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A Highly Chemoselective Cobalt Catalyst for the Hydrosilylation of Alkenes using Tertiary Silanes and Hydrosiloxanes

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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The Hydrosilylation Reaction
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Modern Alchemy: Replacing Precious Metals with Iron in Catalytic Alkene and Carbonyl Hydrogenation Reactions
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Highly Active and Selective Platinum(0)‐Carbene Complexes. Efficient, Catalytic Hydrosilylation of Functionalised Olefins
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Iron‐Catalysed Chemo‐, Regio‐, and Stereoselective Hydrosilylation of Alkenes and Alkynes using a Bench‐Stable Iron(II) Pre‐Catalyst
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Chemoselective Alkene Hydrosilylation Catalyzed by Nickel Pincer Complexes
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Polyisoprene modified poly(alkyl acrylate) foam as oil sorbent material
inferredcites →https://doi.org/10.1002/hlca.19710540510openalex-snapshot
Tetrakis‐triphenylphosphin‐platin(0), ein Katalysator zur selektiven Hydrosilylierung
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Hydrosilylation : a comprehensive review on recent advances
inferredcites →https://doi.org/10.1016/j.ccr.2005.02.025openalex-snapshot
Catalysis by transition metal complexes of alkene silylation–recent progress and mechanistic implications
inferredcites →https://doi.org/10.1016/j.ccr.2010.12.025openalex-snapshot
Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view
inferredcites →https://doi.org/10.1016/s0022-328x(00)88795-1openalex-snapshot
Synthesis of organocyclosiloxanes containing alkenyl groups attached to silicon
inferredcites →https://doi.org/10.1016/s0022-328x(00)92799-2openalex-snapshot
Studies in organosilicon chemistry
inferredcites →https://doi.org/10.1021/acscatal.5b02308openalex-snapshot
Cobalt Complex-Catalyzed Hydrosilylation of Alkenes and Alkynes
inferredcites →https://doi.org/10.1021/acscatal.6b00304openalex-snapshot
Bench-Stable, Substrate-Activated Cobalt Carboxylate Pre-Catalysts for Alkene Hydrosilylation with Tertiary Silanes
inferredcites →https://doi.org/10.1021/ic4018882openalex-snapshot
Chemistry of Reduced Monomeric and Dimeric Cobalt Complexes Supported by a PNP Pincer Ligand
inferredcites →https://doi.org/10.1021/ic501901nopenalex-snapshot
Carbon Dioxide Hydrosilylation Promoted by Cobalt Pincer Complexes
inferredcites →https://doi.org/10.1021/ja00059a008openalex-snapshot
Mechanism of a cobalt(III)-catalyzed olefin hydrosilation reaction: direct evidence for a silyl migration pathway
inferredcites →https://doi.org/10.1021/ja046753topenalex-snapshot
Preparation and Molecular and Electronic Structures of Iron(0) Dinitrogen and Silane Complexes and Their Application to Catalytic Hydrogenation and Hydrosilation
inferredcites →https://doi.org/10.1021/ja106853yopenalex-snapshot
A Strategy for the Synthesis of Well-Defined Iron Catalysts and Application to Regioselective Diene Hydrosilylation
inferredcites →https://doi.org/10.1021/ja404963fopenalex-snapshot
Phosphinite-Iminopyridine Iron Catalysts for Chemoselective Alkene Hydrosilylation
inferredcites →https://doi.org/10.1021/ja5008596openalex-snapshot
1,2-Selective Hydrosilylation of Conjugated Dienes
inferredcites →https://doi.org/10.1021/jacs.5b03092openalex-snapshot
Reversible Substrate Activation and Catalysis at an Intact Metal–Metal Bond Using a Redox-Active Supporting Ligand
inferredcites →https://doi.org/10.1021/jacs.5b08611openalex-snapshot
Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt Catalyst
inferredcites →https://doi.org/10.1021/jacs.5b11311openalex-snapshot
Non-Precious-Metal Catalytic Systems Involving Iron or Cobalt Carboxylates and Alkyl Isocyanides for Hydrosilylation of Alkenes with Hydrosiloxanes
inferredcites →https://doi.org/10.1021/jo00959a025openalex-snapshot
Stereochemistry of methyldichlorosilane additions to pentadienes
inferredcites →https://doi.org/10.1021/ol025658ropenalex-snapshot
Platinum Oxide (PtO2): A Potent Hydrosilylation Catalyst
inferredcites →https://doi.org/10.1021/ol203428copenalex-snapshot
General and Practical One-Pot Synthesis of Dihydrobenzosiloles from Styrenes
