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Halogenated triarylboranes: synthesis, properties and applications in catalysis

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Perfluorophenyl derivatives of the elements

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Borenium Ion Catalyzed Hydroboration of Alkenes with N-Heterocyclic Carbene-Boranes

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Electrophilicity Index

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Frustrated Lewis Pairs

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Synthesis of Syndiotactic Polystyrene Derivatives Containing Amino Groups

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Tridurylboranes Extended by Three Arylethynyl Groups as a New Family of Boron-Based π-Electron Systems

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Ligand Exchange and Alkyl Abstraction Involving (Perfluoroaryl)boranes and -alanes with Aluminum and Gallium Alkyls

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New Mononuclear and Polynuclear Perfluoroarylmetalate Cocatalysts for Stereospecific Olefin Polymerization

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Possible Thermal Decomposition Routes in [MeB(C 6 F 5 ) 3 ] - [L 2 TiMe + ] as Deactivation Pathways in Olefin Polymerization Catalysis: A Combined Density Functional Theory and Molecular Mechanics Investigation

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Dihydrogen Activation by B(p-C6F4H)3 and Phosphines

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Comparative Lewis Acidity in Fluoroarylboranes: B(o-HC6F4)3, B(p-HC6F4)3, and B(C6F5)3

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Frustrated Lewis Pair Route to Hydrodesilylation of Silylphosphines

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Ancillary Metal Centers in Frustrated Lewis Pair Chemistry: Ruthenium Acetylide as a Lewis Base in the Activation of CO2, Aldehyde, and Alkyne

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Establishing the Hydride Donor Abilities of Main Group Hydrides

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Direct and Transfer Hydrosilylation Reactions Catalyzed by Fully or Partially Fluorinated Triarylboranes: A Systematic Study

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Formation of Chelated Counteranions Using Lewis Acidic Diboranes: Relevance to Isobutene Polymerization

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Gas-Phase Lewis Acidity of Perfluoroaryl Derivatives of Group 13 Elements

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“Constrained Geometry” Dialkyl Catalysts. Efficient Syntheses, C−H Bond Activation Chemistry, Monomer−Dimer Equilibration, and α-Olefin Polymerization Catalysis

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New Organo-Lewis Acids. Tris(β-perfluoronaphthyl)borane (PNB) as a Highly Active Cocatalyst for Metallocene-Mediated Ziegler−Natta α-Olefin Polymerization

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A Density Functional Study of Ion-Pair Formation and Dissociation in the Reaction between Boron- and Aluminum-Based Lewis Acids with (1,2-Me2Cp)2ZrMe2

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Zwitterionic metallocenes via reactions of organozirconocenes with highly electrophilic perfluorophenyl substituted boranes

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Ziegler–Natta catalyst activation. Thermodynamic and kinetic aspects of metallocenium ion-pair formation, dissociation, and structural reorganization

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Formal SiH4 chemistry using stable and easy-to-handle surrogates

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Late-stage chemoselective functional-group manipulation of bioactive natural products with super-electrophilic silylium ions

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inferredcites →https://doi.org/10.1039/b819621dopenalex-snapshot

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inferredcites →https://doi.org/10.1039/c0sc00398kopenalex-snapshot

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inferredcites →https://doi.org/10.1039/c2cc36470kopenalex-snapshot

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inferredcites →https://doi.org/10.1039/c2dt30208jopenalex-snapshot

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inferredcites →https://doi.org/10.1039/c2dt30334eopenalex-snapshot

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inferredcites →https://doi.org/10.1039/c2dt30384aopenalex-snapshot

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inferredcites →https://doi.org/10.1039/c2dt32525jopenalex-snapshot

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inferredcites →https://doi.org/10.1039/c2ob25339aopenalex-snapshot

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inferredcites →https://doi.org/10.1039/c3cc48036dopenalex-snapshot

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inferredcites →https://doi.org/10.1039/c3cc49147aopenalex-snapshot

