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Activation of a C−H Bond in a Pyridine Ring. Reaction of 6-Substituted 2,2‘-Bipyridines with Methyl and Phenyl Platinum(II) Derivatives: N‘,C(3)-“Rollover” Cyclometalation

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/9780470132630.ch26openalex-snapshot
(2,2′: 6′,2″‐Terpyridine)Methylplatinum(II) Chloride and (1,10‐Phenanthroline)‐Methylchloroplatinum(II)
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Reversible Formation of Iodosylbenzene–Iron Porphyrin Intermediates in the Reaction of Oxoiron( IV ) Porphyrin π‐Cation Radicals and Iodobenzene
inferredcites →https://doi.org/10.1002/cber.19761091214openalex-snapshot
Protophane und Polyaromaten, XXII. Nucleophile Alkylierung und Arylierung des 2,2′‐Bipyridyls
inferredcites →https://doi.org/10.1007/bf02252169openalex-snapshot
Palladium(II) and platinum(II)-C(3)-substituted 2,2′-bipyridines
inferredcites →https://doi.org/10.1016/0022-328x(86)80181-4openalex-snapshot
Palladium(II) and platinum(II) derivatives with chiral 2,2′-bipyridines. X-ray structure of C18H15ClN2Pd; C- and N-intramolecular coordination in a six-membered metallacycle
inferredcites →https://doi.org/10.1016/0022-328x(94)84102-0openalex-snapshot
Solid-state cyclometallation of the 1-methyl-2,4′-bipyridinium complexes of palladiumII and platinumII
inferredcites →https://doi.org/10.1016/s0010-8545(00)80238-6openalex-snapshot
The trans-influence: its measurement and significance
inferredcites →https://doi.org/10.1016/s0020-1693(00)83570-7openalex-snapshot
N-methyl-2,2′-bipyridylium complexes: synthesis and cyclometallation of M(bpyMe)X3 (M = Pt, Pd; X = Cl, Br)
inferredcites →https://doi.org/10.1016/s0020-1693(00)90478-xopenalex-snapshot
Rates and mechanism of substitution reactions of dimethylsulfoxide and aquo-(diethylenetriamine)platinum(II) ions
inferredcites →https://doi.org/10.1016/s0020-1693(00)93494-7openalex-snapshot
Oxidative addition of alcohols to dimethylplatinum(II) complexes
inferredcites →https://doi.org/10.1016/s0020-1693(01)00775-7openalex-snapshot
Geometrical configuration of monomethyl–platinum(II) complexes driven by the size of entering nitrogen ligands
inferredcites →https://doi.org/10.1016/s0022-328x(00)99687-6openalex-snapshot
Optically active nitrogen ligans
inferredcites →https://doi.org/10.1021/cr00100a004openalex-snapshot
Mechanisms of intramolecular activation of carbon-hydrogen bonds in transition-metal complexes
inferredcites →https://doi.org/10.1021/ic00165a013openalex-snapshot
A carbon-bonded tris(2,2'-bipyridine)iridium(III) complex: (2,2'-bipyridinyl-C3,N')bis(2,2'-bipyridine-N,N')iridium(III) perchlorate-water (3/1)
inferredcites →https://doi.org/10.1021/ic00168a047openalex-snapshot
Analysis of the proton and carbon-13 NMR spectra of [Ir(Hbpy-C3,N')(bpy-N,N')2]3+: evidence for a carbon-bonded structure
inferredcites →https://doi.org/10.1021/ic00189a032openalex-snapshot
Solution structure and properties of the [(2,2'-bipyridinyl-C3,N')bis(2,2'-bipyridine-N,N')iridium(III)](2+) hydrate ion, "pseudo-[Ir(bpy)3(OH)]2+"
inferredcites →https://doi.org/10.1021/ic00248a005openalex-snapshot
Resonance Raman spectra of the ground and charge-transfer excited state of pentaammine(4,4'-bipyridine)ruthenium(II) and pentaammine(4,4'-bipyridinium)ruthenium(II)
inferredcites →https://doi.org/10.1021/ic00264a018openalex-snapshot
Cyclometalated complexes of platinum(II): homoleptic compounds with aromatic C,N ligands
inferredcites →https://doi.org/10.1021/ja00124a009openalex-snapshot
Alkene and Carbon Monoxide Insertion Reactions of Nitrogen-Coordinated Monoorganopalladium(II) Complexes: The Stepwise Construction of Alternating Copolymers of CO and Alkenes on a Palladium(II) Center
inferredcites →https://doi.org/10.1021/ja0156690openalex-snapshot
A Stable Five-Coordinate Platinum(IV) Alkyl Complex
inferredcites →https://doi.org/10.1021/om00081a019openalex-snapshot
Oxidation of dimethylplatinum(II) complexes with alcohols: Synthesis and characterization of alkoxoplatinum(IV) complexes
inferredcites →https://doi.org/10.1021/om000884vopenalex-snapshot
Unprecedented Behavior of 2,2‘:6‘,2‘ ‘-Terpyridine: Dinuclear Platinum(II) Derivatives with a New N,C∧C,N Bridging Ligand
inferredcites →https://doi.org/10.1021/om010913hopenalex-snapshot
