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Mechanistic Insights on the β-(Z) Alkyne Hydrosilylation by a NHC-based Cp*Rh(III) Catalyst: From Catalyst Design to an Alternative Model for H-Si Activation

https://doi.org/10.2139/ssrn.5779546
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A Rh(I) complex with an annulated N-heterocyclic carbene ligand for E-selective alkyne hydrosilylation
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Hydrosilylation of Terminal Alkynes Catalyzed by an Air-Stable Manganese–NHC Complex
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Synthesis, Characterization, and Antimicrobial Activity of RhIII and IrIII N-Heterocyclic Carbene Piano-Stool Complexes
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Self-Isomerized–Cyclometalated Rhodium NHC Complexes as Active Catalysts in the Hydrosilylation of Internal Alkynes
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Preparation of Rhodium(III) Di-NHC Chelate Complexes Featuring Two Different NHC Donors via a Mild NaOAc-Assisted C–H Activation
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Hydrosilylation of Terminal Alkynes Catalyzed by a ONO-Pincer Iridium(III) Hydride Compound: Mechanistic Insights into the Hydrosilylation and Dehydrogenative Silylation Catalysis
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Rhodium(I) Complexes with Ligands Based on N-Heterocyclic Carbene and Hemilabile Pyridine Donors as Highly E Stereoselective Alkyne Hydrosilylation Catalysts
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Synthesis of Iridium(III) and Rhodium(III) Complexes Bearing C8-Metalated Theophylline Ligands by Directed C–H Activation
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Highly β(Z)-Selective Hydrosilylation of Terminal Alkynes Catalyzed by Thiolate-Bridged Dirhodium Complexes
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Hybrid Catalysts Comprised of Graphene Modified with Rhodium-Based N-Heterocyclic Carbenes for Alkyne Hydrosilylation
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β‑(Z) Selectivity Control by Cyclometalated Rhodium(III)–Triazolylidene Homogeneous and Heterogeneous Terminal Alkyne Hydrosilylation Catalysts
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Dinuclear Cobalt Complex-Catalyzed Stereodivergent Semireduction of Alkynes: Switchable Selectivities Controlled by H2O
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Plausible Rh(V) Intermediates in Catalytic C–H Activation Reactions
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Distinct Catalytic Performance of Cobalt(I)–N-Heterocyclic Carbene Complexes in Promoting the Reaction of Alkene with Diphenylsilane: Selective 2,1-Hydrosilylation, 1,2-Hydrosilylation, and Hydrogenation of Alkene
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Catalytic N 2 -to-NH 3 Conversion by Fe at Lower Driving Force: A Proposed Role for Metallocene-Mediated PCET
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Hemilabile and Bimetallic Coordination in Rh and Ir Complexes of NCN Pincer Ligands
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Unusual activity and selectivity in alkyne hydrosilylation with an iridium catalyst stabilized by an oxygen-donor ligand
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Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart’s Cationic Iridium(III) Pincer Complex
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