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Phenomenon of Optical Self-Purification of Chiral Non-Racemic Compounds

https://doi.org/10.1021/ja065603a
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Remarkable Amplification of the Self‐Disproportionation of Enantiomers on Achiral‐Phase Chromatography Columns
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Veränderungen im Deuteriumgehalt bei partiell optisch aktiven, festen Verbindungen im Massenspektrometer
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Optische Aktivierung von N‐Phthalyl‐α‐aminosäure‐Derivaten durch tert.‐Basen‐Katalyse1)
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Thermodynamics of Sublimation, Crystal Lattice Energies, and Crystal Structures of Racemates and Enantiomers: (+)- and (±)-Ibuprofen
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Gold(I)-catalyzed asymmetric aldol reactions of isocyanoacetic acid derivatives with fluoroaryl aldehydes
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Asymmetric aldol reactions of trifluoromethyl ketones with a chiral Ni(II) complex of glycine: Stereocontrolling effect of the trifluoromethyl group
inferredcites →https://doi.org/10.1016/0040-4039(96)01746-7openalex-snapshot
Transition metal-catalyzed diastereoselective aldol reactions of prochiral ketones with methyl isocyanoacetate
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Self-disproportionation of enantiomers of (R)-ethyl 3-(3,5-dinitrobenzamido)-4,4,4-trifluorobutanoate on achiral silica gel stationary phase
inferredcites →https://doi.org/10.1016/s0040-4039(00)79964-3openalex-snapshot
Highly diastereoselective aldol reaction of fluoroalkyl aryl ketones with methyl isocyanoacetate catalyzed by silver(I)/triethylamine
inferredcites →https://doi.org/10.1016/s0040-6031(01)00507-xopenalex-snapshot
The physical approach to the interpretation of the kinetics and mechanisms of thermal decomposition of solids: the state of the art
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Structure/Volatility Correlation of Sodium and Zirconium Fluoroalkoxides
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van der Waals Volumes and Radii
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On the validity of Wallach's rule: on the density and stability of racemic crystals compared with their chiral counterparts
inferredcites →https://doi.org/10.1021/ja00449a054openalex-snapshot
Detection of chirality with the chemical ionization mass spectrometer. "Meso" ions in the gas phase
inferredcites →https://doi.org/10.1021/ja00453a018openalex-snapshot
Asymmetric photolysis of (RS)-leucine with circularly polarized ultraviolet light
inferredcites →https://doi.org/10.1021/ja027129oopenalex-snapshot
Enantioselective Synthesis without Discrete Optically Active Additives
inferredcites →https://doi.org/10.1021/ja0535561openalex-snapshot
Michael Addition Reactions between Chiral Equivalents of a Nucleophilic Glycine and (S)- or (R)-3-[(E)-Enoyl]-4-phenyl-1,3-oxazolidin-2-ones as a General Method for Efficient Preparation of β-Substituted Pyroglutamic Acids. Case of Topographically Controlled Stereoselectivity
inferredcites →https://doi.org/10.1021/jo00427a033openalex-snapshot
Enhancement of optical activity by fractional sublimation. An alternative to fractional crystallization and a warning
inferredcites →https://doi.org/10.1021/jo01281a037openalex-snapshot
Separation of an enantiomorph and its racemate by sublimation
inferredcites →https://doi.org/10.1021/jo9623402openalex-snapshot
Transition Metal/Base-Catalyzed Aldol Reactions of Isocyanoacetic Acid Derivatives with Prochiral Ketones, a Straightforward Approach to Stereochemically Defined β,β-Disubstituted-β-hydroxy-α-amino Acids.1 Scope and Limitations
inferredcites →https://doi.org/10.1021/ol034014wopenalex-snapshot
Highly Regioselective Hydrogenolysis of Bis(α-methylbenzyl)amine Derivatives Affected by the Trifluoromethyl Substituent on the Aromatic Ring
inferredcites →https://doi.org/10.1038/266567a0openalex-snapshot
Was photoresolution of amino acids the origin of optical activity in life?