Multiple C−H Bond Activation. Threefold-Deprotonated 6-Phenyl-2,2‘-bipyridine as a Bridging Ligand in Dinuclear Platinum(II) Derivatives
inferredcites →https://doi.org/10.1039/c39850000609openalex-snapshot
‘Roll-over’ 3-metallation of co-ordinated 2,2′-bipyridyl in the thermal rearrangement of diary(bipyridyl)platinum( II ) complexes: molecular structure of (µ-bidyl)[PtPh(Bu t py)] 2
inferredcites →https://doi.org/10.1039/dt9810000933openalex-snapshot
Synthesis of platinum(II) alkyl and aryl complexes from K2[PtCl4] and tetraorganotin compounds in dimethyl sulphoxide
inferredcites →https://doi.org/10.1039/dt9900002971openalex-snapshot
The mode of co-ordination of the quaternised 2,4′-bipyridinium cation. Crystal structures of trichloro(1′-methyl-2,4′-bipyridinium-χN 1 )platinum( II ) dihydrate and dichloro(1′-methyl-2,4′-bipyridin-3′-ylium-χC 3′ , N 1 )platinum( II )

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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A Study Toward Synthesis of Triaryl(Fluorinated)-Gallium, Their Rollover and Classic Cyclometallated Species and Aryl-Ga Clusters
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“Roll‐over” Cyclometalation of 2,2′‐Bipyridine Platinum(II) Complexes in the Gas Phase: A Combined Experimental and Computational Study
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Triazole Appended Phosphines: Synthesis, Palladium Complexes, and Catalytic Studies
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Organoplatinum(II) Complexes Featuring the 2‐Vinylpyridine Ligand
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Rollover Cyclopalladation via Remote C‐H Bond Activation of Br‐Pyridinbenzothiazole: An Experimental Study
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Platinum in Chemistry: An Adventure from Phosphorescent Materials to Catalytic C−H Functionalization
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Applications of Cyclometalation Reactions and Five-Membered Ring Products for Synthetic Purposes
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Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions
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Examination of a dicationic rhodium methyl aquo complex
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On the Activation of Chloromethanes by Cyclometalated [Pt(bipy – H)]+ in the Gas Phase: A Mechanistic Study
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Studies on gas-phase cyclometalations of [ArNi(PPh3)n]+ (n = 1 or 2) by electrospray ionization tandem mass spectrometry
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Labile Pd-sulphur and Pt-sulphur bonds in organometallic palladium and platinum complexes [(COD)M(alkyl)(S-ligand)]n+—A speciation study
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Dinuclear platinum(II) complexes with bridging twofold deprotonated 2,2′:6′,2″-terpyridine. New molecules with a 3,5-diplatinated-pyridyl inner core: [Pt2(terpy-2H)(Me)2(L)2], [Pt2(terpy-2H)(X)2(L)2] and [Pt2(terpy-2H)(H)2(L)2] (L = neutral ligand; X = halide) – Crystal and molecular structure of…
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N^N^C platinum(II) and palladium(II) cyclometallates of 6,6′-diphenyl-2,2′-bipyridine, L: Crystal and molecular structure of [Pd(L–H)Cl]
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Step by step palladium mediated syntheses of new 2-(pyridin-2-yl)-6-R-nicotinic acids and esters
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2015.08.023openalex-snapshot
From proton transferred to cyclometalated platinum(IV) complex: Crystal structure and biological activity
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Platinum(II), palladium(II) and gold(III) adducts and cyclometalated derivatives of 6-methoxy-2,2′-bipyridine: A comparative study
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Newly designed luminescent di- and tetra-nuclear double rollover cycloplatinated(II) complexes
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Roll-over cyclometalation: A versatile tool to enhance the catalytic activity of transition metal complexes
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Diaryl(fluorinated)-mercury species as potential precursors of triaryl(fluorinated)-gallium to be used in the synthesis of cyclometallated Ga compounds and unexpected formation of aryl-Ga clusters