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inferredcites →https://doi.org/10.1039/c8dt01717dopenalex-snapshot

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inferredcites →https://doi.org/10.1039/c9dt01359hopenalex-snapshot

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inferredcites →https://doi.org/10.1039/cs9972600345openalex-snapshot

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Phosphino‐Phosphination Reactions: Frustrated Lewis Pair Reactivity of Phosphino‐Phosphonium Cations with Alkynes

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Stereoselective Hydrosilylation of 1,2‐Diketones Catalyzed by Chiral Frustrated Lewis Pairs

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Anion‐Responsive Colorimetric and Fluorometric Red‐Shift in Triarylborane Derivatives: Dual Role of Phenazaborine as Lewis Acid and Electron Donor

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Progressing the Frustrated Lewis Pair Abilities of N-Heterocyclic Carbene/GaR3 Combinations for Catalytic Hydroboration of Aldehydes and Ketones

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Substrate Specific Metal–Ligand Cooperative Binding: Considerations for Weak Intramolecular Lewis Acid/Base Pairs

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The Effect of Carborane Substituents on the Lewis Acidity of Boranes

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Regioselective and Diastereoselective Halofunctionalization of Alkenes Promoted by Organophotocatalytic Solar Catalysis

inferred← citeshttps://doi.org/10.1021/acs.joc.4c00775openalex-snapshot

From Building Blocks to Catalysts: The Underinvestigated Potential of Boronic Acid Esters

inferred← citeshttps://doi.org/10.1021/acs.joc.4c02652openalex-snapshot

Aryl Borane as a Catalyst for Dehydrative Amide Synthesis

inferred← citeshttps://doi.org/10.1021/acs.joc.5c00570openalex-snapshot

Selective Reductions of Esters to Aldehydes: Extended Scope and Downstream Reactivity

inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00378openalex-snapshot

High Lewis Acidity at Planar, Trivalent, and Neutral Bismuth Centers

inferred← citeshttps://doi.org/10.1021/acs.organomet.5c00376openalex-snapshot

Taming the Piers–Rubinsztajn Reaction: Beyond B(C 6 F 5 ) 3

inferred← citeshttps://doi.org/10.1021/acs.orglett.1c01073openalex-snapshot

Controlling the Lewis Acidity and Polymerizing Effectively Prevent Frustrated Lewis Pairs from Deactivation in the Hydrogenation of Terminal Alkynes

inferred← citeshttps://doi.org/10.1021/acs.orglett.3c00727openalex-snapshot

Tris(pentafluorophenyl)borane-Catalyzed Stereospecific Bromocyanation of Styrene Derivatives with Cyanogen Bromide

inferred← citeshttps://doi.org/10.1021/acs.orglett.5c04669openalex-snapshot

Triarylboranes Bearing ( ortho -Carboran-1-yl)aryl Groups for Catalytic Hydrogenation with Pure or Crude H 2

inferred← citeshttps://doi.org/10.1021/acscatal.0c02023openalex-snapshot

Establishing the Role of Triflate Anions in H2 Activation by a Cationic Triorganotin(IV) Lewis Acid

inferred← citeshttps://doi.org/10.1021/acscatal.1c01940openalex-snapshot

Transition Metal-Free Direct Hydrogenation of Esters via a Frustrated Lewis Pair

inferred← citeshttps://doi.org/10.1021/acscatal.1c04746openalex-snapshot

Triarylborane Catalyzed Carbene Transfer Reactions Using Diazo Precursors

inferred← citeshttps://doi.org/10.1021/acscatal.2c04905openalex-snapshot

Resolving the Mechanistic Complexity in Triarylborane-Induced Conjugate Additions

inferred← citeshttps://doi.org/10.1021/acscatal.5c08127openalex-snapshot

Diastereoselective Synthesis of cis -α,α′-Disubstituted Cyclic Ethers via Borane-Catalyzed Reductive Cyclization of Diketones

