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Medium effects on the α-effect in DMSO–H2O mixtures — Comparative studies of p-nitrophenyl benzoate and acetate — Dissection of ground-state and transition-state effects
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
inferredcites →https://doi.org/10.1002/1099-0690(200109)2001:17<3279::aid-ejoc3279>3.0.co;2-9openalex-snapshot
The α-Effect in SNAr Substitutions − Reaction between Oximate Nucleophiles and 2,4-Dinitrofluorobenzene in Aqueous Solution
inferredcites →https://doi.org/10.1002/poc.897openalex-snapshot
The size of the alpha‐effects in methyl transfers correlate with Koopmans' theorem ionization potentials
inferredcites →https://doi.org/10.1016/0040-4039(95)01426-iopenalex-snapshot
The effect of solvent on the α-effect: Abnormal nucleophilic reactivity of substituted acetophenone oximate anions in aqueous DMSO
inferredcites →https://doi.org/10.1016/j.tet.2004.05.006openalex-snapshot
The α-effect and its modulation by solvent
inferredcites →https://doi.org/10.1021/ar00156a004openalex-snapshot
Equilibrium acidities in dimethyl sulfoxide solution
inferredcites →https://doi.org/10.1021/bk-2005-0902openalex-snapshot
Ionic Liquids IIIB: Fundamentals, Progress, Challenges, and Opportunities
inferredcites →https://doi.org/10.1021/cr60257a001openalex-snapshot
Protic-dipolar aprotic solvent effects on rates of bimolecular reactions
inferredcites →https://doi.org/10.1021/j100618a016openalex-snapshot
Ultrasound propagation in binary mixtures of dimethyl sulfoxide and water
inferredcites →https://doi.org/10.1021/ja00277a032openalex-snapshot
Nucleophilic addition to olefins. 18. Kinetics of the addition of primary amines and .alpha.-effect nucleophiles to benzylidene Meldrum's acid
inferredcites →https://doi.org/10.1021/ja00346a066openalex-snapshot
Absence of an .alpha.-effect in the gas-phase nucleophilic reactions of hydroperoxide ion
inferredcites →https://doi.org/10.1021/ja00418a027openalex-snapshot
The ionization of feeble organic acids in DMSO-water mixtures. Acidity constants derived by extrapolation to the aqueous state
inferredcites →https://doi.org/10.1021/ja00756a013openalex-snapshot
Enhancement of saponificiation rates in aqueous dipolar solvents. Hydroxide ion solvation vs. transition state solvation
inferredcites →https://doi.org/10.1021/ja01182a117openalex-snapshot
The Correlation of Solvolysis Rates
inferredcites →https://doi.org/10.1021/ja016917vopenalex-snapshot
Ground-State versus Transition-State Effects on the α-Effect as Expressed by Solvent Effects
inferredcites →https://doi.org/10.1021/ja020379kopenalex-snapshot
Reactions of Oximate α-Nucleophiles with Esters: Evidence from Solvation Effects for Substantial Decoupling of Desolvation and Bond Formation
inferredcites →https://doi.org/10.1021/jo00111a037openalex-snapshot
Nonlinear Broensted Relationships in the Reactions of Phenoxide Ions with Bis(4-nitrophenyl) Phenylphosphonate in H2O-Me2SO Mixtures. Solvation Effects
inferredcites →https://doi.org/10.1021/jo0156114openalex-snapshot
Solvent Effect on the α-Effect for the Reactions of Aryl Acetates with Butane-2,3-dione Monoximate and p-Chlorophenoxide in MeCN−H2O Mixtures
inferredcites →https://doi.org/10.1021/jo9816459openalex-snapshot
An Unexpectedly Small α-Effect in Nucleophilic Attack at sp-Hybridized Carbon: Michael-Type Additions of Primary Amines to 3-Butyn-2-one
inferredcites →https://doi.org/10.1021/ol0526930openalex-snapshot
The α-Effect in Gas-Phase SN2 Reactions Revisited
inferredcites →https://doi.org/10.1039/a605249eopenalex-snapshot
