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The structure of water in the hydration shell of cations from x-ray Raman and small angle x-ray scattering measurements

https://doi.org/10.1063/1.3533958
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Zur Lehre von der Wirkung der Salze
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The quasi-lattice structure in concentrated aqueous solutions
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Small-angle maxima and cation-cation distances. Differences between iron nitrate and perchlorate solutions
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Correlation between intramolecular bond lengths and K-shell σ-shape resonances in gas-phase molecules
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Physisorbed, chemisorbed and dissociated O2 on Pt(111) studied by different core level spectroscopy methods
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Ion selectivity in potassium channels
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High resolution X-ray emission spectroscopy of liquid water: The observation of two structural motifs
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Theoretical approximations to X-ray absorption spectroscopy of liquid water and ice
inferredcites →https://doi.org/10.1016/j.elspec.2010.02.005openalex-snapshot
X-ray absorption spectroscopy and X-ray Raman scattering of water and ice; an experimental view
inferredcites →https://doi.org/10.1016/j.elspec.2010.02.009openalex-snapshot
The solvation of ions and molecules probed via soft X-ray spectroscopies
inferredcites →https://doi.org/10.1016/s0005-2736(00)00345-xopenalex-snapshot
Potassium and sodium ions in a potassium channel studied by molecular dynamics simulations
inferredcites →https://doi.org/10.1016/s0009-2614(02)00890-4openalex-snapshot
The interpretation of X-ray absorption spectra of water and ice
inferredcites →https://doi.org/10.1016/s0301-4622(02)00153-9openalex-snapshot
Dynamic hydration numbers for biologically important ions
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Correlation spectroscopy with coherent X-rays
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Small-angle scattering: a view on the properties, structures and structural changes of biological macromolecules in solution
inferredcites →https://doi.org/10.1021/cr00019a014openalex-snapshot
Structure and dynamics of hydrated ions
inferredcites →https://doi.org/10.1021/cr00040a004openalex-snapshot
Viscosity B-Coefficients of Ions in Solution
inferredcites →https://doi.org/10.1021/cr0403741openalex-snapshot
Specific Ion Effects at the Air/Water Interface
inferredcites →https://doi.org/10.1021/cr8003828openalex-snapshot
Effect of Ions on the Structure of Water: Structure Making and Breaking
inferredcites →https://doi.org/10.1021/j100173a018openalex-snapshot
Infrared spectroscopic evidence for second-sphere hydration in aqueous solutions of aluminum(3+), chromium(3+) and rhodium(3+)
inferredcites →https://doi.org/10.1021/ja01385a012openalex-snapshot
THE VISCOSITY OF AQUEOUS SOLUTIONS OF STRONG ELECTROLYTES WITH SPECIAL REFERENCE TO BARIUM CHLORIDE
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How Ions Affect the Structure of Water
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Second Coordination Shell Water Exchange Rate and Mechanism: Experiments and Modeling on Hexaaquachromium(III)
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First-Principles Ion−Water Interaction Potentials for Highly Charged Monatomic Cations. Computer Simulations of Al3+, Mg2+, and Be2+in Water
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Ionic Hydration Behavior Derived from Infrared Spectra in HDO
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Direct Evidence of Orbital Mixing between Water and Solvated Transition-Metal Ions: An Oxygen 1s XAS and DFT Study of Aqueous Systems
inferredcites →https://doi.org/10.1021/jp0445324openalex-snapshot
Effects of Alkali Metal Halide Salts on the Hydrogen Bond Network of Liquid Water
inferredcites →https://doi.org/10.1021/jp050413sopenalex-snapshot
X-ray Absorption Spectroscopy Study of the Hydrogen Bond Network in the Bulk Water of Aqueous Solutions
inferredcites →https://doi.org/10.1021/jp054699copenalex-snapshot
Effects of Cations on the Hydrogen Bond Network of Liquid Water: New Results from X-ray Absorption Spectroscopy of Liquid Microjets
inferredcites →https://doi.org/10.1021/jp075913vopenalex-snapshot
Hydration of Sodium, Potassium, and Chloride Ions in Solution and the Concept of Structure Maker/Breaker
inferredcites →https://doi.org/10.1021/jp805177vopenalex-snapshot
Cation-Specific Interactions with Carboxylate in Amino Acid and Acetate Aqueous Solutions: X-ray Absorption and ab initio Calculations
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On the Range of Water Structure Models Compatible with X-ray and Neutron Diffraction Data
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Solvent Structure, Dynamics, and Ion Mobility in Aqueous Solutions at 25 °C
inferredcites →https://doi.org/10.1038/171944a0openalex-snapshot
International Tables for X-Ray Crystallography
inferredcites →https://doi.org/10.1038/35102009openalex-snapshot
Chemistry of ion coordination and hydration revealed by a K+ channel–Fab complex at 2.0 Å resolution
inferredcites →https://doi.org/10.1038/nchem.768openalex-snapshot
Charge transfer to solvent identified using dark channel fluorescence-yield L-edge spectroscopy
inferredcites →https://doi.org/10.1039/b505723jopenalex-snapshot
Half or full core hole in density functional theory X-ray absorption spectrum calculations of water?
