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The self-disproportionation of enantiomers (SDE): a menace or an opportunity?

https://doi.org/10.1039/c7sc05138g
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Remarkable Amplification of the Self‐Disproportionation of Enantiomers on Achiral‐Phase Chromatography Columns
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Kinetic Rationalization of Nonlinear Effects in Asymmetric Catalysis Based on Phase Behavior
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Possible Case of Halogen Bond‐Driven Self‐Disproportionation of Enantiomers (SDE) via Achiral Chromatography
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Terminology Related to the Phenomenon ‘Self‐Disproportionation of Enantiomers’ (SDE)
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Enantiomeric Enrichments via the Self‐Disproportionation of Enantiomers (SDE) by Achiral, Gravity‐Driven Column Chromatography: a Case Study Using N‐(1‐Phenylethyl)acetamide for Optimizing the Enantiomerically Pure Yield and Magnitude of the SDE
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Enantioselective Gas Chromatography in Search of the Origin of Biomolecular Asymmetry in Outer Space
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An Examination of the Thermodynamics of Fusion, Vaporization, and Sublimation of Ibuprofen and Naproxen by Correlation Gas Chromatography
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Self-disproportionation of Enantiomers of Enantiomerically Enriched Compounds
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Remarkable magnitude of the self-disproportionation of enantiomers (SDE) via achiral chromatography: application to the practical-scale enantiopurification of β-amino acid esters
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Stereochemistry of organic compounds
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Computer simulation of three scenarios for the separation of non-racemic mixtures by chromatography on achiral stationary phases
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Resolution of non-racemic mixtures in achiral chromatographic systems: A model for, the enantioselective effects observed
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Asymmetric aldol reactions of trifluoromethyl ketones with a chiral Ni(II) complex of glycine: Stereocontrolling effect of the trifluoromethyl group
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Enantiomeric enrichment by the use of density differences between racemic compounds and optically active enantiomers
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General model for the achiral chromatography of enantiomers forming dimers: application to binaphthol
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Elaborate treatment of retention in chemoselective chromatography—The retention increment approach and non-linear effects
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Self-disproportionation of enantiomers via achiral gravity-driven column chromatography: A case study of N -acyl-α-phenylethylamines
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Toward ideal separation by size-exclusion chromatography
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Self-disproportionation of enantiomers of (R)-ethyl 3-(3,5-dinitrobenzamido)-4,4,4-trifluorobutanoate on achiral silica gel stationary phase
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Self-disproportionation of enantiomers of 3,3,3-trifluorolactic acid amides via sublimation
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NMR spectral enantioresolution of spirobrassinin and 1-methoxyspirobrassinin enantiomers using (S)-(−)-ethyl lactate and modeling of spirobrassinin self-association for rationalization of its self-induced diastereomeric anisochromism (SIDA) and enantiomer self-disproportionation on achiral-phase…
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Self-disproportionation of enantiomers of α-trifluoromethyl lactic acid amides via sublimation
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Chirality-dependent sublimation of -(trifluoromethyl)-lactic acid: Relative vapor pressures of racemic, eutectic, and enantiomerically pure forms, and vibrational spectroscopy of isolated (S,S) and (S,R) dimers
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Self-disproportionation of enantiomers of isopropyl 3,3,3-(trifluoro)lactate via sublimation: Sublimation rates vs. enantiomeric composition
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Self-disproportionation of enantiomers of heterocyclic compounds having a tertiary trifluoromethyl alcohol center on chromatography with a non-chiral system
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Discrimination of enantiomeric excess of optically active trifluorolactate by distillation: Evidence for a multi-center hydrogen bonding network in the liquid state
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Attempts to explain the self-disproportionation observed in the partial sublimation of enantiomerically enriched carboxylic acids
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Amplification of chirality as a pathway to biological homochirality
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First principle lattice energy calculations for enantiopure and racemic crystals of α-(trifluoromethyl)lactic acid: Is self-disproportionation of enantiomers controlled by thermodynamic stability of crystals?
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Self-Disproportionation of Enantiomers (SDE) via achiral gravity-driven column chromatography of N -fluoroacyl-1-phenylethylamines
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3-Trifluoromethyl- and 3-difluoromethyl-thalidomides
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Atropisomeric lactam chemistry: catalytic enantioselective synthesis, application to asymmetric enolate chemistry and synthesis of key intermediates for NET inhibitors
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Self-disproportionation of enantiomers of non-racemic chiral amine derivatives through achiral chromatography
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Asymmetric Michael addition reaction organocatalyzed by stereoisomeric pyrrolidine sulfinamides under neat conditions. A brief study of self-disproportionation of enantiomers
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Nonlinear effects in enantioselective chromatography: prediction of unusual elution profiles of enantiomers in non-racemic mixtures on an achiral stationary phase doped with small amounts of a chiral selector
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Rational application of self-disproportionation of enantiomers via sublimation—a novel methodological dimension for enantiomeric purifications
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Catalytic enantioselective synthesis of atropisomeric 2-aryl-4-quinolinone derivatives with an N–C chiral axis
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Self-disproportionation of enantiomers of prazoles via achiral, gravity-driven silica gel column chromatography
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Chiral additive induced self-disproportionation of enantiomers under MPLC conditions: preparation of enantiomerically pure samples of 1-(aryl)ethylamines from racemates
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A question of policy: should tests for the self-disproportionation of enantiomers (SDE) be mandatory for reports involving scalemates?