Similar catalytic behaviour of oximate and phenoxide bases in the ionization of bis(2,4-dinitrophenyl)methane in 50% water– 50% Me2SO. Revisiting the role of solvational imbalances in determining the nucleophilic reactivity of α-effect oximate bases
inferredcites →https://doi.org/10.1039/b212160nopenalex-snapshot
The levelling effect of solvational imbalances in the reactions of oximate α-nucleophiles with electrophilic phosphorus centers. Relevance to detoxification of organophosphorus esters
inferredcites →https://doi.org/10.1039/p29910000153openalex-snapshot
Non-linear Brønsted correlations: evidence for a levelling off in the reactivity of oximate ions in aqueous solution
inferredcites →https://doi.org/10.5860/choice.41-4672openalex-snapshot
The role of the solvent in chemical reactions
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
inferred← citeshttps://doi.org/10.1002/9780470669587.ch2openalex-snapshot
Reactions of Carboxylic, Phosphoric and Sulfonic Acids and their Derivatives
inferred← citeshttps://doi.org/10.1002/9780470979525.ch2openalex-snapshot
Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives
inferred← citeshttps://doi.org/10.1002/bkcs.10836openalex-snapshot
Kinetic Study on Nucleophilic Substitution Reactions of Aryl Diphenylphosphinates with Butane‐2,3‐dione Monoximate and Aryloxide Anions: Reaction Mechanism and Origin of the α‐Effect
inferred← citeshttps://doi.org/10.1002/chem.200801534openalex-snapshot
Effects on the Reactivity by Changing the Electrophilic Center from CO to CS: Contrasting Reactivity of Hydroxide, p‐Chlorophenoxide, and Butan‐2,3‐dione Monoximate in DMSO/H2O Mixtures
inferred← citeshttps://doi.org/10.1002/jcc.23356openalex-snapshot
The α-effect exhibited in gas-phase S N 2@N and S N 2@C reactions
inferred← citeshttps://doi.org/10.1002/jcc.23862openalex-snapshot
Probing the reactivity of microhydrated α‐nucleophile in the anionic gas‐phase SN2 reaction
inferred← citeshttps://doi.org/10.1016/j.ijms.2012.07.016openalex-snapshot
The α-effect in elimination reactions and competing mechanisms in the gas phase
inferred← citeshttps://doi.org/10.1016/j.jphotochem.2024.116239openalex-snapshot
Estimation of the nucleophilic α- and their relative β-, γ- and δ-effects in solution through fluorometry
inferred← citeshttps://doi.org/10.1016/j.molliq.2015.12.044openalex-snapshot
Specific salt effects on the hydrolysis reaction rate of tropolone tosylate in binary MeCN–H2O media containing n-Bu4NOH
inferred← citeshttps://doi.org/10.1016/j.seppur.2024.126943openalex-snapshot
Alpha effect-driven enhancement of CO2 capture kinetics and size-controlled NaHCO3 crystals: Promoter-added NaOH absorbent study
inferred← citeshttps://doi.org/10.1021/ja205741mopenalex-snapshot
Experimental Validation of the α-Effect in the Gas Phase
inferred← citeshttps://doi.org/10.1021/jo1006575openalex-snapshot
Enhanced Reactivity of RC≡CZ− (R = H and Cl; Z = O, S, and Se) and the Influence of Leaving Group on the α-Effect in the E2 Reactions
inferred← citeshttps://doi.org/10.1021/jo101978xopenalex-snapshot
Pitfalls in Assessing the α-Effect: Reactions of Substituted Phenyl Methanesulfonates with HOO−, OH−, and Substituted Phenoxides in H2O
inferred← citeshttps://doi.org/10.1021/jo401415fopenalex-snapshot
Dissection of Activation Parameters in the Bell-Shaped α-Effect Following Solvent Modulation (DMSO–H2O Media)
inferred← citeshttps://doi.org/10.1039/b719310fopenalex-snapshot
Reaction mechanisms : Part (iii) Polar reactions
inferred← citeshttps://doi.org/10.1039/c5cp07803bopenalex-snapshot
