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Photo/Ni dual-catalyzed radical defluorinative sulfonylation to synthesize gem -difluoro allylsulfones

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/adsc.201800740openalex-snapshot

Visible Light‐Mediated Trifluoromethylation of Fluorinated Alkenes via C−F Bond Cleavage

inferredcites →https://doi.org/10.1002/anie.201709487openalex-snapshot

Photoredox Generation of Carbon‐Centered Radicals Enables the Construction of 1,1‐Difluoroalkene Carbonyl Mimics

inferredcites →https://doi.org/10.1002/anie.201805292openalex-snapshot

Transition‐Metal‐Mediated and ‐Catalyzed C−F Bond Activation by Fluorine Elimination

inferredcites →https://doi.org/10.1002/anie.201911819openalex-snapshot

Visible‐Light‐Induced Selective Defluoroborylation of Polyfluoroarenes, gem‐Difluoroalkenes, and Trifluoromethylalkenes

inferredcites →https://doi.org/10.1002/anie.201915840openalex-snapshot

NiH‐Catalyzed Migratory Defluorinative Olefin Cross‐Coupling: Trifluoromethyl‐Substituted Alkenes as Acceptor Olefins to Form gem‐Difluoroalkenes

inferredcites →https://doi.org/10.1002/anie.202106531openalex-snapshot

Selective C–F Bond Allylation of Trifluoromethylalkenes

inferredcites →https://doi.org/10.1002/anie.202111892openalex-snapshot

Photocatalytic gem‐Difluoroolefination Reactions by a Formal C−C Coupling/Defluorination Reaction with Diazoacetates

inferredcites →https://doi.org/10.1007/s11426-021-1210-yopenalex-snapshot

Precise electro-reduction of alkyl halides for radical defluorinative alkylation

inferredcites →https://doi.org/10.1016/j.ccr.2022.214479openalex-snapshot

Photoinduced nickel-catalyzed enantioselective coupling reactions

inferredcites →https://doi.org/10.1016/j.jfluchem.2005.12.013openalex-snapshot

Fluoro-artemisinins: When a gem-difluoroethylene replaces a carbonyl group

inferredcites →https://doi.org/10.1016/j.tetlet.2016.12.054openalex-snapshot

Recent advances in the synthesis and CF functionalization of gem-difluoroalkenes

inferredcites →https://doi.org/10.1021/acs.chemrev.1c00383openalex-snapshot

Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis

inferredcites →https://doi.org/10.1021/acs.chemrev.6b00620openalex-snapshot

Recent Advances in Radical C–H Activation/Radical Cross-Coupling

inferredcites →https://doi.org/10.1021/acs.joc.6b01620openalex-snapshot

Synthesis of Functionalized gem-Difluoroalkenes via a Photocatalytic Decarboxylative/Defluorinative Reaction

inferredcites →https://doi.org/10.1021/acs.orglett.2c01247openalex-snapshot

Electrochemical-Promoted Nickel-Catalyzed Reductive Allylation of Aryl Halides

inferredcites →https://doi.org/10.1021/acs.orglett.2c02528openalex-snapshot

Visible-Light-Induced C–F and C–N Bond Cleavage for the Synthesis of gem-Difluoroalkenes

inferredcites →https://doi.org/10.1021/acs.orglett.2c03046openalex-snapshot

Superbase-Mediated gem -Difluoroalkenylations of Sulfoximines

inferredcites →https://doi.org/10.1021/acscatal.5b01463openalex-snapshot

Nickel-Catalyzed Allylic C(sp 3 )–F Bond Activation of Trifluoromethyl Groups via β-Fluorine Elimination: Synthesis of Difluoro-1,4-dienes

inferredcites →https://doi.org/10.1021/acscatal.8b02784openalex-snapshot

Synthesis of gem-Difluoroalkenes via Nickel-Catalyzed Allylic Defluorinative Reductive Cross-Coupling

inferredcites →https://doi.org/10.1021/acscatal.8b04348openalex-snapshot

Synthesis of gem-Difluoroalkenes via Nickel-Catalyzed Reductive C–F and C–O Bond Cleavage

inferredcites →https://doi.org/10.1021/cr200165qopenalex-snapshot

Synthesis and Metal-Catalyzed Reactions of gem-Dihalovinyl Systems

inferredcites →https://doi.org/10.1021/cr500235vopenalex-snapshot

Organocatalytic Carbon–Sulfur Bond-Forming Reactions

inferredcites →https://doi.org/10.1021/cr800309ropenalex-snapshot

Evolving Organic Synthesis Fostered by the Pluripotent Phenylsulfone Moiety

inferredcites →https://doi.org/10.1021/ja021487+openalex-snapshot

Reversal of the Apparent Regiospecificity of NAD(P)H-Dependent Hydride Transfer: The Properties of the Difluoromethylene Group, A Carbonyl Mimic