inferredcites →https://doi.org/10.1021/om060492+openalex-snapshot
Stoichiometric and Catalytic Reactions Involving Si−H Bond Activations by Rh and Ir Complexes Containing a Pyridylindolide Ligand
inferredcites →https://doi.org/10.1021/om400452qopenalex-snapshot
Homobimetallic Rhodium NHC Complexes as Versatile Catalysts for Hydrosilylation of a Multitude of Substrates in the Presence of Ambient Air
inferredcites →https://doi.org/10.1021/om50005a041openalex-snapshot
Silafunctional compounds in organic synthesis. Part 20. Hydrogen peroxide oxidation of the silicon-carbon bond in organoalkoxysilanes
inferredcites →https://doi.org/10.1039/c2cc32974copenalex-snapshot
Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(ii) complex
inferredcites →https://doi.org/10.1039/c39840000029openalex-snapshot
The phenyldimethylsilyl group as a masked form of the hydroxy group
inferredcites →https://doi.org/10.1039/c39940001777openalex-snapshot
Cationic rhodium complex-catalysed highly selective hydrosilylation of propynylic alcohols: a convenient synthesis of (E)-γ-silyl allylic alcohols
inferredcites →https://doi.org/10.1039/c5dt04723dopenalex-snapshot
Monoanionic bis(carbene) pincer complexes featuring cobalt( I–III ) oxidation states
inferredcites →https://doi.org/10.1055/s-2003-44373openalex-snapshot
Cobalt(I)-Catalyzed Diels-Alder, 1,4-Hydrovinylation and 1,4-Hydrosilylation Reactions of Non-Activated Starting Materials on a Large Scale
inferredcites →https://doi.org/10.1126/science.1214451openalex-snapshot
Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes
inferredcites →https://doi.org/10.1135/cccc19740144openalex-snapshot
Vibrational spectra of the trihalosilyl-1- or -2-butenes obtained by hydrosilylation
inferredcites →https://doi.org/10.1595/003214097x4126675openalex-snapshot
Platinum Catalysts Used in the Silicones Industry
inferredcites →https://doi.org/10.5860/choice.38-4470openalex-snapshot
Silicon in organic, organometallic, and polymer chemistry

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4581369openalex-extracted
Anti-Markovnikov Hydrosilylation and Markovnikov Hydroboration of Alkenes by a Phenanthroline-Based Tridentate Manganese(Ii) Catalyst
inferred← citeshttps://doi.org/10.1002/9780470682531.pat0994openalex-snapshot
Structural Chemistry of Organocobalt Compounds
inferred← citeshttps://doi.org/10.1002/9780470682531.pat0997openalex-snapshot
Cobalt N ‐Heterocyclic Carbene Complexes in Organic Synthesis
inferred← citeshttps://doi.org/10.1002/9781118930786.ch3openalex-snapshot
Oxidation and Reduction
inferred← citeshttps://doi.org/10.1002/9781119288657.ch10openalex-snapshot
Addition Reactions
inferred← citeshttps://doi.org/10.1002/9781119288657.ch3openalex-snapshot
Oxidation and Reduction
inferred← citeshttps://doi.org/10.1002/9781119288657.ch4openalex-snapshot
Carbenes and Nitrenes
inferred← citeshttps://doi.org/10.1002/9783527344260.ch7openalex-snapshot
Group 9 Transition Metal–Dinitrogen Complexes
inferred← citeshttps://doi.org/10.1002/9783527699087.ch6openalex-snapshot
Base Metal‐Catalyzed Addition Reactions Across C C Multiple Bonds
inferred← citeshttps://doi.org/10.1002/9783527804801.ch4openalex-snapshot
Hydrofunctionalization of Carbon–Carbon Double Bonds
inferred← citeshttps://doi.org/10.1002/9783527814787.ch11openalex-snapshot
Hydrosilylation Catalyzed by Base Metals
inferred← citeshttps://doi.org/10.1002/adsc.202400309openalex-snapshot
Selective Hydrosilylation and Hydroboration of Allenes Catalyzed by Cobalt‐Pincer Complexes
inferred← citeshttps://doi.org/10.1002/ajoc.202100361openalex-snapshot
Cobalt‐Catalysed, Ligand‐Controlled Regiodivergent Alkene Hydrosilylation
inferred← citeshttps://doi.org/10.1002/ajoc.202200201openalex-snapshot
Recent Advances in Cobalt‐catalyzed Functionalization of Unactivated Olefins
inferred← citeshttps://doi.org/10.1002/ange.201612460openalex-snapshot
(Aminomethyl)pyridine Complexes for the Cobalt‐Catalyzed Anti‐Markovnikov Hydrosilylation of Alkoxy‐ or Siloxy(vinyl)silanes with Alkoxy‐ or Siloxyhydrosilanes
inferred← citeshttps://doi.org/10.1002/ange.201702349openalex-snapshot
Iron‐Catalyzed Intermolecular 1,2‐Difunctionalization of Styrenes and Conjugated Alkenes with Silanes and Nucleophiles
inferred← citeshttps://doi.org/10.1002/ange.202007930openalex-snapshot