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A fast, new method to enhance the enantiomeric purity of non-racemic mixtures: self-disproportionation of enantiomers in the gas antisolvent fractionation of chlorine-substituted mandelic acid derivatives
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Chiral initiator-induces self-disproportionation of enantiomers via achiral chromatography: application to enantiomer separation of racemate
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Separation of binaphthol enantiomers through achiral chromatography
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Unexpected pehnomenon in the high-performance liquid chromatographic anlaysis of racemic 14C-labelled nicotine: Separation of enantiomers in a totally achiral system
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MOD: an organic detector for the future robotic exploration of Mars
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Interactions diastereoisomeres d'antipodes en phase liquide
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Asymmetric synthesis of novel highly sterically constrained (2S,3S)-3-methyl-3-trifluoromethyl- and (2S,3S,4R)-3-trifluoromethyl-4-methylpyroglutamic acids
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Zum destillationsverhalten flüssiger gemische optischer antipoden
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Interactions diastereoisomeres d'enantiomeres en phase liquide - II
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High-performance liquid chromatographic method for the determination of N-methylated metabolites of nicotine
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Resolution of omeprazole by inclusion complexation with a chiral host BINOL
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α-Fluoro-substituted thalidomide analogues
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Foam Flotation Enrichment of Enantiomers
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Self-induced chiral recognition in the association of enantiomeric mixtures on silica gel chromatography
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Bubble Fractionation of Enantiomers from Solution Using Molecularly Imprinted Polymers as Collectors
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Catalytic Enantioselective Synthesis of N-C Axially Chiral Phenanthridin-6-one Derivatives
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Catalytic Enantioselective Synthesis of N–C Axially Chiral Mebroqualone and Its Derivatives through Reductive Asymmetric Desymmetrization
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Diastereoselective α-Alkylation of Metallo Enamines Generated from N–C Axially Chiral Mebroqualone Derivatives
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Kinetic Aspects of Nonlinear Effects in Asymmetric Catalysis
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Symmetry Breaking in Asymmetric Catalysis: Racemic Catalysis to Autocatalysis
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Modified BINOL Ligands in Asymmetric Catalysis
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Chiral Poisoning and Asymmetric Activation
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Enantiomer Recognition of Asymmetric Catalysts. Thermodynamic Properties of Homochiral and Heterochiral Dimers of the Methylzinc Alkoxide Formed from Dimethylzinc and Enantiomeric 3-exo-(Dimethylamino)isoborneol
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DIASTEREOAZEOTROPES AS A MEANS OF RESOLUTION
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On the validity of Wallach's rule: on the density and stability of racemic crystals compared with their chiral counterparts
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Nonlinear Effects in Asymmetric Catalysis
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Enantioselective addition of dialkylzincs to aldehydes promoted by chiral amino alcohols. Mechanism and nonlinear effect
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Nonlinear effects in asymmetric synthesis. Examples in asymmetric oxidations and aldolization reactions
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Homochiral Supramolecular Polymerization of an “S”-Shaped Chiral Monomer: Translation of Optical Purity into Molecular Weight Distribution
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Phenomenon of Optical Self-Purification of Chiral Non-Racemic Compounds
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Separation of Racemate from Excess Enantiomer of Chiral Nonracemic Compounds via Density Gradient Ultracentrifugation
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Mimics of the Self-Assembling Chlorosomal Bacteriochlorophylls: Regio- and Stereoselective Synthesis and Stereoanalysis of Acyl(1-hydroxyalkyl)porphyrins
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Amplification of a Slight Enantiomeric Imbalance in Molecules Based on Asymmetric Autocatalysis: The First Correlation between High Enantiomeric Enrichment in a Chiral Molecule and Circularly Polarized Light
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Quantitative Analysis of the Chiral Amplification in the Amino Alcohol-Promoted Asymmetric Alkylation of Aldehydes with Dialkylzincs
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Enantiomeric enrichment of sulfoxides by preparative flash chromatography on an achiral phase
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Enhancement of optical activity by fractional sublimation. An alternative to fractional crystallization and a warning
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Separation of an enantiomorph and its racemate by sublimation
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Synthesis, Absolute Configuration, and Enantiomeric Enrichment of a Cruciferous Oxindole Phytoalexin, (S)-(−)-Spirobrassinin, and Its Oxazoline Analog
