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A direct access to heterobimetallic complexes by roll-over cyclometallation

https://doi.org/10.1039/c7cc07119a
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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(η 5 ‐Pentamethylcyclopentadienyl)Rhodium and ‐Iridium Compounds
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Luminescent Ionic Transition‐Metal Complexes for Light‐Emitting Electrochemical Cells
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“Roll‐over” Cyclometalation of 2,2′‐Bipyridine Platinum(II) Complexes in the Gas Phase: A Combined Experimental and Computational Study
inferredcites →https://doi.org/10.1002/chem.201702877openalex-snapshot
Cyclopalladation in the Periphery of a NHC Ligand as the Crucial Step in the Synthesis of Highly Active Suzuki–Miyaura Cross‐Coupling Catalysts
inferredcites →https://doi.org/10.1002/ejic.201100659openalex-snapshot
Small Substituents Make Large Differences: Aminopyrimidinyl Phosphanes Undergoing C–H Activation
inferredcites →https://doi.org/10.1002/ejic.201300480openalex-snapshot
C–H Activation at a Ruthenium(II) Complex – The Key Step for a Base‐Free Catalytic Transfer Hydrogenation?
inferredcites →https://doi.org/10.1002/ejoc.201600515openalex-snapshot
A Rapid and Additive‐Free Ruthenium‐Catalyzed Reductive Amination of Aromatic Aldehydes
inferredcites →https://doi.org/10.1002/hlca.19830660808openalex-snapshot
cis‐Bis(2‐Phenylpyridine)platinum(II) (CBPPP). A simple molecular platinum compound preliminary communication
inferredcites →https://doi.org/10.1002/jccs.201200408openalex-snapshot
Ionic Liquid in Synthesis: A Phase Transfer Reagent and a Redox Mediating Medium
inferredcites →https://doi.org/10.1002/mrc.1740openalex-snapshot
Experimental and quantum‐chemical studies of 15N NMR coordination shifts in palladium and platinum chloride complexes with pyridine, 2,2′‐bipyridine and 1,10‐phenanthroline
inferredcites →https://doi.org/10.1002/zaac.200390119openalex-snapshot
Ligand Substitution Reactions on Aquapentachloro‐ and Hexachloroplatinic Acid — Synthesis and Characterization of Tetrachloroplatinum(IV) Complexes with Heterocyclic N, N Donors
inferredcites →https://doi.org/10.1016/j.ccr.2008.03.014openalex-snapshot
Optimising the luminescence of platinum(II) complexes and their application in organic light emitting devices (OLEDs)☆
inferredcites →https://doi.org/10.1016/j.ccr.2010.08.001openalex-snapshot
Transition metal-catalyzed cyclocarbonylation in organic synthesis
inferredcites →https://doi.org/10.1016/j.ccr.2011.04.006openalex-snapshot
Sensory luminescent iridium(III) and platinum(II) complexes for cation recognition
inferredcites →https://doi.org/10.1016/j.ccr.2013.03.024openalex-snapshot
Anticancer cyclometalated complexes of platinum group metals and gold
inferredcites →https://doi.org/10.1016/j.ccr.2014.07.019openalex-snapshot
Applications of five-membered ring products of cyclometalation reactions as anticancer agents
inferredcites →https://doi.org/10.1016/j.ccr.2016.01.002openalex-snapshot
Electronic coupling in cyclometalated ruthenium complexes
inferredcites →https://doi.org/10.1016/j.electacta.2015.02.206openalex-snapshot
Advances in Copper Electrodeposition in Chloride Excess. A Theoretical and Experimental Approach
inferredcites →https://doi.org/10.1016/s0010-8545(96)01300-8openalex-snapshot
Photophysics, photochemistry and electrochemistry of mixed-ligand platinum(II) complexes with 2-phenylpyridine and 2-(2′-thienyl)pyridine as cyclometalating ligands
inferredcites →https://doi.org/10.1016/s0013-4686(02)00161-5openalex-snapshot
Electrodeposition of copper: the nucleation mechanisms
inferredcites →https://doi.org/10.1021/acs.accounts.5b00055openalex-snapshot
