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The Reaction Mechanism for the Organocatalytic Ring-Opening Polymerization of l -Lactide Using a Guanidine-Based Catalyst: Hydrogen-Bonded or Covalently Bound?
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Outgoing claims: the papers this work cites, builds on, or argues with.
inferredcites →https://doi.org/10.1002/anie.200461442openalex-snapshot
Highly Efficient Dynamic Kinetic Resolution of Azlactones by Urea‐Based Bifunctional Organocatalysts
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Enantio‐ and Diastereoselective Michael Reaction of 1,3‐Dicarbonyl Compounds to Nitroolefins Catalyzed by a Bifunctional Thiourea.
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Energies, structures, and electronic properties of molecules in solution with the C‐PCM solvation model
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Efficient diffuse function‐augmented basis sets for anion calculations. III. The 3‐21+G basis set for first‐row elements, Li–F
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General atomic and molecular electronic structure system
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1,5,7-Triazabicyclo[4.4.0]dec-5-ene (TBD) catalyzed Michael reactions
inferredcites →https://doi.org/10.1021/cr040002sopenalex-snapshot
Controlled Ring-Opening Polymerization of Lactide and Glycolide
inferredcites →https://doi.org/10.1021/ct600265copenalex-snapshot
Computational Investigation of Mechanisms for Ring-Opening Polymerization of ε-Caprolactone: Evidence for Bifunctional Catalysis by Alcohols
inferredcites →https://doi.org/10.1021/ja044370popenalex-snapshot
Enantio- and Diastereoselective Michael Reaction of 1,3-Dicarbonyl Compounds to Nitroolefins Catalyzed by a Bifunctional Thiourea
inferredcites →https://doi.org/10.1021/ja050909nopenalex-snapshot
Single-Component Catalyst/Initiators for the Organocatalytic Ring-Opening Polymerization of Lactide
inferredcites →https://doi.org/10.1021/ja0543346openalex-snapshot
Thiourea-Based Bifunctional Organocatalysis: Supramolecular Recognition for Living Polymerization
inferredcites →https://doi.org/10.1021/ja060662+openalex-snapshot
Triazabicyclodecene: A Simple Bifunctional Organocatalyst for Acyl Transfer and Ring-Opening Polymerization of Cyclic Esters
inferredcites →https://doi.org/10.1021/jp9716997openalex-snapshot
Quantum Calculation of Molecular Energies and Energy Gradients in Solution by a Conductor Solvent Model
inferredcites →https://doi.org/10.1021/ma0619381openalex-snapshot
Guanidine and Amidine Organocatalysts for Ring-Opening Polymerization of Cyclic Esters
inferredcites →https://doi.org/10.1021/ol990623lopenalex-snapshot
Enantioselective Synthesis of α-Amino Nitriles from N -Benzhydryl Imines and HCN with a Chiral Bicyclic Guanidine as Catalyst
inferredcites →https://doi.org/10.1039/b418666dopenalex-snapshot
Second-generation organocatalysts for the highly enantioselective dynamic kinetic resolution of azlactones
inferredcites →https://doi.org/10.1063/1.1677527openalex-snapshot
Self—Consistent Molecular Orbital Methods. XII. Further Extensions of Gaussian—Type Basis Sets for Use in Molecular Orbital Studies of Organic Molecules
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Electron affinities of the first-row atoms revisited. Systematic basis sets and wave functions
inferredcites →https://doi.org/10.1063/1.470645openalex-snapshot
Gaussian basis sets for use in correlated molecular calculations. V. Core-valence basis sets for boron through neon