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Biomimetic Reductive Amination of Fluoro Aldehydes and Ketones via [1,3]-Proton Shift Reaction.1 Scope and Limitations
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Biomimetic Transamination of α-Alkyl β-Keto Carboxylic Esters. Chemoenzymatic Approach to the Stereochemically Defined α-Alkyl β-Fluoroalkyl β-Amino Acids
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Measurement of the Dimerization Equilibrium Constants of Enantiomers
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Overall Stability for the Ibuprofen Racemate: Experimental and Topological Results Leading to the Pressure–Temperature Phase Relationships between Its Racemate and Conglomerate
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Enantiomeric Excess of a Cruciferous Phytoalexin, Spirobrassinin, and Its Enantiomeric Enrichment in an Achiral HPLC System
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Efficient Asymmetric Synthesis of Novel 4-Substituted and Configurationally Stable Analogues of Thalidomide
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Direct, Catalytic Enantioselective Nitroaldol (Henry) Reaction of Trifluoromethyl Ketones: An Asymmetric Entry to α-Trifluoromethyl-Substituted Quaternary Carbons
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(R)- and (S)-3-Fluorothalidomides: Isosteric Analogues of Thalidomide
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In Vivo Formation of a Glutathione Conjugate Derived from Thalidomide in Humanized uPA-NOG Mice
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Human Liver Microsomal Cytochrome P450 3A Enzymes Involved in Thalidomide 5-Hydroxylation and Formation of a Glutathione Conjugate
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Alanine enantiomers in the Murchison meteorite
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Recent experimental and theoretical developments towards the observation of parity violation (PV) effects in molecules by spectroscopy
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Serine sublimes with spontaneous chiral amplification
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An astrophysically-relevant mechanism for amino acid enantiomer enrichment
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NMR and molecular modeling of the dimeric self-association of the enantiomers of 1,1′-bi-2-naphthol and 1-phenyl-2,2,2-trifluoroethanol in the solution state and their relevance to enantiomer self-disproportionation on achiral-phase chromatography (ESDAC)
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A simple explanation of the enhancement or depletion of the enantiomeric excess in the partial sublimation of enantiomerically enriched amino acids
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Chiral oxorhenium(v) complexes as candidates for the experimental observation of molecular parity violation: a structural, synthetic and theoretical study
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Asymmetric amplification in amino acidsublimation involving racemic compound to conglomerate conversion
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Theoretical investigations into the enantiomeric and racemic forms of α-(trifluoromethyl)lactic acid
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Reply to the ‘Comment on “Theoretical investigations into the enantiomeric and racemic forms of α-(trifluoromethyl)lactic acid”’ by M. A. Suhm and M. Albrecht, Phys. Chem. Chem. Phys., 2011, 13, DOI: 10.1039/c0cp02455d
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Highly enantioselective zinc/BINOL-catalyzed alkynylation of α-ketoimine ester: a new entry to optically active quaternary α-CF 3 α-amino acids
inferredcites →https://doi.org/10.1039/c2cc18129kopenalex-snapshot
Enantioenrichment in sublimed amino acid mixtures
inferredcites →https://doi.org/10.1039/c2cc37491aopenalex-snapshot
Unconventional preparation of racemic crystals of isopropyl 3,3,3-trifluoro-2-hydroxypropanoate and their unusual crystallographic structure: the ultimate preference for homochiral intermolecular interactions
inferredcites →https://doi.org/10.1039/c2cs35006hopenalex-snapshot
Self-disproportionation of enantiomers via achiral chromatography: a warning and an extra dimension in optical purifications
inferredcites →https://doi.org/10.1039/c4ob00831fopenalex-snapshot
The self-disproportionation of the enantiomers (SDE) of methyl n-pentyl sulfoxide via achiral, gravity-driven column chromatography: a case study
inferredcites →https://doi.org/10.1039/c4ra13928copenalex-snapshot
A comprehensive examination of the self-disproportionation of enantiomers (SDE) of chiral amides via achiral, laboratory-routine, gravity-driven column chromatography
inferredcites →https://doi.org/10.1039/c4sc03047hopenalex-snapshot
Self-disproportionation of enantiomers of thalidomide and its fluorinated analogue via gravity-driven achiral chromatography: mechanistic rationale and implications
inferredcites →https://doi.org/10.1039/c5cc00254kopenalex-snapshot
High temperature sublimation of α-amino acids: a realistic prebiotic process leading to large enantiomeric excess
inferredcites →https://doi.org/10.1039/c6cc05544copenalex-snapshot
Replication of α-amino acids via Strecker synthesis with amplification and multiplication of chiral intermediate aminonitriles
inferredcites →https://doi.org/10.1039/c6ra21253kopenalex-snapshot
Synthesis of fluorinated donepezil by palladium-catalyzed decarboxylative allylation of α-fluoro-β-keto ester with tri-substituted heterocyclic alkene and the self-disproportionation of its enantiomers
inferredcites →https://doi.org/10.1055/s-0031-1289756openalex-snapshot