inferredcites →https://doi.org/10.1038/28306openalex-snapshot
Alanine enantiomers in the Murchison meteorite
inferredcites →https://doi.org/10.1038/314438a0openalex-snapshot
Weak neutral currents and the origin of biomolecular chirality
inferredcites →https://doi.org/10.1038/329712a0openalex-snapshot
Nuclear β-decay and the origin of biomolecular chirality
inferredcites →https://doi.org/10.1039/c39870001121openalex-snapshot
The vapour pressure of enantiomers and of their mixtures
inferredcites →https://doi.org/10.1039/p19930003143openalex-snapshot
General method for the synthesis of enantiomerically pure β-hydroxy-α-amino acids, containing fluorine atoms in the side chains. Case of stereochemical distinction between methyl and trifluoromethyl groups. X-Ray crystal and molecular structure of the nickel( II ) complex of…
inferredcites →https://doi.org/10.1103/physrev.104.254openalex-snapshot
Question of Parity Conservation in Weak Interactions
inferredcites →https://doi.org/10.1126/science.2237441openalex-snapshot
Localized All-or-None Calcium Liberation by Inositol Trisphosphate
inferredcites →https://doi.org/10.1126/science.250.4983.975openalex-snapshot
Chiral Symmetry Breaking in Sodium Chlorate Crystallization

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Resolution of Alcohols
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The Self‐Disproportionation of Enantiomers ( SDE ): Fluorine as an SDE ‐Phoric Substituent
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Opportunities and Challenges in Applying Solid‐State NMR Spectroscopy in Organic Mechanochemistry
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Organocatalytic Asymmetric Synthesis of Cyclic Compounds Bearing a Trifluoromethylated Stereogenic Center: Recent Developments
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Entstehung von Homochiralität unter präbiotischen Bedingungen
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Amino Acid Silica Hybrid Materials with Mesoporous Structure and Enantiopure Surfaces
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Enantioselective CC Bond Formation as a Result of the Oriented Prochirality of an Achiral Aldehyde at the Single‐Crystal Face upon Treatment with a Dialkyl Zinc Vapor
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Reversible Heterochiral Aggregation/Dissociation of Bis(2‐hydroxyphenyl)diamides Driven by UV/Vis Irradiation
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Construction of Axial Chirality by Rhodium‐Catalyzed Asymmetric Dehydrogenative Heck Coupling of Biaryl Compounds with Alkenes
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Assembly of Fluorinated Quaternary Stereogenic Centers through Catalytic Enantioselective Detrifluoroacetylative Aldol Reactions
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An Enantioselective Synthesis of Spirobilactams through Copper‐Catalyzed Intramolecular Double N‐Arylation and Phase Separation
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Crystal Structure of the Isopropylzinc Alkoxide of Pyrimidyl Alkanol: Mechanistic Insights for Asymmetric Autocatalysis with Amplification of Enantiomeric Excess
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Asymmetric Induction by a Nitrogen 14N/15N Isotopomer in Conjunction with Asymmetric Autocatalysis
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Achiral Inorganic Gypsum Acts as an Origin of Chirality through Its Enantiotopic Surface in Conjunction with Asymmetric Autocatalysis
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Molecular Recognition in Mechanochemistry: Insights from Solid‐State NMR Spectroscopy
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Sublime Arguments: Rethinking the Generation of Homochirality under Prebiotic Conditions
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Amino Acid Silica Hybrid Materials with Mesoporous Structure and Enantiopure Surfaces
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Enantioselective CC Bond Formation as a Result of the Oriented Prochirality of an Achiral Aldehyde at the Single‐Crystal Face upon Treatment with a Dialkyl Zinc Vapor
inferred← citeshttps://doi.org/10.1002/anie.201106832openalex-snapshot
Reversible Heterochiral Aggregation/Dissociation of Bis(2‐hydroxyphenyl)diamides Driven by UV/Vis Irradiation
inferred← citeshttps://doi.org/10.1002/anie.201408805openalex-snapshot
Construction of Axial Chirality by Rhodium‐Catalyzed Asymmetric Dehydrogenative Heck Coupling of Biaryl Compounds with Alkenes
inferred← citeshttps://doi.org/10.1002/anie.201500908openalex-snapshot
Assembly of Fluorinated Quaternary Stereogenic Centers through Catalytic Enantioselective Detrifluoroacetylative Aldol Reactions
inferred← citeshttps://doi.org/10.1002/anie.201504589openalex-snapshot
An Enantioselective Synthesis of Spirobilactams through Copper‐Catalyzed Intramolecular Double N‐Arylation and Phase Separation
inferred← citeshttps://doi.org/10.1002/anie.201508036openalex-snapshot
Crystal Structure of the Isopropylzinc Alkoxide of Pyrimidyl Alkanol: Mechanistic Insights for Asymmetric Autocatalysis with Amplification of Enantiomeric Excess
inferred← citeshttps://doi.org/10.1002/anie.201608955openalex-snapshot
Asymmetric Induction by a Nitrogen 14N/15N Isotopomer in Conjunction with Asymmetric Autocatalysis
inferred← citeshttps://doi.org/10.1002/anie.201610099openalex-snapshot
Achiral Inorganic Gypsum Acts as an Origin of Chirality through Its Enantiotopic Surface in Conjunction with Asymmetric Autocatalysis
inferred← citeshttps://doi.org/10.1002/anie.202410801openalex-snapshot
Molecular Recognition in Mechanochemistry: Insights from Solid‐State NMR Spectroscopy
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Enantiotopic Discrimination by Coordination‐Desymmetrized meso‐Ligands
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Solvent‐Dependent Self‐Discrimination of Bis(2‐hydroxyphenyl)diamides
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Attracting Enantiomers: Chiral Analytes That Are Simultaneously Shift Reagents Allow Rapid Screening of Enantiomeric Ratios by NMR Spectroscopy
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Possible Case of Halogen Bond‐Driven Self‐Disproportionation of Enantiomers (SDE) via Achiral Chromatography
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Enantiomer self‐disproportionation and chiral stationary phase based selective chiral separation of organic compounds
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On the Physical Basis of Asymmetry and Homochirality
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Optical Purifications via Self‐Disproportionation of Enantiomers by Achiral Chromatography: Case Study of a Series of α‐CF3‐containing Secondary Alcohols
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Selecting Resolving Agents with Respect to Their Eutectic Compositions
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Does Pressure Break Mirror‐Image Symmetry? A Perspective and New Insights
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Accelerated Cocrystallization of Cytosine and Succinic Acid Through Compaction+Grinding
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Recent Progress in the in situ Detrifluoroacetylative Generation of Fluoro Enolates and Their Reactions with Electrophiles
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Substrate and Catalyst Effects in the Enantioselective Copper‐Catalysed C–H Insertion Reactions of α‐Diazo‐β‐oxo Sulfones
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The self‐disproportionation of enantiomers (SDE): The effect of scaling down, potential problems versus prospective applications, possible new occurrences, and unrealized opportunities?
