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Transition metal-promoted biomimetic steps in total syntheses
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Isoprenoid Biosynthesis through the Methylerythritol Phosphate Pathway: The (E)-4-Hydroxy-3-methylbut-2-enyl Diphosphate Synthase (GcpE) is a [4Fe–4S] Protein
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Asymmetric Synthesis and Biosynthetic Implications of (+)‐Fusarisetin A
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Bio‐Inspired Dimerization Reaction of Tryptophan Derivatives in Aqueous Acidic Media: Three‐Step Syntheses of (+)‐WIN 64821, (−)‐Ditryptophenaline, and (+)‐Naseseazine B
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Total Synthesis of Exiguamines A and B Inspired by Catecholamine Chemistry
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Total Synthesis of 3‐Hydroxydrimanes Mediated by Titanocene( III ) – Evaluation of Their Antifeedant Activity
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A Highly Efficient Procedure for Ruthenium Tetroxide Catalyzed Oxidative Cyclizations of 1,5‐Dienes
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Titanocene‐Mediated Radical Cyclization: An Emergent Method Towards the Synthesis of Natural Products
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Transition‐Metal‐Catalyzed Allylic Substitution and Titanocene‐Catalyzed Epoxypolyene Cyclization as a Powerful Tool for the Preparation of Terpenoids
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Zur Kenntnis der Triterpene. 190. Mitteilung. Eine stereochemische Interpretation der biogenetischen Isoprenregel bei den Triterpenen
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Taxol Biosynthesis and Molecular Genetics
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Directed oxidative cyclization of 5-hydroxyalkenes with rhenium oxide
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Modular approach to annonaceous acetogenins. total synthesis of asimicin and bullatacin.
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A review: synthesis of alkaloids by oxidative phenol and nonphenol coupling reactions
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Biomimetic polyene cyclizations
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The Conservation of Orbital Symmetry
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Studies in Natural Product Chemistry
inferredcites →https://doi.org/10.1016/j.chembiol.2006.01.013openalex-snapshot
Evidence for the Role of the monB Genes in Polyether Ring Formation during Monensin Biosynthesis
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Functional Genomic Analysis of Alkaloid Biosynthesis in Hyoscyamus niger Reveals a Cytochrome P450 Involved in Littorine Rearrangement
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Halogenation Strategies In Natural Product Biosynthesis
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The polyketide cyclase RemF from Streptomyces resistomycificus contains an unusual octahedral zinc binding site
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The biomimetic synthesis of SNF4435C and SNF4435D, and the total synthesis of the polyene metabolites aureothin, N-acetyl-aureothamine and spectinabilin
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Synthesis of five- to seven-membered polyfunctional terpenic carbocycles via Ti(III)-catalyzed radical cyclizations of epoxypolyprenes
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Discovery of a novel one-step RuO4-catalysed tandem oxidative polycyclization/double spiroketalization process. Access to a new type of polyether bis-spiroketal compound displaying antitumour activity
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A biomimetic total synthesis of (+)-intricarene
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Total synthesis of fomitellic acid B
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Expedient synthesis of ialibinones A and B by manganese(III)-mediated oxidative free radical cyclisation
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The distribution of elements in cells
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Isoprenoid biosynthesis via the methylerythritol phosphate pathway: the (E)‐4‐hydroxy‐3‐methylbut‐2‐enyl diphosphate reductase (LytB/IspH) from Escherichia coli is a [4Fe–4S] protein
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Purification, characterization, and kinetic analysis of a 2-oxoglutarate-dependent dioxygenase involved in vindoline biosynthesis from Catharanthus roseus.