inferred← citeshttps://doi.org/10.1021/acscatal.6c02801openalex-snapshot

Tuned Heteroleptic Aryl Borane Catalysts Enable Stereoselective 2-Deoxy Nucleoside Analog Synthesis

inferred← citeshttps://doi.org/10.1021/acsomega.3c05071openalex-snapshot

Metal-free C–H Borylation and Hydroboration of Indoles

inferred← citeshttps://doi.org/10.1021/jacs.0c05454openalex-snapshot

ROMP-Boranes as Moisture-Tolerant and Recyclable Lewis Acid Organocatalysts

inferred← citeshttps://doi.org/10.1021/jacs.0c09505openalex-snapshot

Defluorinative Functionalization of Pd(II) Fluoroalkyl Complexes

inferred← citeshttps://doi.org/10.1021/jacs.1c01622openalex-snapshot

Site-Selective Csp3–Csp/Csp3–Csp2 Cross-Coupling Reactions Using Frustrated Lewis Pairs

inferred← citeshttps://doi.org/10.1021/jacs.3c05278openalex-snapshot

Borane-Catalyzed C–F Bond Functionalization of gem-Difluorocyclopropenes Enables the Synthesis of Orphaned Cyclopropanes

inferred← citeshttps://doi.org/10.1021/jacs.3c08373openalex-snapshot

Deoxyfluorination of 1°, 2°, and 3° Alcohols by Nonbasic O–H Activation and Lewis Acid-Catalyzed Fluoride Shuttling

inferred← citeshttps://doi.org/10.1021/jacs.4c03133openalex-snapshot

Precise Distance Control and Functionality Adjustment of Frustrated Lewis Pairs in Metal–Organic Frameworks

inferred← citeshttps://doi.org/10.1021/jacs.4c07818openalex-snapshot

Frustrated Lewis Pair-Promoted Organocatalytic Transformation of Hydrosilanes into Silanols with Water Oxidant

inferred← citeshttps://doi.org/10.1021/jacs.4c14596openalex-snapshot

Selective Reduction of Esters to Access Aldehydes Using Fiddler Crab-Type Boranes

inferred← citeshttps://doi.org/10.1021/jacs.4c15892openalex-snapshot

Monodentate σ-Accepting Boron-Based Ligands Bearing Square-Planar Ni(0) Centers

inferred← citeshttps://doi.org/10.1021/jacs.5c13835openalex-snapshot

Borane/Transition Metal–Catalyzed Allenylic and Allylic Alkylation of Unactivated 2-Alkylbenzoxazoles

inferred← citeshttps://doi.org/10.1021/jacsau.5c00196openalex-snapshot

Organocatalyzed Enantioselective C–N Bond-Forming S N Ar Reactions for Synthesizing Stereogenic-at-Boron BODIPYs

inferred← citeshttps://doi.org/10.1038/s41467-024-47984-0openalex-snapshot

In-silico-assisted derivatization of triarylboranes for the catalytic reductive functionalization of aniline-derived amino acids and peptides with H2

inferred← citeshttps://doi.org/10.1038/s41467-025-66712-wopenalex-snapshot

Catalytic photoinduced deoxygenation via B(C6F5)3-enabled oxygen atom transfer for aromatic C–H amination of alkylarenes

inferred← citeshttps://doi.org/10.1039/d0cy01339kopenalex-snapshot

Triarylborane catalysed N -alkylation of amines with aryl esters

inferred← citeshttps://doi.org/10.1039/d0ob01721copenalex-snapshot

Transition metal-free synthesis of alkyl pinacol boronates

inferred← citeshttps://doi.org/10.1039/d0ob02478copenalex-snapshot

Tris(pentafluorophenyl)borane catalyzed C–C and C–heteroatom bond formation

inferred← citeshttps://doi.org/10.1039/d0sc03712eopenalex-snapshot

Defunctionalisation catalysed by boron Lewis acids

inferred← citeshttps://doi.org/10.1039/d1cc01856fopenalex-snapshot

Borane catalysed cyclopropenation of arylacetylenes

inferred← citeshttps://doi.org/10.1039/d1cc03873gopenalex-snapshot

A strongly Lewis-acidic and fluorescent borenium cation supported by a tridentate formazanate ligand