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Purification of Enantiomeric Mixtures in Enantioselective Synthesis: Overlooked Errors and Scientific Basis of Separation in Achiral Environment
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Terminology Related to the Phenomenon ‘Self‐Disproportionation of Enantiomers’ (SDE)
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Enantiomeric Enrichments via the Self‐Disproportionation of Enantiomers (SDE) by Achiral, Gravity‐Driven Column Chromatography: a Case Study Using N‐(1‐Phenylethyl)acetamide for Optimizing the Enantiomerically Pure Yield and Magnitude of the SDE
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On the Chiral Homogeneity of Nature: From Atoms to Small Molecules
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Asymmetric Autocatalysis Triggered by Chiral Crystals Formed from Achiral Compounds and Chiral Isotopomers
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Self‐disproportionation of Enantiomers (SDE) of Chiral Nonracemic Amides via Achiral Chromatography
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Detection of Chiral Defects in Crystalline Organic Solids Using Solid-State NMR Spectroscopy
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Revisited conformational analysis of perhydro‐3a,6a,9a‐triazaphenalene based on Raman analysis
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Absolute Autocatalytic Amplification under Heterogenous Phase Conditions Involving Subsequent Hydride Transfer and a Hemiacetal Intermediate
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The Origins of Homochirality Examined by Using Asymmetric Autocatalysis
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Self-disproportionation of Enantiomers of Enantiomerically Enriched Compounds
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Remarkable magnitude of the self-disproportionation of enantiomers (SDE) via achiral chromatography: application to the practical-scale enantiopurification of β-amino acid esters
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The self-disproportionation of enantiomers (SDE) of amino acids and their derivatives
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Deracemization of Amino Acids by Partial Sublimation and via Homochiral Self-Organization
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Transfer of Asymmetry between Proteinogenic Amino Acids under Harsh Conditions
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6.14 C–N Bond Formation: α-Amination and α-Hydrazination of Carbonyl Compounds with DEAD and Related Compounds
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Asymmetric Autocatalysis and the Origins of Homochirality of Organic Compounds. An Overview
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Structural Study of Asymmetric Autocatalysis by X-Ray Crystallography
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Fluorine-Containing Pharmaceuticals and the Phenomenon of the Self-Disproportionation of Enantiomers
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NMR in operando monitoring of mechanochemically accelerated sublimations
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Self-disproportionation of enantiomers via achiral gravity-driven column chromatography: A case study of N -acyl-α-phenylethylamines
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Altering the mobile phase composition to enhance self-disproportionation of enantiomers in achiral chromatography
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Effect of temperature on chromatographic separation driven by enantiomer self-disproportionation
inferred← citeshttps://doi.org/10.1016/j.chroma.2026.467101openalex-snapshot
Effect of modification of silica surface on the extent of enantiomer self-disproportionation
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High-pressure melting equilibrium of chiral compounds: A practical study on chlorinated mandelic acids under carbon dioxide atmosphere
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Crystallization of the polymorphs of succinic acid via sublimation at different temperatures in the presence or absence of water and isopropanol vapor
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Asymmetric synthesis of fluorine-containing amines, amino alcohols, α- and β-amino acids mediated by chiral sulfinyl group
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Self-disproportionation of enantiomers of 3,3,3-trifluorolactic acid amides via sublimation
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Biomimetic reductive amination under the continuous-flow reaction conditions
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Self-disproportionation of enantiomers of α-trifluoromethyl lactic acid amides via sublimation
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Chirality-dependent sublimation of -(trifluoromethyl)-lactic acid: Relative vapor pressures of racemic, eutectic, and enantiomerically pure forms, and vibrational spectroscopy of isolated (S,S) and (S,R) dimers
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Self-disproportionation of enantiomers of isopropyl 3,3,3-(trifluoro)lactate via sublimation: Sublimation rates vs. enantiomeric composition
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Self-disproportionation of enantiomers of heterocyclic compounds having a tertiary trifluoromethyl alcohol center on chromatography with a non-chiral system
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Discrimination of enantiomeric excess of optically active trifluorolactate by distillation: Evidence for a multi-center hydrogen bonding network in the liquid state
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Attempts to explain the self-disproportionation observed in the partial sublimation of enantiomerically enriched carboxylic acids
inferred← citeshttps://doi.org/10.1016/j.jfluchem.2009.12.014openalex-snapshot
Amplification of chirality as a pathway to biological homochirality
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First principle lattice energy calculations for enantiopure and racemic crystals of α-(trifluoromethyl)lactic acid: Is self-disproportionation of enantiomers controlled by thermodynamic stability of crystals?