Recent Advances in the Asymmetric Synthesis of α-(Trifluoromethyl)-Containing α-Amino Acids
inferredcites →https://doi.org/10.1055/s-0032-1316812openalex-snapshot
Self-Disproportionation of Enantiomers of Chiral, Non-Racemic Fluoroorganic Compounds: Role of Fluorine as Enabling Element
inferredcites →https://doi.org/10.1055/s-2001-14660openalex-snapshot
Nonlinear Effects in Asymmetric Catalysis: A Personal Account
inferredcites →https://doi.org/10.1071/ch9920651openalex-snapshot
Partially Racemic Compounds as Brushtail Possum Urinary Metabolites
inferredcites →https://doi.org/10.1080/03602547308068939openalex-snapshot
Foam Separation Methods
inferredcites →https://doi.org/10.1080/10826079208018806openalex-snapshot
Resolution of Enantiomers with Achiral Phase Chromatography
inferredcites →https://doi.org/10.1093/chromsci/18.10.559openalex-snapshot
Preparative Liquid Chromatography
inferredcites →https://doi.org/10.1093/toxsci/kfr086openalex-snapshot
Fluorothalidomide: A Characterization of Maternal and Developmental Toxicity in Rabbits and Mice
inferredcites →https://doi.org/10.1097/icu.0b013e3283499f24openalex-snapshot
What can we learn from the thalidomide experience
inferredcites →https://doi.org/10.1107/s0108270189004713openalex-snapshot
Structure of 5-methoxy-2-{[4-methoxy-3,5-dimethyl-2-pyridinylmethyl]sulfinyl}-1H-benzimidazole (omeprazole)
inferredcites →https://doi.org/10.1111/j.1742-1241.2001.tb11143.xopenalex-snapshot
THALIDOMIDE: 40 YEARS ON
inferredcites →https://doi.org/10.1134/s0036024416100320openalex-snapshot
Effects of the dynamic modification of stationary phases by sorbates in gas chromatography: The possibility of separating enantiomers in achiral systems
inferredcites →https://doi.org/10.1139/cjc-78-6-816openalex-snapshot
On diastereomeric perturbations
inferredcites →https://doi.org/10.1246/cl.1996.115openalex-snapshot
Separation of an Enantiomorph and Its Racemate by Distillation: Strong Chiral Recognizing Ability of Trifluorolactates
inferredcites →https://doi.org/10.1246/cl.2001.1330openalex-snapshot
Chiral Recognition by Multicenter Single Proton Hydrogen Bonding of Trifluorolactates
inferredcites →https://doi.org/10.1248/cpb.58.110openalex-snapshot
Synthesis and Configurational Stability of (S)- and (R)-Deuteriothalidomides
inferredcites →https://doi.org/10.1371/journal.pone.0182152openalex-snapshot
Biological evaluation of both enantiomers of fluoro-thalidomide using human myeloma cell line H929 and others
inferredcites →https://doi.org/10.1515/zpch-1899-2832openalex-snapshot
Löslichkeit und Schmelzpunkt als Kriterien für racemische Verbindungen, pseudoracemische Mischkrystalle und inaktive Konglomerate
inferredcites →https://doi.org/10.2174/157017911794697303openalex-snapshot
Self-Disproportionation of Enantiomers via Sublimation; New and Truly Green Dimension in Optical Purification
inferredcites →https://doi.org/10.24820/ark.5550190.p009.829openalex-snapshot
Self-disproportionation of enantiomers (SDE) of chiral sulfur-containing compounds via achiral chromatography
inferredcites →https://doi.org/10.3390/e5030271openalex-snapshot
Chirality and Symmetry Measures: A Transdisciplinary Review
inferredcites →https://doi.org/10.4155/fmc.09.63openalex-snapshot
Concise Asymmetric Synthesis of Configurationally Stable 4-Trifluoromethyl Thalidomide
inferredcites →https://doi.org/10.4155/fmc.09.70openalex-snapshot
Practical Synthesis of Fluorine-Containing α- and β-Amino Acids: Recipes from Kiev, Ukraine
inferredcites →https://doi.org/10.4236/ijoc.2012.23031openalex-snapshot
Suggested New Terms for Describing Chiral States and the State-Dependent Behavior of Chiral Systems

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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inferred← citeshttps://doi.org/10.1002/9783527825158.ch9openalex-snapshot
The Self‐Disproportionation of Enantiomers ( SDE ): Fluorine as an SDE ‐Phoric Substituent
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Direct Chiral Discrimination with NMR
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Cu(I)‐Ming‐phos Catalyzed Enantioselective [3+2] Cycloadditions of Glycine ketimines to β‐Trifluoromethyl Enones
inferred← citeshttps://doi.org/10.1002/adsc.201801647openalex-snapshot
Organocatalytic Asymmetric Synthesis of Cyclic Compounds Bearing a Trifluoromethylated Stereogenic Center: Recent Developments
inferred← citeshttps://doi.org/10.1002/adsc.202000966openalex-snapshot
Recent Advances in Catalytic Enantioselective Synthesis of Fluorinated α‐ and β‐Amino Acids
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DBU Catalysed Enantioselective Degradative Rearrangement: a Way to Tetrasubstituted 2‐Aryl‐2‐Amino Esters
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Mechanistic Insights into Annulation of Arylidene‐Δ2‐Pyrrolin‐4‐Ones by Cinchona Squaramide‐Based Organocatalysts
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Evolution and Future of Hetero‐ and Hydro‐Trifluoromethylations of Unsaturated C−C Bonds
inferred← citeshttps://doi.org/10.1002/ange.202008572openalex-snapshot
Asymmetric Transfer Hydrogenation of gem‐Difluorocyclopropenyl Esters: Access to Enantioenriched gem‐Difluorocyclopropanes
inferred← citeshttps://doi.org/10.1002/ange.202014955openalex-snapshot
Chiral Amplification of Phosphoramidates of Amines and Amino Acids in Water
inferred← citeshttps://doi.org/10.1002/anie.202008572openalex-snapshot
Asymmetric Transfer Hydrogenation of gem‐Difluorocyclopropenyl Esters: Access to Enantioenriched gem‐Difluorocyclopropanes
inferred← citeshttps://doi.org/10.1002/anie.202014955openalex-snapshot
Chiral Amplification of Phosphoramidates of Amines and Amino Acids in Water
inferred← citeshttps://doi.org/10.1002/asia.202200230openalex-snapshot
Gelation of a π‐Decorated Glutamate as a Homochiral Selective Self‐assembly to Obtain Macroscopic Chiral Symmetry Breaking