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Ten Problems in Polymer Reactivity Prediction
inferred← citeshttps://doi.org/10.1021/acs.macromol.5b00040openalex-snapshot
Self-Activation of Poly(methylenelactide) through Neighboring-Group Effects: A Sophisticated Type of Reactive Polymer
inferred← citeshttps://doi.org/10.1021/acs.macromol.5b02137openalex-snapshot
Electronic Activity Tuning of Acyclic Guanidines for Lactide Polymerization
inferred← citeshttps://doi.org/10.1021/acs.macromol.5b02520openalex-snapshot
1,1,3,3-Tetramethylguanidine-Promoted Ring-Opening Polymerization of N-Butyl N-Carboxyanhydride Using Alcohol Initiators
inferred← citeshttps://doi.org/10.1021/acs.macromol.7b01991openalex-snapshot
H-Bonding Organocatalysts for the Living, Solvent-Free Ring-Opening Polymerization of Lactones: Toward an All-Lactones, All-Conditions Approach
inferred← citeshttps://doi.org/10.1021/acs.macromol.7b02293openalex-snapshot
Organocatalytic Synthesis and Evaluation of Polycarbonate Pendant Polymer:β-Cyclodextrin-Based Nucleic Acid Delivery Vectors
inferred← citeshttps://doi.org/10.1021/acs.macromol.7b02493openalex-snapshot
Selective Initiation from Unprotected Aminoalcohols for the N-Heterocyclic Carbene-Organocatalyzed Ring-Opening Polymerization of 2-Methyl-N-tosyl Aziridine: Telechelic and Block Copolymer Synthesis
inferred← citeshttps://doi.org/10.1021/acs.macromol.9b01853openalex-snapshot
Benzoic Acid as an Efficient Organocatalyst for the Statistical Ring-Opening Copolymerization of ε-Caprolactone and L -Lactide: A Computational Investigation
inferred← citeshttps://doi.org/10.1021/acs.oprd.2c00248openalex-snapshot
Unique Superbase TBD (1,5,7-Triazabicyclo[4.4.0]dec-5-ene): From Catalytic Activity and One-Pot Synthesis to Broader Application in Industrial Chemistry
inferred← citeshttps://doi.org/10.1021/acscatal.8b02446openalex-snapshot
Decoupling Catalysis and Chain-Growth Functions of Mono(μ-alkoxo)bis(alkylaluminums) in Epoxide Polymerization: Emergence of the N–Al Adduct Catalyst
inferred← citeshttps://doi.org/10.1021/acsmacrolett.1c00523openalex-snapshot
Degradable Polymer Structures from Carbon Dioxide and Butadiene
inferred← citeshttps://doi.org/10.1021/acsmacrolett.1c00637openalex-snapshot
Strategy for Synthesis of Statistically Sequence-Controlled Uniform PLGA and Effects of Sequence Distribution on Interaction and Drug Release Properties
inferred← citeshttps://doi.org/10.1021/acsmacrolett.3c00716openalex-snapshot
Ring-Opening Polymerization of Cyclic Esters and Carbonates with (Thio)urea/Cyclopropenimine Organocatalytic Systems
inferred← citeshttps://doi.org/10.1021/acsmacrolett.5b00421openalex-snapshot
Cyclopropenimine Superbases: Competitive Initiation Processes in Lactide Polymerization
inferred← citeshttps://doi.org/10.1021/acsmacrolett.9b00418openalex-snapshot
Ionic Organocatalyst with a Urea Anion and Tetra-n-butyl Ammonium Cation for Rapid, Selective, and Versatile Ring-Opening Polymerization of Lactide
inferred← citeshttps://doi.org/10.1021/acsomega.0c03883openalex-snapshot
Homoconjugated Acids as Low Cyclosiloxane-Producing Silanol Polycondensation Catalysts
inferred← citeshttps://doi.org/10.1021/ar400072zopenalex-snapshot
Zwitterionic Ring-Opening Polymerization for the Synthesis of High Molecular Weight Cyclic Polymers
inferred← citeshttps://doi.org/10.1021/bk-2011-1063.ch011openalex-snapshot
Zinc Complexes with Mono- and Polydentate Behaving Guanidine Ligands and Their Application in Lactide Polymerization
