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Remarkable magnitude of the self-disproportionation of enantiomers (SDE) via achiral chromatography: application to the practical-scale enantiopurification of β-amino acid esters
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Outgoing claims: the papers this work cites, builds on, or argues with.
inferredcites →https://doi.org/10.1002/(sici)1097-0282(200002)53:2<200::aid-bip10>3.0.co;2-lopenalex-snapshot
Conformational restriction through C?i ? C?i cyclization: Ac12c, the largest cycloaliphatic C?,?- disubstituted glycine known
inferredcites →https://doi.org/10.1002/(sici)1099-0690(200001)2000:1<83::aid-ejoc83>3.0.co;2-2openalex-snapshot
Diastereoselective Synthesis of β2-Amino Acids
inferredcites →https://doi.org/10.1002/(sici)1520-636x(1996)8:3<234::aid-chir2>3.0.co;2-hopenalex-snapshot
Enantiomeric enrichment of non-racemic mixtures of binaphthol with non-chiral packings
inferredcites →https://doi.org/10.1002/1097-0282(2000)55:2<101::aid-bip20>3.0.co;2-oopenalex-snapshot
Design, synthesis, and conformational analysis of azacycloalkane amino acids as conformationally constrained probes for mimicry of peptide secondary structures
inferredcites →https://doi.org/10.1002/adsc.201000035openalex-snapshot
Efficient Tandem Biocatalytic Process for the Kinetic Resolution of Aromatic β‐Amino Acids
inferredcites →https://doi.org/10.1002/anie.200300599openalex-snapshot
Industrial Methods for the Production of Optically Active Intermediates
inferredcites →https://doi.org/10.1002/anie.200503373openalex-snapshot
Remarkable Amplification of the Self‐Disproportionation of Enantiomers on Achiral‐Phase Chromatography Columns
inferredcites →https://doi.org/10.1002/anie.201403556openalex-snapshot
Chemical Kinetic Resolution of Unprotected β‐Substituted β‐Amino Acids Using Recyclable Chiral Ligands
inferredcites →https://doi.org/10.1002/anie.201500908openalex-snapshot
Assembly of Fluorinated Quaternary Stereogenic Centers through Catalytic Enantioselective Detrifluoroacetylative Aldol Reactions
inferredcites →https://doi.org/10.1002/bip.360330709openalex-snapshot
Conformational and topographical considerations in the design of biologically active peptides
inferredcites →https://doi.org/10.1002/cbic.200900184openalex-snapshot
Kinetic Resolution of Aliphatic β‐Amino Acid Amides by β‐Aminopeptidases
inferredcites →https://doi.org/10.1002/cctc.201000343openalex-snapshot
Enzymatic Dynamic Kinetic Resolution of Oxazinones: A New Approach to Enantiopure β2‐Amino Acids
inferredcites →https://doi.org/10.1002/chin.199236199openalex-snapshot
ChemInform Abstract: A Novel Approach to the Synthesis of Symmetric Optically Active 2,5‐ Dioxopiperazines.
inferredcites →https://doi.org/10.1002/chir.22180openalex-snapshot
Optical Purifications via Self‐Disproportionation of Enantiomers by Achiral Chromatography: Case Study of a Series of α‐CF3‐containing Secondary Alcohols
inferredcites →https://doi.org/10.1002/hlca.201400122openalex-snapshot
Terminology Related to the Phenomenon ‘Self‐Disproportionation of Enantiomers’ (SDE)
inferredcites →https://doi.org/10.1002/hlca.201500041openalex-snapshot
Enantiomeric Enrichments via the Self‐Disproportionation of Enantiomers (SDE) by Achiral, Gravity‐Driven Column Chromatography: a Case Study Using N‐(1‐Phenylethyl)acetamide for Optimizing the Enantiomerically Pure Yield and Magnitude of the SDE
inferredcites →https://doi.org/10.1007/bf00476607openalex-snapshot
Is it possible to affect the enantiomeric composition by a simple distillation process?