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Trifluoroacetaldehyde: A useful industrial bulk material for the synthesis of trifluoromethylated amino compounds
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Convenient synthesis of fluoroalkyl α- and β-aminophosphonates
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Large-scale Mannich-type reactions of (SS)-N-tert-butanesulfinyl-(3,3,3)-trifluoroacetaldimine with C-nucleophiles
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Recent advances in the trifluoromethylation methodology and new CF3-containing drugs
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Organocatalytic enantioselective Diels–Alder reaction of 4,4,4-trifluorocrotonaldehyde
inferred← citeshttps://doi.org/10.1016/j.jfluchem.2016.01.008openalex-snapshot
Catalytic asymmetric detrifluoroacetylative aldol reactions of aliphatic aldehydes for construction of C-F quaternary stereogenic centers
inferred← citeshttps://doi.org/10.1016/j.jfluchem.2016.07.016openalex-snapshot
Self-Disproportionation of Enantiomers (SDE) via achiral gravity-driven column chromatography of N -fluoroacyl-1-phenylethylamines
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Asymmetric synthesis of erythro-8-O-4’-neolignan Machilin C
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Separation of nonracemic mixtures of enantiomers by achiral simulated moving bed chromatography
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Chiral counteranion-directed silver-catalyzed asymmetric synthesis of 1,2-dihydroisoquinolines by Friedel–Crafts alkylation reactions
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Self-disproportionation of enantiomers of non-racemic chiral amine derivatives through achiral chromatography
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Asymmetric Michael addition reaction organocatalyzed by stereoisomeric pyrrolidine sulfinamides under neat conditions. A brief study of self-disproportionation of enantiomers
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Access to the enantiopure pyrrolobenzodiazepine (PBD) dilactam nucleus via self-disproportionation of enantiomers
inferred← citeshttps://doi.org/10.1016/j.tetasy.2010.04.026openalex-snapshot
Asymmetric synthesis of deuterated and fluorinated aromatic α,α-disubstituted amino acid derivatives
inferred← citeshttps://doi.org/10.1016/j.tetasy.2010.04.040openalex-snapshot
Rational application of self-disproportionation of enantiomers via sublimation—a novel methodological dimension for enantiomeric purifications
inferred← citeshttps://doi.org/10.1016/j.tetasy.2013.06.008openalex-snapshot
Self-disproportionation of enantiomers of prazoles via achiral, gravity-driven silica gel column chromatography
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The effect of SDE on the separation of diastereomeric salts: a case study for the resolution of mandelic acid derivatives with Pregabalin
inferred← citeshttps://doi.org/10.1016/j.tetasy.2015.02.006openalex-snapshot
The effect of the eutectic composition on the outcome of kinetically and thermodynamically controlled resolutions that are based on the formation of diastereomers
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Chiral additive induced self-disproportionation of enantiomers under MPLC conditions: preparation of enantiomerically pure samples of 1-(aryl)ethylamines from racemates
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Determination of the absolute structure of the chiral crystal consisting of achiral dibutylhydroxytoluene and asymmetric autocatalysis triggered by this chiral crystal
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A question of policy: should tests for the self-disproportionation of enantiomers (SDE) be mandatory for reports involving scalemates?