Ligand‐Regulated Regiodivergent Hydrosilylation of Isoprene under Iron Catalysis
inferred← citeshttps://doi.org/10.1002/ange.202100775openalex-snapshot
Asymmetric Cobalt‐Catalyzed Regioselective Hydrosilylation/Cyclization of 1,6‐Enynes
inferred← citeshttps://doi.org/10.1002/ange.202303853openalex-snapshot
Palladium‐Catalyzed Hydrosilylation of Unactivated Alkenes and Conjugated Dienes with Tertiary Silanes Controlled by Hemilabile Hybrid P,O Ligand
inferred← citeshttps://doi.org/10.1002/ange.202410334openalex-snapshot
Triphasic Hydroxysilylation of Alkenes by Mechanically Piezoelectric Catalysis
inferred← citeshttps://doi.org/10.1002/ange.202424273openalex-snapshot
Silylchromium‐Catalyzed Selective Semihydrogenation of Undirected Allenes by Sila‐Metalation and β‐Silyl Elimination
inferred← citeshttps://doi.org/10.1002/anie.201612460openalex-snapshot
(Aminomethyl)pyridine Complexes for the Cobalt‐Catalyzed Anti‐Markovnikov Hydrosilylation of Alkoxy‐ or Siloxy(vinyl)silanes with Alkoxy‐ or Siloxyhydrosilanes
inferred← citeshttps://doi.org/10.1002/anie.201702349openalex-snapshot
Iron‐Catalyzed Intermolecular 1,2‐Difunctionalization of Styrenes and Conjugated Alkenes with Silanes and Nucleophiles
inferred← citeshttps://doi.org/10.1002/anie.202007930openalex-snapshot
Ligand‐Regulated Regiodivergent Hydrosilylation of Isoprene under Iron Catalysis
inferred← citeshttps://doi.org/10.1002/anie.202100775openalex-snapshot
Asymmetric Cobalt‐Catalyzed Regioselective Hydrosilylation/Cyclization of 1,6‐Enynes
inferred← citeshttps://doi.org/10.1002/anie.202303853openalex-snapshot
Palladium‐Catalyzed Hydrosilylation of Unactivated Alkenes and Conjugated Dienes with Tertiary Silanes Controlled by Hemilabile Hybrid P,O Ligand
inferred← citeshttps://doi.org/10.1002/anie.202410334openalex-snapshot
Triphasic Hydroxysilylation of Alkenes by Mechanically Piezoelectric Catalysis
inferred← citeshttps://doi.org/10.1002/anie.202424273openalex-snapshot
Silylchromium‐Catalyzed Selective Semihydrogenation of Undirected Allenes by Sila‐Metalation and β‐Silyl Elimination
inferred← citeshttps://doi.org/10.1002/aoc.6027openalex-snapshot
Cobalt bis(2‐ethylhexanoate) and terpyridine derivatives as catalysts for the hydrosilylation of olefins
inferred← citeshttps://doi.org/10.1002/aoc.70509openalex-snapshot
Effect of Silylene Ligand on Catalytic Pathway of Alkene Hydrosilylation Catalyzed by Phosphine Cobalt(III) Hydrides
inferred← citeshttps://doi.org/10.1002/asia.201801241openalex-snapshot
Xantphos Doped POPs‐PPh3 as Heterogeneous Ligand for Cobalt‐Catalyzed Highly Regio‐ and Stereoselective Hydrosilylation of Alkynes
inferred← citeshttps://doi.org/10.1002/asia.202100804openalex-snapshot
Base Metal‐terpyridine Complex Immobilized on Stationary Phase Aimed as Reusable Hydrosilylation Catalyst
inferred← citeshttps://doi.org/10.1002/asia.202400945openalex-snapshot
Intermolecular Sulfenoamination of Alkenes with Free‐Thiols and NIS to Access β‐Succinimide Sulfides
inferred← citeshttps://doi.org/10.1002/cctc.201901717openalex-snapshot
Chemoselective Hydrosilylation of Olefin/Ketone Catalyzed by Iminobipyridine Fe and Co complexes
inferred← citeshttps://doi.org/10.1002/cctc.202300781openalex-snapshot
Co‐Catalyzed Hydrosilylation of Ketones under Base‐Free Conditions: A Convenient Route to Silyl Ethers or Secondary Alcohols
inferred← citeshttps://doi.org/10.1002/chem.201705201openalex-snapshot
Cobalt Pincer Complexes for Catalytic Reduction of Carboxylic Acid Esters
inferred← citeshttps://doi.org/10.1002/chem.201803016openalex-snapshot
Cobalt–Pincer Complexes in Catalysis
inferred← citeshttps://doi.org/10.1002/chem.201901148openalex-snapshot
Additive‐Free Isomerization of Allylic Alcohols to Ketones with a Cobalt PNP Pincer Catalyst
inferred← citeshttps://doi.org/10.1002/chem.202404657openalex-snapshot
Rhodium(III)‐NSi Catalyzed Styrene Hydrosilylation: Evidence of the Hemilabile Character of NSi‐Type Ligands
inferred← citeshttps://doi.org/10.1002/cjoc.201800314openalex-snapshot
Recent Advances in Hydrometallation of Alkenes and Alkynes via the First Row Transition Metal Catalysis
inferred← citeshttps://doi.org/10.1002/cjoc.202300407openalex-snapshot
Nickel‐Catalyzed Regioselective Hydrosilylation of Conjugated Dienes†
inferred← citeshttps://doi.org/10.1002/cphc.202100178openalex-snapshot
Effects of a Tridentate Pincer Ligand on Parahydrogen Induced Polarization
