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Mn 2 (CO) 10 and UV light: a promising combination for regioselective alkene hydrosilylation at low temperature

https://doi.org/10.1039/d2cc00377e
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/adsc.202100151openalex-snapshot
Visible‐Light‐Induced Manganese‐Catalyzed Reactions: Present Approach and Future Prospects
inferredcites →https://doi.org/10.1002/anie.201710206openalex-snapshot
Dichotomy of Manganese Catalysis via Organometallic or Radical Mechanism: Stereodivergent Hydrosilylation of Alkynes
inferredcites →https://doi.org/10.1002/anie.201805483openalex-snapshot
Manganese‐Catalyzed Hydrofunctionalization of Alkenes
inferredcites →https://doi.org/10.1002/cjoc.201800314openalex-snapshot
Recent Advances in Hydrometallation of Alkenes and Alkynes via the First Row Transition Metal Catalysis
inferredcites →https://doi.org/10.1002/ejoc.201600018openalex-snapshot
Recent Advances of Manganese Catalysis for Organic Synthesis
inferredcites →https://doi.org/10.1007/978-1-4020-8172-9openalex-snapshot
Hydrosilylation : a comprehensive review on recent advances
inferredcites →https://doi.org/10.1016/j.ccr.2010.12.025openalex-snapshot
Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view
inferredcites →https://doi.org/10.1016/j.jorganchem.2012.11.028openalex-snapshot
Selective hydrosilylation of allyl esters with octahydridosilsesquioxane
inferredcites →https://doi.org/10.1021/acs.joc.0c01439openalex-snapshot
Developing a Highly Active Catalytic System Based on Cobalt Nanoparticles for Terminal and Internal Alkene Hydrosilylation
inferredcites →https://doi.org/10.1021/acs.organomet.6b00785openalex-snapshot
Half-Sandwich Manganese Complexes Bearing Cp Tethered N-Heterocyclic Carbene Ligands: Synthesis and Mechanistic Insights into the Catalytic Ketone Hydrosilylation
inferredcites →https://doi.org/10.1021/acs.orglett.7b01657openalex-snapshot
Transfer Hydrogenation of Carbonyl Derivatives Catalyzed by an Inexpensive Phosphine-Free Manganese Precatalyst
inferredcites →https://doi.org/10.1021/acs.orglett.9b00701openalex-snapshot
Visible-Light-Initiated Manganese-Catalyzed E-Selective Hydrosilylation and Hydrogermylation of Alkynes
inferredcites →https://doi.org/10.1021/acscatal.6b00304openalex-snapshot
Bench-Stable, Substrate-Activated Cobalt Carboxylate Pre-Catalysts for Alkene Hydrosilylation with Tertiary Silanes
inferredcites →https://doi.org/10.1021/acscatal.6b01134openalex-snapshot
Alkene Hydrosilylation Using Tertiary Silanes with α-Diimine Nickel Catalysts. Redox-Active Ligands Promote a Distinct Mechanistic Pathway from Platinum Catalysts
inferredcites →https://doi.org/10.1021/cs300584bopenalex-snapshot
High-Selectivity Bis(imino)pyridine Iron Catalysts for the Hydrosilylation of 1,2,4-Trivinylcyclohexane
inferredcites →https://doi.org/10.1021/ja046753topenalex-snapshot
Preparation and Molecular and Electronic Structures of Iron(0) Dinitrogen and Silane Complexes and Their Application to Catalytic Hydrogenation and Hydrosilation
inferredcites →https://doi.org/10.1021/jacs.6b02032openalex-snapshot
Ph( i -PrO)SiH 2 : An Exceptional Reductant for Metal-Catalyzed Hydrogen Atom Transfers
inferredcites →https://doi.org/10.1021/jacs.9b08832openalex-snapshot
Direct Synthesis of Cycloalkanes from Diols and Secondary Alcohols or Ketones Using a Homogeneous Manganese Catalyst
inferredcites →https://doi.org/10.1021/jm3010114openalex-snapshot
Organosilicon Molecules with Medicinal Applications
inferredcites →https://doi.org/10.1038/s41557-020-00589-8openalex-snapshot
Manganese-catalysed divergent silylation of alkenes
inferredcites →https://doi.org/10.1039/c0cs00136hopenalex-snapshot
Applications of advanced hybrid organic–inorganic nanomaterials: from laboratory to market
inferredcites →https://doi.org/10.1039/c2dt31339aopenalex-snapshot
Well-defined NHC-rhodium hydroxide complexes as alkenehydrosilylation and dehydrogenative silylation catalysts
inferredcites →https://doi.org/10.1039/c3cc45349aopenalex-snapshot
Selective reduction of carboxylic acids to aldehydes through manganese catalysed hydrosilylation
inferredcites →https://doi.org/10.1039/d0cc03580gopenalex-snapshot
Manganese and rhenium-catalyzed selective reduction of esters to aldehydes with hydrosilanes
inferredcites →https://doi.org/10.1039/d0dt03698fopenalex-snapshot
A family of rhodium( i ) NHC chelates featuring O-containing tethers for catalytic tandem alkene isomerization–hydrosilylation
inferredcites →https://doi.org/10.1080/15287399009531407openalex-snapshot
Teratogenicity of metals to chick embryos
inferredcites →https://doi.org/10.1134/s1070363210040079openalex-snapshot
Effect of catalysts on the reaction of allyl esters with hydrosilanes

