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Rollover Cyclometalation Pathway in Rhodium Catalysis: Dramatic NHC Effects in the C–H Bond Functionalization

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Outgoing claims: the papers this work cites, builds on, or argues with.

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N-Heterocyclic Carbenes: A New Concept in Organometallic Catalysis

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Selective CH Bond Functionalization of 2‐(2‐Thienyl)pyridine by a Rhodium N‐Heterocyclic Carbene Catalyst

inferred← citeshttps://doi.org/10.1002/cctc.201801787openalex-snapshot

Manganese‐Catalyzed C−H Olefination Reactions

inferred← citeshttps://doi.org/10.1002/cctc.202500526openalex-snapshot

Palladium‐Catalyzed Allylation of (Hetero)Aryl Fluorosulfates

inferred← citeshttps://doi.org/10.1002/chem.201300829openalex-snapshot

Controllable Mono‐/Dialkenylation of Benzyl Thioethers through Rh‐Catalyzed Aryl CH Activation

inferred← citeshttps://doi.org/10.1002/chem.201304257openalex-snapshot

Rollover‐Assisted C(sp2)C(sp3) Bond Formation

inferred← citeshttps://doi.org/10.1002/chem.201404859openalex-snapshot

Hydroarylations of Heterobicyclic Alkenes through Rhodium‐Catalyzed Directed CH Functionalizations of S‐Aryl Sulfoximines

inferred← citeshttps://doi.org/10.1002/chem.201406463openalex-snapshot

Facile Synthesis and Versatile Reactivity of an Unusual Cyclometalated Rhodium(I) Pincer Complex

inferred← citeshttps://doi.org/10.1002/chem.201501962openalex-snapshot

Nickel‐Catalyzed Insertion of Alkynes and Electron‐Deficient Olefins into Unactivated sp3 CH Bonds

inferred← citeshttps://doi.org/10.1002/chem.201700643openalex-snapshot

Electronic Control on Linear versus Branched Alkylation of 2‐/3‐Aroylbenzofurans with Acrylates: Combined DFT and Synthetic Studies

inferred← citeshttps://doi.org/10.1002/chem.201703687openalex-snapshot

Switching of Reaction Pathway from C−C Rollover to C−N Ring‐Extension Annulation

inferred← citeshttps://doi.org/10.1002/chem.202302788openalex-snapshot

Pd‐Catalyzed Vicinal Intermolecular Annulations of Iodoarenes, Indoles, and Carbazoles with Enynes

inferred← citeshttps://doi.org/10.1002/chem.202303245openalex-snapshot

Conjugated Olefin Enabled Rollover Cyclometallation of Distant C‐H Bonds: Regioselective Annulation of o‐Alkenyl Phenols with Alkynes

inferred← citeshttps://doi.org/10.1002/cjoc.70091openalex-snapshot

Rhodium(I)‐Catalyzed C–H Carboxylation of Benzoic Acids and Benzamides with CO2 †

inferred← citeshttps://doi.org/10.1002/ejoc.201300004openalex-snapshot

Aryl Bromides and Aryl Chlorides for the Direct Arylation of Benzylic Amines Mediated by Ruthenium(II)

inferred← citeshttps://doi.org/10.1002/ejoc.201402852openalex-snapshot

Copper‐Catalyzed Asymmetric Addition to Isatins to give 3‐Hydroxy‐2‐oxindoles by C–H Activation

inferred← citeshttps://doi.org/10.1002/ejoc.201800485openalex-snapshot

Chiral Unsymmetrically Substituted Bipyridine N,N′‐Dioxides as Catalysts for the Allylation of Aldehydes

inferred← citeshttps://doi.org/10.1002/ejoc.202000565openalex-snapshot

Cobalt‐Catalyzed Direct C(sp2)–H Alkylation with Unactivated Alkenes

inferred← citeshttps://doi.org/10.1002/ejoc.202100048openalex-snapshot

Recent Advances in Retained and Dehydrogenative Dual Functionalization Chemistry

inferred← citeshttps://doi.org/10.1002/ejoc.202100806openalex-snapshot

Synthesis of 2,2’‐Bipyridines through Catalytic C−C Bond Formations from C−H Bonds