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Easy oxidative addition of the carbon–halogen bond by dimethylplatinum(II) complexes containing a related series of diimine ligands: Synthesis, spectral characterization and crystal structure
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Hydridobipyridine rhodium complexes as a result of the C–H bond activation in coordinated ligand, NMR studies
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Forty years on – Covalent hydration of transition metal complexes revisited
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Chapter 2 Organometallic Complexes of Polypyridine Ligands IV
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Ligand-Controlled Csp2–H versus Csp3–H Bond Formation in Cycloplatinated Complexes: A Joint Experimental and Theoretical Mechanistic Investigation
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Two-Dimensional Hybrid Framework Based on Weakley-Type POM as a Heterogeneous Catalyst for Glycolysis of PET and Various Polyesters
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.7b03210openalex-snapshot
Rollover Cyclometalated Bipyridine Platinum Complexes as Potent Anticancer Agents: Impact of the Ancillary Ligands on the Mode of Action
inferred← citeshttps://doi.org/10.1021/acs.joc.5b00059openalex-snapshot
Rh(III)-Catalyzed Oxidative Annulation of 2-Phenylimidazo[1,2-a]pyridines with Alkynes: Mono versus Double C–H Activation
inferred← citeshttps://doi.org/10.1021/acs.joc.7b00444openalex-snapshot
Palladium-Catalyzed Directed Halogenation of Bipyridine N-Oxides
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00156openalex-snapshot
Osmium- and Iridium-Promoted C–H Bond Activation of 2,2′-Bipyridines and Related Heterocycles: Kinetic and Thermodynamic Preferences
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Computational and Experimental Study on Selective sp2/sp3 or Vinylic/Aryl Carbon–Hydrogen Bond Activation by Platinum(II): Geometries and Relative Stability of Isomeric Cycloplatinated Compounds
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Pt(II) Rollover Cyclometalated Complexes Supported by 2,2’-Bipyridine N -Oxide: Synthesis, Characterization, and Biological Evaluation
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Oxidative C–H/C–H Annulation of Imidazopyridines and Indazoles through Rhodium-Catalyzed Vinylene Transfer
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Pt(II) Rollover Complexes with Poor-Donor Bipyridines: Synthesis, Reactivity, and Preliminary Antimicrobial Evaluation
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inferred← citeshttps://doi.org/10.1021/ic0514288openalex-snapshot
2,4,6-Tris(2-pyridyl)-1,3,5-triazine (tptz)-Derived [RuII(tptz)(acac)(CH3CN)]+and Mixed-Valent [(acac)2RuIII{(μ-tptz-H+)-}RuII(acac)(CH3CN)]+
inferred← citeshttps://doi.org/10.1021/ic400908fopenalex-snapshot
Rollover Cyclometalation with 2-(2′-Pyridyl)quinoline
inferred← citeshttps://doi.org/10.1021/ic500811nopenalex-snapshot
C–H Activation of Pyrazolyl Ligands by Ru(II)
inferred← citeshttps://doi.org/10.1021/ic502320mopenalex-snapshot
Orthometalation of Dibenzo[1,2]quinoxaline with Ruthenium(II/III), Osmium(II/III/IV), and Rhodium(III) Ions and Orthometalated [RuNO]6/7Derivatives
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Binuclear Cyclometalated Organoplatinum Complexes Containing 1,1′-Bis(diphenylphosphino)ferrocene as Spacer Ligand: Kinetics and Mechanism of MeI Oxidative Addition
inferred← citeshttps://doi.org/10.1021/ic801767qopenalex-snapshot
Synthesis, Electrochemistry, Photophysics, and Solvatochromism in New Cyclometalated 6-Phenyl-4-(p-R-phenyl)-2,2′-bipyridyl (R = Me, COOMe, P(O)(OEt)2) (C∧N∧N) Platinum(II) Thiophenolate Chromophores
inferred← citeshttps://doi.org/10.1021/ic901502nopenalex-snapshot
Multifaceted Coordination of Naphthyridine−Functionalized N-Heterocyclic Carbene: A Novel “IrIII(C∧N)(C∧C)” Compound and Its Evaluation as Transfer Hydrogenation Catalyst
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Large Effect of a Small Substitution: Competition of Dehydration with Charge Retention and Coulomb Explosion in Gaseous [(bipyR)Au(μ-O)2Au(bipyR)]2+ Dications
inferred← citeshttps://doi.org/10.1021/ja906563zopenalex-snapshot