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4581369openalex-extracted
Anti-Markovnikov Hydrosilylation and Markovnikov Hydroboration of Alkenes by a Phenanthroline-Based Tridentate Manganese(Ii) Catalyst
inferred← citeshttps://doi.org/10.1002/chem.202401440openalex-snapshot
Hydrosilylation of Arynes with Silanes and Silicon‐Based Polymer
inferred← citeshttps://doi.org/10.1016/j.cej.2024.150580openalex-snapshot
Visible-light-initiated air-oxygenation of 5-hydroxymethylfurfural to maleic acid by iron(III) chloride
inferred← citeshttps://doi.org/10.1016/j.inoche.2023.111488openalex-snapshot
Review on catalytic significance of 3d-transition metal-carbonyl complexes for general and selective organic reactions
inferred← citeshttps://doi.org/10.1016/j.inoche.2026.117690openalex-snapshot
Synthesis of substituted silicone-rubber monomers via alkene hydrosilylation using transition metal-complex catalysts
inferred← citeshttps://doi.org/10.1016/j.jcat.2023.115197openalex-snapshot
Anti-Markovnikov hydrosilylation and Markovnikov hydroboration of alkenes by a phenanthroline-based tridentate manganese catalyst
inferred← citeshttps://doi.org/10.1016/j.jcat.2023.115269openalex-snapshot
White-Light initiated Mn2(CO)10/HFIP-Catalyzed anti-Markovnikov hydrosilylation of alkenes
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2025.123579openalex-snapshot
Highly regioselective anti-Markovnikov hydrosilylation of alkenes under mild conditions: Application of CCC-NHC pincer Rh complexes
inferred← citeshttps://doi.org/10.1016/j.tetlet.2023.154798openalex-snapshot
Recent developments in alkene hydrosilylation utilizing manganese catalysts
inferred← citeshttps://doi.org/10.1016/j.xcrp.2023.101313openalex-snapshot
Manganese-catalyzed dehydrogenative coupling of silanes and hydroxyl compound controlled by phosphine oxide
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c03936openalex-snapshot
A General Procedure for the Construction of 2-Alkyl-Substituted Vinyl Sulfonyl Fluoride
inferred← citeshttps://doi.org/10.1021/acscatal.4c01353openalex-snapshot
Platinum(II) Phenylpyridyl Schiff Base Complexes as Latent, Photoactivated, Alkene Hydrosilylation Catalysts
inferred← citeshttps://doi.org/10.1021/acscatal.5c04086openalex-snapshot
Mn-Catalyzed Regioselective Alkene Hydrosilylation: From Mechanism Investigation to the Design of a Pre-Catalyst Candidate
inferred← citeshttps://doi.org/10.1021/acsomega.2c05109openalex-snapshot
Homogeneous Manganese-Catalyzed Hydrofunctionalizations of Alkenes and Alkynes: Catalytic and Mechanistic Tendencies
inferred← citeshttps://doi.org/10.1021/jacs.5c16761openalex-snapshot
Femtosecond-to-Second Time-Resolved Spectroscopy Brings Unparalleled Insight Into the Life Cycle of the Versatile Manganese Photocatalyst [Mn 2 (CO) 10 ]
inferred← citeshttps://doi.org/10.1038/s41467-026-68837-yopenalex-snapshot
Evolution of manganese low-energy photoredox catalysis from high-energy visible light photocatalysis
inferred← citeshttps://doi.org/10.1038/s41467-026-70925-yopenalex-snapshot
Photoinduced Mn catalysis for efficient platform for C-heteroatom bond coupling of aryl halides
inferred← citeshttps://doi.org/10.1039/d2cc05021hopenalex-snapshot
Visible-light-induced Mn(0)-catalyzed direct C-3 mono-, di- and perfluoroalkylation reactions of 2 H -indazoles
inferred← citeshttps://doi.org/10.1039/d3gc00712jopenalex-snapshot
Visible light-initiated manganese-catalyzed hydrosulfonylation of alkenes
inferred← citeshttps://doi.org/10.1039/d3gc02385kopenalex-snapshot
MnBr(CO) 5 : a commercially available highly active catalyst for olefin hydrosilylation under ambient air and green conditions
inferred← citeshttps://doi.org/10.1039/d4md00169aopenalex-snapshot
The role of silicon in drug discovery: a review
inferred← citeshttps://doi.org/10.1039/d4ra08380fopenalex-snapshot
Recyclable and air-stable colloidal manganese nanoparticles catalyzed hydrosilylation of alkenes with tertiary silane
inferred← citeshttps://doi.org/10.1039/d5nj01460copenalex-snapshot
Improvement of regioselectivity of alkene hydrosilylation catalyzed by [PNSiNP] pincer cobalt( iii ) hydrides using sodium methoxide as an additive
inferred← citeshttps://doi.org/10.1039/d5qo00102aopenalex-snapshot
Photo and earth-abundant metal dual catalysis in organic synthesis
inferred← citeshttps://doi.org/10.1055/a-2779-7857openalex-snapshot
Mn(CO)5Br-Catalyzed Hydrosilation of Alkene with Hydrosiloxanes and Hydrogen-Containing Silicone Oil
inferred← citeshttps://doi.org/10.20517/cs.2023.32openalex-snapshot
Recent progress of decacarbonyldimanganese catalysis
inferred← citeshttps://doi.org/10.6023/cjoc202302031openalex-snapshot
Progress in Photocatalytic Hydrosilylation
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