inferredcites →https://doi.org/10.1016/0021-9673(92)85233-jopenalex-snapshot
Computer simulation of three scenarios for the separation of non-racemic mixtures by chromatography on achiral stationary phases
inferredcites →https://doi.org/10.1016/0021-9673(94)80413-3openalex-snapshot
Resolution of non-racemic mixtures in achiral chromatographic systems: A model for, the enantioselective effects observed
inferredcites →https://doi.org/10.1016/0167-7799(90)90187-3openalex-snapshot
Peptidomimetics and the template approach to nucleation of β-sheets and α-helices in peptides
inferredcites →https://doi.org/10.1016/0957-4166(94)80063-4openalex-snapshot
Biocatalytic resolution of β-fluoroalkyl-β-amino acids
inferredcites →https://doi.org/10.1016/0957-4166(94)80163-0openalex-snapshot
Chemo-enzymatic approach to the synthesis of each of the four isomers of α-alkyl-β-fluoroalkyl-substituted β-amino acids
inferredcites →https://doi.org/10.1016/0957-4166(95)00204-3openalex-snapshot
Biocatalytic approach to enantiomerically pure β-amino acids
inferredcites →https://doi.org/10.1016/j.chroma.2003.10.071openalex-snapshot
General model for the achiral chromatography of enantiomers forming dimers: application to binaphthol
inferredcites →https://doi.org/10.1016/j.chroma.2008.11.016openalex-snapshot
Elaborate treatment of retention in chemoselective chromatography—The retention increment approach and non-linear effects
inferredcites →https://doi.org/10.1016/j.jfluchem.2009.10.002openalex-snapshot
Self-disproportionation of enantiomers of 3,3,3-trifluorolactic acid amides via sublimation
inferredcites →https://doi.org/10.1016/j.jfluchem.2009.10.018openalex-snapshot
NMR spectral enantioresolution of spirobrassinin and 1-methoxyspirobrassinin enantiomers using (S)-(−)-ethyl lactate and modeling of spirobrassinin self-association for rationalization of its self-induced diastereomeric anisochromism (SIDA) and enantiomer self-disproportionation on achiral-phase…
inferredcites →https://doi.org/10.1016/j.jfluchem.2009.11.010openalex-snapshot
Self-disproportionation of enantiomers of α-trifluoromethyl lactic acid amides via sublimation
inferredcites →https://doi.org/10.1016/j.jfluchem.2009.11.015openalex-snapshot
Chirality-dependent sublimation of -(trifluoromethyl)-lactic acid: Relative vapor pressures of racemic, eutectic, and enantiomerically pure forms, and vibrational spectroscopy of isolated (S,S) and (S,R) dimers
inferredcites →https://doi.org/10.1016/j.jfluchem.2009.11.026openalex-snapshot
Self-disproportionation of enantiomers of isopropyl 3,3,3-(trifluoro)lactate via sublimation: Sublimation rates vs. enantiomeric composition
inferredcites →https://doi.org/10.1016/j.jfluchem.2009.12.002openalex-snapshot
Self-disproportionation of enantiomers of heterocyclic compounds having a tertiary trifluoromethyl alcohol center on chromatography with a non-chiral system
inferredcites →https://doi.org/10.1016/j.jfluchem.2009.12.007openalex-snapshot
Discrimination of enantiomeric excess of optically active trifluorolactate by distillation: Evidence for a multi-center hydrogen bonding network in the liquid state
inferredcites →https://doi.org/10.1016/j.jfluchem.2009.12.008openalex-snapshot
Attempts to explain the self-disproportionation observed in the partial sublimation of enantiomerically enriched carboxylic acids
inferredcites →https://doi.org/10.1016/j.nbt.2009.06.291openalex-snapshot