inferredcites →https://doi.org/10.1039/b607093kopenalex-snapshot
Theoretical modeling and interpretation of X-ray absorption spectra of liquid water
inferredcites →https://doi.org/10.1039/b701855jopenalex-snapshot
Perturbation of water structure due to monovalent ions in solution
inferredcites →https://doi.org/10.1063/1.1319615openalex-snapshot
What can x-ray scattering tell us about the radial distribution functions of water?
inferredcites →https://doi.org/10.1063/1.1623746openalex-snapshot
Influence of ions on the hydrogen-bond structure in liquid water
inferredcites →https://doi.org/10.1063/1.1641191openalex-snapshot
Many-body potentials for aqueous Li+, Na+, Mg2+, and Al3+: Comparison of effective three-body potentials and polarizable models
inferredcites →https://doi.org/10.1063/1.1703526openalex-snapshot
Calculation of near-edge x-ray-absorption fine structure at finite temperatures: Spectral signatures of hydrogen bond breaking in liquid water
inferredcites →https://doi.org/10.1063/1.1879752openalex-snapshot
The hydrogen bond in ice probed by soft x-ray spectroscopy and density functional theory
inferredcites →https://doi.org/10.1063/1.2064867openalex-snapshot
Spectroscopic characterization of microscopic hydrogen-bonding disparities in supercritical water
inferredcites →https://doi.org/10.1063/1.2176616openalex-snapshot
Molecular and electronic structure in NaCl electrolytes of varying concentration: Identification of spectral fingerprints
inferredcites →https://doi.org/10.1063/1.2199828openalex-snapshot
The local structure of protonated water from x-ray absorption and density functional theory
inferredcites →https://doi.org/10.1063/1.2566868openalex-snapshot
Structure and dynamics of the hydration shells of the Al3+ ion
inferredcites →https://doi.org/10.1063/1.3184764openalex-snapshot
Increased fraction of weakened hydrogen bonds of water in aerosol OT reverse micelles
inferredcites →https://doi.org/10.1063/1.3273874openalex-snapshot
X-ray study of the structure of liquid water
inferredcites →https://doi.org/10.1063/1.3364110openalex-snapshot
A Lennard-Jones plus Coulomb potential for Al3+ ions in aqueous solutions
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Increasing correlation length in bulk supercooled H2O, D2O, and NaCl solution determined from small angle x-ray scattering
inferredcites →https://doi.org/10.1063/1.3533958openalex-snapshot
The structure of water in the hydration shell of cations from x-ray Raman and small angle x-ray scattering measurements
inferredcites →https://doi.org/10.1063/1.452078openalex-snapshot
The relationship between shape resonances and bond lengths
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Liquid GeBr4. II. Molecular packing and liquid structure
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The inhomogeneous structure of water at ambient conditions
inferredcites →https://doi.org/10.1073/pnas.0912158107openalex-snapshot
Is ambient water inhomogeneous on the nanometer-length scale?
inferredcites →https://doi.org/10.1073/pnas.0913504107openalex-snapshot
Reply to Soper et al.: Fluctuations in water around a bimodal distribution of local hydrogen-bonded structural motifs
inferredcites →https://doi.org/10.1073/pnas.1006599107openalex-snapshot
Small-angle scattering and the structure of ambient liquid water
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Sticky ions in biological systems.