inferredcites →https://doi.org/10.1021/ja409941ropenalex-snapshot

Copper-Catalyzed gem-Difluoroolefination of Diazo Compounds with TMSCF3 via C–F Bond Cleavage

inferredcites →https://doi.org/10.1021/jacs.1c03126openalex-snapshot

Site-Selective Defluorinative sp3 C–H Alkylation of Secondary Amides

inferredcites →https://doi.org/10.1021/jacs.1c04531openalex-snapshot

Chromium-Catalyzed Allylic Defluorinative Ketyl Olefin Coupling

inferredcites →https://doi.org/10.1021/jacs.2c02487openalex-snapshot

Switchable 1,2-Rearrangement Enables Expedient Synthesis of Structurally Diverse Fluorine-Containing Scaffolds

inferredcites →https://doi.org/10.1021/jacs.6b04077openalex-snapshot

A Dual-Catalytic Strategy To Direct Asymmetric Radical Aminotrifluoromethylation of Alkenes

inferredcites →https://doi.org/10.1021/jacs.8b04902openalex-snapshot

Enantioselective Copper-Catalyzed Defluoroalkylation Using Arylboronate-Activated Alkyl Grignard Reagents

inferredcites →https://doi.org/10.1021/jacs.9b00669openalex-snapshot

Open-Air Alkylation Reactions in Photoredox-Catalyzed DNA-Encoded Library Synthesis

inferredcites →https://doi.org/10.1021/jacs.9b11382openalex-snapshot

Catalytic Enantioselective Boryl and Silyl Substitution with Trifluoromethyl Alkenes: Scope, Utility, and Mechanistic Nuances of Cu–F β-Elimination

inferredcites →https://doi.org/10.1021/jacs.9b13757openalex-snapshot

Catalyzing the Hydrodefluorination of CF 3 -Substituted Alkenes by PhSiH 3 . H• Transfer from a Nickel Hydride

inferredcites →https://doi.org/10.1021/jm00391a036openalex-snapshot

Synthesis and biological activity of 5-(2,2-difluorovinyl)-2'-deoxyuridine

inferredcites →https://doi.org/10.1021/jm034162sopenalex-snapshot

Design, Synthesis, and Biological Activity of a Difluoro-Substituted, Conformationally Rigid Vigabatrin Analogue as a Potent γ-Aminobutyric Acid Aminotransferase Inhibitor

inferredcites →https://doi.org/10.1038/s41467-020-18658-4openalex-snapshot

Migratory functionalization of unactivated alkyl bromides for construction of all-carbon quaternary centers via transposed tert-C-radicals

inferredcites →https://doi.org/10.1039/c4cs00239copenalex-snapshot

Recent advances in C–S bond formation via C–H bond functionalization and decarboxylation

inferredcites →https://doi.org/10.1039/c8sc04335copenalex-snapshot

Nickel-catalyzed allylic defluorinative alkylation of trifluoromethyl alkenes with reductive decarboxylation of redox-active esters

inferredcites →https://doi.org/10.1039/c9cc06465fopenalex-snapshot

Recent advances in the synthesis and applications of α-(trifluoromethyl)styrenes in organic synthesis

inferredcites →https://doi.org/10.1039/d2gc02266dopenalex-snapshot

Photoinduced allylic defluorinative alkylation of trifluoromethyl alkenes with Katritzky salts under catalyst- and metal-free conditions

inferredcites →https://doi.org/10.1055/a-1509-5541openalex-snapshot

Visible Light as the Key for the Formation of Carbon–Sulfur Bonds in Sulfones, Thioethers, and Sulfonamides: An Update

inferredcites →https://doi.org/10.1093/nsr/nwx039openalex-snapshot

Recent advances in visible-light-driven organic reactions

inferredcites →https://doi.org/10.2174/092986712801323225openalex-snapshot

Sulfonyl Group-Containing Compounds in the Design of Potential Drugs for the Treatment of Diabetes and Its Complications

inferredcites →https://doi.org/10.31635/ccschem.022.202201935openalex-snapshot

A Fruitful Decade of Organofluorine Chemistry: New Reagents and Reactions

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4662834openalex-extracted

Photoredox/Nickel Dual-Catalysis-Enabled Regioselective Cyclization of Alkenes with Alkyl Chlorides