Platinum-Catalyzed Intramolecular Hydrohydrazination: Evidence for Alkene Insertion into a Pt−N Bond
inferred← citeshttps://doi.org/10.1021/ol302375copenalex-snapshot
Rh(III)-Catalyzed C–H Bond Activation along with “Rollover” for the Synthesis of 4-Azafluorenes
inferred← citeshttps://doi.org/10.1021/ol500140eopenalex-snapshot
Mild Synthesis of Chalcones via Rhodium(III)-Catalyzed C–C Coupling of Arenes and Cyclopropenones
inferred← citeshttps://doi.org/10.1021/om050538jopenalex-snapshot
Comparative Studies with Zwitterionic Platinum(II) Bis(pyrazolyl)borate and 2,2‘-Bipyridylborate Complexes
inferred← citeshttps://doi.org/10.1021/om060036lopenalex-snapshot
Protonation of Platinum(II) Dialkyl Complexes Containing Ligands with Proximate H-Bonding Substituents
inferred← citeshttps://doi.org/10.1021/om061137mopenalex-snapshot
Monoarylplatinum(II) Complexes with a 2-Phenylpyridyl Ligand and Coordinated Solvent, [Pt(Ar)(Phpy)(solv)] (Phpy = 2-phenylpyridyl; solv = NCCH 3 , dmso). Preparation from [Pt(Ar) 2 (solv) 2 ], Structures, and Chemical Properties
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Mechanistic Study on the Gas-Phase Generation of “Rollover”-Cyclometalated [M(bipy − H)]+(M = Ni, Pd, Pt)
inferred← citeshttps://doi.org/10.1021/om200172hopenalex-snapshot
Platinum(II)-Cyclometalated “Roll-over” Complexes with a Chiral Pinene-Derived 2,2′-Bipyridine
inferred← citeshttps://doi.org/10.1021/om200293eopenalex-snapshot
Reactions of a Platinum(II) Agostic Complex: Decyclometalation, Dicyclometalation, and Solvent-Switchable Formation of a Rollover Complex
inferred← citeshttps://doi.org/10.1021/om200660aopenalex-snapshot
Heterobimetallic Rollover Derivatives
inferred← citeshttps://doi.org/10.1021/om300824dopenalex-snapshot
Mesoionic Complexes of Platinum(II) Derived from “Rollover” Cyclometalation: A Delicate Balance between Pt–C(sp3) and Pt–C(sp2) Bond Cleavage as a Result of Different Reaction Conditions
inferred← citeshttps://doi.org/10.1021/om400300nopenalex-snapshot
Oxidative Addition of MeI to a Rollover Complex of Platinum(II): Isolation of the Kinetic Product
inferred← citeshttps://doi.org/10.1021/om5000908openalex-snapshot
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inferred← citeshttps://doi.org/10.1021/om5003057openalex-snapshot
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inferred← citeshttps://doi.org/10.1021/om500681uopenalex-snapshot
Electronic and Steric Effects in Rollover C–H Bond Activation
inferred← citeshttps://doi.org/10.1021/om500712eopenalex-snapshot
Carbon–Hydrogen versus Nitrogen–Oxygen Bond Activation in Reactions of N-Oxide Derivatives of 2,2′-Bipyridine and 1,10-Phenanthroline with a Dimethylplatinum(II) Complex
inferred← citeshttps://doi.org/10.1021/om800027gopenalex-snapshot
N,C “Rollover” Cyclometalated Platinum(II) Hydrides: Mono- and Polynuclear Derivatives
inferred← citeshttps://doi.org/10.1021/om800864fopenalex-snapshot
Five- and Seven-Membered Metallacycles in [C,N,N′] and [C,N] Cycloplatinated Compounds
inferred← citeshttps://doi.org/10.1021/om801033gopenalex-snapshot
Cyclometalation of 2,2′-Bipyridine. Mono- and Dinuclear C,N Platinum(II) Derivatives
inferred← citeshttps://doi.org/10.1021/om900388kopenalex-snapshot
Thermal C−H Bond Activation of Benzene with Cationic [Pt(CX3)(L)]+Complexes in the Gas Phase: A Combined Experimental/Theoretical Study (X = H, D; L = 1,10-Phenanthroline, 2,2′-Bipyrimidine, 2,2′-Bipyridine, and (o,o′-Cl2C6H3)N═C(CH3)−C(CH3)═N(o,o′-Cl2C6H3))
inferred← citeshttps://doi.org/10.1021/om900827gopenalex-snapshot
Versatile, Selective, and Switchable Coordination Modes of Pincer Click Ligands
inferred← citeshttps://doi.org/10.1039/b411432aopenalex-snapshot
Cyclometallated Pd( ii ) azido complexes containing 6-phenyl-2,2′-bipyridyl or 2-phenylpyridyl derivatives: synthesis and reactivity toward organic isocyanides and isothiocyanates
inferred← citeshttps://doi.org/10.1039/c001897jopenalex-snapshot
Luminescence and reactivity of 7-azaindole derivatives and complexes
inferred← citeshttps://doi.org/10.1039/c0cc04581kopenalex-snapshot
Solvent-controlled switch of selectivity between sp 2 and sp 3 C–H bond activation by platinum( ii )
inferred← citeshttps://doi.org/10.1039/c0dt00435aopenalex-snapshot
Platinum(ii) N-heterocyclic carbene complexes: coordination and cyclometallation.
