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Recent Progress and Emerging Technologies towards a Sustainable Synthesis of Sulfones

https://doi.org/10.1002/cssc.202101635

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Sulphones and Sulphoxides (1988)

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1,4-Disulfino-1,4-diazabicyclo [2.2.2]octane, bis(inner salt)

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Green Oxidation in Organic Synthesis

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Visible Light‐Mediated Metal‐Free Synthesis of Vinyl Sulfones from Aryl Sulfinates

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Copper‐Mediated Sulfonylation of Aryl C(sp2)H Bonds with Sodium and Lithium Sulfinates

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Copper‐Catalyzed Remote C−H Functionalization of 8‐Aminoquinolines with Sodium and Lithium Sulfinates

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Metal‐Free Iodosulfonylation of Internal Alkynes: Stereodefined Access to Tetrasubstituted Olefins

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Iodine‐Triggered Aerobic Oxysulfonylation of Styrenes

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Photoredox Catalysis in C–S Bond Construction: Recent Progress in Photo‐Catalyzed Formation of Sulfones and Sulfoxides

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Synthesis of Chiral Sulfonyl Lactones via Copper‐Catalyzed Asymmetric Radical Reaction of DABCO⋅(SO2)

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A Three‐Component Reaction of Aryldiazonium Tetrafluoroborates, Sulfur Dioxide, and 1‐(Prop‐2‐yn‐1‐yl)indoles under Catalyst‐Free Conditions

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Recent Advances in Transition‐Metal‐Mediated Chelation‐ Assisted Sulfonylation of Unactivated C−H Bonds

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Electrochemical Three‐Component 1,2‐Aminosulfonylation of Alkenes: Entry to 2‐sulfonylethan‐1‐amines

inferredcites →https://doi.org/10.1002/adsc.201901321openalex-snapshot

Metal Free Sulfonylative Spirocyclization of Alkenyl and Alkynyl Amides via Insertion of Sulfur Dioxide

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Electrochemical Sulfonylation of Alkynes with Sulfonyl Hydrazides: A Metal‐ and Oxidant‐Free Protocol for the Synthesis of Alkynyl Sulfones

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Sulfonyl Hydrazides in Organic Synthesis: A Review of Recent Studies

inferredcites →https://doi.org/10.1002/adsc.202000995openalex-snapshot

Metal‐Free, Multicomponent Anti‐Markovnikov Hydroarylsulfonylation and Alkoxyarylsulfonylation of Vinyl Arenes

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The Development and Application of Sulfur Dioxide Surrogates in Synthetic Organic Chemistry

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Iodine‐Mediated Sulfonylation of Quinoline N‐Oxides: a Mild and Metal‐Free One‐Pot Synthesis of 2‐Sulfonyl Quinolines

inferredcites →https://doi.org/10.1002/ajoc.201800644openalex-snapshot

N‐Iodosuccinimide as Bifunctional Reagent in (E)‐Selective C(sp2)−H Sulfonylation of Styrenes

inferredcites →https://doi.org/10.1002/ajoc.201900447openalex-snapshot

Electrochemical Oxidative C−H Sulfonylation of Anilines

inferredcites →https://doi.org/10.1002/ajoc.202000668openalex-snapshot

Direct C(sp3)−H Sulfonylation and Sulfuration Reactions of Isoquinoline‐1,3(2H,4H)‐diones under Metal‐free Conditions

inferredcites →https://doi.org/10.1002/ange.19740861106openalex-snapshot

Darstellung und Reaktionen von Trifluormethansulfonsäure‐sulfonsäure‐anhydriden

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Oxidative Halogenierungen mit umweltschonenden Oxidationsmitteln: Sauerstoff und Wasserstoffperoxid

inferredcites →https://doi.org/10.1002/ange.200904510openalex-snapshot

BTB‐1, ein niedermolekularer Inhibitor des mitotischen Motorproteins Kif18A

inferredcites →https://doi.org/10.1002/ange.201005489openalex-snapshot

Carbon–Sulfur Reductive Elimination from Palladium(IV) Sulfinate Complexes

inferredcites →https://doi.org/10.1002/ange.201301634openalex-snapshot

Aerobic Oxysulfonylation of Alkenes Leading to Secondary and Tertiary β‐Hydroxysulfones

inferredcites →https://doi.org/10.1002/ange.201310634openalex-snapshot

Aerobic Oxidation in Nanomicelles of Aryl Alkynes, in Water at Room Temperature

inferredcites →https://doi.org/10.1002/ange.201607292openalex-snapshot

Generation of Sulfonyl Radicals from Aryldiazonium Tetrafluoroborates and Sulfur Dioxide: The Synthesis of 3‐Sulfonated Coumarins

inferredcites →https://doi.org/10.1002/ange.201610000openalex-snapshot

Markovnikov‐Selective Radical Addition of S‐Nucleophiles to Terminal Alkynes through a Photoredox Process