inferred← citeshttps://doi.org/10.1039/d1cc06225eopenalex-snapshot

Nucleophilic borylation of fluorobenzenes with reduced arylboranes

inferred← citeshttps://doi.org/10.1039/d1dt00747eopenalex-snapshot

Interaction of dicoordinate phosphorus with boranes: chemistry of 3a,6a-diaza-1,4-diphosphapentalene as masked phosphinidene

inferred← citeshttps://doi.org/10.1039/d1dt03884bopenalex-snapshot

Formation of cyclic (boryl)iminomethane derivatives by the insertion of isocyanides into a boron–carbon bond

inferred← citeshttps://doi.org/10.1039/d1sc02409dopenalex-snapshot

One- and two-electron reduction of triarylborane-based helical donor–acceptor compounds

inferred← citeshttps://doi.org/10.1039/d1sc02937aopenalex-snapshot

Pyrimidine-directed metal-free C–H borylation of 2-pyrimidylanilines: a useful process for tetra-coordinated triarylborane synthesis

inferred← citeshttps://doi.org/10.1039/d1sc06404eopenalex-snapshot

A free boratriptycene-type Lewis superacid

inferred← citeshttps://doi.org/10.1039/d1sc07065gopenalex-snapshot

Primary trifluoroborate-iminiums enable facile access to chiral α-aminoboronic acids via Ru-catalyzed asymmetric hydrogenation and simple hydrolysis of the trifluoroborate moiety

inferred← citeshttps://doi.org/10.1039/d2cc02933bopenalex-snapshot

Phosphinoborinium cation: a synthon for cationic B–P bond systems

inferred← citeshttps://doi.org/10.1039/d2cc06075bopenalex-snapshot

Structure and reactivity studies of the aluminum analogue of Piers’ borane [HAl(C 6 F 5 ) 2 ] 3

inferred← citeshttps://doi.org/10.1039/d2cc06584copenalex-snapshot

Synthesis of triarylborane-centered N-heterocyclic carbene cages with tunable photophysical properties

inferred← citeshttps://doi.org/10.1039/d2cy01441fopenalex-snapshot

Chemo- and regio-selective amidation of indoles with isocyanates using borane Lewis acids

inferred← citeshttps://doi.org/10.1039/d2dt00586gopenalex-snapshot

para -Chlorotetrafluorophenyl-boranes – syntheses and structures of a series of mono- and bidentate Lewis acids

inferred← citeshttps://doi.org/10.1039/d2dt01193jopenalex-snapshot

A deprotonation pathway to reactive [B]CH 2 boraalkenes

inferred← citeshttps://doi.org/10.1039/d2dt04095fopenalex-snapshot

Synthesis and lewis acidity of fluorinated triaryl borates

inferred← citeshttps://doi.org/10.1039/d2qo00552bopenalex-snapshot

Borane-catalyzed dehydrogenative C–C bond formation of indoles with N -tosylhydrazones: an experimental and computational study

inferred← citeshttps://doi.org/10.1039/d2re00123copenalex-snapshot

Convenient and accurate insight into solution-phase equilibria from FlowNMR titrations

inferred← citeshttps://doi.org/10.1039/d3cc05440copenalex-snapshot

The Lewis superacidic aluminium cation: [(NHC)Al(C 6 F 5 ) 2 ] +

inferred← citeshttps://doi.org/10.1039/d3cs00267eopenalex-snapshot

Experimental and computational aspects of molecular frustrated Lewis pairs for CO 2 hydrogenation: en route for heterogeneous systems?

