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Development of Jacobsen Asymmetric Epoxidation and Sharpless Asymmetric Dihydroxylation Methods for the Large-Scale Preparation of a Chiral Dihydrobenzofuran Epoxide
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
inferredcites →https://doi.org/10.1002/(sici)1521-3897(199907)341:5<436::aid-prac436>3.0.co;2-6openalex-snapshot
N,N′-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride - the Jacobsen catalyst
inferredcites →https://doi.org/10.1016/0040-4039(95)00696-aopenalex-snapshot
The behavior of indene oxide in the ritter reaction: A simple route to cis-aminoindanol
inferredcites →https://doi.org/10.1016/0040-4039(95)01088-yopenalex-snapshot
Low Temperature Asymmetric Epoxidation of Unfunctionalized Olefins Catalyzed by (Salen)Mn(III) Complexes
inferredcites →https://doi.org/10.1016/0040-4039(96)00565-5openalex-snapshot
The role of 4-(3-phenylpropyl)pyridine N-Oxide (P3NO) in the manganese-salen-catalyzed asymmetric epoxidation of indene
inferredcites →https://doi.org/10.1016/0040-4039(96)00683-1openalex-snapshot
The effect of catalyst loading and donor ligands in the Mn(III) salen catalysed chiral epoxidation of chromenes: Synthesis of BRL 55834
inferredcites →https://doi.org/10.1016/b978-008046519-7.00137-4openalex-snapshot
Transition Metal-catalyzed Oxidations: Asymmetric Epoxidation
inferredcites →https://doi.org/10.1016/s0040-4020(01)00777-3openalex-snapshot
Synthesis of cyclopropane containing natural products
inferredcites →https://doi.org/10.1016/s0040-4020(01)88349-6openalex-snapshot
A simplified procedure for the stereospecific transformation of 1,2-diols into epoxides
inferredcites →https://doi.org/10.1016/s0040-4020(02)00440-4openalex-snapshot
A critical outlook and comparison of enantioselective oxidation methodologies of olefins
inferredcites →https://doi.org/10.1016/s0040-4020(98)00222-1openalex-snapshot
New aspects of catalytic asymmetric cyclopropanation
inferredcites →https://doi.org/10.1016/s0040-4020(99)01008-xopenalex-snapshot
Asymmetric Epoxidation of Unfunctionalized Alkenes with Ammonium and Phosphonium Monopersulfates Catalyzed by Chiral Mn(III)–Salen Complexes
inferredcites →https://doi.org/10.1016/s0040-4039(00)00548-7openalex-snapshot
Copper(I)-catalyzed intramolecular cyclization reaction of 2-(2′-chlorophenyl)ethanol to give 2,3-dihydrobenzofuran
inferredcites →https://doi.org/10.1016/s0040-4039(00)89008-5openalex-snapshot
Preclusion of the “second cycle” in the osmium-catalyzed asymmetric dihydroxylation of olefins leads to a superior process
inferredcites →https://doi.org/10.1016/s0040-4039(99)01437-9openalex-snapshot
A novel allylic hydroxylation of sterically hindered olefins by Fe-porphyrin-catalyzed mCPBA oxidation
inferredcites →https://doi.org/10.1016/s0040-4039(99)01886-9openalex-snapshot
Oxidation of benzylic methylene compounds to ketones with m-chloroperoxybenzoic acid and oxygen
inferredcites →https://doi.org/10.1021/ja00018a068openalex-snapshot
Highly enantioselective epoxidation catalysts derived from 1,2-diaminocyclohexane
inferredcites →https://doi.org/10.1021/ja00099a062openalex-snapshot
Highly Enantioselective, Low-Temperature Epoxidation of Styrene
inferredcites →https://doi.org/10.1021/ja00163a052openalex-snapshot
Enantioselective epoxidation of unfunctionalized olefins catalyzed by salen manganese complexes
inferredcites →https://doi.org/10.1021/ja00185a050openalex-snapshot
A mechanistic insight leads to a greatly improved osmium-catalyzed asymmetric dihydroxylation process
inferredcites →https://doi.org/10.1021/jo00007a012openalex-snapshot
Asymmetric olefin epoxidation with sodium hypochlorite catalyzed by easily prepared chiral manganese(III) salen complexes
inferredcites →https://doi.org/10.1021/jo00036a003openalex-snapshot
The osmium-catalyzed asymmetric dihydroxylation: a new ligand class and a process improvement