inferred← citeshttps://doi.org/10.1002/asia.202401074openalex-snapshot
Step‐by‐Step Towards Biological Homochirality – from Prebiotic Randomness To Perfect Asymmetry
inferred← citeshttps://doi.org/10.1002/chem.201801670openalex-snapshot
Palladium‐Catalyzed Asymmetric Allylic Alkylations of Colby Pro‐Enolates with MBH Carbonates: Enantioselective Access to Quaternary C−F Oxindoles
inferred← citeshttps://doi.org/10.1002/chem.201901840openalex-snapshot
Fluorine‐Containing Drugs Approved by the FDA in 2018
inferred← citeshttps://doi.org/10.1002/chem.202402637openalex-snapshot
Unraveling the Source of Self‐Induced Diastereomeric Anisochronism in Chiral Dipeptides
inferred← citeshttps://doi.org/10.1002/chem.202403318openalex-snapshot
Fortuitous Enantiomeric Self‐Rectification of an Unreported Partial Racemisation in the Synthesis of a Chiral Phosphoric Acid: A Warning to Practitioners
inferred← citeshttps://doi.org/10.1002/chem.202500662openalex-snapshot
Fluorine in the Pharmaceutical Industry: FDA‐Approved Fluorine‐Containing Drugs in 2024
inferred← citeshttps://doi.org/10.1002/chir.23068openalex-snapshot
Enantiomeric resolution, thermodynamic parameters, and modeling of clausenamidone and neoclausenamidone on polysaccharide‐based chiral stationary phases
inferred← citeshttps://doi.org/10.1002/chir.23303openalex-snapshot
Application of nanoparticles in chiral analysis and chiral separation
inferred← citeshttps://doi.org/10.1002/chir.23376openalex-snapshot
New pharmaceuticals approved by FDA in 2020: Small‐molecule drugs derived from amino acids and related compounds
inferred← citeshttps://doi.org/10.1002/chir.23617openalex-snapshot
Achiral 2‐pyridone and 4‐aminopyridine act as chiral inducers of asymmetric autocatalysis with amplification of enantiomeric excess via the formation of chiral crystals
inferred← citeshttps://doi.org/10.1002/cphc.201901115openalex-snapshot
Does Pressure Break Mirror‐Image Symmetry? A Perspective and New Insights
inferred← citeshttps://doi.org/10.1002/elps.201800414openalex-snapshot
The self‐disproportionation of enantiomers (SDE): The effect of scaling down, potential problems versus prospective applications, possible new occurrences, and unrealized opportunities?
inferred← citeshttps://doi.org/10.1002/ijch.202100047openalex-snapshot
Asymmetric Autocatalysis as a Link Between Crystal Chirality and Highly Enantioenriched Organic Compounds
inferred← citeshttps://doi.org/10.1002/ldr.3179openalex-snapshot
Enantioselectivity in degradation and ecological risk of the chiral pesticide ethiprole
inferred← citeshttps://doi.org/10.1002/open.201900131openalex-snapshot
Large‐Scale Asymmetric Synthesis of Fmoc‐(S)‐2‐Amino‐6,6,6‐Trifluorohexanoic Acid
inferred← citeshttps://doi.org/10.1002/slct.202101229openalex-snapshot
Optical UV Dosimeters Based on Photoracemization of ( R )‐(+)‐1,1′‐Bi(2‐Napthol) (BINOL) within a Chiral Nematic Liquid Crystalline Matrix
inferred← citeshttps://doi.org/10.1002/smll.202514872openalex-snapshot
Enantiopurity‐Dependent Peptide Coacervates and Asymmetric Organocatalysis
inferred← citeshttps://doi.org/10.1002/tcr.202300096openalex-snapshot
N ‐Fluoro Ammonium Salts of Cinchona Alkaloids in Enantioselective Electrophilic Fluorination
inferred← citeshttps://doi.org/10.1007/978-3-030-62456-9_3openalex-snapshot
Enantiomer-Selective High- and Ultra- High-Performance Liquid Chromatography
inferred← citeshttps://doi.org/10.1007/s00726-018-2664-xopenalex-snapshot
The self-disproportionation of enantiomers (SDE) of α-amino acid derivatives: facets of steric and electronic properties
inferred← citeshttps://doi.org/10.1007/s00726-019-02729-yopenalex-snapshot
The self-disproportionation of enantiomers (SDE) of amino acids and their derivatives
inferred← citeshttps://doi.org/10.1007/s00726-019-02774-7openalex-snapshot
The self-disproportionation of enantiomers (SDE) via column chromatography of β-amino-α,α-difluorophosphonic acid derivatives
inferred← citeshttps://doi.org/10.1007/s00726-020-02887-4openalex-snapshot
Tailor-made amino acid-derived pharmaceuticals approved by the FDA in 2019
inferred← citeshttps://doi.org/10.1007/s11084-022-09626-7openalex-snapshot
Asymmetric Autocatalysis as an Efficient Link Between the Origin of Homochirality and Highly Enantioenriched Compounds
inferred← citeshttps://doi.org/10.1007/s11084-025-09681-wopenalex-snapshot
Early genetic code is explained by preferential amplification of enantiomeric excess of amino acids and nucleosides
inferred← citeshttps://doi.org/10.1016/b978-0-12-812958-6.00010-0openalex-snapshot
Fluorine-Containing Pharmaceuticals and the Phenomenon of the Self-Disproportionation of Enantiomers
inferred← citeshttps://doi.org/10.1016/bs.coac.2024.10.005openalex-snapshot
Chiral pesticide fate in soils: Processes, experimental considerations, and case studies
inferred← citeshttps://doi.org/10.1016/j.cclet.2020.03.050openalex-snapshot
Fluorine-containing drugs approved by the FDA in 2019
inferred← citeshttps://doi.org/10.1016/j.cclet.2021.05.042openalex-snapshot
Fluorine-containing pharmaceuticals approved by the FDA in 2020: Synthesis and biological activity
inferred← citeshttps://doi.org/10.1016/j.cclet.2022.06.001openalex-snapshot
Fluorine-containing drugs approved by the FDA in 2021
inferred← citeshttps://doi.org/10.1016/j.cclet.2023.108901openalex-snapshot
Probing the dynamic thermodynamic resolution and biological activity of Cu(II) and Pd(II) complexes with Schiff base ligand derived from proline
inferred← citeshttps://doi.org/10.1016/j.cclet.2024.109780openalex-snapshot
FDA approved fluorine-containing drugs in 2023
inferred← citeshttps://doi.org/10.1016/j.chempr.2023.02.022openalex-snapshot
NMR in operando monitoring of mechanochemically accelerated sublimations
inferred← citeshttps://doi.org/10.1016/j.chroma.2018.07.039openalex-snapshot
Enantiomeric ratios: Why so many notations?