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Experiments and speculations on the role of oxidative cyclization chemistry in natural product biosynthesis
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Production of 3', 4'-anhydrovinblastine: a unique chemical synthesis
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Die permanganatoxydation von 1,5-dienverbindungen
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Dioxygenase enzymes: catalytic mechanisms and chemical models
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Conversion of prelaureatin into laurallene, a bromo-allene compound, by enzymatic and chemical bromo-etherification reactions
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Hydrogen bonding control in the oxidative cyclisation of 1,5-dienes
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Epoxide-initiated cationic polyene cyclisations
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Free radical additions to squalene
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Oxidative cyclization of farnesyl acetate by a free radical path
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Stereocontrolled oxidation of 5-hydroxyalkenes with rhenium oxide. III
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Oxidative cyclization of 5-hydroxyalkenes with rhenium oxide, utilizing a co-oxidant. IV
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Le (trifluoroacétate) de ruthénium(IV), nouveau catalyseur a température ambiante du couplage biarylique oxydant non phénolique -première synthèse totale biomimétique du néoisostégane-
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A biogenetically patterned total synthesis of prostaglandin E1
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Stereospecific tetracyclization of icosatetraenes via Mn(III) promoted oxidative free-radical cyclization
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A stereoselective synthesis of the tetrahydrofuran unit in ionomycin
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Mercury salts as initiators for electrophilic cyclization of isoprenoids
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Cyclisations radicalaires XXIV - cyclisation oxydante du phenyl-13 trimethyl-2,6,10 tridecatriene-2,6,10 par le peroxyde de benzoyle.
inferredcites →https://doi.org/10.1016/s0040-4039(98)00738-2openalex-snapshot
Ferric chloride, an efficient promoter of cationic polyene cyclizations
inferredcites →https://doi.org/10.1016/s0040-4039(98)02172-8openalex-snapshot
OsO4-Catalyzed oxidative cyclization of geranyl and neryl acetate to cis-2,5-bis(hydroxymethyl)tetrahydrofurans
inferredcites →https://doi.org/10.1016/s0045-6535(03)00204-2openalex-snapshot
Biological dehalogenation and halogenation reactions
inferredcites →https://doi.org/10.1016/s0065-3233(08)60534-3openalex-snapshot
Structural Aspects of Metal Liganding to Functional Groups in Proteins
inferredcites →https://doi.org/10.1021/ar50001a001openalex-snapshot
Nonenzymic biogenetic-like olefinic cyclizations
inferredcites →https://doi.org/10.1021/ar50004a003openalex-snapshot
Bioorganic chemistry: sterols and acrylic terpene terminal expoxides
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Bioorganic chemistry. Total synthesis of tetra- and pentacyclic triterpenoids
inferredcites →https://doi.org/10.1021/bi061998zopenalex-snapshot
In Vitro Biosynthesis of Violacein from l -Tryptophan by the Enzymes VioA−E from Chromobacterium violaceum
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Metallaoxetanes as intermediate in oxygen-transfer reactions - reality or fiction?
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Mode of Action of Bi- and Trinuclear Zinc Hydrolases and Their Synthetic Analogues
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Mechanistic Studies on Synthetic Fe−S-Based Clusters and Their Relevance to the Action of Nitrogenases
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Structure and Chemistry of Cytochrome P450
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Biosynthetic and Biomimetic Electrocyclizations
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A Case Study in Biomimetic Total Synthesis: Polyolefin Carbocyclizations to Terpenes and Steroids
inferredcites →https://doi.org/10.1021/cr040653oopenalex-snapshot
Reaction Mechanisms of Mononuclear Non-Heme Iron Oxygenases
inferredcites →https://doi.org/10.1021/cr050286wopenalex-snapshot
Structural Biology and Chemistry of the Terpenoid Cyclases
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Manganese(III)-Based Oxidative Free-Radical Cyclizations