inferred← citeshttps://doi.org/10.1039/d3dt00745fopenalex-snapshot

B(3,4,5-F 3 H 2 C 6 ) 3 Lewis acid-catalysed C3-allylation of indoles

inferred← citeshttps://doi.org/10.1039/d3dt01557bopenalex-snapshot

Examining the reactivity of tris( ortho -carboranyl)borane with Lewis bases and application in frustrated Lewis pair Si–H bond cleavage

inferred← citeshttps://doi.org/10.1039/d3dt03660jopenalex-snapshot

Coordination chemistry and FLP reactivity of 1,1- and 1,2-bis-boranes

inferred← citeshttps://doi.org/10.1039/d3qo00054kopenalex-snapshot

B(C 6 F 5 ) 3 -catalyzed Wolff rearrangement/[2 + 2] and [4 + 2] cascade cyclization of α-diazoketones with imines

inferred← citeshttps://doi.org/10.1039/d3qo00737eopenalex-snapshot

Consecutive regulation of catalytic activities of B(C 6 F 5 ) 3 ·H 2 O: direct nucleophilic substitution of benzyl fluorides with alcohol via dual activation

inferred← citeshttps://doi.org/10.1039/d3qo00944kopenalex-snapshot

Boron Lewis acid-catalyzed formal insertion of isocyanides into a C–O bond of benzyl esters

inferred← citeshttps://doi.org/10.1039/d3qo01617jopenalex-snapshot

A catalyst-free cross-coupling of isocyanates and triarylboranes for secondary amide synthesis

inferred← citeshttps://doi.org/10.1039/d3qo01637dopenalex-snapshot

B(C 6 F 5 ) 3 -catalyzed stepwise 1,5-hydride migration/cyclization: diastereoselective construction of carbocyclic β-amino acid derivatives

inferred← citeshttps://doi.org/10.1039/d3sc00037kopenalex-snapshot

An easy-to-perform evaluation of steric properties of Lewis acids

inferred← citeshttps://doi.org/10.1039/d3sc00917copenalex-snapshot

Planar bismuth triamides: a tunable platform for main group Lewis acidity and polymerization catalysis

inferred← citeshttps://doi.org/10.1039/d3sc01394dopenalex-snapshot

Atom-economic and stereoselective catalytic synthesis of fully substituted enol esters/carbonates of amides in acyclic systems enabled by boron Lewis acid catalysis

inferred← citeshttps://doi.org/10.1039/d3sc05071hopenalex-snapshot

Rapid, iterative syntheses of unsymmetrical di- and triarylboranes from crystalline aryldifluoroboranes

inferred← citeshttps://doi.org/10.1039/d4cc01059kopenalex-snapshot

Unlocking Lewis acidity via the redox non-innocence of a phenothiazine-substituted borane

inferred← citeshttps://doi.org/10.1039/d4cc04490hopenalex-snapshot

Reactivity of N -(isocyanoimino)triphenylphosphorane toward group 13 Lewis acids

inferred← citeshttps://doi.org/10.1039/d4nr02220copenalex-snapshot

A gel polymer electrolyte functionalized separator for high-performance lithium–sulfur batteries

inferred← citeshttps://doi.org/10.1039/d4sc06144fopenalex-snapshot

Structure-constraint induced increase in Lewis acidity of tris( ortho -carboranyl)borane and selective complexation with Bestmann ylides

inferred← citeshttps://doi.org/10.1039/d5cc01555copenalex-snapshot

Oxidative addition of diaryldichalcogenides to the diferrocenylphosphenium ion: synthesis, structure and organocatalytic activity

inferred← citeshttps://doi.org/10.1039/d5cc02299aopenalex-snapshot

Müller versus Gutmann–Beckett for assessing the Lewis acidity of boranes

inferred← citeshttps://doi.org/10.1039/d5cc02623gopenalex-snapshot

Group 13 Lewis acid-mediated formation of 5-oxazolone derivatives from tert -butyl isocyanoacetate