inferred← citeshttps://doi.org/10.1002/cplu.201900366openalex-snapshot
Hydrosilylation of Ketones Catalyzed by Iron Iminobipyridine Complexes and Accelerated by Lewis Bases
inferred← citeshttps://doi.org/10.1002/ejic.201701195openalex-snapshot
Coordination Chemistry of the PdmBOX Pincer Ligand: Reactivity at the Metal and the Ligand
inferred← citeshttps://doi.org/10.1002/ejic.201801221openalex-snapshot
Cobalt(II) and (I) Complexes of Diphosphine‐Ketone Ligands: Catalytic Activity in Hydrosilylation Reactions
inferred← citeshttps://doi.org/10.1002/ejic.202000444openalex-snapshot
Structure Function Relationships in Ruthenium Carbon Dioxide Reduction Catalysts with CNC Pincers Containing Donor Groups
inferred← citeshttps://doi.org/10.1002/ejoc.202500069openalex-snapshot
Hydrosilylation of Terminal Alkenes Catalyzed by a Scandium Metalloligand Supported Ni(0) Complex
inferred← citeshttps://doi.org/10.1002/ejoc.202500215openalex-snapshot
Earth‐Abundant Metal Complexes as Catalysts for the Dehydrogenative Coupling of Hydrosilanes and Alcohols
inferred← citeshttps://doi.org/10.1002/ejoc.202500578openalex-snapshot
Efficient Hydrosilylation Reaction of Olefins Catalyzed by a Dinuclear Ruthenium Complex
inferred← citeshttps://doi.org/10.1002/slct.202202482openalex-snapshot
Imidazolinium‐functionalized Complexes of Cobalt and Iron as Catalysts for Hydrosilylation Reactions
inferred← citeshttps://doi.org/10.1002/slct.202303916openalex-snapshot
Progress in Cobalt Complexes for Enabling Asymmetric Hydrogenation, H 2 Production Catalysis and Alkene/Alkyne Hydro‐functionalization: A Review
inferred← citeshttps://doi.org/10.1007/3418_2023_101openalex-snapshot
Recent Development of Cobalt-Catalyzed Hydrosilylation Reactions: New Catalysts, Mechanistic Understandings, and Future Trends
inferred← citeshttps://doi.org/10.1007/s10118-020-2398-6openalex-snapshot
Preparation of Titanium-silphenylene-siloxane Hybrid Polymers with High Refractive Index, Transmittance, and Thermal Stability
inferred← citeshttps://doi.org/10.1007/s10562-020-03267-zopenalex-snapshot
Enantioselective Nickel Catalyzed Butadiene Hydroalkoxylation with Ethanol: from Experimental Results to Kinetics Parameters
inferred← citeshttps://doi.org/10.1016/b978-0-08-102688-5.00083-0openalex-snapshot
Reactivity and Structure of Complexes of Small Molecules: Dinitrogen
inferred← citeshttps://doi.org/10.1016/b978-0-08-102688-5.00094-5openalex-snapshot
Dihydrogen and Dinitrogen Complexes of Cobalt and Nickel
inferred← citeshttps://doi.org/10.1016/b978-0-08-102688-5.00114-8openalex-snapshot
Carbene-Based Pincer Ligands
inferred← citeshttps://doi.org/10.1016/b978-0-08-102688-5.00116-1openalex-snapshot
Transition Metal Complexes for Dinitrogen Coordination and Activation
inferred← citeshttps://doi.org/10.1016/b978-0-12-812931-9.00008-6openalex-snapshot
Complexes of NHC-Based CEC Pincer Ligands
inferred← citeshttps://doi.org/10.1016/b978-0-12-812931-9.00012-8openalex-snapshot
CCC-NHC Pincer Complexes
inferred← citeshttps://doi.org/10.1016/b978-0-12-820206-7.00027-5openalex-snapshot
Organometallic Chemistry of NHCs and Analogues
inferred← citeshttps://doi.org/10.1016/b978-0-12-820206-7.00109-8openalex-snapshot
N-Heterocyclic Carbene Complexes of Cobalt
inferred← citeshttps://doi.org/10.1016/b978-0-12-820206-7.00145-1openalex-snapshot
Organometallic Pincer Complexes of Cobalt, Rhodium, and Iridium
inferred← citeshttps://doi.org/10.1016/b978-0-323-96025-0.00015-6openalex-snapshot
Hydrosilylation of C–C π-Bonds
inferred← citeshttps://doi.org/10.1016/b978-0-323-96025-0.00125-3openalex-snapshot
Update Hydrometallation Group 4 (Si, Ge and Sn)
inferred← citeshttps://doi.org/10.1016/b978-0-443-15712-7.00003-3openalex-snapshot
Hydrosilylation reactions with homogeneous catalysts
inferred← citeshttps://doi.org/10.1016/bs.adomc.2019.09.002openalex-snapshot
Recent advances in the chemistry of group 9—Pincer organometallics
inferred← citeshttps://doi.org/10.1016/j.apcata.2020.117665openalex-snapshot
The effect of Schiff base ligands on the structure and catalytic activity of cobalt complexes in hydrosilylation of olefins
inferred← citeshttps://doi.org/10.1016/j.cclet.2023.108682openalex-snapshot
Four-coordinate disilyl cobalt(II) complexes with NHC ligation: Synthesis, characterization, and reactivity