inferredcites →https://doi.org/10.1021/ic0509276openalex-snapshot
Molecular Chemistry of Consequence to Renewable Energy
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A Fully Synthetic Route to the Neurotrophic Illicinones: Syntheses of Tricycloillicinone and Bicycloillicinone Aldehyde
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Ellagitannin Chemistry. The First Total Chemical Synthesis of an Ellagitannin Natural Product, Tellimagrandin I
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syn-Oxidative Polycyclization of Hydroxy Polyenes: A New Approach to Polyether Synthesis
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Combined Osmium-Rhenium Approach to Synthesis of Naturally Occurring Polyethers
inferredcites →https://doi.org/10.1021/ja00170a028openalex-snapshot
Total synthesis of ionophores. 6. Asymmetric induction in the permanganate-promoted oxidative cyclization of 1,5-dienes
inferredcites →https://doi.org/10.1021/ja00295a025openalex-snapshot
Stereoselective total synthesis of the complement inhibitor K-76
inferredcites →https://doi.org/10.1021/ja00349a040openalex-snapshot
Unified stereochemical model of polyether antibiotic structure and biogenesis
inferredcites →https://doi.org/10.1021/ja00384a077openalex-snapshot
The endiandric acid cascade. Electrocyclizations in organic synthesis. I. Stepwise, stereocontrolled total synthesis of endiandric acids A and B
inferredcites →https://doi.org/10.1021/ja00384a078openalex-snapshot
The endiandric acid cascade. Electrocyclizations in organic synthesis. 2. Stepwise, stereocontrolled total synthesis of endiandric acids C-G
inferredcites →https://doi.org/10.1021/ja00384a079openalex-snapshot
The endiandric acid cascade. Electrocyclizations in organic synthesis. 3. "Biomimetic" approach to endiandric acids A-G. Synthesis of precursors
inferredcites →https://doi.org/10.1021/ja00384a080openalex-snapshot
The endiandric acid cascade. Electrocyclizations in organic synthesis. 4. Biomimetic approach to endiandric acids A-G. Total synthesis and thermal studies
inferredcites →https://doi.org/10.1021/ja00389a060openalex-snapshot
Polyether biosynthesis. 2. Origin of the oxygen atoms of monensin A
inferredcites →https://doi.org/10.1021/ja00417a060openalex-snapshot
Total synthesis of (+-)-steganacin
inferredcites →https://doi.org/10.1021/ja00451a043openalex-snapshot
Chromyl chloride oxidations of olefins. Possible role of organometallic intermediates in the oxidations of olefins by oxo transition metal species
inferredcites →https://doi.org/10.1021/ja00707a074openalex-snapshot
Intramolecular oxidative phenol coupling. II. Biogenetic-type synthesis of (+-)-maritidine
inferredcites →https://doi.org/10.1021/ja00793a047openalex-snapshot
Intramolecular oxidative coupling of monophenolic benzylisoquinolines. Quinonoid oxoaporphines
inferredcites →https://doi.org/10.1021/ja00803a048openalex-snapshot
Mechanism of a nonenzymic biogenetic-like olefinic cyclization
inferredcites →https://doi.org/10.1021/ja01013a066openalex-snapshot
A new approach to steroid total synthesis. A nonenzymic biogenetic-like olefinic cyclization involving the stereospecific formation of five asymmetric centers
inferredcites →https://doi.org/10.1021/ja01038a073openalex-snapshot
Intramolecular oxidative phenol coupling. A new method
inferredcites →https://doi.org/10.1021/ja01624a038openalex-snapshot
The Stereochemistry of Polyene Cyclization
inferredcites →https://doi.org/10.1021/ja027745kopenalex-snapshot
General Approach for the Synthesis of Chiral Perylenequinones via Catalytic Enantioselective Oxidative Biaryl Coupling
inferredcites →https://doi.org/10.1021/ja034397topenalex-snapshot
Total Synthesis of Elisabethin A: Intramolecular Diels−Alder Reaction under Biomimetic Conditions
inferredcites →https://doi.org/10.1021/ja044733lopenalex-snapshot
The Total Synthesis of (−)-SNF4435 C and (+)-SNF4435 D
inferredcites →https://doi.org/10.1021/ja047925popenalex-snapshot
Vanadium Bromoperoxidase-Catalyzed Biosynthesis of Halogenated Marine Natural Products
inferredcites →https://doi.org/10.1021/ja050092yopenalex-snapshot
Biomimetic Synthesis of Antimalarial Naphthoquinones
inferredcites →https://doi.org/10.1021/ja054316oopenalex-snapshot
7-endo Radical Cyclizations Catalyzed by Titanocene(III). Straightforward Synthesis of Terpenoids with Seven-Membered Carbocycles
inferredcites →https://doi.org/10.1021/ja073573lopenalex-snapshot
Regioselective Oxidative Cation-Olefin Cyclization of Poly-enes: Catalyst Turnover via Hydride Abstraction
inferredcites →https://doi.org/10.1021/ja078192mopenalex-snapshot