inferredcites →https://doi.org/10.1021/jo00086a062openalex-snapshot
A Practical Method for the Large-Scale Preparation of [N,N'-Bis(3,5-di-tertbutylsalicylidene)-1,2-cyclohexanediaminato(2-)]manganese(III) chloride, a Highly Enantioselective Epoxidation Catalyst
inferredcites →https://doi.org/10.1021/jo01030a078openalex-snapshot
Epoxidations with m-Chloroperbenzoic Acid
inferredcites →https://doi.org/10.1021/jo01280a018openalex-snapshot
Stereochemistry of epoxidation of rigid methylenecyclohexane systems. Determination of stereochemistry of exocyclic epoxides in rigid cyclohexanes by nuclear magnetic resonance half band widths
inferredcites →https://doi.org/10.1021/jo971476copenalex-snapshot
Asymmetric Synthesis of CDP840 by Jacobsen Epoxidation. An Unusual Syn Selective Reduction of an Epoxide
inferredcites →https://doi.org/10.1021/jo9819032openalex-snapshot
TEMPO-Catalyzed Oxidations of Alcohols Using m-CPBA: The Role of Halide Ions
inferredcites →https://doi.org/10.1021/op0202033openalex-snapshot
Development of a Practical, Safe, and High-Yielding Process for the Preparation of Enantiomerically Pure trans-Cyclopropane Carboxylic Acid
inferredcites →https://doi.org/10.1021/op030201yopenalex-snapshot
A Practical Pilot-Scale Synthesis of 4-Vinyl-2,3-dihydrobenzofuran Using Imidate Ester Chemistry and Phase-Transfer Catalysis
inferredcites →https://doi.org/10.1021/op970030vopenalex-snapshot
Sharpless Asymmetric Dihydroxylation on an Industrial Scale
inferredcites →https://doi.org/10.1055/s-1987-28153openalex-snapshot
Oxidation Reactions Using Magnesium Monoperphthalate: A Comparison withm-Chloroperoxybenzoic Acid
inferredcites →https://doi.org/10.1055/s-2000-8715openalex-snapshot
Chiral Ketone-Catalyzed Asymmetric Epoxidation of Olefins
inferredcites →https://doi.org/10.1080/00945719408001399openalex-snapshot
Catalytic Asymmetric Synthesis
inferredcites →https://doi.org/10.1351/pac199870051123openalex-snapshot
New catalysts and methods for highly enantioselective metal carbene reactions
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
inferred← citeshttps://doi.org/10.2139/ssrn.4806578openalex-extracted
Thermostabilization and Molecular Dynamic Simulation of Nastya for Highly Enantioselective (R)-Epoxidation of Styrene Analogues
inferred← citeshttps://doi.org/10.1002/047084289x.rc140.pub2openalex-snapshot
m-Chloroperbenzoic Acid
inferred← citeshttps://doi.org/10.1002/0471227617.eoc025openalex-snapshot
Asymmetric Catalysis — Industrial
inferred← citeshttps://doi.org/10.1002/0471264180.or066.02openalex-snapshot
Asymmetric Dihydroxylation of Alkenes
inferred← citeshttps://doi.org/10.1002/14356007.a13_533.pub2openalex-snapshot
Hypnotics and Sedatives (N05C)
inferred← citeshttps://doi.org/10.1002/9780470638859.conrr582openalex-snapshot
Sharpless Dihydroxylation
inferred← citeshttps://doi.org/10.1002/9783527628179.ch3openalex-snapshot
Cinchona Alkaloids as Chiral Ligands in Asymmetric Oxidations
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Industrial Applications of Homogeneous Enantioselective Catalysts
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Oxidation: Nobel Prize Chemistry Catalysis
inferred← citeshttps://doi.org/10.1002/adsc.200800269openalex-snapshot
Sharpless Asymmetric Dihydroxylation of Olefins in WaterSurfactant Media with Recycling of the Catalytic System by Membrane Nanofiltration
inferred← citeshttps://doi.org/10.1016/b978-0-08-095167-6.00906-xopenalex-snapshot
9.6 Industrial Applications of Asymmetric Oxidations
inferred← citeshttps://doi.org/10.1016/b978-0-32-390644-9.00089-5openalex-snapshot
Asymmetric Synthesis of Cyclopropane and Cyclobutane-Containing Small Molecule Pharmaceuticals
inferred← citeshttps://doi.org/10.1016/j.bej.2022.108359openalex-snapshot