β-Aminopeptidases: enzymatic degradation and synthesis of β-amino acid containing peptides and kinetic resolution of β-amino acid amides
inferredcites →https://doi.org/10.1016/j.tet.2004.05.051openalex-snapshot
Synthesis of fluorinated amino acids
inferredcites →https://doi.org/10.1016/j.tet.2006.03.109openalex-snapshot
Biocatalysis as a profound tool in the preparation of highly enantiopure β-amino acids
inferredcites →https://doi.org/10.1016/j.tet.2012.03.054openalex-snapshot
Self-disproportionation of enantiomers of non-racemic chiral amine derivatives through achiral chromatography
inferredcites →https://doi.org/10.1016/j.tetasy.2010.03.035openalex-snapshot
Enantiodifferentiation of phytoalexin spirobrassinin derivatives using the chiral solvating agent (R)-(+)-1,1′-bi-2-naphthol in conjunction with molecular modeling
inferredcites →https://doi.org/10.1016/j.tetasy.2010.04.027openalex-snapshot
Nonlinear effects in enantioselective chromatography: prediction of unusual elution profiles of enantiomers in non-racemic mixtures on an achiral stationary phase doped with small amounts of a chiral selector
inferredcites →https://doi.org/10.1016/j.tetasy.2010.04.040openalex-snapshot
Rational application of self-disproportionation of enantiomers via sublimation—a novel methodological dimension for enantiomeric purifications
inferredcites →https://doi.org/10.1016/j.tetasy.2013.06.008openalex-snapshot
Self-disproportionation of enantiomers of prazoles via achiral, gravity-driven silica gel column chromatography
inferredcites →https://doi.org/10.1016/j.tetasy.2015.02.006openalex-snapshot
The effect of the eutectic composition on the outcome of kinetically and thermodynamically controlled resolutions that are based on the formation of diastereomers
inferredcites →https://doi.org/10.1016/j.tetlet.2013.07.061openalex-snapshot
Chiral initiator-induces self-disproportionation of enantiomers via achiral chromatography: application to enantiomer separation of racemate
inferredcites →https://doi.org/10.1016/s0021-9673(01)01366-8openalex-snapshot
Separation of binaphthol enantiomers through achiral chromatography
inferredcites →https://doi.org/10.1016/s0040-4020(01)00540-3openalex-snapshot
Enantioselective synthesis of β-amino acids. Part 11: Diastereoselective alkylation of chiral derivatives of β-aminopropionic acid containing the α-phenethyl group
inferredcites →https://doi.org/10.1016/s0040-4020(01)85527-7openalex-snapshot
Recent stereoselective synthetic approaches to β-amino acids
inferredcites →https://doi.org/10.1016/s0040-4020(01)90214-5openalex-snapshot
A hierarchical approach to peptidomimetic design
inferredcites →https://doi.org/10.1021/ja065603aopenalex-snapshot
Phenomenon of Optical Self-Purification of Chiral Non-Racemic Compounds
inferredcites →https://doi.org/10.1021/ja067905iopenalex-snapshot
Separation of Racemate from Excess Enantiomer of Chiral Nonracemic Compounds via Density Gradient Ultracentrifugation
inferredcites →https://doi.org/10.1021/jo00081a015openalex-snapshot
Enantiomeric enrichment of sulfoxides by preparative flash chromatography on an achiral phase
inferredcites →https://doi.org/10.1021/jo4017474openalex-snapshot
Partial Sublimation of Enantioenriched Amino Acids at Low Temperature. Is it Coming From the Formation of a Euatmotic Composition1 of the Gaseous Phase?