inferred← citeshttps://doi.org/10.1016/j.tetasy.2017.09.005openalex-snapshot
A fast, new method to enhance the enantiomeric purity of non-racemic mixtures: self-disproportionation of enantiomers in the gas antisolvent fractionation of chlorine-substituted mandelic acid derivatives
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Asymmetric synthesis of phosphonotrifluoroalanine and its derivatives using N-tert-butanesulfinyl imine derived from fluoral
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Chiral initiator-induces self-disproportionation of enantiomers via achiral chromatography: application to enantiomer separation of racemate
inferred← citeshttps://doi.org/10.1021/acs.iecr.5c00412openalex-snapshot
Coupling Achiral and Chiral Chromatography for Efficient Separation of Enantiomeric Mixtures
inferred← citeshttps://doi.org/10.1021/acscatal.5b01300openalex-snapshot
Principles and Applications of Enantioselective Hydroformylation of Terminal Disubstituted Alkenes
inferred← citeshttps://doi.org/10.1021/ar5003208openalex-snapshot
Asymmetric Autocatalysis of Pyrimidyl Alkanol and Its Application to the Study on the Origin of Homochirality
inferred← citeshttps://doi.org/10.1021/cg201219gopenalex-snapshot
First Experimental Evidence of an Intramolecular H Bond between Aliphatic Cl and Aromatic C–H
inferred← citeshttps://doi.org/10.1021/cr1002479openalex-snapshot
Crystalline Architectures as Templates of Relevance to the Origins of Homochirality
inferred← citeshttps://doi.org/10.1021/cr100352kopenalex-snapshot
Bicyclic Conformationally Restricted Diamines
inferred← citeshttps://doi.org/10.1021/cr4002879openalex-snapshot
Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)
inferred← citeshttps://doi.org/10.1021/cr500193bopenalex-snapshot
Synthetic Methods for Compounds Having CF 3 –S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions
inferred← citeshttps://doi.org/10.1021/ja1018628openalex-snapshot
Stereoselective Construction of Halogenated Quaternary Stereogenic Centers via Catalytic Asymmetric Diels−Alder Reaction
inferred← citeshttps://doi.org/10.1021/ja304806jopenalex-snapshot
Highly Enantioselective Chlorination of β-Keto Esters and Subsequent SN2 Displacement of Tertiary Chlorides: A Flexible Method for the Construction of Quaternary Stereogenic Centers
inferred← citeshttps://doi.org/10.1021/ja905628hopenalex-snapshot
Mimics of the Self-Assembling Chlorosomal Bacteriochlorophylls: Regio- and Stereoselective Synthesis and Stereoanalysis of Acyl(1-hydroxyalkyl)porphyrins
inferred← citeshttps://doi.org/10.1021/jo102031bopenalex-snapshot
Asymmetric Synthesis of Sterically and Electronically Demanding Linear ω-Trifluoromethyl Containing Amino Acids via Alkylation of Chiral Equivalents of Nucleophilic Glycine and Alanine
inferred← citeshttps://doi.org/10.1021/jo301513xopenalex-snapshot
Enantioselective Synthesis of Coumarin Derivatives by PYBOX-DIPH-Zn(II) Complex Catalyzed Michael Reaction
inferred← citeshttps://doi.org/10.1021/jo400115ropenalex-snapshot
Synthesis of Optically Pure 2-Trifluoromethyl Lactic Acid by Asymmetric Hydroformylation
inferred← citeshttps://doi.org/10.1021/jo4017474openalex-snapshot
Partial Sublimation of Enantioenriched Amino Acids at Low Temperature. Is it Coming From the Formation of a Euatmotic Composition1 of the Gaseous Phase?
inferred← citeshttps://doi.org/10.1021/ol103093ropenalex-snapshot
Enantioselective Organocatalytic Synthesis of Quaternary α-Amino Acids Bearing a CF3 Moiety
inferred← citeshttps://doi.org/10.1021/ol200616topenalex-snapshot
Enantioselective Synthesis Induced by Chiral Crystal Composed of dl -Serine in Conjunction with Asymmetric Autocatalysis
inferred← citeshttps://doi.org/10.1021/ol201007eopenalex-snapshot
Enantioselective gem -Chlorofluorination of Active Methylene Compounds Using a Chiral Spiro Oxazoline Ligand
inferred← citeshttps://doi.org/10.1021/ol501011topenalex-snapshot
One-Pot Organocatalytic Enantioselective Michael–Michael–Aldol–Henry Reaction Cascade. A Facile Entry to the Steroid System with Six Contiguous Stereogenic Centers
inferred← citeshttps://doi.org/10.1021/ol900357dopenalex-snapshot
New Sterically Driven Mode for Generation of Helical Chirality
inferred← citeshttps://doi.org/10.1038/s41598-018-35457-6openalex-snapshot
Understanding the Thalidomide Chirality in Biological Processes by the Self-disproportionation of Enantiomers
inferred← citeshttps://doi.org/10.1039/9781839163685-00104openalex-snapshot
Mechanisms of Amplification
inferred← citeshttps://doi.org/10.1039/9781839166273-00289openalex-snapshot
Symmetry Breaking in a Heterogenous Phase: Intriguing Intermediates and Side-products During Asymmetric Amplification
inferred← citeshttps://doi.org/10.1039/b814905dopenalex-snapshot