Theoretical estimation of kinetic parameters for nucleophilic substitution reactions in solution: an application of a solution translational entropy model
inferred← citeshttps://doi.org/10.1039/c9py01199dopenalex-snapshot
Catalyst-free, aza-Michael polymerization of hydrazides: polymerizability, kinetics, and mechanistic origin of an α-effect
inferred← citeshttps://doi.org/10.1139/cjc-2015-0073openalex-snapshot
The α-effect in the SNAr reaction of 1-(4-nitrophenoxy)-2,4-dinitrobenzene with anionic nucleophiles: effects of solvation and polarizability on the α-effect
inferred← citeshttps://doi.org/10.1139/cjc-2018-0290openalex-snapshot
Hydrazinolysis of aryl cinnamates and related esters: the α-effect arises from stabilization of five-membered cyclic transition state
inferred← citeshttps://doi.org/10.1139/cjc-2020-0503openalex-snapshot
Effect of medium on reactivity for alkaline hydrolysis of p-nitrophenyl acetate and S-p-nitrophenyl thioacetate in DMSO–H2O mixtures of varying compositions: ground state and transition state contributions
inferred← citeshttps://doi.org/10.1246/bcsj.20090246openalex-snapshot
Gas-Phase Acidities of Acetophenone Oximes. Substituent Effect and Solvent Effects
inferred← citeshttps://doi.org/10.5012/bkcs.2009.30.10.2393openalex-snapshot
The α-Effect and Mechanism of Reactions of Y-Substituted Phenyl Benzenesulfonates with Hydrogen Peroxide Ion
inferred← citeshttps://doi.org/10.5012/bkcs.2009.30.11.2785openalex-snapshot
Origin of the α-Effect in Aminolysis of Y-Substituted Phenyl Diphenylphosphinates: Ground-state Versus Transition-state Contribution
inferred← citeshttps://doi.org/10.5012/bkcs.2009.30.12.2913openalex-snapshot
Origin of the α-Effect in Nucleophilic Substitution Reactions of Y-Substituted Phenyl Benzoates with Butane-2,3-dione Monoximate and Z-Substituted Phenoxides: Ground-State Destabilization vs. Transition-State Stabilization
inferred← citeshttps://doi.org/10.5012/bkcs.2011.32.8.2955openalex-snapshot
Aminolysis of Y- Substituted Phenyl Benzenesulfonates in MeCN: Effect of Medium on Reactivity and Reaction Mechanism
inferred← citeshttps://doi.org/10.5012/bkcs.2013.34.1.49openalex-snapshot
Nucleophilic Substitution Reactions of Phenyl Y-Substituted-Phenyl Carbonates with Butane-2,3-dione Monoximate and 4-Chlorophenoxide: Origin of the α-Effect
inferred← citeshttps://doi.org/10.5012/bkcs.2013.34.12.3855openalex-snapshot
Origin of the α-Effect in Detoxification of Paraoxon and Parathion by Hydrogen Peroxide Anion
inferred← citeshttps://doi.org/10.5012/bkcs.2013.34.8.2251openalex-snapshot
The α-Effect in Nucleophilic Substitution Reactions of Y-Substituted-Phenyl Diphenylphosphinates with HOO-and OH-
inferred← citeshttps://doi.org/10.5012/bkcs.2014.35.2.436openalex-snapshot
Kinetic Study on Nucleophilic Displacement Reactions of 2-Chloro-4-Nitrophenyl X-Substituted-Benzoates with Primary Amines: Reaction Mechanism and Origin of the α-Effect
inferred← citeshttps://doi.org/10.5012/bkcs.2014.35.8.2271openalex-snapshot
The α-Effect in Hydrazinolysis of 4-Chloro-2-Nitrophenyl X-Substituted-Benzoates: Effect of Substituent X on Reaction Mechanism and the α-Effect
inferred← citeshttps://doi.org/10.5012/bkcs.2014.35.8.2371openalex-snapshot
The α-Effect in SNAr Reaction of 1-Fluoro-2,4-dinitrobenzene with Hydrazine: Ground-State Destabilization versus Transition-State Stabilization
inferred← citeshttps://doi.org/10.5012/bkcs.2014.35.8.2448openalex-snapshot
The α-Effect in SNAr Reaction of Y-Substituted-Phenoxy-2,4-Dinitrobenzenes with Amines: Reaction Mechanism and Origin of the α-Effect
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