Nickel and Iron Pincer Complexes as Catalysts for the Reduction of Carbonyl Compounds
inferredcites →https://doi.org/10.1021/acs.accounts.5b00211openalex-snapshot
Luminescent Rhenium(I) and Iridium(III) Polypyridine Complexes as Biological Probes, Imaging Reagents, and Photocytotoxic Agents
inferredcites →https://doi.org/10.1021/acs.inorgchem.5b01835openalex-snapshot
Ir(III)-Based Phosphors with Bipyrazolate Ancillaries; Rational Design, Photophysics, and Applications in Organic Light-Emitting Diodes
inferredcites →https://doi.org/10.1021/acs.inorgchem.5b02444openalex-snapshot
Homoleptic Tris-Cyclometalated Iridium Complexes with Substituted o-Carboranes: Green Phosphorescent Emitters for Highly Efficient Solution-Processed Organic Light-Emitting Diodes
inferredcites →https://doi.org/10.1021/acs.organomet.5b00447openalex-snapshot
Highly Selective Detection of H+ and OH– with a Single-Emissive Iridium(III) Complex: A Mild Approach to Conversion of Non-AIEE to AIEE Complex
inferredcites →https://doi.org/10.1021/ar300289xopenalex-snapshot
Proton-Coupled Electron Transfer with Photoexcited Metal Complexes
inferredcites →https://doi.org/10.1021/ar400266copenalex-snapshot
Organoiridium Complexes: Anticancer Agents and Catalysts
inferredcites →https://doi.org/10.1021/ar500310zopenalex-snapshot
Group 9 Organometallic Compounds for Therapeutic and Bioanalytical Applications
inferredcites →https://doi.org/10.1021/cr960118ropenalex-snapshot
Cyclometalated Phosphine-Based Pincer Complexes: Mechanistic Insight in Catalysis, Coordination, and Bond Activation
inferredcites →https://doi.org/10.1021/ic00193a030openalex-snapshot
cis-Bis(2-phenylpyridine)platinum(II) (CBPPP): a simple molecular platinum compound
inferredcites →https://doi.org/10.1021/ic060796oopenalex-snapshot
Highly Phosphorescent Iridium Complexes Containing Both Tridentate Bis(benzimidazolyl)-benzene or -pyridine and Bidentate Phenylpyridine: Synthesis, Photophysical Properties, and Theoretical Study of Ir-Bis(benzimidazolyl)benzene Complex
inferredcites →https://doi.org/10.1021/ic4013872openalex-snapshot
Cyclometalated Iridium(III) Complexes for Phosphorescence Sensing of Biological Metal Ions
inferredcites →https://doi.org/10.1021/ic800196sopenalex-snapshot
Syntheses and Phosphorescent Properties of Blue Emissive Iridium Complexes with Tridentate Pyrazolyl Ligands
inferredcites →https://doi.org/10.1021/om020637mopenalex-snapshot
Terpyridine-Analogous (N,N,C)-Tridentate Ligands: Synthesis, Structures, and Electrochemical Properties of Ruthenium(II) Complexes Bearing Tridentate Pyridinium and Pyridinylidene Ligands
inferredcites →https://doi.org/10.1021/om801033gopenalex-snapshot
Cyclometalation of 2,2′-Bipyridine. Mono- and Dinuclear C,N Platinum(II) Derivatives
inferredcites →https://doi.org/10.1021/om900014hopenalex-snapshot
Cyclometalation of 6-Phenyl-2,2′-Bipyridine and Iridium: Synthesis, Characterization, and Reactivity Studies
inferredcites →https://doi.org/10.1039/b205617hopenalex-snapshot
C–H activation with N-heterocyclic carbene complexes of iridium and rhodium
inferredcites →https://doi.org/10.1039/b916237bopenalex-snapshot
Transition-metal phosphors with cyclometalating ligands: fundamentals and applications
inferredcites →https://doi.org/10.1039/c1sc00651gopenalex-snapshot
“Rollover” cyclometalation – early history, recent developments, mechanistic insights and application aspects
inferredcites →https://doi.org/10.1039/c39810001284openalex-snapshot
Nature of the ‘[Ir(bpy) 2 (H 2 O)(bpy)] 3+ ’, (bipy = 2,2′-bipyridine) cation. Monodentate or covalently hydrated bipyridine ligand? X-Ray crystal structure of the perchlorate salt
inferredcites →https://doi.org/10.1039/c4dt01717jopenalex-snapshot