inferredcites →https://doi.org/10.1088/0953-8984/14/8/106openalex-snapshot
Spectroscopic probing of local hydrogen-bonding structures in liquid water
inferredcites →https://doi.org/10.1103/physrevb.39.7590openalex-snapshot
X-ray Raman scattering as a substitute for soft-x-ray extended x-ray-absorption fine structure
inferredcites →https://doi.org/10.1103/physrevb.66.092107openalex-snapshot
X-ray Raman spectroscopy at the oxygenKedge of water and ice: Implications on local structure models
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X-ray absorption spectrum of liquid water from molecular dynamics simulations: Asymmetric model
inferredcites →https://doi.org/10.1103/physrevb.76.024202openalex-snapshot
Isotope effects in liquid water probed by x-ray Raman spectroscopy
inferredcites →https://doi.org/10.1103/physrevb.80.233404openalex-snapshot
Sensitivity of x-ray absorption spectroscopy to hydrogen bond topology
inferredcites →https://doi.org/10.1103/physrevlett.105.017802openalex-snapshot
X-Ray Absorption Signatures of the Molecular Environment in Water and Ice
inferredcites →https://doi.org/10.1103/physrevlett.51.2414openalex-snapshot
Bonding and Bond Lengths of Chemisorbed Molecules from Near-Edge X-Ray-Absorption Fine-Structure Studies
inferredcites →https://doi.org/10.1103/physrevlett.84.614openalex-snapshot
Shape Resonances of Oriented Molecules:ab initioTheory and Experiment on Hydrocarbon Molecules
inferredcites →https://doi.org/10.1103/physrevlett.89.276102openalex-snapshot
Structure and Bonding of Water on Pt(111)
inferredcites →https://doi.org/10.1103/physrevlett.96.215502openalex-snapshot
X-Ray Absorption Spectra of Water from First Principles Calculations
inferredcites →https://doi.org/10.1107/s0567740876006080openalex-snapshot
International Tables for X-ray Crystallography
inferredcites →https://doi.org/10.1126/science.1084801openalex-snapshot
Negligible Effect of Ions on the Hydrogen-Bond Structure in Liquid Water
inferredcites →https://doi.org/10.1126/science.1096205openalex-snapshot
The Structure of the First Coordination Shell in Liquid Water
inferredcites →https://doi.org/10.1126/science.1106525openalex-snapshot
Electron Spectroscopy of Aqueous Solution Interfaces Reveals Surface Enhancement of Halides
inferredcites →https://doi.org/10.1126/science.1183512openalex-snapshot
Cooperativity in Ion Hydration
inferredcites →https://doi.org/10.1143/jpsj.22.445openalex-snapshot
Theory of X-Ray Raman Scattering

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Mechanisms of Acceleration and Retardation of Water Dynamics by Ions
inferred← citeshttps://doi.org/10.1021/jacs.3c05004openalex-snapshot
Electro-Freezing of Supercooled Water Is Induced by Hydrated Al 3+ and Mg 2+ Ions: Experimental and Theoretical Studies
inferred← citeshttps://doi.org/10.1021/jp309312qopenalex-snapshot
On the Effects of Temperature, Pressure, and Dissolved Salts on the Hydrogen-Bond Network of Water
inferred← citeshttps://doi.org/10.1021/jp403065yopenalex-snapshot
In Situ Electrochemical Quartz Crystal Admittance Methodology for Tracking Compositional and Mechanical Changes in Porous Carbon Electrodes
inferred← citeshttps://doi.org/10.1021/jp405578wopenalex-snapshot
Charge and Electric Field Fluctuations in Aqueous NaCl Electrolytes
inferred← citeshttps://doi.org/10.1021/jp502922copenalex-snapshot
Understanding the Rates and Molecular Mechanism of Water-Exchange around Aqueous Ions Using Molecular Simulations
inferred← citeshttps://doi.org/10.1021/jp504245copenalex-snapshot
How Much Weaker Are the Effects of Cations than Those of Anions? The Effects of K+ and Cs+ on the Molecular Organization of Liquid H2O
inferred← citeshttps://doi.org/10.1021/jz502186aopenalex-snapshot
Ion-Solvation-Induced Molecular Reorganization in Liquid Water Probed by Resonant Inelastic Soft X-ray Scattering
inferred← citeshttps://doi.org/10.1021/la300868vopenalex-snapshot