inferred← citeshttps://doi.org/10.1002/ejoc.202301023openalex-snapshot

Efficient Synthesis of Highly Fused Quinazolinone Derivatives via Multiple C−C Bond Formations and 1,4‐Palladium Migration

inferred← citeshttps://doi.org/10.1002/ejoc.202500590openalex-snapshot

General and Anti‐Markovnikov Selective Ni‐Catalyzed Alkylation of Arenes and Heteroarenes with Non‐Activated Olefins

inferred← citeshttps://doi.org/10.1002/hc.21158openalex-snapshot

Synthesis of Multicyclic Heterocycles Initiated by C–H Bond Activation Along with “Rollover” Using a Rh(III) Catalyst

inferred← citeshttps://doi.org/10.1002/slct.202205028openalex-snapshot

Rhodium‐Catalyzed Annulations of 6‐Arylimidazothiazoles with Alkynes through Rollover Dual C−H Bond Activation Strategy

inferred← citeshttps://doi.org/10.1002/tcr.201500250openalex-snapshot

Transition-Metal-Catalyzed Direct Addition of Aryl C-H Bonds to Unsaturated Electrophiles

inferred← citeshttps://doi.org/10.1007/7081_2017_3openalex-snapshot

Pyridine N-Oxides and Derivatives Thereof in Organocatalysis

inferred← citeshttps://doi.org/10.1007/978-4-431-54604-7_6openalex-snapshot

Reasons Why Organometallic Intramolecular-Coordination Five-Membered Ring Compounds Are Extremely Easily Synthesized Through Cyclometalation Reactions

inferred← citeshttps://doi.org/10.1007/978-4-431-54604-7_7openalex-snapshot

Applications of Cyclometalation Reactions and Five-Membered Ring Products for Synthetic Purposes

inferred← citeshttps://doi.org/10.1007/978-981-16-0432-4_3openalex-snapshot

Theoretical Study of Rh-Catalyzed C–C Bond Formation Through C–H Activation

inferred← citeshttps://doi.org/10.1007/s00214-017-2116-9openalex-snapshot

Structural effects in octahedral carbonyl complexes: an atoms-in-molecules study

inferred← citeshttps://doi.org/10.1007/s12649-016-9612-3openalex-snapshot

Screening of Ionic Liquids for Pretreatment of Taiwan Grass in Q-Tube Minireactors for Improving Bioethanol Production

inferred← citeshttps://doi.org/10.1016/b978-0-08-102688-5.00067-2openalex-snapshot

Bipyridine Ligands

inferred← citeshttps://doi.org/10.1016/b978-0-12-820206-7.00085-8openalex-snapshot

N-Heterocyclic Carbene (NHC) Complexes of Rhodium and Iridium

inferred← citeshttps://doi.org/10.1016/j.ccr.2020.213683openalex-snapshot

Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions

inferred← citeshttps://doi.org/10.1016/j.chemphys.2014.03.005openalex-snapshot

Excited-state dynamics of a ruthenium(II) catalyst studied by transient photofragmentation in gas phase and transient absorption in solution

inferred← citeshttps://doi.org/10.1016/j.jorganchem.2015.01.015openalex-snapshot

A kinetic approach to carbon–iodide bond activation by rollover cycloplatinated(II) complexes containing monodentate phosphine ligands

inferred← citeshttps://doi.org/10.1016/j.jorganchem.2016.06.023openalex-snapshot

Platinum(II), palladium(II) and gold(III) adducts and cyclometalated derivatives of 6-methoxy-2,2′-bipyridine: A comparative study

inferred← citeshttps://doi.org/10.1016/j.jorganchem.2023.122853openalex-snapshot

Diaryl(fluorinated)-mercury species as potential precursors of triaryl(fluorinated)-gallium to be used in the synthesis of cyclometallated Ga compounds and unexpected formation of aryl-Ga clusters