inferredcites →https://doi.org/10.1021/ol006614qopenalex-snapshot
Synthesis of α-Substituted β-Amino Acids Using Pseudoephedrine as a Chiral Auxiliary
inferredcites →https://doi.org/10.1039/b814905dopenalex-snapshot
NMR and molecular modeling of the dimeric self-association of the enantiomers of 1,1′-bi-2-naphthol and 1-phenyl-2,2,2-trifluoroethanol in the solution state and their relevance to enantiomer self-disproportionation on achiral-phase chromatography (ESDAC)
inferredcites →https://doi.org/10.1039/b915610kopenalex-snapshot
A simple explanation of the enhancement or depletion of the enantiomeric excess in the partial sublimation of enantiomerically enriched amino acids
inferredcites →https://doi.org/10.1039/c2cc37491aopenalex-snapshot
Unconventional preparation of racemic crystals of isopropyl 3,3,3-trifluoro-2-hydroxypropanoate and their unusual crystallographic structure: the ultimate preference for homochiral intermolecular interactions
inferredcites →https://doi.org/10.1039/c4ob00831fopenalex-snapshot
The self-disproportionation of the enantiomers (SDE) of methyl n-pentyl sulfoxide via achiral, gravity-driven column chromatography: a case study
inferredcites →https://doi.org/10.1039/c4ra13928copenalex-snapshot
A comprehensive examination of the self-disproportionation of enantiomers (SDE) of chiral amides via achiral, laboratory-routine, gravity-driven column chromatography
inferredcites →https://doi.org/10.1039/cs9962500117openalex-snapshot
Asymmetric synthesis of ß-amino acids and α-substituted β-amino acids
inferredcites →https://doi.org/10.1055/s-0030-1260173openalex-snapshot
Synthesis of Fluorinated β-Amino Acids
inferredcites →https://doi.org/10.1055/s-0032-1316812openalex-snapshot
Self-Disproportionation of Enantiomers of Chiral, Non-Racemic Fluoroorganic Compounds: Role of Fluorine as Enabling Element
inferredcites →https://doi.org/10.1055/s-1992-26131openalex-snapshot
A Novel Approach to the Synthesis of Symmetric Optically Active 2,5-Dioxopiperazines
inferredcites →https://doi.org/10.1055/s-1993-22447openalex-snapshot
An Enzymatic Entry to Enantiopure β-Amino Acids
inferredcites →https://doi.org/10.1055/s-2005-869903openalex-snapshot
Resolution of Enantiomers by Non-Conventional Methods
inferredcites →https://doi.org/10.1071/ch9910895openalex-snapshot
The Optical Fractionation of a Partially Racemic Natural Product by Chromatography Over an Achiral Substrate
inferredcites →https://doi.org/10.1146/annurev.bi.61.070192.002131openalex-snapshot
CONSTRAINED PEPTIDES: MODELS OF BIOACTIVE PEPTIDES AND PROTEIN SUBSTRUCTURES
inferredcites →https://doi.org/10.1246/cl.1996.115openalex-snapshot
Separation of an Enantiomorph and Its Racemate by Distillation: Strong Chiral Recognizing Ability of Trifluorolactates
inferredcites →https://doi.org/10.2174/0929867003374499openalex-snapshot
Conformational and Topographical Considerations in Designing Agonist Peptidomimetics from Peptide Leads
inferredcites →https://doi.org/10.2174/0929867024606759openalex-snapshot
β-Amino Acids: Versatile Peptidomimetics
inferredcites →https://doi.org/10.2174/092986712804485683openalex-snapshot
Recent Lipase-Catalyzed Hydrolytic Approaches to Pharmacologically Important β-and γ-Amino Acids
inferredcites →https://doi.org/10.2174/092986730610220401161510openalex-snapshot
Recent Advances in the Enantioselective Synthesis of β-Amino Acids
inferredcites →https://doi.org/10.2174/157017911794697303openalex-snapshot
Self-Disproportionation of Enantiomers via Sublimation; New and Truly Green Dimension in Optical Purification
inferredcites →https://doi.org/10.2174/1570193043488908openalex-snapshot
Direct and Indirect Enzymatic Methods for the Preparation of Enantiopure Cyclic β-Amino Acids and Derivatives from β-Lactams
inferredcites →https://doi.org/10.4236/ijoc.2012.23031openalex-snapshot
Suggested New Terms for Describing Chiral States and the State-Dependent Behavior of Chiral Systems
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
inferred← citeshttps://doi.org/10.1002/9783527825158.ch9openalex-snapshot
The Self‐Disproportionation of Enantiomers ( SDE ): Fluorine as an SDE ‐Phoric Substituent
inferred← citeshttps://doi.org/10.1002/adsc.202100493openalex-snapshot
DBU Catalysed Enantioselective Degradative Rearrangement: a Way to Tetrasubstituted 2‐Aryl‐2‐Amino Esters
inferred← citeshttps://doi.org/10.1002/chem.201703308openalex-snapshot
Possible Case of Halogen Bond‐Driven Self‐Disproportionation of Enantiomers (SDE) via Achiral Chromatography
inferred← citeshttps://doi.org/10.1002/chir.23203openalex-snapshot
Michael addition reactions of chiral glycine Schiff base Ni (II)‐complex with 1‐(1‐phenylsulfonyl)benzene
inferred← citeshttps://doi.org/10.1002/chir.23376openalex-snapshot
New pharmaceuticals approved by FDA in 2020: Small‐molecule drugs derived from amino acids and related compounds
inferred← citeshttps://doi.org/10.1002/elps.201800414openalex-snapshot
The self‐disproportionation of enantiomers (SDE): The effect of scaling down, potential problems versus prospective applications, possible new occurrences, and unrealized opportunities?