Structural Evolution during Geopolymerization from an Early Age to Consolidated Material
inferred← citeshttps://doi.org/10.1029/2018jc014457openalex-snapshot
How Much H2O Is There in the Ocean? The Structure of Water in Sea Water
inferred← citeshttps://doi.org/10.1029/2018rg000597openalex-snapshot
What Is the Range of Soil Water Density? Critical Reviews With a Unified Model
inferred← citeshttps://doi.org/10.1038/s41467-025-61740-yopenalex-snapshot
Hydrate-melt electrolyte design for aqueous aluminium-bromine batteries with enhanced energy-power merits
inferred← citeshttps://doi.org/10.1038/s41557-022-00977-2openalex-snapshot
Time-resolved terahertz–Raman spectroscopy reveals that cations and anions distinctly modify intermolecular interactions of water
inferred← citeshttps://doi.org/10.1038/s42005-024-01768-6openalex-snapshot
Ionization by XFEL radiation produces distinct structure in liquid water
inferred← citeshttps://doi.org/10.1038/srep01074openalex-snapshot
Highly Compressed Two-Dimensional Form of Water at Ambient Conditions
inferred← citeshttps://doi.org/10.1038/srep26831openalex-snapshot
The decisive role of free water in determining homogenous ice nucleation behavior of aqueous solutions
inferred← citeshttps://doi.org/10.1039/c2cp23255copenalex-snapshot
Spectrum of excess partial molar absorptivity. Part II: a near infrared spectroscopic study of aqueous Na-halides
inferred← citeshttps://doi.org/10.1039/c3cp51650dopenalex-snapshot
1-Propanol probing methodology: two-dimensional characterization of the effect of solute on H2O
inferred← citeshttps://doi.org/10.1039/c4cp00762jopenalex-snapshot
Solvation dependence of valence electronic states of water diluted in organic solvents probed by soft X-ray spectroscopy
inferred← citeshttps://doi.org/10.1039/c4cp04759aopenalex-snapshot
Long-range ion–water and ion–ion interactions in aqueous solutions
inferred← citeshttps://doi.org/10.1039/c5cp03919copenalex-snapshot
Requirements of first-principles calculations of X-ray absorption spectra of liquid water
inferred← citeshttps://doi.org/10.1039/c5ra21962kopenalex-snapshot
Investigation of different aqueous electrolytes on the electrochemical performance of activated carbon-based supercapacitors
inferred← citeshttps://doi.org/10.1039/c6cp04101aopenalex-snapshot
Dynamic behaviour of the silica-water-bio electrical double layer in the presence of a divalent electrolyte
inferred← citeshttps://doi.org/10.1039/c7cp03395hopenalex-snapshot
Orientational ordering of water in extended hydration shells of cations is ion-specific and is correlated directly with viscosity and hydration free energy
inferred← citeshttps://doi.org/10.1039/c8cp05308aopenalex-snapshot
Hydration in aqueous solutions of ectoine and hydroxyectoine
inferred← citeshttps://doi.org/10.1039/c8nr02859aopenalex-snapshot
Lubricating properties of single metal ions at interfaces
inferred← citeshttps://doi.org/10.1039/c9cp05014kopenalex-snapshot
Understanding the effect of nanoconfinement on the structure of water hydrogen bond networks
inferred← citeshttps://doi.org/10.1039/d0cp01095bopenalex-snapshot
Fragment-based quantum mechanical approach to biomolecules, molecular clusters, molecular crystals and liquids
inferred← citeshttps://doi.org/10.1039/d1cp01490kopenalex-snapshot
Ion association in hydrothermal aqueous NaCl solutions: implications for the microscopic structure of supercritical water
inferred← citeshttps://doi.org/10.1039/d1cp02173gopenalex-snapshot
The tug of war between Al 3+ and Na + for order–disorder transitions in lipid-A membranes
inferred← citeshttps://doi.org/10.1039/d1tb02798kopenalex-snapshot
Microfluidics-assisted synthesis and functionalization of monodisperse colloidal hydrogel particles for optomechanical biosensors
inferred← citeshttps://doi.org/10.1039/d2cp00162dopenalex-snapshot
Hydration in aqueous NaCl
inferred← citeshttps://doi.org/10.1039/d2cp00227bopenalex-snapshot