inferred← citeshttps://doi.org/10.1021/acs.chemrev.5b00514openalex-snapshot

Alkenylation of Arenes and Heteroarenes with Alkynes

inferred← citeshttps://doi.org/10.1021/acs.chemrev.6b00574openalex-snapshot

Transition-Metal-Catalyzed C–H Alkylation Using Alkenes

inferred← citeshttps://doi.org/10.1021/acs.chemrev.9b00634openalex-snapshot

N-Heterocyclic Carbene Complexes in C–H Activation Reactions

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.7b02678openalex-snapshot

Which is the Stronger Nucleophile, Platinum or Nitrogen in Rollover Cycloplatinated(II) Complexes?

inferred← citeshttps://doi.org/10.1021/acs.joc.0c02467openalex-snapshot

Rhodium(III)-Catalyzed Dehydrogenative Annulation and Spirocyclization of 2-Arylindoles and 2-(1H-Pyrazol-1-yl)-1H-indoles with Maleimides: A Facile Access to Isogranulatimide Alkaloid Analogues

inferred← citeshttps://doi.org/10.1021/acs.joc.2c00026openalex-snapshot

Cobalt-Catalyzed Regioselective para-Amination of Azobenzenes via Nucleophilic Aromatic Substitution of Hydrogen

inferred← citeshttps://doi.org/10.1021/acs.joc.4c02939openalex-snapshot

Nickel-Catalyzed Linear-Selective C–H Alkylation of N-Heteroarenes with Unactivated α-Olefins

inferred← citeshttps://doi.org/10.1021/acs.joc.5b00059openalex-snapshot

Rh(III)-Catalyzed Oxidative Annulation of 2-Phenylimidazo[1,2-a]pyridines with Alkynes: Mono versus Double C–H Activation

inferred← citeshttps://doi.org/10.1021/acs.joc.7b00008openalex-snapshot

Ruthenium-Catalyzed Oxidative Annulation and Hydroarylation of Chromene-3-carboxamides with Alkynes via Double C–H Functionalization

inferred← citeshttps://doi.org/10.1021/acs.joc.7b00444openalex-snapshot

Palladium-Catalyzed Directed Halogenation of Bipyridine N-Oxides

inferred← citeshttps://doi.org/10.1021/acs.joc.9b01013openalex-snapshot

Ruthenium(II)-Catalyzed C–H Acylmethylation between (Hetero)arenes and α-Cl Ketones/Sulfoxonium Ylides

inferred← citeshttps://doi.org/10.1021/acs.organomet.5b00317openalex-snapshot

Mechanistic Understanding of the Aryl-Dependent Ring Formations in Rh(III)-Catalyzed C–H Activation/Cycloaddition of Benzamides and Methylenecyclopropanes by DFT Calculations

inferred← citeshttps://doi.org/10.1021/acs.organomet.5c00184openalex-snapshot

N-Heterocyclic Carbene Ligand Effects on Pd-Catalyzed C–H Activation: A Computational Analysis

inferred← citeshttps://doi.org/10.1021/acs.organomet.6b00933openalex-snapshot

Synthesis, Structures, and Reactivity of Cyclometalated Complexes Formed by Insertion of Alkynes into M–C (M = Ir and Rh) Bonds

inferred← citeshttps://doi.org/10.1021/acs.organomet.6c00275openalex-snapshot

Chiral Rh Diene NHC Complexes and Their Application in Rh-Catalyzed Cycloisomerization of Enynes

inferred← citeshttps://doi.org/10.1021/acs.orglett.0c00975openalex-snapshot

Oxidative C–H/C–H Annulation of Imidazopyridines and Indazoles through Rhodium-Catalyzed Vinylene Transfer

inferred← citeshttps://doi.org/10.1021/acs.orglett.0c01260openalex-snapshot

The C–H Activation/Bidirecting Group Strategy for Selective Direct Synthesis of Diverse 1,1′-Biisoquinolines