inferred← citeshttps://doi.org/10.1016/j.ccr.2017.03.007openalex-snapshot
Multidentate N-heterocyclic carbene complexes of the 3d metals: Synthesis, structure, reactivity and catalysis
inferred← citeshttps://doi.org/10.1016/j.ccr.2019.01.024openalex-snapshot
Recent advances in tridentate iron and cobalt complexes for alkene and alkyne hydrofunctionalizations
inferred← citeshttps://doi.org/10.1016/j.ccr.2019.213110openalex-snapshot
Earth-abundant metal catalyzed hydrosilylative reduction of various functional groups
inferred← citeshttps://doi.org/10.1016/j.ccr.2020.213731openalex-snapshot
Multidentate NHC complexes of group IX metals featuring carbon-based tethers: Synthesis and applications
inferred← citeshttps://doi.org/10.1016/j.ica.2017.08.050openalex-snapshot
Free methylidyne? CCC-NHC tantalum bis(imido) reactivity: protonation, rearrangement to a mixed unsymmetrical CCC-N-heterocyclic carbene/N-heterocyclic dicarbene (CCC-NHC/NHDC) pincer tantalum bis(imido) complex
inferred← citeshttps://doi.org/10.1016/j.jcat.2023.115197openalex-snapshot
Anti-Markovnikov hydrosilylation and Markovnikov hydroboration of alkenes by a phenanthroline-based tridentate manganese catalyst
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2025.123579openalex-snapshot
Highly regioselective anti-Markovnikov hydrosilylation of alkenes under mild conditions: Application of CCC-NHC pincer Rh complexes
inferred← citeshttps://doi.org/10.1016/j.poly.2018.05.040openalex-snapshot
Investigation of metallation/transmetallation reactions to synthesize a series of CCC–NHC Co pincer complexes and their X-ray structures
inferred← citeshttps://doi.org/10.1016/j.tetlet.2019.151314openalex-snapshot
Cobalt-catalyzed hydrocyanation and hydroarylation of enamines
inferred← citeshttps://doi.org/10.1016/j.tetlet.2019.151513openalex-snapshot
Hydrosilylation reactions of functionalized alkenes
inferred← citeshttps://doi.org/10.1016/j.tetlet.2023.154798openalex-snapshot
Recent developments in alkene hydrosilylation utilizing manganese catalysts
inferred← citeshttps://doi.org/10.1021/acs.chemrev.8b00404openalex-snapshot
Hydride Transfer Reactions Catalyzed by Cobalt Complexes
inferred← citeshttps://doi.org/10.1021/acs.chemrev.8b00505openalex-snapshot
N-Heterocyclic Carbene Complexes of Copper, Nickel, and Cobalt
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.0c02332openalex-snapshot
The Effect of Substituents on the Formation of Silyl [PSiP] Pincer Cobalt(I) Complexes and Catalytic Application in Both Nitrogen Silylation and Alkene Hydrosilylation
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.0c03451openalex-snapshot
Manganese-Catalyzed Hydroboration of Terminal Olefins and Metal-Dependent Selectivity in Internal Olefin Isomerization–Hydroboration
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.0c03483openalex-snapshot
Selectivity Reverse of Hydrosilylation of Aryl Alkenes Realized by Pyridine N-Oxide with [PSiP] Pincer Cobalt(III) Hydride as Catalyst
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.2c02094openalex-snapshot
Control over Selectivity in Alkene Hydrosilylation Catalyzed by Cobalt(III) Hydride Complexes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.4c00521openalex-snapshot
Catalytic Properties of [PSiP] Pincer Cobalt(II) Chlorides Supported by Trimethylphosphine for Alkene Hydrosilylation Reactions
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6c03171openalex-snapshot
Catalytic Alkene Hydrosilylation and Dinitrogen Silylation by Bis(silylene) and Bis(diphenylphosphino) Cobalt Chlorides
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.7b00029openalex-snapshot
Studies on the Activation and Hydrosilylation Catalysis of RhCl3(Bu2S)3
inferred← citeshttps://doi.org/10.1021/acs.joc.0c01540openalex-snapshot
Iridium Complex-Catalyzed C2-Extension of Primary Alcohols with Ethanol via a Hydrogen Autotransfer Reaction
inferred← citeshttps://doi.org/10.1021/acs.joc.3c00127openalex-snapshot
Hydrosilylation of Terminal Alkynes Catalyzed by an Air-Stable Manganese–NHC Complex
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00018openalex-snapshot
Synthesis and Reactivity of Cobalt(I) and Iridium(I) Complexes Bearing a Pentadentate N-Homoallyl-Substituted Bis(NHC) Pincer Ligand
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00241openalex-snapshot