Direct Coupling of Catharanthine and Vindoline to Provide Vinblastine: Total Synthesis of (+)- and ent-(−)-Vinblastine
inferredcites →https://doi.org/10.1021/ja100185popenalex-snapshot
Enantioselective Polyene Cyclization via Organo-SOMO Catalysis
inferredcites →https://doi.org/10.1021/ja1027748openalex-snapshot
Total Synthesis and Evaluation of a Key Series of C5-Substituted Vinblastine Derivatives
inferredcites →https://doi.org/10.1021/ja201088kopenalex-snapshot
A Stereoselective Vanadium-Dependent Chloroperoxidase in Bacterial Antibiotic Biosynthesis
inferredcites →https://doi.org/10.1021/ja206906dopenalex-snapshot
Comparative Characterization of Fungal Anthracenone and Naphthacenedione Biosynthetic Pathways Reveals an α-Hydroxylation-Dependent Claisen-like Cyclization Catalyzed by a Dimanganese Thioesterase
inferredcites →https://doi.org/10.1021/ja209459fopenalex-snapshot
Total Synthesis of the Potent Androgen Receptor Antagonist (−)-Arabilin: A Strategic, Biomimetic [1,7]-Hydrogen Shift
inferredcites →https://doi.org/10.1021/ja305665fopenalex-snapshot
Merochlorins A–D, Cyclic Meroterpenoid Antibiotics Biosynthesized in Divergent Pathways with Vanadium-Dependent Chloroperoxidases
inferredcites →https://doi.org/10.1021/ja310386mopenalex-snapshot
Iridium-Catalyzed Enantioselective Polyene Cyclization
inferredcites →https://doi.org/10.1021/ja405518uopenalex-snapshot
Spiro-Ring Formation is Catalyzed by a Multifunctional Dioxygenase in Austinol Biosynthesis
inferredcites →https://doi.org/10.1021/ja804570bopenalex-snapshot
Mechanistic Study of Asymmetric Oxidative Biaryl Coupling: Evidence for Self-Processing of the Copper Catalyst to Achieve Control of Oxidase vs Oxygenase Activity
inferredcites →https://doi.org/10.1021/ja806668qopenalex-snapshot
Structure of ( E )-4-Hydroxy-3-methyl-but-2-enyl Diphosphate Reductase, the Terminal Enzyme of the Non-Mevalonate Pathway
inferredcites →https://doi.org/10.1021/ja809842bopenalex-snapshot
Total Synthesis of Vinblastine, Vincristine, Related Natural Products, and Key Structural Analogues
inferredcites →https://doi.org/10.1021/ja962837topenalex-snapshot
syn-Oxidative Polycyclizations of Hydroxypolyenes: Highly Stereoselective and Potentially Biomimetic Syntheses ofall-trans-Polytetrahydrofurans
inferredcites →https://doi.org/10.1021/ja964273zopenalex-snapshot
Tandem Oxidative Cyclization with Rhenium Oxide. Total Synthesis of 17,18-bisepi-Goniocin
inferredcites →https://doi.org/10.1021/ja964419uopenalex-snapshot
Synthesis and Conformational Properties of the M(4-6)(5-7) Bicyclic Tetrapeptide Common to the Vancomycin Antibiotics
inferredcites →https://doi.org/10.1021/ja9730425openalex-snapshot
Highly Diastereoselective Cyclizations of Bishomoallylic Tertiary Alcohols Promoted by Rhenium(VII) Oxide. Critical Steric versus Chelation Effects in Alkoxyrhenium Intermediates
inferredcites →https://doi.org/10.1021/ja981324eopenalex-snapshot
Rules of Stereoselectivity in Tandem Oxidative Polycyclization Reaction with Rhenium(VII) Oxides
inferredcites →https://doi.org/10.1021/ja9934091openalex-snapshot
Enantioselective Total Synthesis of the Kinesin Motor Protein Inhibitor Adociasulfate 1
inferredcites →https://doi.org/10.1021/ja994313+openalex-snapshot
Carbene Complexes in the Synthesis of Complex Natural Products: Total Synthesis of the Calphostins
inferredcites →https://doi.org/10.1021/jo000450+openalex-snapshot
Endo Mode Cyclization of 5,6-Epoxy-7-octyn-1-ol Derivatives
inferredcites →https://doi.org/10.1021/jo00088a011openalex-snapshot
The First Examples of Nonenzymic, Biomimetic Polyene Pentacyclizations. Total Synthesis of the Pentacyclic Triterpenoid Sophoradiol
inferredcites →https://doi.org/10.1021/jo00123a005openalex-snapshot
Acylperrhenate-Induced Tandem syn-Oxidative Cyclizations of Hydroxydienes
inferredcites →https://doi.org/10.1021/jo0014663openalex-snapshot
Total Synthesis of the Calphostins: Application of Fischer Carbene Complexes and Thermodynamic Control of Atropisomers
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Furans in synthesis. 3. Furans as terminators in cationic cyclization
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Studies aimed at the synthesis of morphine. 7. Biomimetic total synthesis of (.+-.)-pallidine
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Ruthenium(II)-catalyzed reactions of 1,4-epiperoxides
inferredcites →https://doi.org/10.1021/jo00330a037openalex-snapshot
Internal nucleophilic termination in mercuric ion initiated diene cyclizations