inferred← citeshttps://doi.org/10.1021/acs.orglett.1c01735openalex-snapshot

Bipyridine-Type Bidentate Auxiliary-Enabled Copper-Mediated C–H/C–H Biaryl Coupling of Phenols and 1,3-Azoles

inferred← citeshttps://doi.org/10.1021/acs.orglett.5b00471openalex-snapshot

Nickel-Catalyzed Direct Thioetherification of β-C(sp3)–H Bonds of Aliphatic Amides

inferred← citeshttps://doi.org/10.1021/acs.orglett.5b01192openalex-snapshot

Copper-Mediated Aryloxylation and Vinyloxylation of β-C(sp3)–H Bond of Propionamides with Organosilanes

inferred← citeshttps://doi.org/10.1021/acs.orglett.5b01452openalex-snapshot

Synthesis of Indolo[1,2-a][1,8]naphthyridines by Rhodium(III)-Catalyzed Dehydrogenative Coupling via Rollover Cyclometalation

inferred← citeshttps://doi.org/10.1021/acs.orglett.5b03273openalex-snapshot

Rh(III)-Catalyzed C–H Cyclization of Arylnitrones with Diazo Compounds: Access to N-Hydroxyindolines

inferred← citeshttps://doi.org/10.1021/acs.orglett.5c04772openalex-snapshot

Divergent C–H Alkylation and Allylation of Indoles with Unactivated Alkene via Mechanochemical Rh(III) Catalysis

inferred← citeshttps://doi.org/10.1021/acs.orglett.7b01159openalex-snapshot

Rhodium(III)-Catalyzed Annulation of Pyridinones with Alkynes via Double C–H Activation: A Route to Functionalized Quinolizinones

inferred← citeshttps://doi.org/10.1021/acs.orglett.7b02950openalex-snapshot

Hydroxoiridium-Catalyzed Hydroarylation of Alkynes and Bicycloalkenes with N-Sulfonylbenzamides

inferred← citeshttps://doi.org/10.1021/acs.orglett.8b01434openalex-snapshot

Rhodium(III)-Catalyzed Oxidative Annulation of 2,2′-Bipyridine N-Oxides with Alkynes via Dual C–H Bond Activation

inferred← citeshttps://doi.org/10.1021/acs.orglett.8b01632openalex-snapshot

Palladium-Catalyzed Site-Selective C–H Arylation of 2,2′-Bipyridine-6-carboxamides via a Rollover Cyclometalation Pathway

inferred← citeshttps://doi.org/10.1021/acs.orglett.9b02253openalex-snapshot

Rhodium(III)-Catalyzed Regioselective C3–H Acylmethylation of [2,2′-Bipyridine]-6-carboxamides with Sulfoxonium Ylides

inferred← citeshttps://doi.org/10.1021/acscatal.0c05580openalex-snapshot

Unactivated Alkyl Halides in Transition-Metal-Catalyzed C–H Bond Alkylation

inferred← citeshttps://doi.org/10.1021/acscatal.1c00602openalex-snapshot

Metal–Ligand Cooperative Proton Transfer as an Efficient Trigger for Rhodium-NHC-Pyridonato Catalyzed gem-Specific Alkyne Dimerization

inferred← citeshttps://doi.org/10.1021/acscatal.3c01098openalex-snapshot

Bifunctional NHC-Promoted C2-Alkylation of Pyridine via Ni–Al Bimetallic-Catalyzed Hydroarylation of Unactivated Alkenes

inferred← citeshttps://doi.org/10.1021/acscatal.5b01143openalex-snapshot

Transition-Metal-Catalyzed Site-Selective C–H Functionalization of Quinolines beyond C2 Selectivity

inferred← citeshttps://doi.org/10.1021/acscatal.5b02540openalex-snapshot

Switching of “Rollover Pathway” in Rhodium(III)-Catalyzed C–H Activation of Chelating Molecules

