Diastereoselective synthesis of chroman bearing spirobenzofuranone scaffolds via oxa-Michael/1,6-conjugated addition of para -quinone methides with benzofuranone-type olefins

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Total Synthesis of Lycoposerramine-R

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Design and synthesis of novel oridonin analogues as potent anticancer agents

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Design and synthesis of oridonin derivatives as cytotoxic agents

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Isodon rubescens research literature based on Web of Science database for visual analysis: A review

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Cytotoxic, apoptotic, and sensitization properties of ent ‐kaurane‐type diterpenoids from Croton tonkinensis Gagnep on human liver cancer HepG2 and Hep3b cell lines

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Effect of Natural and Semisynthetic Pseudoguianolides on the Stability of NF-κB:DNA Complex Studied by Agarose Gel Electrophoresis

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Targeting XBP1-mediated β-catenin expression associated with bladder cancer with newly synthetic Oridonin analogues

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Recent Development of Oridonin Derivatives with Diverse Pharmacological Activities

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Recent Progress of Oridonin and Its Derivatives for the Treatment of Acute Myelogenous Leukemia

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Recent advances in oridonin derivatives with anticancer activity

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Oridonin, a Promising ent-Kaurane Diterpenoid Lead Compound

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Therapeutic Potential of Oridonin and Its Analogs: From Anticancer and Antiinflammation to Neuroprotection

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