NMR and molecular modeling of the dimeric self-association of the enantiomers of 1,1′-bi-2-naphthol and 1-phenyl-2,2,2-trifluoroethanol in the solution state and their relevance to enantiomer self-disproportionation on achiral-phase chromatography (ESDAC)
inferred← citeshttps://doi.org/10.1039/b915610kopenalex-snapshot
A simple explanation of the enhancement or depletion of the enantiomeric excess in the partial sublimation of enantiomerically enriched amino acids
inferred← citeshttps://doi.org/10.1039/b917564dopenalex-snapshot
Separation of non-racemic mixtures of enantiomers: an essential part of optical resolution
inferred← citeshttps://doi.org/10.1039/c0cp01155jopenalex-snapshot
Theoretical investigations into the enantiomeric and racemic forms of α-(trifluoromethyl)lactic acid
inferred← citeshttps://doi.org/10.1039/c0cp02876bopenalex-snapshot
Reply to the ‘Comment on “Theoretical investigations into the enantiomeric and racemic forms of α-(trifluoromethyl)lactic acid”’ by M. A. Suhm and M. Albrecht, Phys. Chem. Chem. Phys., 2011, 13, DOI: 10.1039/c0cp02455d
inferred← citeshttps://doi.org/10.1039/c0ob00424copenalex-snapshot
Straightforward synthesis of enantiopure (R)- and (S)-trifluoroalaninol
inferred← citeshttps://doi.org/10.1039/c1cc10403aopenalex-snapshot
Highly enantioselective zinc/BINOL-catalyzed alkynylation of α-ketoimine ester: a new entry to optically active quaternary α-CF 3 α-amino acids
inferred← citeshttps://doi.org/10.1039/c1cc15889aopenalex-snapshot
A Diels–Alder approach to the enantioselective construction of fluoromethylated stereogenic carbon centers
inferred← citeshttps://doi.org/10.1039/c2cc32757kopenalex-snapshot
Practical synthesis of 4,4,4-trifluorocrotonaldehyde: a versatile precursor for the enantioselective formation of trifluoromethylated stereogenic centers via organocatalytic 1,4-additions
inferred← citeshttps://doi.org/10.1039/c2cc34928kopenalex-snapshot
Asymmetric autocatalysis initiated by achiral nucleic acid base adenine: implications on the origin of homochirality of biomolecules
inferred← citeshttps://doi.org/10.1039/c2cc37491aopenalex-snapshot
Unconventional preparation of racemic crystals of isopropyl 3,3,3-trifluoro-2-hydroxypropanoate and their unusual crystallographic structure: the ultimate preference for homochiral intermolecular interactions
inferred← citeshttps://doi.org/10.1039/c2cs35006hopenalex-snapshot
Self-disproportionation of enantiomers via achiral chromatography: a warning and an extra dimension in optical purifications
inferred← citeshttps://doi.org/10.1039/c4ob00831fopenalex-snapshot
The self-disproportionation of the enantiomers (SDE) of methyl n-pentyl sulfoxide via achiral, gravity-driven column chromatography: a case study
inferred← citeshttps://doi.org/10.1039/c4ra13928copenalex-snapshot
A comprehensive examination of the self-disproportionation of enantiomers (SDE) of chiral amides via achiral, laboratory-routine, gravity-driven column chromatography
inferred← citeshttps://doi.org/10.1039/c4sc03047hopenalex-snapshot
Self-disproportionation of enantiomers of thalidomide and its fluorinated analogue via gravity-driven achiral chromatography: mechanistic rationale and implications
inferred← citeshttps://doi.org/10.1039/c5cc00254kopenalex-snapshot
High temperature sublimation of α-amino acids: a realistic prebiotic process leading to large enantiomeric excess
inferred← citeshttps://doi.org/10.1039/c5cc05848aopenalex-snapshot
Spontaneous formation and amplification of an enantioenriched α-amino nitrile: a chiral precursor for Strecker amino acid synthesis
inferred← citeshttps://doi.org/10.1039/c5nj01459jopenalex-snapshot
Asymmetric induction by retgersite, nickel sulfate hexahydrate, in conjunction with asymmetric autocatalysis
inferred← citeshttps://doi.org/10.1039/c6cc05544copenalex-snapshot
Replication of α-amino acids via Strecker synthesis with amplification and multiplication of chiral intermediate aminonitriles
inferred← citeshttps://doi.org/10.1039/c6cs00703aopenalex-snapshot
Chiral sulfoxides: advances in asymmetric synthesis and problems with the accurate determination of the stereochemical outcome
inferred← citeshttps://doi.org/10.1039/c6ob02415gopenalex-snapshot
Unusual reversal of enantioselectivity in the asymmetric autocatalysis of pyrimidyl alkanol triggered by chiral aromatic alkanols and amines
inferred← citeshttps://doi.org/10.1039/c6ra22430jopenalex-snapshot
Constructing densely functionalized Hajos–Parrish-type ketones with six contiguous stereogenic centers and two quaternary carbons in a formal [2 + 2 + 2] cycloaddition cascade
inferred← citeshttps://doi.org/10.1039/c7sc05138gopenalex-snapshot
The self-disproportionation of enantiomers (SDE): a menace or an opportunity?
