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Genuine quadruple bonds between two main-group atoms. Chemical bonding in AeF − (Ae = Be–Ba) and isoelectronic EF (E = B–Tl) and the particular role of d orbitals in covalent interactions of heavier alkaline-earth atoms

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Outgoing claims: the papers this work cites, builds on, or argues with.

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Relativistic Effects on Donor–Acceptor Interactions in Coinage Metal Carbonyl Complexes [TM(CO)n]+ (TM=Cu, Ag, Au; n=1, 2)
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NBO 7.0 : New vistas in localized and delocalized chemical bonding theory
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Electric dipole polarity of diatomic molecules
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Infrared Emission Spectroscopy of BF and AlF
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Gilbert Lewis and the Model of Dative Bonding
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Molecular Spectra and Molecular Structure
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Multiple Bonds Between Metal Atoms
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Ab initio calculations of infrared transition probabilities in the electronic ground states of AlF and AlF+
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Applications of natural orbitals for chemical valence in a description of bonding in conjugated molecules
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Some recent advances in the chemistry of silicon and its homologues in low coordination states
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Statistical Exchange-Correlation in the Self-Consistent Field
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Transition-Metal Chemistry of the Heavier Alkaline Earth Atoms Ca, Sr, and Ba
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NHCs in Main Group Chemistry
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Chemical Bonding and Bonding Models of Main-Group Compounds
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Bonding in Binuclear Carbonyl Complexes M2(CO)9(M = Fe, Ru, Os)
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Quantum Interference Contribution to the Dipole Moment of Diatomic Molecules
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The Nature of the Chemical Bond in BeF– and Related Species
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Dative Bonding between Closed-Shell Atoms: The BeF– Anion
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Observation of Four-Fold Boron–Metal Bonds in RhB(BO – ) and RhB
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Structure of Divalent Carbon Compounds.
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The Nature of the Bonding in Transition-Metal Compounds
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Insights into the Perplexing Nature of the Bonding in C2 from Generalized Valence Bond Calculations
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OCBBCO: A Neutral Molecule with Some Boron−Boron Triple Bond Character
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The [2 + 4] Diels−Alder Cycloadditon Product of a Probable Dialuminene, Ar‘AlAlAr‘ (Ar‘ = C6H3- 2,6-Dipp2; Dipp = C6H3-2,6-Pri2), with Toluene
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The Electronic Theory of Valency
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Octa-coordinated alkaline earth metal–dinitrogen complexes M(N2)8 (M=Ca, Sr, Ba)
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Triple bonding between beryllium and nitrogen in HNBeCO
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Microwave Spectrum of BF
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What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Multiple Bonding in AeN− (Ae=Ca, Sr, Ba)
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Chemical Bonds in Molecules Are Covalent but Not Ionic
inferred← citeshttps://doi.org/10.1021/acs.jpca.4c02711openalex-snapshot
B3H3Be ← F–: A Case of Extremely Strong Dative Bond
inferred← citeshttps://doi.org/10.1021/acs.jpca.4c05641openalex-snapshot
Systematic Study of Hard-Wall Confinement-Induced Effects on Atomic Electronic Structure
inferred← citeshttps://doi.org/10.1021/acs.jpca.4c06334openalex-snapshot
Ab Initio Structure and Dynamics of Beryllium Monofluoride and Its Anion
inferred← citeshttps://doi.org/10.1021/jacs.4c03977openalex-snapshot
Exploring the Use of “Honorary Transition Metals” To Push the Boundaries of Planar Hypercoordinate Alkaline-Earth Metals
inferred← citeshttps://doi.org/10.1021/jacs.5c04320openalex-snapshot
Monomeric Two-coordinate Beryllium Imido and Boryloxide Complexes Featuring Be–N and Be–O Triple Bonds
inferred← citeshttps://doi.org/10.1021/jacsau.6c01036openalex-snapshot
Electron-Reservoir Multiple Bond in RhC– for Dinitrogen Cleavage
inferred← citeshttps://doi.org/10.1038/s41467-023-43208-zopenalex-snapshot
The unusual quadruple bonding of nitrogen in ThN
inferred← citeshttps://doi.org/10.1039/d3cp01096aopenalex-snapshot
Probing the local structure of FLiBe melts and solidified salts by in situ high-temperature NMR
inferred← citeshttps://doi.org/10.1039/d4cp00468jopenalex-snapshot
Planar tetracoordinate beryllium compounds with a partially covalent Be–Ng bond
inferred← citeshttps://doi.org/10.1039/d4cp01778aopenalex-snapshot
Chemical bonding misnomer in AeF − (Ae = Be–Ca) anions
inferred← citeshttps://doi.org/10.1039/d4cp01909aopenalex-snapshot
The strongest dative bond in main-group compounds. Theoretical study of OAeF − (Ae = Be–Ba)
inferred← citeshttps://doi.org/10.1039/d4cp04332dopenalex-snapshot
Exploring the bonding in alkaline earth halides AeX − (Ae = Be–Ba, X = F–I) from Fermi hole localization and QTAIM perspectives
inferred← citeshttps://doi.org/10.1039/d4qi03234aopenalex-snapshot
Synthesis and characterization of neutral and cationic 1-tris(pyrazolyl)borate organo-beryllium complexes
inferred← citeshttps://doi.org/10.1039/d4ra03345kopenalex-snapshot
Computational modelling of graphene/aluminum nitride (GP/AlN) hybrid materials for the detection of 2,4 dichlorophenoxyacetic acid (DCP) pollutant
inferred← citeshttps://doi.org/10.1039/d4sc01979bopenalex-snapshot
Unusual quadruple bonds featuring collective interaction-type σ bonds between first octal-row atoms in the alkaline-earth compounds AeOLi 2 (Ae = Be–Ba)
inferred← citeshttps://doi.org/10.1039/d5cp03025kopenalex-snapshot
Electronic structure and chemical bonding of the MoBe molecule
inferred← citeshttps://doi.org/10.1039/d5cp03285gopenalex-snapshot
Strong beryllium–beryllium bonds
inferred← citeshttps://doi.org/10.1039/d5dt02876kopenalex-snapshot
Beryllium gets going, finally. Recent highlights in the organometallic chemistry of beryllium
inferred← citeshttps://doi.org/10.1039/d5sc08399kopenalex-snapshot
Dinitrogen complexes N 2 L 2 (L = N 2 , CO, CS, NO + , CN − )
inferred← citeshttps://doi.org/10.1063/5.0181343openalex-snapshot
BeM(CO)3− (M = Co, Rh, Ir) and BeM(CO)3 (M = Ni, Pd, Pt): Triply bonded terminal beryllium in zero oxidation state
inferred← citeshttps://doi.org/10.1063/5.0199318openalex-snapshot
How electrons still guard the space: Electron number distribution functions based on QTAIM∩ELF intersections
inferred← citeshttps://doi.org/10.1080/00268976.2025.2531237openalex-snapshot
Chemical bonding in N 2 O and N 3 H*
inferred← citeshttps://doi.org/10.1088/1361-6455/ae5ffdopenalex-snapshot
Elastic and inelastic cross sections for electron scattering from BeF
inferred← citeshttps://doi.org/10.26434/chemrxiv-2025-wzn23openalex-snapshot
Janus-Faced Reactivity of Heterobimetallic Al–Zn Complexes
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