Engineering the regiocomplementarity of an epoxide hydrolase from Rhodotorula paludigena by means of computer-aided design for the scale-up enantioconvergent hydrolysis of racemic m-nitrostyrene oxide
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Synthetic approaches to the 2014 new drugs
inferred← citeshttps://doi.org/10.1016/j.enzmictec.2018.02.001openalex-snapshot
Characterization of two styrene monooxygenases from marine microbes
inferred← citeshttps://doi.org/10.1016/j.ijbiomac.2020.08.011openalex-snapshot
Highly regio- and enantio-selective hydrolysis of two racemic epoxides by GmEH3, a novel epoxide hydrolase from Glycine max
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2005.04.025openalex-snapshot
Osmium catalyzed asymmetric dihydroxylation of methyl trans-cinnamate in ionic liquids, followed by supercritical CO2 product recovery
inferred← citeshttps://doi.org/10.1016/j.mcat.2021.111851openalex-snapshot
Remarkable improvement in the regiocomplementarity of a Glycine max epoxide hydrolase by reshaping its substrate-binding pocket for the enantioconvergent preparation of (R)-hexane-1,2-diol
inferred← citeshttps://doi.org/10.1016/j.mcat.2023.113055openalex-snapshot
Stereo-Complementary Epoxidation of 4-Vinyl-2,3-Dihydrobenzofuran Using Mutants of Sestya with Enhanced Stability and Enantioselectivity
inferred← citeshttps://doi.org/10.1016/j.mcat.2024.114312openalex-snapshot
Thermostabilization and molecular dynamics simulation of NaStyA for highly enantioselective (R)-epoxidation of styrene analogues
inferred← citeshttps://doi.org/10.1016/j.tetasy.2010.12.022openalex-snapshot
Asymmetric epoxidation of styrene derivatives by styrene monooxygenase from Pseudomonas sp. LQ26: effects of α- and β-substituents
inferred← citeshttps://doi.org/10.1016/j.tetasy.2011.01.003openalex-snapshot
First enantioselective synthesis of 4-aminoalcohol quinoline derivatives through a regioselective SN2 epoxide opening mechanism
inferred← citeshttps://doi.org/10.1016/j.tetlet.2019.06.048openalex-snapshot
Total synthesis of Tasimelteon
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Potential Safety Hazards Associated with Using N , N -Dimethylformamide in Chemical Reactions
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Integrating Process Safety Consideration to Enhance Route Development and Optimization
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Chromium− and Manganese−salen Promoted Epoxidation of Alkenes
inferred← citeshttps://doi.org/10.1021/cr040700copenalex-snapshot
Asymmetric Synthesis of Active Pharmaceutical Ingredients
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Safer Preparation of m-CPBA/DMF Solution in Pilot Plant
inferred← citeshttps://doi.org/10.1021/op800230fopenalex-snapshot
An Improved Process for the Synthesis and Isolation of (S)-N-(1-Phenylethyl)hydroxylamine
inferred← citeshttps://doi.org/10.1039/c3ra45702hopenalex-snapshot
meta-Chloroperbenzoic acid (mCPBA): a versatile reagent in organic synthesis
inferred← citeshttps://doi.org/10.1055/a-2508-9744openalex-snapshot
Aggregation-Induced Electrochemical Boronation–Dihydroxylation of Alkenes
inferred← citeshttps://doi.org/10.1080/00397911.2018.1545031openalex-snapshot
An efficient and practical asymmetric synthesis of (−)-tasimelteon
inferred← citeshttps://doi.org/10.1201/b17114-14openalex-snapshot
CATALYTIC ORGANIC SYNTHESIS: A NEW PARADIGM IN INDUSTRIAL PROCESS INTENSIFICATION
inferred← citeshttps://doi.org/10.3184/174751916x14758368248634openalex-snapshot
A Facile and Practical Synthesis of (-)-tasimelteon
inferred← citeshttps://doi.org/10.3184/174751917x15094552081161openalex-snapshot
Efficient Preparation of 2,3-Disubstituted Cyclopropane-1-Carbonitriles via Selective Decarboxylation of 1-Cyanocyclopropane-1-Carboxylates
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Epoxide Syntheses and Ring-Opening Reactions in Drug Development
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