Mechanistic Study of Alkene Hydrosilylation Catalyzed by a β-Dialdiminate Cobalt(I) Complex
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00459openalex-snapshot
Cobalt-Catalyzed Ammonia Borane Dehydrogenation: Mechanistic Insight and Isolation of a Cobalt Hydride-Amidoborane Complex
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00553openalex-snapshot
Silane Activation with Cobalt on the POCOP Pincer Ligand Platform
inferred← citeshttps://doi.org/10.1021/acs.organomet.1c00309openalex-snapshot
[P,C]-Chelate Cobalt(III) Hydride Catalyzed Hydrosilylation of Alkenes
inferred← citeshttps://doi.org/10.1021/acs.organomet.1c00613openalex-snapshot
[P, C] Chelate Cobalt(I)-Catalyzed Distinct Selective Hydrosilylation of Alkenes under Mild Conditions
inferred← citeshttps://doi.org/10.1021/acs.organomet.3c00326openalex-snapshot
Well-Defined Cobalt-Silyl Complexes and Their Role in Catalytic Carbonyl Hydrosilylation
inferred← citeshttps://doi.org/10.1021/acs.organomet.4c00044openalex-snapshot
Joint Experimental/Theoretical Investigation of the Chemoselective Iridium(III) Metallacycle-Catalyzed Reduction of Substituted γ-Lactams by Et3SiH
inferred← citeshttps://doi.org/10.1021/acs.organomet.6c00169openalex-snapshot
Controllable Hydrosilylation and Dehydrogenative Silylation of Alkenes Catalyzed by a Manganese Alkyl Complex
inferred← citeshttps://doi.org/10.1021/acs.organomet.7b00087openalex-snapshot
Hydrosilylation of Olefins Catalyzed by Iron Complexes Bearing Ketimine-Type Iminobipyridine Ligands
inferred← citeshttps://doi.org/10.1021/acs.organomet.7b00772openalex-snapshot
Iron Pincer Complexes Incorporating Bipyridine: A Strategy for Stabilization of Reactive Species
inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00389openalex-snapshot
Cobalt(0) and Iron(0) Isocyanides as Catalysts for Alkene Hydrosilylation with Hydrosiloxanes
inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00416openalex-snapshot
Fe and Co Complexes of Rigidly Planar Phosphino-Quinoline-Pyridine Ligands for Catalytic Hydrosilylation and Dehydrogenative Silylation
inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00511openalex-snapshot
Synthesis of (POCOP)Co(Ph)(X) Pincer Complexes and Observation of Aryl–Aryl Reductive Elimination Involving the Pincer Aryl
inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00668openalex-snapshot
Aldehyde Decarbonylation by a Cobalt(I) Pincer Complex
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b01987openalex-snapshot
Regio- and Stereoselective Hydrosilylation of Unsymmetrical Alkynes Catalyzed by a Well-Defined, Low-Valent Cobalt Catalyst
inferred← citeshttps://doi.org/10.1021/acs.orglett.7b02940openalex-snapshot
Iridium-Catalyzed Hydrosilylation of Sulfur-Containing Olefins
inferred← citeshttps://doi.org/10.1021/acs.orglett.9b00874openalex-snapshot
Synthesis of Functionalized Organoboron/Silicon Compounds by Copper-Catalyzed Coupling of Alkylsilyl Peroxides and Diboron/Silylborane Reagents
inferred← citeshttps://doi.org/10.1021/acscatal.1c05869openalex-snapshot
Cobalt–N-Heterocyclic Carbene Complexes in Catalysis
inferred← citeshttps://doi.org/10.1021/acscatal.2c03580openalex-snapshot
(NHC)Ni(0)-Catalyzed Branched-Selective Alkene Hydrosilylation with Secondary and Tertiary Silanes
inferred← citeshttps://doi.org/10.1021/acscatal.2c06259openalex-snapshot
Cobalt(I)-Catalyzed Transformation of Si–H Bonds: H/D Exchange in Hydrosilanes and Hydrosilylation of Olefins
inferred← citeshttps://doi.org/10.1021/acscatal.3c02852openalex-snapshot
Cross-Electrophile Silylation of Aryl Carboxylic Esters with Hydrochlorosilanes by SiH-Directed and Cr-Catalyzed Couplings
inferred← citeshttps://doi.org/10.1021/acscatal.3c05747openalex-snapshot
Rare-Earth-Catalyzed Regiodivergent Hydrosilylation of Aryl Alkenes
inferred← citeshttps://doi.org/10.1021/acscatal.5c00006openalex-snapshot
Cobalt-Catalyzed Chemoselective and Divergent Synthesis of Vinylsilanes through Hydrosilylation of Acetylene
inferred← citeshttps://doi.org/10.1021/acscatal.5c03717openalex-snapshot
Catalyst-Controlled Mono- and Double-Dehydrosilylation of Arylalkenes: Divergent Synthesis of (E)-Vinylsilanes and (E)-Divinylsilanes
inferred← citeshttps://doi.org/10.1021/acscatal.6b01134openalex-snapshot
Alkene Hydrosilylation Using Tertiary Silanes with α-Diimine Nickel Catalysts. Redox-Active Ligands Promote a Distinct Mechanistic Pathway from Platinum Catalysts