inferred← citeshttps://doi.org/10.1021/acscatal.6b00612openalex-snapshot

Cp*Co(III)-Catalyzed C(sp3)–H Bond Activation: A Highly Stereoselective and Regioselective Alkenylation of 8-Methylquinoline with Alkynes

inferred← citeshttps://doi.org/10.1021/acscatal.6b00711openalex-snapshot

Ketone-Assisted Ruthenium(II)-Catalyzed C–H Imidation: Access to Primary Aminoketones by Weak Coordination

inferred← citeshttps://doi.org/10.1021/acscatal.9b01233openalex-snapshot

Hydride–Rhodium(III)-N-Heterocyclic Carbene Catalyst for Tandem Alkylation/Alkenylation via C–H Activation

inferred← citeshttps://doi.org/10.1021/acsomega.7b01846openalex-snapshot

To “Rollover” or Not? Stereoelectronically Guided C–H Functionalization Pathways from Rhodium–Abnormal NHC Intermediates

inferred← citeshttps://doi.org/10.1021/ic400908fopenalex-snapshot

Rollover Cyclometalation with 2-(2′-Pyridyl)quinoline

inferred← citeshttps://doi.org/10.1021/ja3104389openalex-snapshot

Rh(III)-Catalyzed Regioselective Synthesis of Pyridines from Alkenes and α,β-Unsaturated Oxime Esters

inferred← citeshttps://doi.org/10.1021/ja4033555openalex-snapshot

RhIII/CuII-Cocatalyzed Synthesis of 1H-Indazoles through C–H Amidation and N–N Bond Formation

inferred← citeshttps://doi.org/10.1021/jacs.5b01065openalex-snapshot

Selective Cyclization of Arylnitrones to Indolines under External Oxidant-Free Conditions: Dual Role of Rh(III) Catalyst in the C–H Activation and Oxygen Atom Transfer

inferred← citeshttps://doi.org/10.1021/jacs.5b07424openalex-snapshot

Cobalt-Catalyzed Cyclization of Aliphatic Amides and Terminal Alkynes with Silver-Cocatalyst

inferred← citeshttps://doi.org/10.1021/jacs.7b08158openalex-snapshot

Photoinduced Nickel-Catalyzed Chemo- and Regioselective Hydroalkylation of Internal Alkynes with Ether and Amide α-Hetero C(sp3)–H Bonds

inferred← citeshttps://doi.org/10.1021/jo501460hopenalex-snapshot

Ruthenium(II)-Catalyzed Direct Addition of Indole/Pyrrole C2–H Bonds to Alkynes

inferred← citeshttps://doi.org/10.1021/ol401209fopenalex-snapshot

Rh[III]-Catalyzed C–H Amidation Using Aroyloxycarbamates To Give N-Boc Protected Arylamines

inferred← citeshttps://doi.org/10.1021/ol401407vopenalex-snapshot

Synthesis of Phosphaisocoumarins through Rhodium-Catalyzed Cyclization Using Alkynes and Arylphosphonic Acid Monoesters

inferred← citeshttps://doi.org/10.1021/ol401540kopenalex-snapshot

Rhodium(III)-Catalyzed Oxidative Olefination of Pyridines and Quinolines: Multigram-Scale Synthesis of Naphthyridinones

inferred← citeshttps://doi.org/10.1021/ol402201copenalex-snapshot

Rhodium Catalyzed Cyanation of Chelation Assisted C–H Bonds

inferred← citeshttps://doi.org/10.1021/ol402921wopenalex-snapshot

Palladium(II)-Catalyzed ortho-Olefination of Arenes Applying Sulfoxides as Remote Directing Groups

inferred← citeshttps://doi.org/10.1021/ol403311bopenalex-snapshot

Rh(III)-Catalyzed Amide-Directed Cross-Dehydrogenative Heteroarylation of Pyridines