Mono- and bimetallic Ir( iii ) based catalysts for the homogeneous photocatalytic reduction of CO 2 under visible light irradiation. New insights into catalyst deactivation
inferredcites →https://doi.org/10.1039/c5dt02483hopenalex-snapshot
Chiral cyclometalation of 6-(1-phenylbenzyl)-2,2′-bipyridine
inferredcites →https://doi.org/10.1039/c7nj01079fopenalex-snapshot
Gas-phase reactivity of Cp* group IX metal complexes bearing aromatic N,N′-chelating ligands

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4475968openalex-extracted
A Study Toward Synthesis of Triaryl(Fluorinated)-Gallium, Their Rollover and Classic Cyclometallated Species and Aryl-Ga Clusters
inferred← citeshttps://doi.org/10.1002/chem.202102815openalex-snapshot
Advancing Inorganic Coordination Chemistry by Spectroscopy of Isolated Molecules: Methods and Applications
inferred← citeshttps://doi.org/10.1002/cplu.202100049openalex-snapshot
Quantification of Cooperativity between Metal Sites in Dinuclear Transition Metal Complexes Containing the (2‐Dimethylamino)‐4‐(2‐pyrimidinyl)pyrimidine Ligand
inferred← citeshttps://doi.org/10.1002/ijch.202300045openalex-snapshot
Probing Intermediates of Ion/Molecule Reactions by their Independent Gas‐Phase Synthesis and Fragmentation – The Thiomethoxymethyl Complexes [(bipy)M(CH2SCH3)]+ (M=Pt, Pd, Ni)
inferred← citeshttps://doi.org/10.1002/slct.202205028openalex-snapshot
Rhodium‐Catalyzed Annulations of 6‐Arylimidazothiazoles with Alkynes through Rollover Dual C−H Bond Activation Strategy
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2018.03.022openalex-snapshot
Roll-over cyclometalation: A versatile tool to enhance the catalytic activity of transition metal complexes
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2021.121780openalex-snapshot
Structure-dependent regioselectivity of a roll-over cyclopalladation occuring at 2,2′-bipyridine-type ligands
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2021.122063openalex-snapshot
A gas-phase study on the cyclometallation of a series of Cp*Ir(III) complexes bearing bidentate pyrimidine ligands
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2023.122853openalex-snapshot
Diaryl(fluorinated)-mercury species as potential precursors of triaryl(fluorinated)-gallium to be used in the synthesis of cyclometallated Ga compounds and unexpected formation of aryl-Ga clusters
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2025.123976openalex-snapshot
Cyclometalated iridium complexes: Synthesis, photoluminescence, and catalysis
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00138openalex-snapshot
Complexes of Platinum Group Elements Containing the Intrinsically Chiral Cyclopentadienide Ligand (CpC)−1
inferred← citeshttps://doi.org/10.1021/acsomega.7b01846openalex-snapshot
To “Rollover” or Not? Stereoelectronically Guided C–H Functionalization Pathways from Rhodium–Abnormal NHC Intermediates
inferred← citeshttps://doi.org/10.1021/jacs.5c15308openalex-snapshot
The Role of Quantum Tunneling in Metal–Ligand Proton Tautomerism
inferred← citeshttps://doi.org/10.1039/c8ra03799jopenalex-snapshot
C–H activation-annulation on the N-heterocyclic carbene platform
inferred← citeshttps://doi.org/10.1039/d1dt02086bopenalex-snapshot
Tetranuclear rollover cyclometalated organoplatinum–rhenium compounds; C–I oxidative addition and C–C reductive elimination using a rollover cycloplatinated dimer
inferred← citeshttps://doi.org/10.1039/d2nj06026dopenalex-snapshot
A rollover Ir( iii ) complex of 2-(6-bromopyridin-2-yl)imidazo[1,2- a ]pyridine
inferred← citeshttps://doi.org/10.3390/molecules26020328openalex-snapshot
Rollover Cyclometalation as a Valuable Tool for Regioselective C–H Bond Activation and Functionalization
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