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Chemical simulation of polycyclic diterpenoid biosynthesis using mercury(II) triflate/N,N-dimethylaniline complex: mechanistic aspects of a biomimetic olefin cyclization
inferredcites →https://doi.org/10.1021/jo00406a051openalex-snapshot
Intramolecular nonphenol oxidative coupling of phenethylisoquinolines
inferredcites →https://doi.org/10.1021/jo00887a034openalex-snapshot
Novel nonphenol oxidative coupling of phenethylisoquinolines
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A New Strategy for the Synthesis of Cyclic Terpenoids Based on the Radical Opening of Acyclic Epoxypolyenes
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Effects of Solvents and Water in Ti(III)-Mediated Radical Cyclizations of Epoxygermacrolides. Straightforward Synthesis and Absolute Stereochemistry of (+)-3α-Hydroxyreynosin and Related Eudesmanolides
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Synthesis of (+)-8-Deoxyvernolepin and Its 11,13-Dihydroderivative. A Novel Reaction Initiated by Sulfene Elimination Leads to the 2-Oxa-cis-decalin Skeleton
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Biosynthesis of Structurally Unique Fungal Metabolite GKK1032A2: Indication of Novel Carbocyclic Formation Mechanism in Polyketide Biosynthesis
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Synthesis of Epoxyquinol A and Related Molecules: Probing Chemical Reactivity of Epoxyquinol Dimers and 2H-Pyran Precursors
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Attempted Synthesis of Spongidines by a Radical Cascade Terminating onto a Pyridine Ring
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Total Synthesis of (+)-seco-C-Oleanane via Stepwise Controlled Radical Cascade Cyclization
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Enantioselective Oxidative Biaryl Coupling Reactions Catalyzed by 1,5-Diazadecalin Metal Complexes
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Synthetic Studies toward SNF4435 C and SNF4435 D
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Total Synthesis of Panepophenanthrin
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Stereoselective Intramolecular Nicholas Reaction Using Epoxides as Nucleophiles
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Biomimetic Synthesis of the Shimalactones
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A Concise, Biomimetic Total Synthesis of (+)-Davanone
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Gold(I)-Catalyzed Cascade Cyclization of Allenyl Epoxides
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Peroxidase and the biosynthesis of terpenoid indole alkaloids in the medicinal plant Catharanthus roseus (L.) G. Don
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Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å
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The inorganic side of chemical biology
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Substrate-assisted catalysis in cytochrome P450eryF
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Bioinspired terpene synthesis: a radical approach
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What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
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Explaining the Dramatic Changes in Performance of U.S. Banks: Technological Change, Deregulation, and Dynamic Changes in Competition
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Stereoselectivity and nonmigratory insertion mechanism of dimethylacetylene dicarboxylate into metallocene‐hydride of Cp2M(L)H [Cp =η5‐C5H5; M = Nb, V; L = CO, P (OMe)3]: A DFT study
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Recent Advances of Transition Metal‐Mediated Oxidative Radical Reactions in Total Synthesis of Indole Alkaloids
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Engineered C–S Bond Construction
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Methods Utilizing First-Row Transition Metals in Natural Product Total Synthesis
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Chromium–Salen Complex/Nitroxyl Radical Cooperative Catalysis: A Combination for Aerobic Intramolecular Dearomative Coupling of Phenols
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A Bioinspired Cascade Sequence Enables Facile Assembly of Methanodibenzo[b,f][1,5]dioxocin Flavonoid Scaffold
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Oxidative Cyclization of 5H-Chromeno[2,3-b]pyridines to Benzo[b]chromeno[4,3,2-de][1,6]naphthyridines, Their NMR Study and Computer Evaluation as Material for LED
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