inferred← citeshttps://doi.org/10.1021/ol500140eopenalex-snapshot

Mild Synthesis of Chalcones via Rhodium(III)-Catalyzed C–C Coupling of Arenes and Cyclopropenones

inferred← citeshttps://doi.org/10.1021/ol500579nopenalex-snapshot

Chelation-Assisted Hydroesterification of Alkenes: New Ruthenium Catalyst Systems and Ligand Effects

inferred← citeshttps://doi.org/10.1021/om300824dopenalex-snapshot

Mesoionic Complexes of Platinum(II) Derived from “Rollover” Cyclometalation: A Delicate Balance between Pt–C(sp3) and Pt–C(sp2) Bond Cleavage as a Result of Different Reaction Conditions

inferred← citeshttps://doi.org/10.1021/om400300nopenalex-snapshot

Oxidative Addition of MeI to a Rollover Complex of Platinum(II): Isolation of the Kinetic Product

inferred← citeshttps://doi.org/10.1021/om500080zopenalex-snapshot

Ruthenium-Catalyzed Direct C–H Amidation of Arenes: A Mechanistic Study

inferred← citeshttps://doi.org/10.1021/om500681uopenalex-snapshot

Electronic and Steric Effects in Rollover C–H Bond Activation

inferred← citeshttps://doi.org/10.1038/s41467-019-11420-5openalex-snapshot

Rhodium-catalysed direct hydroarylation of alkenes and alkynes with phosphines through phosphorous-assisted C−H activation

inferred← citeshttps://doi.org/10.1038/s42004-020-0287-0openalex-snapshot

Iodide-enhanced palladium catalysis via formation of iodide-bridged binuclear palladium complex

inferred← citeshttps://doi.org/10.1039/c3sc50348hopenalex-snapshot

Pd-catalyzed oxidative C–H/C–H cross-coupling of pyridines with heteroarenes

inferred← citeshttps://doi.org/10.1039/c4cc02499kopenalex-snapshot

Highly selective directed arylation reactions via back-to-back dehydrogenative C–H borylation/arylation reactions

inferred← citeshttps://doi.org/10.1039/c4cc03602fopenalex-snapshot

AgSbF6-controlled diastereodivergence in alkyne hydroarylation: facile access to Z- and E-alkenyl arenes

inferred← citeshttps://doi.org/10.1039/c4cc10144hopenalex-snapshot

Regioselective oxidative Pd-catalysed coupling of alkylboronic acids with pyridin-2-yl-substituted heterocycles

inferred← citeshttps://doi.org/10.1039/c4dt02080dopenalex-snapshot

Assembly of symmetrical and unsymmetrical platinum( ii ) rollover complexes with bidentate phosphine ligands

inferred← citeshttps://doi.org/10.1039/c4ob00612gopenalex-snapshot

Rh( iii )-catalyzed regioselective hydroarylation of alkynes via directed C–H functionalization of pyridines

inferred← citeshttps://doi.org/10.1039/c4qo00068dopenalex-snapshot

Recent advances in directed C–H functionalizations using monodentate nitrogen-based directing groups

inferred← citeshttps://doi.org/10.1039/c5cc09960aopenalex-snapshot

Rhodium-catalyzed selective C–H functionalization of NNN tridentate chelating compounds via a rollover pathway

inferred← citeshttps://doi.org/10.1039/c5cp04982bopenalex-snapshot

Towards the first theoretical scale of the trans effect in octahedral complexes

inferred← citeshttps://doi.org/10.1039/c5cy01505gopenalex-snapshot

Reversible cyclometalation at Rh I as a motif for metal–ligand bifunctional bond activation and base-free formic acid dehydrogenation

inferred← citeshttps://doi.org/10.1039/c5dt02483hopenalex-snapshot

Chiral cyclometalation of 6-(1-phenylbenzyl)-2,2′-bipyridine

inferred← citeshttps://doi.org/10.1039/c5sc01885dopenalex-snapshot

Rh I /Rh III catalyst-controlled divergent aryl/heteroaryl C–H bond functionalization of picolinamides with alkynes