inferred← citeshttps://doi.org/10.1002/ijch.201600077openalex-snapshot
Self‐disproportionation of Enantiomers (SDE) of Chiral Nonracemic Amides via Achiral Chromatography
inferred← citeshttps://doi.org/10.1002/ijch.201600086openalex-snapshot
Enantioseparations in Achiral Environments and Chromatographic Systems
inferred← citeshttps://doi.org/10.1007/s00726-018-2664-xopenalex-snapshot
The self-disproportionation of enantiomers (SDE) of α-amino acid derivatives: facets of steric and electronic properties
inferred← citeshttps://doi.org/10.1007/s00726-019-02729-yopenalex-snapshot
The self-disproportionation of enantiomers (SDE) of amino acids and their derivatives
inferred← citeshttps://doi.org/10.1007/s00726-019-02774-7openalex-snapshot
The self-disproportionation of enantiomers (SDE) via column chromatography of β-amino-α,α-difluorophosphonic acid derivatives
inferred← citeshttps://doi.org/10.1016/b978-0-12-812958-6.00010-0openalex-snapshot
Fluorine-Containing Pharmaceuticals and the Phenomenon of the Self-Disproportionation of Enantiomers
inferred← citeshttps://doi.org/10.1016/j.chroma.2016.05.044openalex-snapshot
Self-disproportionation of enantiomers via achiral gravity-driven column chromatography: A case study of N -acyl-α-phenylethylamines
inferred← citeshttps://doi.org/10.1016/j.chroma.2023.464603openalex-snapshot
Altering the mobile phase composition to enhance self-disproportionation of enantiomers in achiral chromatography
inferred← citeshttps://doi.org/10.1016/j.chroma.2025.466175openalex-snapshot
Effect of temperature on chromatographic separation driven by enantiomer self-disproportionation
inferred← citeshttps://doi.org/10.1016/j.chroma.2025.466608openalex-snapshot
Equilibrium theory-based framework for descripting separation of enantiomers by frontal achiral chromatography
inferred← citeshttps://doi.org/10.1016/j.chroma.2026.467101openalex-snapshot
Effect of modification of silica surface on the extent of enantiomer self-disproportionation
inferred← citeshttps://doi.org/10.1016/j.jfluchem.2016.07.016openalex-snapshot
Self-Disproportionation of Enantiomers (SDE) via achiral gravity-driven column chromatography of N -fluoroacyl-1-phenylethylamines
inferred← citeshttps://doi.org/10.1016/j.jfluchem.2016.12.007openalex-snapshot
Detrifluoroacetylative generation and chemistry of fluorine containing tertiary enolates
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Preparation of peanut shell-like calcium carbonate from biowaste chicken eggshell and its application for aqueous Victoria Blue B removal
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Asymmetric Michael addition reaction organocatalyzed by stereoisomeric pyrrolidine sulfinamides under neat conditions. A brief study of self-disproportionation of enantiomers
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Access to the enantiopure pyrrolobenzodiazepine (PBD) dilactam nucleus via self-disproportionation of enantiomers
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A question of policy: should tests for the self-disproportionation of enantiomers (SDE) be mandatory for reports involving scalemates?