inferred← citeshttps://doi.org/10.1021/bk-2012-1105.ch018openalex-snapshot
Novel Biomass-Based Polymers: Synthesis, Characterization, and Application
inferred← citeshttps://doi.org/10.1021/cr100212hopenalex-snapshot
Quantum Mechanical Investigations of Organocatalysis: Mechanisms, Reactivities, and Selectivities
inferred← citeshttps://doi.org/10.1021/ic2010584openalex-snapshot
Synthesis and Characterization of Heterobimetallic Oxo-Bridged Aluminum–Rare Earth Metal Complexes
inferred← citeshttps://doi.org/10.1021/ja307712yopenalex-snapshot
Mechanism of Amination of β-Keto Esters by Azadicarboxylates Catalyzed by an Axially Chiral Guanidine: Acyclic Keto Esters React through an E Enolate
inferred← citeshttps://doi.org/10.1021/ja312313fopenalex-snapshot
Interdigitated Hydrogen Bonds: Electrophile Activation for Covalent Capture and Fluorescence Turn-On Detection of Cyanide
inferred← citeshttps://doi.org/10.1021/ja408641gopenalex-snapshot
Organic Acid-Catalyzed Polyurethane Formation via a Dual-Activated Mechanism: Unexpected Preference of N-Activation over O-Activation of Isocyanates
inferred← citeshttps://doi.org/10.1021/ja409843vopenalex-snapshot
Zwitterionic Polymerization to Generate High Molecular Weight Cyclic Poly(Carbosiloxane)s
inferred← citeshttps://doi.org/10.1021/jacs.0c05610openalex-snapshot
Invoking Side-Chain Functionality for the Mediation of Regioselectivity during Ring-Opening Polymerization of Glucose Carbonates
inferred← citeshttps://doi.org/10.1021/jacs.1c12278openalex-snapshot
Closing the “One Monomer–Two Polymers–One Monomer” Loop via Orthogonal (De)polymerization of a Lactone/Olefin Hybrid
inferred← citeshttps://doi.org/10.1021/jacs.3c03253openalex-snapshot
Living/Controlled Anionic Polymerization of Glycolide in Fluoroalcohols: Toward Sustainable Bioplastics
inferred← citeshttps://doi.org/10.1021/jacs.4c00526openalex-snapshot
Topology-Accelerated and Selective Cascade Depolymerization of Architecturally Complex Polyesters
inferred← citeshttps://doi.org/10.1021/jacs.5b06355openalex-snapshot
A Simple and Facile Approach to Aliphatic N-Substituted Functional Eight-Membered Cyclic Carbonates and Their Organocatalytic Polymerization
inferred← citeshttps://doi.org/10.1021/jacs.6b11864openalex-snapshot
Urea Anions: Simple, Fast, and Selective Catalysts for Ring-Opening Polymerizations
inferred← citeshttps://doi.org/10.1021/jacsau.1c00545openalex-snapshot
Complexities of Regioselective Ring-Opening vs Transcarbonylation-Driven Structural Metamorphosis during Organocatalytic Polymerizations of Five-Membered Cyclic Carbonate Glucose Monomers
inferred← citeshttps://doi.org/10.1021/jo100488gopenalex-snapshot
Theoretical Mechanistic Study of the TBD-Catalyzed Intramolecular Aldol Reaction of Ketoaldehydes
inferred← citeshttps://doi.org/10.1021/jo101346topenalex-snapshot
Ring-Opening Polymerization of ε-Caprolactone Catalyzed by Sulfonic Acids: Computational Evidence for Bifunctional Activation
inferred← citeshttps://doi.org/10.1021/jo102410ropenalex-snapshot
A Model for the Enantioselectivity of Imine Reactions Catalyzed by BINOL−Phosphoric Acid Catalysts
inferred← citeshttps://doi.org/10.1021/jo301158copenalex-snapshot
Origin of Asymmetric Induction in Bicyclic Guanidine-Catalyzed Thio-Michael Reaction: A Bifunctional Mode of Lewis Acid-Brønsted Acid Activation
inferred← citeshttps://doi.org/10.1021/jo902369gopenalex-snapshot
Cyclic Guanidine Organic Catalysts: What Is Magic About Triazabicyclodecene?