inferred← citeshttps://doi.org/10.1021/acscatal.6b02518openalex-snapshot
Cobalt-Catalyzed Regiodivergent Hydrosilylation of Vinylarenes and Aliphatic Alkenes: Ligand- and Silane-Dependent Regioselectivities
inferred← citeshttps://doi.org/10.1021/acscatal.6b02990openalex-snapshot
Advances in Base-Metal-Catalyzed Alkene Hydrosilylation
inferred← citeshttps://doi.org/10.1021/acscatal.6b03373openalex-snapshot
Control of Selectivity through Synergy between Catalysts, Silanes, and Reaction Conditions in Cobalt-Catalyzed Hydrosilylation of Dienes and Terminal Alkenes
inferred← citeshttps://doi.org/10.1021/acscatal.7b00362openalex-snapshot
Insights into a Chemoselective Cobalt Catalyst for the Hydroboration of Alkenes and Nitriles
inferred← citeshttps://doi.org/10.1021/acscatal.8b01410openalex-snapshot
Cobalt-Catalyzed ( E )-Selective anti -Markovnikov Hydrosilylation of Terminal Alkynes
inferred← citeshttps://doi.org/10.1021/acscatal.8b02513openalex-snapshot
Distinct Catalytic Performance of Cobalt(I)–N-Heterocyclic Carbene Complexes in Promoting the Reaction of Alkene with Diphenylsilane: Selective 2,1-Hydrosilylation, 1,2-Hydrosilylation, and Hydrogenation of Alkene
inferred← citeshttps://doi.org/10.1021/acscatal.8b04481openalex-snapshot
Cobalt-Catalyzed Regio- and Enantioselective Markovnikov 1,2-Hydrosilylation of Conjugated Dienes
inferred← citeshttps://doi.org/10.1021/jacs.6b07066openalex-snapshot
Well-Defined Cobalt(I) Dihydrogen Catalyst: Experimental Evidence for a Co(I)/Co(III) Redox Process in Olefin Hydrogenation
inferred← citeshttps://doi.org/10.1021/jacs.6b12938openalex-snapshot
Mode of Activation of Cobalt(II) Amides for Catalytic Hydrosilylation of Alkenes with Tertiary Silanes
inferred← citeshttps://doi.org/10.1021/jacs.7b07368openalex-snapshot
Cobalt-Catalyzed and Lewis Acid-Assisted Nitrile Hydrogenation to Primary Amines: A Combined Effort
inferred← citeshttps://doi.org/10.1021/jacs.9b03337openalex-snapshot
Enabling Two-Electron Pathways with Iron and Cobalt: From Ligand Design to Catalytic Applications
inferred← citeshttps://doi.org/10.1038/s41467-017-02382-7openalex-snapshot
Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes
inferred← citeshttps://doi.org/10.1038/s41467-020-20233-wopenalex-snapshot
Biomimetic caged platinum catalyst for hydrosilylation reaction with high site selectivity
inferred← citeshttps://doi.org/10.1038/s41467-023-42847-6openalex-snapshot
Nucleophilic aromatization of monoterpenes from isoprene under nickel/iodine cascade catalysis
inferred← citeshttps://doi.org/10.1038/s41570-018-0001-2openalex-snapshot
Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration
inferred← citeshttps://doi.org/10.1039/c6cc04225bopenalex-snapshot
Peroxodisulfate-mediated selenoamination of alkenes yielding amidoselenide-containing sulfamides and azoles
inferred← citeshttps://doi.org/10.1039/c7dt04339bopenalex-snapshot
Preparation and reactivity of a square-planar PNP cobalt( ii )–hydrido complex: isolation of the first {Co–NO} 8 –hydride
inferred← citeshttps://doi.org/10.1039/c7nj03856aopenalex-snapshot
Mechanistic insights into the catalytic carbonyl hydrosilylation by cationic [CpM(CO) 2 (IMes)] + (M = Mo, W) complexes: the intermediacy of η 1 -H(Si) metal complexes
inferred← citeshttps://doi.org/10.1039/c7sc04002dopenalex-snapshot
Cobalt-catalyzed regioselective stereoconvergent Markovnikov 1,2-hydrosilylation of conjugated dienes
inferred← citeshttps://doi.org/10.1039/c8cc07267aopenalex-snapshot
Regiocontrol in the cobalt-catalyzed hydrosilylation of alkynes
inferred← citeshttps://doi.org/10.1039/c8dt04608eopenalex-snapshot
Anti-Markovnikov terminal and gem -olefin hydrosilylation using a κ 4 -diimine nickel catalyst: selectivity for alkene hydrosilylation over ether C–O bond cleavage
inferred← citeshttps://doi.org/10.1039/c8sc02768dopenalex-snapshot
A β-diketiminate manganese catalyst for alkene hydrosilylation: substrate scope, silicone preparation, and mechanistic insight
inferred← citeshttps://doi.org/10.1039/c9gc01981bopenalex-snapshot
Air-stable and reusable cobalt ion-doped titanium oxide catalyst for alkene hydrosilylation
inferred← citeshttps://doi.org/10.1039/c9sc00126copenalex-snapshot
Alkene hydrosilylation catalyzed by easily assembled Ni( ii )-carboxylate MOFs