inferred← citeshttps://doi.org/10.1016/j.chroma.2023.463877openalex-snapshot
Separation of non-racemic mixtures of enantiomers by achiral chromatography
inferred← citeshttps://doi.org/10.1016/j.chroma.2023.464603openalex-snapshot
Altering the mobile phase composition to enhance self-disproportionation of enantiomers in achiral chromatography
inferred← citeshttps://doi.org/10.1016/j.ejmech.2019.111826openalex-snapshot
Applications of fluorine-containing amino acids for drug design
inferred← citeshttps://doi.org/10.1016/j.ejmech.2021.113448openalex-snapshot
Tailor-made amino acids in the design of small-molecule blockbuster drugs
inferred← citeshttps://doi.org/10.1016/j.jfluchem.2018.12.009openalex-snapshot
Catalytic enantioselective Michael addition reactions between in situ detrifluoroacetylatively generated 3-fluorooxindole-derived enolates and 1-(1-(phenylsulfonyl)vinylsulfonyl)benzene
inferred← citeshttps://doi.org/10.1016/j.jfluchem.2022.109978openalex-snapshot
Successful trifluoromethoxy-containing pharmaceuticals and agrochemicals
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2026.124205openalex-snapshot
γ-Selective allylic- and propargylic-substitution reactions with Grignard reagents catalyzed by a zinc N-heterocyclic-carbene complex
inferred← citeshttps://doi.org/10.1016/j.tet.2024.133835openalex-snapshot
Asymmetric autocatalysis with amplification of enantiomeric excess utilizing chiral crystals of achiral o-terphenyls as chiral triggers
inferred← citeshttps://doi.org/10.1021/acs.iecr.2c04290openalex-snapshot
Green and Strategic Approach for Chiral Resolution by Diastereomeric Salt Formation: The Study of Racemic Ibuprofen
inferred← citeshttps://doi.org/10.1021/acs.jnatprod.2c01139openalex-snapshot
Natural Cannabichromene (CBC) Shows Distinct Scalemicity Grades and Enantiomeric Dominance in Cannabis sativa Strains
inferred← citeshttps://doi.org/10.1021/acs.joc.0c00751openalex-snapshot
Expanding the Boxmi Ligand Family: Synthesis and Application of NON and NSN Ligands
inferred← citeshttps://doi.org/10.1021/acs.joc.0c01094openalex-snapshot
Localized Partitioning of Enantiomers in Solid Samples of Sulfoxides: Importance of Sampling Method in Determination of Enantiopurity
inferred← citeshttps://doi.org/10.1021/acs.joc.1c02640openalex-snapshot
Enantioenriched γ-Aminoalcohols, β-Amino Acids, β-Lactams, and Azetidines Featuring Tetrasubstituted Fluorinated Stereocenters via Palladacycle-Catalyzed Asymmetric Fluorination of Isoxazolinones
inferred← citeshttps://doi.org/10.1021/acs.joc.2c01041openalex-snapshot
Deracemization of Binaphthyl by Suzuki Diarylation: The Role of Electronic and Steric Effects
inferred← citeshttps://doi.org/10.1021/acs.joc.8b03160openalex-snapshot
Desymmetrization by Asymmetric Copper-Catalyzed Intramolecular C–H Insertion Reactions of α-Diazo-β-oxosulfones
inferred← citeshttps://doi.org/10.1021/acs.joc.9b00832openalex-snapshot
HBED-NN: A Bifunctional Chelator for Constructing Radiopharmaceuticals
inferred← citeshttps://doi.org/10.1021/acs.jpcc.3c02638openalex-snapshot
Steering the Surface-Confined Self-Assembly of Multifunctional Star-Shaped Molecules
inferred← citeshttps://doi.org/10.1021/acs.langmuir.0c02373openalex-snapshot
Chiral Templating of Polycarbonate Membranes by Pinene Using the Modified Atomic Layer Deposition Approach
inferred← citeshttps://doi.org/10.1021/acs.orglett.3c02614openalex-snapshot
Ligand-Controlled Diastereodivergency in Propargylic Alkylation of Vinylogous Aza-Enamines: Construction of 1,3-Stereocenters
inferred← citeshttps://doi.org/10.1021/acscatal.8b02543openalex-snapshot
Cu(II)-Catalyzed Enantioselective β-Boration of β-Trifluoromethyl, β,β-Disubstituted Enones and Esters: Construction of a CF3- and Boron-Containing Quaternary Stereocenter
inferred← citeshttps://doi.org/10.1021/acsomega.9b03271openalex-snapshot
Detrifluoroacetylative in Situ Generated Cyclic Fluorinated Enolates for the Preparation of Compounds Featuring a C–F Stereogenic Center
inferred← citeshttps://doi.org/10.1021/jacs.2c10911openalex-snapshot
Turning Enantiomeric Relationships into Diastereomeric Ones: Self-Resolving α-Ureidophosphonates and Their Organocatalytic Enantioselective Synthesis
inferred← citeshttps://doi.org/10.1021/jacs.5c22456openalex-snapshot
Switchable and Self-Learning Enantioseparation Based on Ultrafast Helix Induction and Memory of a Helical Polyacetylene