inferred← citeshttps://doi.org/10.1039/c9cc01875aopenalex-snapshot
Formation of enantioenriched alkanol with stochastic distribution of enantiomers in the absolute asymmetric synthesis under heterogeneous solid–vapor phase conditions
inferred← citeshttps://doi.org/10.1039/d1cc04206hopenalex-snapshot
Circular dichroism spectroscopy of catalyst preequilibrium in asymmetric autocatalysis of pyrimidyl alkanol
inferred← citeshttps://doi.org/10.1039/d3sc00359kopenalex-snapshot
Chirally and chemically reversible Strecker reaction
inferred← citeshttps://doi.org/10.1039/d5cp00275copenalex-snapshot
The influence of fluorine spin-diffusion on 13 C solid-state NMR line shapes of CF 3 groups
inferred← citeshttps://doi.org/10.1039/d5ob01564bopenalex-snapshot
A one-pot visible-light strategy for cyclobutanone synthesis via sequential [2 + 2] cycloaddition and Nef reaction of nitroalkenes and 2-vinylpyridines
inferred← citeshttps://doi.org/10.1080/01496395.2010.539192openalex-snapshot
Loading Effects and Adsorption Isotherms for Single and Dual Chiral Systems Applying Ligand Exchange Chromatography
inferred← citeshttps://doi.org/10.1098/rsos.160102openalex-snapshot
Difluoromethanesulfonyl hypervalent iodonium ylides for electrophilic difluoromethylthiolation reactions under copper catalysis
inferred← citeshttps://doi.org/10.1107/s1600536813003097openalex-snapshot
rac-3,3,3-Trifluorolactic acid
inferred← citeshttps://doi.org/10.1201/b12252-7openalex-snapshot
Photochirogenesis
inferred← citeshttps://doi.org/10.1246/bcsj.20160160openalex-snapshot
Elucidation of the Structures of Asymmetric Autocatalyst Based on X-ray Crystallography
inferred← citeshttps://doi.org/10.1246/bcsj.20190116openalex-snapshot
Self-Replication of Chiral α-Amino Acids in Strecker-Type Synthesis via Asymmetric Induction and Amplification of Their Own Chiral Intermediate α-Aminonitriles
inferred← citeshttps://doi.org/10.1246/cl.150052openalex-snapshot
Asymmetric Autocatalysis Triggered by Chiral Crystal of Achiral Ethylenediamine Sulfate
inferred← citeshttps://doi.org/10.1515/ncrs-2014-8193openalex-snapshot
Crystal structure of rac-4,4,4-trifluoro-3-hydroxy-3-methylbutanoic acid, C5H7O2F3
inferred← citeshttps://doi.org/10.15407/bioorganica2023.01.010openalex-snapshot
Applications of chiral sulfinyl auxiliaries in the asymmetric synthesis of fluorinated amines and amino acids
inferred← citeshttps://doi.org/10.15407/bioorganica2023.02.003openalex-snapshot
Discovery of biomimetic transamination as a general synthetic method for preparation of fluorine-containing amines and amino acids
inferred← citeshttps://doi.org/10.15407/bioorganica2024.01.021openalex-snapshot
Enzymatic approaches for preparation of α-aminophosphonic acids and fluorine-containing β-amino acids
inferred← citeshttps://doi.org/10.2183/pjab.95.009openalex-snapshot
Asymmetric autocatalysis. Chiral symmetry breaking and the origins of homochirality of organic molecules
inferred← citeshttps://doi.org/10.24820/ark.5550190.p009.829openalex-snapshot
Self-disproportionation of enantiomers (SDE) of chiral sulfur-containing compounds via achiral chromatography
inferred← citeshttps://doi.org/10.33609/2708-129x.90.9.2024.31-56openalex-snapshot
NEW DRUGS ON THE PHARMACEUTICAL MARKET CONTAINING FLUORINE AND RESIDUES OF TAILOR-MADE AMINO ACIDS
inferred← citeshttps://doi.org/10.33609/2708-129x.91.12.2025.33-72openalex-snapshot
ENANTIOSELECTIVE CATALYSIS FOR THE SYNTHESIS OF 1-SUBSTITUTED-2,2,2-TRIFLUOROETHYLAMINES
inferred← citeshttps://doi.org/10.33609/2708-129x.91.3.2025.34-48openalex-snapshot
ENANTIOMER PURIFICATION THROUGH ACHIRAL CHROMATOGRAPHY: INTEGRATING SIMULATED MOVING BED AND SELF-DISPROPORTIONATION OF ENANTIOMERS
inferred← citeshttps://doi.org/10.33609/2708-129x.91.6.2025.15-54openalex-snapshot