inferred← citeshttps://doi.org/10.1039/c5sc03110aopenalex-snapshot

Rhodium-catalyzed regioselective addition of the ortho C–H bond in aromatic amides to the C–C double bond in α,β-unsaturated γ-lactones and dihydrofurans

inferred← citeshttps://doi.org/10.1039/c6ob00209aopenalex-snapshot

Rhodium-catalyzed C–C coupling reactions via double C–H activation

inferred← citeshttps://doi.org/10.1039/c6ra16627jopenalex-snapshot

Efficient hydroarylation and hydroalkenylation of vinylarenes by Brønsted acid catalysis

inferred← citeshttps://doi.org/10.1039/c7cc02166fopenalex-snapshot

Catalytic dehydrogenative dual functionalization of ethers: dealkylation–oxidation–bromination accompanied by C–O bond cleavage via aerobic oxidation of bromide

inferred← citeshttps://doi.org/10.1039/c7nj01079fopenalex-snapshot

Gas-phase reactivity of Cp* group IX metal complexes bearing aromatic N,N′-chelating ligands

inferred← citeshttps://doi.org/10.1039/c8cc03147aopenalex-snapshot

Weakly-coordinating N -oxide and carbonyl groups for metal-catalyzed C–H activation: the case of A-ring functionalization

inferred← citeshttps://doi.org/10.1039/c8qo00557eopenalex-snapshot

Rh-Catalyzed regioselective C–H activation and C–C bond formation: synthesis and photophysical studies of indazolo[2,3- a ]quinolines

inferred← citeshttps://doi.org/10.1039/c8ra03799jopenalex-snapshot

C–H activation-annulation on the N-heterocyclic carbene platform

inferred← citeshttps://doi.org/10.1039/c9cc02199jopenalex-snapshot

PdCl 2 (CH 3 CN) 2 -catalyzed regioselective C–H olefinations of 2-amino biaryls with vinylsilanes as unactivated alkenes

inferred← citeshttps://doi.org/10.1039/c9cc02710fopenalex-snapshot

Orchestrated catalytic double rollover annulation: rapid access to N-enriched cationic and neutral PAHs

inferred← citeshttps://doi.org/10.1039/c9ob01531kopenalex-snapshot

Rhodium( iii )-catalyzed unreactive C(sp 3 )–H alkenylation of N -alkyl-1 H -pyrazoles with alkynes

inferred← citeshttps://doi.org/10.1039/d0cc01077dopenalex-snapshot

A novel approach for rhodium( iii )-catalyzed C–H functionalization of 2,2′-bipyridine derivatives with alkynes: a significant substituent effect

inferred← citeshttps://doi.org/10.1039/d0qo00248hopenalex-snapshot

Rh( iii )-Catalyzed switchable C–H functionalization of 2-(1 H -pyrazol-1-yl)pyridine with internal alkynes

inferred← citeshttps://doi.org/10.1039/d0qo01325kopenalex-snapshot

Rh( iii )-Catalyzed switchable C–H monoalkenylation and dialkenylation of 2-(1 H -pyrazol-1-yl)pyridine with alkenes via rollover cyclometalation

inferred← citeshttps://doi.org/10.1039/d1cc05590aopenalex-snapshot

Cationic π-extended heteroaromatics via a catalytic C–H activation annulative alkyne-insertion sequence

inferred← citeshttps://doi.org/10.1039/d1cs00923kopenalex-snapshot

Transition-metal-catalyzed C–H bond alkylation using olefins: recent advances and mechanistic aspects

inferred← citeshttps://doi.org/10.1039/d1ob00590aopenalex-snapshot

Rhodium( iii )-catalyzed switchable C–H acylmethylation and annulation of 2,2′-bipyridine derivatives with sulfoxonium ylides

inferred← citeshttps://doi.org/10.1039/d1qo01186copenalex-snapshot

Rhodium( iii )-catalyzed annulation of 3-arylquinazolinones with alkynes via double C–H activation: an efficient route for quinolino[2,1- b ]quinazolinones