inferred← citeshttps://doi.org/10.1039/c6cs00703aopenalex-snapshot
Chiral sulfoxides: advances in asymmetric synthesis and problems with the accurate determination of the stereochemical outcome
inferred← citeshttps://doi.org/10.1039/c7sc05138gopenalex-snapshot
The self-disproportionation of enantiomers (SDE): a menace or an opportunity?
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Can enantiomers be separated in achiral chromatographic systems?
inferred← citeshttps://doi.org/10.15407/bioorganica2021.01.003openalex-snapshot
Aldol Addition-Cyclization Reaction Cascade on a Platform of Chiral Ni(II) Complex of Glycine Schiff Base
inferred← citeshttps://doi.org/10.15407/bioorganica2023.02.003openalex-snapshot
Discovery of biomimetic transamination as a general synthetic method for preparation of fluorine-containing amines and amino acids
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New drugs appearing on the market in 2023: molecules containing fluorine and fragments of tailor-made amino acids
inferred← citeshttps://doi.org/10.15407/bioorganica2024.01.021openalex-snapshot
Enzymatic approaches for preparation of α-aminophosphonic acids and fluorine-containing β-amino acids
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NEW DRUGS ON THE PHARMACEUTICAL MARKET CONTAINING FLUORINE AND RESIDUES OF TAILOR-MADE AMINO ACIDS
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CUTTING-EDGE STRATEGIES IN THE ASYMMETRIC SYNTHESIS OF α-AMINOCYCLOPROPANE CARBOXYLIC ACIDS: ESSENTIAL SCAFFOLDS FOR DRUG DISCOVERY
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ENANTIOSELECTIVE CATALYSIS FOR THE SYNTHESIS OF 1-SUBSTITUTED-2,2,2-TRIFLUOROETHYLAMINES
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ENANTIOMER PURIFICATION THROUGH ACHIRAL CHROMATOGRAPHY: INTEGRATING SIMULATED MOVING BED AND SELF-DISPROPORTIONATION OF ENANTIOMERS
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MODERN PHARMACEUTICAL DRUGS FEATURING ALIPHATIC FLUORINE-CONTAINING GROUPS
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ORGANOFLUORINE CHEMISTRY IN ONCOLOGY: A REVIEW OF US FDA-APPROVED ANTICANCER DRUGS IN 2025 (review)
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The Synthesis of α-Aminophosphonates via Enantioselective Organocatalytic Reaction of 1-(N-Acylamino)alkylphosphonium Salts with Dimethyl Phosphite
inferred← citeshttps://doi.org/10.3390/molecules26092757openalex-snapshot
Recommended Tests for the Self-Disproportionation of Enantiomers (SDE) to Ensure Accurate Reporting of the Stereochemical Outcome of Enantioselective Reactions
inferred← citeshttps://doi.org/10.3390/molecules27123797openalex-snapshot
Asymmetric Michael Addition in Synthesis of β-Substituted GABA Derivatives
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Catalytic Asymmetric α-Functionalization of α-Branched Aldehydes
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Copper (II) Ions Induced Self-Disproportionation of Enantiomers in Capillary Electrophoresis for the Quantification of Atenolol Enantiomers
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The Latest FDA-Approved Pharmaceuticals Containing Fragments of Tailor-Made Amino Acids and Fluorine
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The Self-Disproportionation of Enantiomers (SDE) of α-Pinene via Evaporation off Silica Gel and Foam Fractionation—Validation of the Plausibility of SDE via Gas Chromatography (GC) for α-Pinene
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Investigation of Self-Disproportionation of Enantiomers via Column Chromatography (SDEvCC) Using 3-(ortho-Substituted-phenyl)quinazolin-4-one Derivatives
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