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A Zinc-Catalyzed Synthesis of 3-Trifluoromethyl-4-Trifluoroacetyl Pyrazoles

https://doi.org/10.2139/ssrn.4133499
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Solvent‐ and Transition Metal Catalyst‐Dependent Regioselectivity in the [3+2] Cyclocondensation of Trifluoromethyl‐α,β‐ynones with Hydrazines: Switchable Access to 3‐ and 5‐Trifluoromethylpyrazoles
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Silver‐Mediated Cycloaddition of Alkynes with CF3CHN2: Highly Regioselective Synthesis of 3‐Trifluoromethylpyrazoles
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Copper‐Catalyzed Synthesis of 5‐Aryl‐6‐(Trifluoromethyl)‐2,3‐Dihydropyrazolo[1,2‐a]Pyrazol‐1(5H)‐One
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Multigram Synthesis of Fluoroalkyl‐Substituted Pyrazole‐4‐carboxylic Acids
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Selective Incorporation of Fluorine in Pyrazoles
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Synthesis of 3‐(Trifluoromethyl)pyrazoles and Polysubstituted Pyrazoles by a tBuOK‐Mediated Intramolecular Cyclization
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Mild and Regioselective Synthesis of 3‐CF3‐Pyrazoles by the AgOTf‐Catalysed Reaction of CF3‐Ynones with Hydrazines
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A convenient and versatile synthesis of 4‐trifluoromethyl‐substituted pyrazoles
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Effect of the new pyrazole carboxamide fungicide penthiopyrad on late leaf spot and stem rot of peanut
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5-(4-Chlorophenyl)-1-(4-methoxyphenyl)-3-trifluoromethylpyrazole acts in a reactive oxygen species-dependent manner to suppress human lung cancer growth
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Recently reported biological activities of pyrazole compounds
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Recent advances in bioactive pyrazoles
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Recent advances of pyrazole-containing derivatives as anti-tubercular agents
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Reaction of 2-hydroxyethylhydrazine with a trifluoromethyl-β-diketone: Study and structural characterization of a new 5-hydroxy-5-trifluoromethyl-4,5-dihydropyrazole intermediate
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Trifluoromethylpyrazoles as anti-inflammatory and antibacterial agents: A review
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An efficient route to 3-trifluoromethylpyrazole via cyclization/1,5-H shift and its applications in the synthesis of bioactive compounds
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Synthesis of fluazolate via the application of regioselective [3+2] cyclocondensation and nucleophilic substitution-cyclization strategies
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Microwave-assisted synthesis utilizing supported reagents: a rapid and versatile synthesis of 1,5-diarylpyrazoles
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A facile synthesis of pyrazoles with multi-point structural diversity by 1,3-dipolar cycloaddition
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Direct [3+2]-cycloaddition of electron-deficient alkynes with CF3CHN2: Regioselective one-pot synthesis of 3-trifluoromethylpyrazoles
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Synthesis of fluorinated heterocycles
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Fluorinated Pyrazoles: From Synthesis to Applications
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Selective, Metal-Free Approach to 3- or 5-CF3-Pyrazoles: Solvent Switchable Reaction of CF3-Ynones with Hydrazines
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Trifluoromethylated Pyrazoles via Sequential (3 + 2)-Cycloaddition of Fluorinated Nitrile Imines with Chalcones and Solvent-Dependent Deacylative Oxidation Reactions
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New hydroxy-pyrazoline intermediates, subtle regio-selectivity and relative reaction rate variations observed during acid catalyzed and neutral pyrazole cyclization
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Synthesis of 3-trifluoromethylpyrazoles via trifluoromethylation/cyclization of α,β-alkynic hydrazones using a hypervalent iodine reagent
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Review: biologically active pyrazole derivatives
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Sydnone–alkyne cycloaddition: applications in synthesis and bioconjugation
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Polysubstituted 3-trifluoromethylpyrazoles: regioselective (3 + 2)-cycloaddition of trifluoroacetonitrile imines with enol ethers and functional group transformations
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Celecoxib
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Synthesis and Pharmacological Activities of Pyrazole Derivatives: A Review
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[3 + 2]-Cycloaddition reaction of sydnones with alkynes
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On the Structure of the Diels-Alder Adducts Obtained from (E)-3-Methoxycarbonylmethylene-2-oxoindoline with Unsymmetrical Butadiene Derivatives
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