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Experimental Validation of the α-Effect in the Gas Phase

https://doi.org/10.1021/ja205741m
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Outgoing claims: the papers this work cites, builds on, or argues with.

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G2(+) Investigation on the α‐Effect in the SN2 Reactions at Saturated Carbon
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The tandem flowing afterglow-shift-drift
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The α-effect and its modulation by solvent
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Gas phase nucleophilic substitution
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Mass Spectrometric Studies of Organic Ion/Molecule Reactions
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Vibrational Excitation in Products of Nucleophilic Substitution: The Dissociation of Metastable X-(CH3Y) in the Gas Phase
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Absence of an .alpha.-effect in the gas-phase nucleophilic reactions of hydroperoxide ion
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The Factors Determining Nucleophilic Reactivities
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Acid Ionization Constants of Alcohols. II. Acidities of Some Substituted Methanols and Related Compounds1,2
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Leaving Group Effects in Gas-Phase Substitutions and Eliminations
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Reactions of α-Nucleophiles with Alkyl Chlorides: Competition between SN2 and E2 Mechanisms and the Gas-Phase α-Effect
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Factors Affecting Competitive Ion−Molecule Reactions: ClO - + C 2 H 5 Cl and C 2 D 5 Cl via E2 and S N 2 Channels
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Intrinsic Barriers in Identity SN2 Reactions and the Periodic Table
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The .alpha. effect: on the origin of transition-state stabilization
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On Gas Phase α-Effects. 1. The Gas-Phase Manifestation and Potential SET Character
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The α-Effect in Gas-Phase SN2 Reactions: Existence and the Origin of the Effect
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Rate Constants as a Function of Temperature and Kinetic Energy for the Reactions of Cl- with C2H5Br and n-C3H7Br
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Anchoring the Gas-Phase Acidity Scale
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Reactions of the hydroperoxide anion with dimethyl methylphosphonate in an ion trap mass spectrometer: evidence for a gas phase α-effect
inferredcites →https://doi.org/10.1063/1.442828openalex-snapshot
Parametrization of the ion–polar molecule collision rate constant by trajectory calculations
inferredcites →https://doi.org/10.1126/science.266.5187.998openalex-snapshot
Simulations of Gas-Phase Chemical Reactions: Applications to S N 2 Nucleophilic Substitution
inferredcites →https://doi.org/10.1139/v06-156openalex-snapshot
Medium effects on the α-effect in DMSO–H2O mixtures — Comparative studies of p-nitrophenyl benzoate and acetate — Dissection of ground-state and transition-state effects
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Gaseous ions and chemical mass spectrometry
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CRC Handbook of Chemistry and Physics
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Steric and electronic effects in SN2 reactions
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Origin of the α-Effect in Nucleophilic Substitution Reactions of Y-Substituted Phenyl Benzoates with Butane-2,3-dione Monoximate and Z-Substituted Phenoxides: Ground-State Destabilization vs. Transition-State Stabilization

What points at this work

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The α-Effect in Gas-Phase SN2 Reactions of Microsolvated Anions: Methanol as a Solvent
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