inferred← citeshttps://doi.org/10.1038/s41570-024-00627-wopenalex-snapshot
The astrochemical evolutionary traits of phospholipid membrane homochirality
inferred← citeshttps://doi.org/10.1038/s41598-018-35457-6openalex-snapshot
Understanding the Thalidomide Chirality in Biological Processes by the Self-disproportionation of Enantiomers
inferred← citeshttps://doi.org/10.1038/s42004-021-00586-zopenalex-snapshot
Biomimetic enantioselective synthesis of β,β-difluoro-α-amino acid derivatives
inferred← citeshttps://doi.org/10.1039/9781839166273-00001openalex-snapshot
Asymmetric Autocatalysis: The Soai Reaction, an Overview
inferred← citeshttps://doi.org/10.1039/9781839166273-00097openalex-snapshot
Reaction Mechanism in the Study of Amplifying Asymmetric Autocatalysis
inferred← citeshttps://doi.org/10.1039/9781839166273-00317openalex-snapshot
Unusual Aspects of Asymmetric Induction and Amplification Observed in the Soai Reaction
inferred← citeshttps://doi.org/10.1039/c8ob02843eopenalex-snapshot
Chemistry of detrifluoroacetylatively in situ generated fluoro-enolates
inferred← citeshttps://doi.org/10.1039/c8ob03092hopenalex-snapshot
Absolute asymmetric Strecker synthesis in a mixed aqueous medium: reliable access to enantioenriched α-aminonitrile
inferred← citeshttps://doi.org/10.1039/c9cc01875aopenalex-snapshot
Formation of enantioenriched alkanol with stochastic distribution of enantiomers in the absolute asymmetric synthesis under heterogeneous solid–vapor phase conditions
inferred← citeshttps://doi.org/10.1039/d1cc04206hopenalex-snapshot
Circular dichroism spectroscopy of catalyst preequilibrium in asymmetric autocatalysis of pyrimidyl alkanol
inferred← citeshttps://doi.org/10.1039/d1cs01179kopenalex-snapshot
Possible chemical and physical scenarios towards biological homochirality
inferred← citeshttps://doi.org/10.1039/d1sc05801kopenalex-snapshot
Unified total synthesis of the brevianamide alkaloids enabled by chemical investigations into their biosynthesis
inferred← citeshttps://doi.org/10.1039/d2ob02311copenalex-snapshot
Regioselective synthesis of enantiopure 1,2- and 1,3-dispirooxindoles along with a DFT study
inferred← citeshttps://doi.org/10.1039/d2qo00241hopenalex-snapshot
Resolution of aryl- H -phosphinates applied in the synthesis of P-stereogenic compounds including a Brønsted acid NMR solvating agent
inferred← citeshttps://doi.org/10.1039/d3np00014aopenalex-snapshot
Scalemic natural products
inferred← citeshttps://doi.org/10.1039/d3sc02101gopenalex-snapshot
Enantioselective isothiourea-catalysed reversible Michael addition of aryl esters to 2-benzylidene malononitriles
inferred← citeshttps://doi.org/10.1039/d5cp00275copenalex-snapshot
The influence of fluorine spin-diffusion on 13 C solid-state NMR line shapes of CF 3 groups
inferred← citeshttps://doi.org/10.1039/d5cs00938copenalex-snapshot
Halogen bonding in functional chiral systems
inferred← citeshttps://doi.org/10.1039/d6py00593dopenalex-snapshot
Helical poly(biphenylylacetylene)s with static memory of macromolecular helicity: synthesis, structures, and applications
inferred← citeshttps://doi.org/10.1080/17460441.2020.1740203openalex-snapshot
Fluorinated scaffolds for antimalarial drug discovery
inferred← citeshttps://doi.org/10.1246/bcsj.20190116openalex-snapshot
Self-Replication of Chiral α-Amino Acids in Strecker-Type Synthesis via Asymmetric Induction and Amplification of Their Own Chiral Intermediate α-Aminonitriles
inferred← citeshttps://doi.org/10.15407/bioorganica2023.01.010openalex-snapshot
Applications of chiral sulfinyl auxiliaries in the asymmetric synthesis of fluorinated amines and amino acids
inferred← citeshttps://doi.org/10.15407/bioorganica2023.02.003openalex-snapshot
Discovery of biomimetic transamination as a general synthetic method for preparation of fluorine-containing amines and amino acids
inferred← citeshttps://doi.org/10.15407/bioorganica2024.01.003openalex-snapshot
New drugs appearing on the market in 2023: molecules containing fluorine and fragments of tailor-made amino acids
inferred← citeshttps://doi.org/10.15407/bioorganica2024.01.021openalex-snapshot
Enzymatic approaches for preparation of α-aminophosphonic acids and fluorine-containing β-amino acids
inferred← citeshttps://doi.org/10.33609/2708-129x.90.9.2024.31-56openalex-snapshot
NEW DRUGS ON THE PHARMACEUTICAL MARKET CONTAINING FLUORINE AND RESIDUES OF TAILOR-MADE AMINO ACIDS