inferred← citeshttps://doi.org/10.1021/jp304212yopenalex-snapshot
Mechanisms of Organocatalytic Amidation and Trans-Esterification of Aromatic Esters As a Model for the Depolymerization of Poly(ethylene) Terephthalate
inferred← citeshttps://doi.org/10.1021/ma1001244openalex-snapshot
Alternating Copolymerization of Bicyclic Bis(γ-butyrolactone) and Epoxide through Zwitterion Process by Phosphines
inferred← citeshttps://doi.org/10.1021/ma100798uopenalex-snapshot
Controlled/Living Ring-Opening Polymerization of δ-Valerolactone Using Triflylimide as an Efficient Cationic Organocatalyst
inferred← citeshttps://doi.org/10.1021/ma101461yopenalex-snapshot
Ring-Opening Polymerization of Trimethylene Carbonate Catalyzed by Methanesulfonic Acid: Activated Monomer versus Active Chain End Mechanisms
inferred← citeshttps://doi.org/10.1021/ma101688dopenalex-snapshot
Ring-Opening Polymerization of l -Lactide Catalyzed by an Organocatalytic System Combining Acidic and Basic Sites
inferred← citeshttps://doi.org/10.1021/ma200021mopenalex-snapshot
A Versatile Monomer for Preparing Well-Defined Functional Polycarbonates and Poly(ester−carbonates)
inferred← citeshttps://doi.org/10.1021/ma2007199openalex-snapshot
Cinchona Alkaloids as Stereoselective Organocatalysts for the Partial Kinetic Resolution Polymerization of rac-Lactide
inferred← citeshttps://doi.org/10.1021/ma201164nopenalex-snapshot
Ring-Opening Polymerization of γ-(4-Vinylbenzyl)- l -glutamate N-Carboxyanhydride for the Synthesis of Functional Polypeptides
inferred← citeshttps://doi.org/10.1021/ma2026258openalex-snapshot
Cyclic Guanidines as Efficient Organocatalysts for the Synthesis of Polyurethanes
inferred← citeshttps://doi.org/10.1021/ma3001675openalex-snapshot
ω-Pentandecalactone Polymerization and ω-Pentadecalactone/ε-Caprolactone Copolymerization Reactions Using Organic Catalysts
inferred← citeshttps://doi.org/10.1021/ma300387jopenalex-snapshot
Renewable Biobased Polymeric Materials: Facile Synthesis of Itaconic Anhydride-Based Copolymers with Poly( l -lactic acid) Grafts
inferred← citeshttps://doi.org/10.1021/ma400709jopenalex-snapshot
Thermally Stabilized Poly(lactide)s Stereocomplex with Bio-Based Aromatic Groups at Both Initiating and Terminating Chain Ends
inferred← citeshttps://doi.org/10.1021/ma400894topenalex-snapshot
Organocatalytic Copolymerization of a Cyclic Carbonate Bearing Protected 2,2-bis(hydroxymethyl) Groups and d , l -lactide. Effect of Hydrophobic Block Chemistry on Nanoparticle Properties
inferred← citeshttps://doi.org/10.1021/ma5012304openalex-snapshot
Ring-Closing Depolymerization: A Powerful Tool for Synthesizing the Allyloxy-Functionalized Six-Membered Aliphatic Carbonate Monomer 2-Allyloxymethyl-2-ethyltrimethylene Carbonate
inferred← citeshttps://doi.org/10.1021/ma901776xopenalex-snapshot
Acyclic Guanidines as Organic Catalysts for Living Polymerization of Lactide
inferred← citeshttps://doi.org/10.1021/ma9025948openalex-snapshot
Organocatalysis: Opportunities and Challenges for Polymer Synthesis
inferred← citeshttps://doi.org/10.1021/mz2001675openalex-snapshot
Cyclic Brush Polymers by Combining Ring-Expansion Metathesis Polymerization and the “Grafting from” Technique
inferred← citeshttps://doi.org/10.1021/mz300276uopenalex-snapshot
Amidine-Mediated Zwitterionic Polymerization of Lactide
inferred← citeshttps://doi.org/10.1021/mz3006523openalex-snapshot
Polymerizing Base Sensitive Cyclic Carbonates Using Acid Catalysis
inferred← citeshttps://doi.org/10.1038/nchem.2574openalex-snapshot
Fast and selective ring-opening polymerizations by alkoxides and thioureas
inferred← citeshttps://doi.org/10.1038/pj.2013.62openalex-snapshot