inferred← citeshttps://doi.org/10.1002/adsc.202400174openalex-snapshot

Photocatalyzed Formation of gem‐Difluoroalkenes Using Oxime Esters

inferred← citeshttps://doi.org/10.1002/ajoc.202300608openalex-snapshot

Synthesis of 2‐(β‐Trifluoromethyl‐β‐arylethylthio)pyridine through DBU‐Mediated Regioselective Addition of Pyridine‐2(1H)‐thione Onto α‐(Trifluoromethyl)styrenes

inferred← citeshttps://doi.org/10.1002/cbdv.202501527openalex-snapshot

Research Progress of DBU in C─C, C–Heteroatom, and Heteroatom–Heteroatom Bond Formations

inferred← citeshttps://doi.org/10.1002/chem.202501384openalex-snapshot

Oxidative Thiolated Aromatization of Terpenes for Divergent Construction of Organosulfur Compounds

inferred← citeshttps://doi.org/10.1002/cjoc.202300751openalex-snapshot

Transition‐Metal‐Free Allylic Defluorination Cross‐Electrophile Coupling Employing Rongalite

inferred← citeshttps://doi.org/10.1002/ejoc.202300883openalex-snapshot

Metal‐Free Photoinduced Defluorinative Carboxylation of Trifluoromethylalkenes with Formate

inferred← citeshttps://doi.org/10.1002/ejoc.202400011openalex-snapshot

N‐Directed defluorinative γ‐C(sp3)−H allylation of sulfamate esters for synthesis of gem‐difluoroalkenes via photoredox catalysis

inferred← citeshttps://doi.org/10.1016/j.cclet.2024.110461openalex-snapshot

Modular and practical synthesis of gem-difluoroalkenes via consecutive Ni-catalyzed reductive cross-coupling

inferred← citeshttps://doi.org/10.1016/j.jfluchem.2024.110273openalex-snapshot

Synthesis of substituted (trifluoromethyl)alkenes: (Trifluoromethyl)alkylidenation of thioketones via CF3-thiiranes

inferred← citeshttps://doi.org/10.1016/j.mcat.2023.113806openalex-snapshot

Photoredox/nickel dual-catalysis-enabled synthesis of N-heterocycles from alkyl chlorides and alkenes

inferred← citeshttps://doi.org/10.1021/acs.joc.4c00084openalex-snapshot

Synthesis of gem-Difluorohomoallyl Amines via a Transition-Metal-Free Defluorinative Alkylation of Benzyl Amines with Trifluoromethyl Alkenes

inferred← citeshttps://doi.org/10.1021/acs.joc.4c03056openalex-snapshot

Three-Component Sulfonylation and Heteroannulation Enabled by 3-Fold Defluorofunctionalization of Trifluoromethyl Enones

inferred← citeshttps://doi.org/10.1021/acs.joc.4c03088openalex-snapshot

Visible Light Photoredox-Catalyzed Radical Defluorinative Arylation of α-Trifluoromethyl Alkenes with Aryl Chlorides

inferred← citeshttps://doi.org/10.1021/acs.orglett.3c03713openalex-snapshot

Photoredox Enabled Defluorinative Benzylation of Trifluoromethyl Alkenes with Alkylarenes

inferred← citeshttps://doi.org/10.1021/acscatal.3c02087openalex-snapshot

Photo-Induced Formal Trifluoropropanation of Organic Halides

inferred← citeshttps://doi.org/10.1039/d3qo01053hopenalex-snapshot

Auxiliary-controlled regiodivergent NiH-catalyzed gem -difluoroallylation of alkenyl amines via defluorinative olefin cross-coupling

inferred← citeshttps://doi.org/10.1039/d4cc02503bopenalex-snapshot

Hydroazidation of trifluoromethyl alkenes with trimethylsilyl azide enabled by organic photoredox catalysis

inferred← citeshttps://doi.org/10.1039/d5qo01008jopenalex-snapshot

Photocatalyzed defluorinative allylsulfonylation of alkynes to access gem -difluorinated sulfonyl-1,4-dienes

inferred← citeshttps://doi.org/10.1039/d5qo01324kopenalex-snapshot

Selective defluorinative [4 + 3] annulation to access fluorinated oxazepines and thiazepines

inferred← citeshttps://doi.org/10.1039/d5qo01732gopenalex-snapshot

Recent advances in visible-light-induced defluorinative functionalization of α-trifluoromethyl arylalkenes

inferred← citeshttps://doi.org/10.1055/a-2307-0567openalex-snapshot

Efficient Synthesis of N-(Difluoropropenyl)amides/Amines from Fluorinated Olefins under Base Promotion

inferred← citeshttps://doi.org/10.6023/a25070258openalex-snapshot

Photochemical Driven Diverse Transformation of α-Trifluoromethyl Olefins

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