MODERN PHARMACEUTICAL DRUGS FEATURING ALIPHATIC FLUORINE-CONTAINING GROUPS
inferred← citeshttps://doi.org/10.33609/2708-129x.92.4.2026.52-78openalex-snapshot
ORGANOFLUORINE CHEMISTRY IN ONCOLOGY: A REVIEW OF US FDA-APPROVED ANTICANCER DRUGS IN 2025 (review)
inferred← citeshttps://doi.org/10.3390/molecules15085782openalex-snapshot
Asymmetric Synthesis of α-Aminophosphonates Using the Inexpensive Chiral Catalyst 1,1’-Binaphthol Phosphate
inferred← citeshttps://doi.org/10.3390/molecules24122218openalex-snapshot
Recyclable and Stable α-Methylproline-Derived Chiral Ligands for the Chemical Dynamic Kinetic Resolution of free C,N-Unprotected α-Amino Acids
inferred← citeshttps://doi.org/10.3390/molecules26092757openalex-snapshot
Recommended Tests for the Self-Disproportionation of Enantiomers (SDE) to Ensure Accurate Reporting of the Stereochemical Outcome of Enantioselective Reactions
inferred← citeshttps://doi.org/10.3390/molecules26133994openalex-snapshot
A Call for a Change in Policy Regarding the Necessity for SDE Tests to Validate the Veracity of the Outcome of Enantioselective Syntheses, the Inherent Chiral State of Natural Products, and Other Cases Involving Enantioenriched Samples
inferred← citeshttps://doi.org/10.3390/molecules26175166openalex-snapshot
Application of Polyamines and Amino Acid Derivatives Based on 2-Azabicycloalkane Backbone in Enantioselective Aldol Reaction
inferred← citeshttps://doi.org/10.3390/molecules27072369openalex-snapshot
Intermolecular Halogen Bond Detected in Racemic and Optically Pure N-C Axially Chiral 3-(2-Halophenyl)quinazoline-4-thione Derivatives
inferred← citeshttps://doi.org/10.3390/molecules28155908openalex-snapshot
Copper (II) Ions Induced Self-Disproportionation of Enantiomers in Capillary Electrophoresis for the Quantification of Atenolol Enantiomers
inferred← citeshttps://doi.org/10.3390/separations10070382openalex-snapshot
The Self-Disproportionation of Enantiomers (SDE) of α-Pinene via Evaporation off Silica Gel and Foam Fractionation—Validation of the Plausibility of SDE via Gas Chromatography (GC) for α-Pinene
inferred← citeshttps://doi.org/10.3390/sym11050694openalex-snapshot
Role of Asymmetric Autocatalysis in the Elucidation of Origins of Homochirality of Organic Compounds
inferred← citeshttps://doi.org/10.3390/sym12071106openalex-snapshot
Potentially Mistaking Enantiomers for Different Compounds Due to the Self-Induced Diastereomeric Anisochronism (SIDA) Phenomenon
inferred← citeshttps://doi.org/10.3390/sym13040543openalex-snapshot
Flurbiprofen: A Study of the Behavior of the Scalemate by Chromatography, Sublimation, and NMR
inferred← citeshttps://doi.org/10.3390/sym13040667openalex-snapshot
The Stoichiometry, Structure and Possible Formation of Crystalline Diastereomeric Salts
inferred← citeshttps://doi.org/10.3762/bjoc.10.30openalex-snapshot
Organocatalytic asymmetric fluorination of α-chloroaldehydes involving kinetic resolution
inferred← citeshttps://doi.org/10.3762/bjoc.7.85openalex-snapshot
Alkene selenenylation: A comprehensive analysis of relative reactivities, stereochemistry and asymmetric induction, and their comparisons with sulfenylation
inferred← citeshttps://doi.org/10.4155/fmc.09.70openalex-snapshot
Practical Synthesis of Fluorine-Containing α- and β-Amino Acids: Recipes from Kiev, Ukraine
inferred← citeshttps://doi.org/10.4236/ijoc.2012.23031openalex-snapshot
Suggested New Terms for Describing Chiral States and the State-Dependent Behavior of Chiral Systems
inferred← citeshttps://doi.org/10.5059/yukigoseikyokaishi.71.109openalex-snapshot
Approaches Toward the Origin of Homochirality Using the Synthetic Organic Chemistry ^|^mdash;Asymmetric Autocatalysis with Amplification of Enantiomeric Excess^|^mdash;
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