inferred← citeshttps://doi.org/10.1039/c9sc06136copenalex-snapshot
Ligand-controlled cobalt-catalyzed regiodivergent hydroboration of aryl,alkyl-disubstituted internal allenes
inferred← citeshttps://doi.org/10.1039/d0sc01813aopenalex-snapshot
Concerted aryl-sulfur reductive elimination from PNP pincer-supported Co( iii ) and subsequent Co( i )/Co( iii ) comproportionation
inferred← citeshttps://doi.org/10.1039/d1cy00920fopenalex-snapshot
Co 2 (CO) 8 and unsaturated epoxides as unexpected partners in generating functionalized siloxane oils and cross-linked materials
inferred← citeshttps://doi.org/10.1039/d1ob02318gopenalex-snapshot
Copper-promoted difunctionalization of unactivated alkenes with silanes
inferred← citeshttps://doi.org/10.1039/d2cc03917fopenalex-snapshot
Oxime ester-enabled anti-Markovnikov hydrosilylation of alkenes
inferred← citeshttps://doi.org/10.1039/d2dt03471aopenalex-snapshot
Research on inorganic activators of dibromo Co-terpyridine complex precatalyst for hydrosilylation
inferred← citeshttps://doi.org/10.1039/d3dt00463eopenalex-snapshot
Synthesis and catalytic activity of well-defined Co( i ) complexes based on NHC–phosphane pincer ligands
inferred← citeshttps://doi.org/10.1039/d3nj01062gopenalex-snapshot
Catalytic hydrosilylation using an immobilized Co-terpyridine complex activated by inorganic salts and its application in a flow reactor
inferred← citeshttps://doi.org/10.1039/d3nj03878eopenalex-snapshot
Distinct selective alkene hydrosilylation catalyzed by acylenalato cobalt hydrides
inferred← citeshttps://doi.org/10.1039/d3qo00041aopenalex-snapshot
Ligand-controlled regiodivergence in cobalt-catalyzed hydrosilylation of isoprene
inferred← citeshttps://doi.org/10.1039/d4nj04379kopenalex-snapshot
Copper formate supported on sepiolite as a reusable catalyst for the hydrosilylation of olefins
inferred← citeshttps://doi.org/10.1039/d4ob00333kopenalex-snapshot
Siloxane-containing phosphine (oxide) ligands for enhanced catalytic activity of cobalt complexes for hydrosilylation reactions
inferred← citeshttps://doi.org/10.1039/d5cc03676copenalex-snapshot
Sustainable synthesis of hydrosilanes and alkoxysilanes in a sequential one-pot olefin hydrosilylation and dehydrogenative coupling with alcohol under phenoxyiminato cobalt( ii ) catalysis
inferred← citeshttps://doi.org/10.1039/d5nj01460copenalex-snapshot
Improvement of regioselectivity of alkene hydrosilylation catalyzed by [PNSiNP] pincer cobalt( iii ) hydrides using sodium methoxide as an additive
inferred← citeshttps://doi.org/10.1039/d6cc01831aopenalex-snapshot
Hydrosilylation of ω-hydroxyalkenes catalysed with 2-methacryloyloxyethyl-phosphorylcholine-protected ruthenium nanoparticles
inferred← citeshttps://doi.org/10.1055/a-2335-8516openalex-snapshot
Recent Advances in Ligand-Controlled Regio- or Stereodivergent Transition-Metal-Catalyzed Hydroelementation (H[E]) (E = H, B, Si, Ge) of C–C Unsaturated Systems
inferred← citeshttps://doi.org/10.1246/bcsj.20170071openalex-snapshot
Catalyst Design of Iron Complexes
inferred← citeshttps://doi.org/10.1246/bcsj.20180197openalex-snapshot
Hydrosilylation of Diene Derivatives Catalyzed by Fe-Iminobipyridine Complexes Aiming at Syntheses of Organosilane Compounds Containing a Terminal Olefin Portion
inferred← citeshttps://doi.org/10.1246/bcsj.20200043openalex-snapshot
Regioselective Hydrosilylation of Olefins Catalyzed by Co-Iminobipyridine Complexes: The Role of Cyclohexyl Substituent on the Imino Nitrogen
inferred← citeshttps://doi.org/10.24820/ark.5550190.p012.092openalex-snapshot
Copper-catalyzed silylation of activated alkenes by photoinduced ligand-to-metal charge transfer
inferred← citeshttps://doi.org/10.3390/polym9100534openalex-snapshot
Fifty Years of Hydrosilylation in Polymer Science: A Review of Current Trends of Low-Cost Transition-Metal and Metal-Free Catalysts, Non-Thermally Triggered Hydrosilylation Reactions, and Industrial Applications
inferred← citeshttps://doi.org/10.6023/cjoc202305016openalex-snapshot
Hydrosilylation Reactions of Alkene with Tertiary Silanes Catalyzed by Iron-Series Metals
inferred← citeshttps://doi.org/10.70675/c9654db2zc7c3z4206zb79bz0148c603fd3copenalex-snapshot
Nouveaux catalyseurs d’hydrosilylation pour la synthèse de silicones
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