inferred← citeshttps://doi.org/10.1039/d5cc05893gopenalex-snapshot

Recent advances in transition-metal-free deconstructive functionalization of saturated N-, O-, P-, and S-heterocycles

inferred← citeshttps://doi.org/10.1039/d5cp00867kopenalex-snapshot

Three-fold aromatic boranes: spherical aromaticity in borane ortho -carboranes as useful trimer nodes for cluster-based architectures

inferred← citeshttps://doi.org/10.1039/d5cs01242bopenalex-snapshot

Recent research progress on organoboron-based stimuli responsive materials

inferred← citeshttps://doi.org/10.1039/d5py00783fopenalex-snapshot

Synthesis of sterically unhindered Lewis acidic boron-doped π-conjugated polymers

inferred← citeshttps://doi.org/10.1039/d5qo00863hopenalex-snapshot

B(C 6 F 5 ) 3 -catalyzed TMSOTf-assisted intermolecular redox-neutral cyclization of N , N -dialkyl arylamines and allylic esters

inferred← citeshttps://doi.org/10.1039/d6cp02860hopenalex-snapshot

Chiroptical absorption and emission properties of chiral triarylboranes

inferred← citeshttps://doi.org/10.1055/a-1701-7679openalex-snapshot

Synthesis and Applications of Chiral Bicyclic Bisborane Catalysts

inferred← citeshttps://doi.org/10.1055/a-2005-5443openalex-snapshot

Frustrated Lewis Pair Catalyzed Reactions

inferred← citeshttps://doi.org/10.1055/a-2110-5359openalex-snapshot

Remote Back Strain: A Strategy for Modulating the Reactivity of Triarylboranes

inferred← citeshttps://doi.org/10.1055/a-2118-3046openalex-snapshot

Activation of Diazo Compounds by Fluorinated Triarylborane Catalysts

inferred← citeshttps://doi.org/10.1055/s-0043-1775394openalex-snapshot

Recent Trends in Triarylborane Chemistry: Diversification of Structures and Reactivity via meta-Substitution of the Aryl Groups

inferred← citeshttps://doi.org/10.1080/01614940.2024.2334462openalex-snapshot

The organoboron compounds: their Lewis acidity and catalytic activity

inferred← citeshttps://doi.org/10.1080/10408347.2024.2324299openalex-snapshot

Mechanistic Insight Into the Reactivity of Frustrated Lewis Pairs: Liquid-State NMR Studies

inferred← citeshttps://doi.org/10.1134/s0022476625020040openalex-snapshot

Donor-Acceptor Complexes of the Lewis Acid Ga[N(C6F5)2]3 with Pyridine and Diethyl Ether

inferred← citeshttps://doi.org/10.20517/cs.2021.11openalex-snapshot

Future prospects in boron chemistry: new boron compounds and Lewis acids for catalysis and materials science

inferred← citeshttps://doi.org/10.2139/ssrn.4906560openalex-snapshot

C3-Symmetric Triarylboron Building Blocks: Synthesis, Structures, and Photophysical Properties

inferred← citeshttps://doi.org/10.26434/chemrxiv-2023-3mwbdopenalex-snapshot

In-Silico-Assisted Derivatization of Triarylboranes for the Catalytic Reductive Functionalization of Amino Acids with H2

inferred← citeshttps://doi.org/10.3390/molecules28020642openalex-snapshot

Recent Advances in Asymmetric Catalysis Associated with B(C6F5)3

inferred← citeshttps://doi.org/10.5059/yukigoseikyokaishi.82.1097openalex-snapshot

Triarylborane Catalysis: From Hydrogenation of Unsaturated Molecules to H2 Purification

inferred← citeshttps://doi.org/10.71267/mencom.7575openalex-snapshot

Promising route to aryl(polyfluoroorganyl)borates: aryltris(pentafluorophenyl)borates

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