inferred← citeshttps://doi.org/10.33609/2708-129x.91.10.2025.27-71openalex-snapshot
CUTTING-EDGE STRATEGIES IN THE ASYMMETRIC SYNTHESIS OF α-AMINOCYCLOPROPANE CARBOXYLIC ACIDS: ESSENTIAL SCAFFOLDS FOR DRUG DISCOVERY
inferred← citeshttps://doi.org/10.33609/2708-129x.91.12.2025.33-72openalex-snapshot
ENANTIOSELECTIVE CATALYSIS FOR THE SYNTHESIS OF 1-SUBSTITUTED-2,2,2-TRIFLUOROETHYLAMINES
inferred← citeshttps://doi.org/10.33609/2708-129x.91.2.2025.55-90openalex-snapshot
CHIRAL, FLUORINE-CONTAINING PHARMACEUTICALS
inferred← citeshttps://doi.org/10.33609/2708-129x.91.3.2025.34-48openalex-snapshot
ENANTIOMER PURIFICATION THROUGH ACHIRAL CHROMATOGRAPHY: INTEGRATING SIMULATED MOVING BED AND SELF-DISPROPORTIONATION OF ENANTIOMERS
inferred← citeshttps://doi.org/10.33609/2708-129x.91.6.2025.15-54openalex-snapshot
MODERN PHARMACEUTICAL DRUGS FEATURING ALIPHATIC FLUORINE-CONTAINING GROUPS
inferred← citeshttps://doi.org/10.33609/2708-129x.92.4.2026.52-78openalex-snapshot
ORGANOFLUORINE CHEMISTRY IN ONCOLOGY: A REVIEW OF US FDA-APPROVED ANTICANCER DRUGS IN 2025 (review)
inferred← citeshttps://doi.org/10.3390/molecules24061007openalex-snapshot
Enantiomeric Recognition and Separation by Chiral Nanoparticles
inferred← citeshttps://doi.org/10.3390/molecules24244521openalex-snapshot
Preparative Method for Asymmetric Synthesis of (S)-2-Amino-4,4,4-trifluorobutanoic Acid
inferred← citeshttps://doi.org/10.3390/molecules25020405openalex-snapshot
The Synthesis of α-Aminophosphonates via Enantioselective Organocatalytic Reaction of 1-(N-Acylamino)alkylphosphonium Salts with Dimethyl Phosphite
inferred← citeshttps://doi.org/10.3390/molecules26092757openalex-snapshot
Recommended Tests for the Self-Disproportionation of Enantiomers (SDE) to Ensure Accurate Reporting of the Stereochemical Outcome of Enantioselective Reactions
inferred← citeshttps://doi.org/10.3390/molecules26133994openalex-snapshot
A Call for a Change in Policy Regarding the Necessity for SDE Tests to Validate the Veracity of the Outcome of Enantioselective Syntheses, the Inherent Chiral State of Natural Products, and Other Cases Involving Enantioenriched Samples
inferred← citeshttps://doi.org/10.3390/molecules27123797openalex-snapshot
Asymmetric Michael Addition in Synthesis of β-Substituted GABA Derivatives
inferred← citeshttps://doi.org/10.3390/molecules28052115openalex-snapshot
Experimental Determination of a Chiral Ternary Solubility Diagram and Its Interpretation in Gas Antisolvent Fractionation
inferred← citeshttps://doi.org/10.3390/molecules28062694openalex-snapshot
Catalytic Asymmetric α-Functionalization of α-Branched Aldehydes
inferred← citeshttps://doi.org/10.3390/ph15080999openalex-snapshot
The Latest FDA-Approved Pharmaceuticals Containing Fragments of Tailor-Made Amino Acids and Fluorine
inferred← citeshttps://doi.org/10.3390/separations10070382openalex-snapshot
The Self-Disproportionation of Enantiomers (SDE) of α-Pinene via Evaporation off Silica Gel and Foam Fractionation—Validation of the Plausibility of SDE via Gas Chromatography (GC) for α-Pinene
inferred← citeshttps://doi.org/10.3390/sym11040578openalex-snapshot
Convenient Asymmetric Synthesis of Fmoc-(S)-6,6,6-Trifluoro-Norleucine
inferred← citeshttps://doi.org/10.3390/sym11050694openalex-snapshot
Role of Asymmetric Autocatalysis in the Elucidation of Origins of Homochirality of Organic Compounds
inferred← citeshttps://doi.org/10.3390/sym12071106openalex-snapshot
Potentially Mistaking Enantiomers for Different Compounds Due to the Self-Induced Diastereomeric Anisochronism (SIDA) Phenomenon
inferred← citeshttps://doi.org/10.3390/sym13040543openalex-snapshot
Flurbiprofen: A Study of the Behavior of the Scalemate by Chromatography, Sublimation, and NMR
inferred← citeshttps://doi.org/10.3390/sym13040667openalex-snapshot
The Stoichiometry, Structure and Possible Formation of Crystalline Diastereomeric Salts
inferred← citeshttps://doi.org/10.3762/bjoc.16.155openalex-snapshot
Stereoselective Biginelli-like reaction catalyzed by a chiral phosphoric acid bearing two hydroxy groups
inferred← citeshttps://doi.org/10.4155/fdd-2023-0006openalex-snapshot
Widened Scope of Drug Repurposing/Chiral Switches, Elements of Secondary Pharmaceuticals: The Quinine/Quinidine Case
inferred← citeshttps://doi.org/10.6023/cjoc202102043openalex-snapshot
Electrochemical Approaches for Preparation of Tailor-Made Amino Acids
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