inferred← citeshttps://doi.org/10.1039/c1sc00651gopenalex-snapshot
“Rollover” cyclometalation – early history, recent developments, mechanistic insights and application aspects
inferred← citeshttps://doi.org/10.1039/c3dt51339dopenalex-snapshot
Selectivity in metal–carbon bond protonolysis in p-tolyl- (or methyl)-cycloplatinated(ii) complexes: kinetics and mechanism of the uncatalyzed isomerization of the resulting Pt(ii) products
inferred← citeshttps://doi.org/10.1039/c4dt01143kopenalex-snapshot
Hemilability of P(X)N-type ligands (X = O, N–H): rollover cyclometalation and benzene C–H activation from (P(X)N)PtMe 2 complexes
inferred← citeshttps://doi.org/10.1039/c4dt03424dopenalex-snapshot
“Aggregation induced phosphorescence” active “rollover” iridium( iii ) complex as a multi-stimuli-responsive luminescence material
inferred← citeshttps://doi.org/10.1039/c5cc02355fopenalex-snapshot
Intramolecular transcyclometallation: the exchange of an aryl–Pt bond for an alkyl–Pt bond via an agostic intermediate
inferred← citeshttps://doi.org/10.1039/c5dt02483hopenalex-snapshot
Chiral cyclometalation of 6-(1-phenylbenzyl)-2,2′-bipyridine
inferred← citeshttps://doi.org/10.1039/c7nj01079fopenalex-snapshot
Gas-phase reactivity of Cp* group IX metal complexes bearing aromatic N,N′-chelating ligands
inferred← citeshttps://doi.org/10.1039/c7nj04183gopenalex-snapshot
Cycloplatinated( ii ) complexes bearing 1,1′-bis(diphenylphosphino)ferrocene ligand: biological evaluation and molecular docking studies
inferred← citeshttps://doi.org/10.1039/d0ra03824eopenalex-snapshot
The shiny side of copper: bringing copper( i ) light-emitting electrochemical cells closer to application
inferred← citeshttps://doi.org/10.1039/d1dt00546dopenalex-snapshot
Synthesis and characterization of new Pd( ii ) and Pt( ii ) complexes with 3-substituted 1-(2-pyridyl)imidazo[1,5- a ]pyridine ligands
inferred← citeshttps://doi.org/10.1039/d3sc04864kopenalex-snapshot
Modular preparation of cationic bipyridines and azaarenes via C–H activation
inferred← citeshttps://doi.org/10.3390/app10196665openalex-snapshot
Pt(II) Derivatives with Rollover-Coordinated 6-substituted 2,2′-bipyridines: Ligands with Multiple Personalities
inferred← citeshttps://doi.org/10.3390/inorganics2010115openalex-snapshot
Diarylplatinum(II) Compounds as Versatile Metallating Agents in the Synthesis of Cyclometallated Platinum Compounds with N-Donor Ligands
inferred← citeshttps://doi.org/10.3390/molecules26020328openalex-snapshot
Rollover Cyclometalation as a Valuable Tool for Regioselective C–H Bond Activation and Functionalization
inferred← citeshttps://doi.org/10.3390/molecules27217249openalex-snapshot
Classical vs. Non-Classical Cyclometalated Pt(II) Complexes
inferred← citeshttps://doi.org/10.3390/molecules29030707openalex-snapshot
Regioselective C(sp2)-C(sp3) Coupling Mediated by Classical and Rollover Cyclometalation
inferred← citeshttps://doi.org/10.3762/bjoc.9.153openalex-snapshot
True and masked three-coordinate T-shaped platinum(II) intermediates
inferred← citeshttps://doi.org/10.5012/bkcs.2007.28.11.2045openalex-snapshot
Cyclometalated Platinum(II) Complexes Derived from a Chiral Pyridine Ligand: Synthesis, Structure, and Catalytic Activity
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