Probing aqueous ions with non-local Auger relaxation
inferred← citeshttps://doi.org/10.1039/d2cp01828dopenalex-snapshot
Unveiling the structure of aqueous magnesium nitrate solutions by combining X-ray diffraction and theoretical calculations
inferred← citeshttps://doi.org/10.1039/d4cp03684kopenalex-snapshot
Structure and crystallization behavior of aqueous KCl–MgCl 2 solutions
inferred← citeshttps://doi.org/10.1039/d5ma00339copenalex-snapshot
Composite hydrogels of phenylalanine dipeptides with trivalent metal cations
inferred← citeshttps://doi.org/10.1061/jenmdt.emeng-8618openalex-snapshot
Determining Soil Water Structure, Density, and Viscosity via Infrared Spectroscopy
inferred← citeshttps://doi.org/10.1063/1.3597606openalex-snapshot
Increased fraction of low-density structures in aqueous solutions of fluoride
inferred← citeshttps://doi.org/10.1063/1.3655468openalex-snapshot
X-ray Raman scattering provides evidence for interfacial acetonitrile-water dipole interactions in aqueous solutions
inferred← citeshttps://doi.org/10.1063/1.3679021openalex-snapshot
Influence of monovalent ions on density fluctuations in hydrothermal aqueous solutions by small angle X-ray scattering
inferred← citeshttps://doi.org/10.1063/1.3684988openalex-snapshot
The structure of liquid N-methyl pyrrolidone probed by x-ray scattering and molecular simulations
inferred← citeshttps://doi.org/10.1063/1.4704458openalex-snapshot
A high resolution and large solid angle x-ray Raman spectroscopy end-station at the Stanford Synchrotron Radiation Lightsource
inferred← citeshttps://doi.org/10.1063/1.4735267openalex-snapshot
Long-range hydrogen-bond structure in aqueous solutions and the vapor-water interface
inferred← citeshttps://doi.org/10.1063/1.4801512openalex-snapshot
Solvation structures of protons and hydroxide ions in water
inferred← citeshttps://doi.org/10.1063/1.4881600openalex-snapshot
A different view of structure-making and structure-breaking in alkali halide aqueous solutions through x-ray absorption spectroscopy
inferred← citeshttps://doi.org/10.1063/1.4890035openalex-snapshot
Comparison of x-ray absorption spectra between water and ice: New ice data with low pre-edge absorption cross-section
inferred← citeshttps://doi.org/10.1063/1.4899070openalex-snapshot
On the intermolecular vibrational coupling, hydrogen bonding, and librational freedom of water in the hydration shell of mono- and bivalent anions
inferred← citeshttps://doi.org/10.1063/5.0046188openalex-snapshot
Role of water model on ion dissociation at ambient conditions
inferred← citeshttps://doi.org/10.1063/5.0256865openalex-snapshot
Dynamical correlation between ions in liquid seen in real space and time
inferred← citeshttps://doi.org/10.1063/5.0311238openalex-snapshot
Medium-range ordering of interfacial water at charged clay interfaces: From layering to network connectivity
inferred← citeshttps://doi.org/10.1073/pnas.1319054111openalex-snapshot
A repulsion mechanism explains magnesium permeation and selectivity in CorA
inferred← citeshttps://doi.org/10.1073/pnas.2531352123openalex-snapshot
Structure making and breaking in electrolyte solutions explained by water energetics
inferred← citeshttps://doi.org/10.1080/01490451.2023.2192216openalex-snapshot
Assessment and Selection of Cyanobacterial Strains for CO2 Mineral Sequestration: Implications for Carbonation Mechanism
inferred← citeshttps://doi.org/10.1103/physrevb.85.115135openalex-snapshot
Real-space Green's function calculations of Compton profiles
inferred← citeshttps://doi.org/10.1103/physrevmaterials.3.065604openalex-snapshot
Local correlated motions in aqueous solution of sodium chloride
inferred← citeshttps://doi.org/10.1107/s2053229614014302openalex-snapshot
Crystal structures of hydrates of simple inorganic salts. III. Water-rich aluminium halide hydrates: AlCl3·15H2O, AlBr3·15H2O, AlI3·15H2O, AlI3·17H2O and AlBr3·9H2O