Green polymer chemistry: lipase-catalyzed synthesis of bio-based reactive polyesters employing itaconic anhydride as a renewable monomer
inferred← citeshttps://doi.org/10.1038/pj.2016.80openalex-snapshot
Biodegradable functional biomaterials exploiting substituted trimethylene carbonates and organocatalytic transesterification
inferred← citeshttps://doi.org/10.1038/pj.2017.49openalex-snapshot
Recyclable and scalable organocatalytic transesterification of polysaccharides in a mixed solvent of 1-ethyl-3-methylimidazolium acetate and dimethyl sulfoxide
inferred← citeshttps://doi.org/10.1038/s41467-020-18460-2openalex-snapshot
Ring-opening polymerization-induced crystallization-driven self-assembly of poly-L-lactide-block-polyethylene glycol block copolymers (ROPI-CDSA)
inferred← citeshttps://doi.org/10.1038/s41557-022-00969-2openalex-snapshot
Tunable and recyclable polyesters from CO2 and butadiene
inferred← citeshttps://doi.org/10.1038/s41598-017-00464-6openalex-snapshot
Synthesis of Thermoplastic Xylan-Lactide Copolymer with Amidine-Mediated Organocatalyst in Ionic Liquid
inferred← citeshttps://doi.org/10.1038/s41598-018-22171-6openalex-snapshot
Organocatalyzed chemoselective ring-opening polymerizations
inferred← citeshttps://doi.org/10.1039/9781788015738-00087openalex-snapshot
Bifunctional and Supramolecular Organocatalysts for Polymerization
inferred← citeshttps://doi.org/10.1039/9781788015738-00121openalex-snapshot
Base Catalysts for Organopolymerization
inferred← citeshttps://doi.org/10.1039/9781788015738-00367openalex-snapshot
Ring-opening Polymerization of N-carboxyanhydrides Using Organic Initiators or Catalysts
inferred← citeshttps://doi.org/10.1039/9781788015738-00607openalex-snapshot
Organocatalysis for Depolymerisation
inferred← citeshttps://doi.org/10.1039/9781788016490-00415openalex-snapshot
Influence of Noncovalent Interactions in Catalytic Ring-opening Polymerization Processes
inferred← citeshttps://doi.org/10.1039/b507874copenalex-snapshot
The chemistry and biology of organic guanidine derivatives
inferred← citeshttps://doi.org/10.1039/b813059kopenalex-snapshot
Controlled ring-opening polymerisation of cyclic esters: polymer blocks in self-assembled nanostructures
inferred← citeshttps://doi.org/10.1039/b820162popenalex-snapshot
Synthesis of polycaprolactone: a review
inferred← citeshttps://doi.org/10.1039/b901940eopenalex-snapshot
Bicyclic-guanidines, -guanidinates and -guanidinium salts: wide ranging applications from a simple family of molecules
inferred← citeshttps://doi.org/10.1039/b911577copenalex-snapshot
TBD-organocatalysed synthesis of pyrazolines
inferred← citeshttps://doi.org/10.1039/b923622hopenalex-snapshot
Recoverable and recyclable magnetic nanoparticle supported aluminium isopropoxide for ring-opening polymerization of ε-caprolactone
inferred← citeshttps://doi.org/10.1039/c0cc03691aopenalex-snapshot
Mechanistic considerations of guanidine-catalyzed reactions
inferred← citeshttps://doi.org/10.1039/c0cc03987jopenalex-snapshot
Catalytic insights into acid/base conjugates: highly selective bifunctional catalysts for the ring-opening polymerization of lactide
inferred← citeshttps://doi.org/10.1039/c0np00016gopenalex-snapshot
The chemistry and biology of organic guanidine derivatives
inferred← citeshttps://doi.org/10.1039/c0ob01233eopenalex-snapshot
Computational investigation on the mechanism and stereochemistry of guanidine-catalyzed enantioselective isomerization of 3-alkynoates to allenoates
inferred← citeshttps://doi.org/10.1039/c1cc15032dopenalex-snapshot
Introduction of abnormal N-heterocyclic carbene as an efficient organocatalyst: ring opening polymerization of cyclic esters
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