inferred← citeshttps://doi.org/10.1039/d3cp02445hopenalex-snapshot

C–H functionalization of quinoline N-oxides catalyzed by Pd( ii ) complexes: a computational study

inferred← citeshttps://doi.org/10.1039/d3qo01396kopenalex-snapshot

Directing group-assisted selective C–H activation of six-membered N-heterocycles and benzo-fused N-heterocycles

inferred← citeshttps://doi.org/10.1039/d4ob01689kopenalex-snapshot

Pd-catalyzed ortho -/ meta -C–H-annulation of biphenyl amines with enynes through non-rollover cyclometallation

inferred← citeshttps://doi.org/10.1039/d4qo00726copenalex-snapshot

Stereo-selective synthesis of complex dienes and eneynes by sequential hydroarylation and olefinic C–H functionalization

inferred← citeshttps://doi.org/10.1039/d4sc06005aopenalex-snapshot

Visible light-induced ruthenium( ii )-catalyzed hydroarylation of unactivated olefins

inferred← citeshttps://doi.org/10.1039/d5cc00318kopenalex-snapshot

Ru( ii )-catalyzed oxidative (4+3) C–H/C–H annulation of 2-aryl-4 H -pyrido[1,2- a ]pyrimidin-4-ones with allyl alcohol

inferred← citeshttps://doi.org/10.1055/a-1790-0869openalex-snapshot

Rhodium(I)-Catalyzed Regioselective C–H Alkenylation of 2,2′-Bipyridine Derivatives with Alkynes

inferred← citeshttps://doi.org/10.1055/s-0036-1591765openalex-snapshot

Ruthenium-Catalyzed Ortho C(sp2)–H Amidation of Benzaldehydes with Organic Azides

inferred← citeshttps://doi.org/10.1055/sos-sd-217-00139openalex-snapshot

1.2 C—C Bond Formation by Hetarene C—H Activation

inferred← citeshttps://doi.org/10.1055/sos-sd-223-00229openalex-snapshot

1.4.8 Hydroarylation

inferred← citeshttps://doi.org/10.1126/science.1254465openalex-snapshot

Regioselective ketone α-alkylation with simple olefins via dual activation

inferred← citeshttps://doi.org/10.3390/app10196665openalex-snapshot

Pt(II) Derivatives with Rollover-Coordinated 6-substituted 2,2′-bipyridines: Ligands with Multiple Personalities

inferred← citeshttps://doi.org/10.3390/molecules25020330openalex-snapshot

Heteroaromatic N-Oxides in Asymmetric Catalysis: A Review

inferred← citeshttps://doi.org/10.3390/molecules26020328openalex-snapshot

Rollover Cyclometalation as a Valuable Tool for Regioselective C–H Bond Activation and Functionalization

inferred← citeshttps://doi.org/10.3390/molecules27217249openalex-snapshot

Classical vs. Non-Classical Cyclometalated Pt(II) Complexes

inferred← citeshttps://doi.org/10.3390/molecules29030707openalex-snapshot

Regioselective C(sp2)-C(sp3) Coupling Mediated by Classical and Rollover Cyclometalation

inferred← citeshttps://doi.org/10.3762/bjoc.19.62openalex-snapshot

Pyridine C(sp 2 )–H bond functionalization under transition-metal and rare earth metal catalysis

inferred← citeshttps://doi.org/10.6023/cjoc202206005openalex-snapshot

Amide Functionalized Pyridine/Pyrimidine Chelating N-Heterocyclic Carbene Palladium Complexes: Synthesis, Structure, and Catalysis for C-5 Arylation of Imidazoles

inferred← citeshttps://doi.org/10.70675/e9a5976bzbb94z43bdzab3bz0deb39ae7379openalex-snapshot

Joint experimental and theoretical approaches in coordination chemistry : from the trans effects to Single Molecule Magnets

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