inferred← citeshttps://doi.org/10.1134/s0036029516110033openalex-snapshot
Some physicochemical properties of aluminum and iron chloride solutions
inferred← citeshttps://doi.org/10.1134/s1070363213010039openalex-snapshot
Structural parameters of the close environment of group III metal ions in aqueous solutions of their salts
inferred← citeshttps://doi.org/10.1134/s1070363223030143openalex-snapshot
Comparative Characteristics of the Nearest Environment Structures of Metal Ions in Water and Acetonitrile (A Review)
inferred← citeshttps://doi.org/10.1146/annurev-chembioeng-120919-114657openalex-snapshot
Water Structure and Properties at Hydrophilic and Hydrophobic Surfaces
inferred← citeshttps://doi.org/10.1177/0003702818776662openalex-snapshot
A New Approach to Measuring the Temperature of Fluids Reaching 300 ℃ and 2 mol/kg NaCl Based on the Raman Shift of Water
inferred← citeshttps://doi.org/10.1194/jlr.m039172openalex-snapshot
Volumetric determination of apolipoprotein stoichiometry of circulating HDL subspecies
inferred← citeshttps://doi.org/10.12700/aph.20.7.2023.7.13openalex-snapshot
Analysis of the Soil Selective Potassium Content, using Multifrequency EC Sensors
inferred← citeshttps://doi.org/10.1393/ncr/i2016-10123-5openalex-snapshot
X-ray and simulation studies of water
inferred← citeshttps://doi.org/10.2138/am.2014.4846openalex-snapshot
Interlayer structure model of tri-hydrated low-charge smectite by X-ray diffraction and Monte Carlo modeling in the Grand Canonical ensemble
inferred← citeshttps://doi.org/10.2139/ssrn.5749743openalex-snapshot
CO2 Solubility and Dissolution Sequestration Capacity in Deep Groundwater: From Micro-Visualization Studies to Basin-Scale Assessments in Zhejiang Province
inferred← citeshttps://doi.org/10.2139/ssrn.6418140openalex-snapshot
CO2 Solubility and Dissolution Sequestration Capacity in Deep Groundwater: From Micro-Visualization Studies to Basin-Scale Assessments in Zhejiang Province
inferred← citeshttps://doi.org/10.2139/ssrn.7499182openalex-snapshot
In-situ Raman Combined with Fused Silica Capillary Cell for Quantifying CO₂ Solubility and Sequestration Evaluation of Deep Groundwater
inferred← citeshttps://doi.org/10.2175/106143013x13807328849936openalex-snapshot
Study on the Application of Raman Spectroscopy on Detecting Water Hardness
inferred← citeshttps://doi.org/10.29121/granthaalayah.v11.i12.2023.5437openalex-snapshot
COMPATIBILITY ANALYSIS OF THE SOIL CALCIUM CONTENT BY MULTIFREQUENCY EC SENSORS
inferred← citeshttps://doi.org/10.31857/s0044460x23030149openalex-snapshot
Comparative characteristics of the nearest environment structural parameters of metal ions in water and acetonitrile
inferred← citeshttps://doi.org/10.3390/colloids10040060openalex-snapshot
Does the State of the Art Knowledge on Water Structure Require Thinking About a New Thermodynamic Framework for Aqueous Solutions?
inferred← citeshttps://doi.org/10.3390/ijms25031613openalex-snapshot
Insights into the Effect of Charges on Hydrogen Bonds
inferred← citeshttps://doi.org/10.3390/inorganics9050031openalex-snapshot
Assessing the Intrinsic Strengths of Ion–Solvent and Solvent–Solvent Interactions for Hydrated Mg2+ Clusters
inferred← citeshttps://doi.org/10.3390/liquids4010001openalex-snapshot
Inclusion Bodies in Ionic Liquids
inferred← citeshttps://doi.org/10.3390/s24113296openalex-snapshot
An Electrical Conductivity Sensor for the Selective Determination of Soil Salinity
inferred← citeshttps://doi.org/10.70675/c1f8807az5389z4c28z94a1z22b43f3efcacopenalex-snapshot
Influence des paramètres de formulation sur la texturation et la structuration des géopolymères
inferred← citeshttps://doi.org/10.70675/cb9e565azdb63z47c3z8ccdz66ec561f8860openalex-snapshot
A new approach towards understanding the ion transfer dynamics in nanostructured carbon-based thin films for energy storage applications
showing the first 148 of 149
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