inferredcites →https://doi.org/10.1002/ange.201707791openalex-snapshot

Hydrosulfonylation Reaction with Arenesulfonyl Chlorides and Tetrahydrofuran: Conversion of Terminal Alkynes into Cyclopentylmethyl Sulfones

inferredcites →https://doi.org/10.1002/ange.202004070openalex-snapshot

Hydrosulfonylation of Alkenes with Sulfonyl Chlorides under Visible Light Activation

inferredcites →https://doi.org/10.1002/anie.197404091openalex-snapshot

Preparation and Reactions of Trifluoromethanesulfonic Arenesulfonic Anhydrides

inferredcites →https://doi.org/10.1002/anie.200901223openalex-snapshot

Oxidative Halogenation with “Green” Oxidants: Oxygen and Hydrogen Peroxide

inferredcites →https://doi.org/10.1002/anie.200904510openalex-snapshot

BTB‐1: A Small Molecule Inhibitor of the Mitotic Motor Protein Kif18A

inferredcites →https://doi.org/10.1002/anie.201005489openalex-snapshot

Carbon–Sulfur Reductive Elimination from Palladium(IV) Sulfinate Complexes

inferredcites →https://doi.org/10.1002/anie.201301634openalex-snapshot

Aerobic Oxysulfonylation of Alkenes Leading to Secondary and Tertiary β‐Hydroxysulfones

inferredcites →https://doi.org/10.1002/anie.201309851openalex-snapshot

Metal‐Free Aminosulfonylation of Aryldiazonium Tetrafluoroborates with DABCO⋅(SO 2 ) 2 and Hydrazines

inferredcites →https://doi.org/10.1002/anie.201310634openalex-snapshot

Aerobic Oxidation in Nanomicelles of Aryl Alkynes, in Water at Room Temperature

inferredcites →https://doi.org/10.1002/anie.201607292openalex-snapshot

Generation of Sulfonyl Radicals from Aryldiazonium Tetrafluoroborates and Sulfur Dioxide: The Synthesis of 3‐Sulfonated Coumarins

inferredcites →https://doi.org/10.1002/anie.201610000openalex-snapshot

Markovnikov‐Selective Radical Addition of S‐Nucleophiles to Terminal Alkynes through a Photoredox Process

inferredcites →https://doi.org/10.1002/anie.201707791openalex-snapshot

Hydrosulfonylation Reaction with Arenesulfonyl Chlorides and Tetrahydrofuran: Conversion of Terminal Alkynes into Cyclopentylmethyl Sulfones

inferredcites →https://doi.org/10.1002/anie.202004070openalex-snapshot

Hydrosulfonylation of Alkenes with Sulfonyl Chlorides under Visible Light Activation

inferredcites →https://doi.org/10.1002/aoc.4553openalex-snapshot

Reusable BNPs‐SiO2@(CH2)3NHSO3H‐catalysed selective oxidation of sulfides to sulfones

inferredcites →https://doi.org/10.1002/asia.201500498openalex-snapshot

Visible‐Light Photoredox Catalysis: Direct Synthesis of Sulfonated Oxindoles from N‐Arylacrylamides and Arylsulfinic Acids by Means of a Cascade C−S/C−C Formation Process

inferredcites →https://doi.org/10.1002/asia.201501407openalex-snapshot

Remote C−H Activation of Quinolines through Copper‐Catalyzed Radical Cross‐Coupling

inferredcites →https://doi.org/10.1002/cctc.201500917openalex-snapshot

Catalyst‐Controlled Selectivity in C−S Bond Formation: Highly Efficient Synthesis of C2‐ and C3‐Sulfonylindoles

inferredcites →https://doi.org/10.1002/celc.201901212openalex-snapshot

Straightforward Electrochemical Sulfonylation of Arenes and Aniline Derivatives using Sodium Sulfinates

inferredcites →https://doi.org/10.1002/celc.202000761openalex-snapshot

Electrosynthesis 2.0 in 1,1,1,3,3,3‐Hexafluoroisopropanol/Amine Mixtures

inferredcites →https://doi.org/10.1002/chem.201601000openalex-snapshot

Eosin Y (EY) Photoredox‐Catalyzed Sulfonylation of Alkenes: Scope and Mechanism

inferredcites →https://doi.org/10.1002/chem.201605101openalex-snapshot

Copper‐Catalyzed Remote para‐C−H Functionalization of Anilines with Sodium and Lithium Sulfinates

inferredcites →https://doi.org/10.1002/chem.201701465openalex-snapshot

Generation of β‐Halo Vinylsulfones through a Multicomponent Reaction with Insertion of Sulfur Dioxide

inferredcites →https://doi.org/10.1002/chem.201702040openalex-snapshot

N‐Radical‐Initiated Cyclization through Insertion of Sulfur Dioxide under Photoinduced Catalyst‐Free Conditions

inferredcites →https://doi.org/10.1002/chem.201702190openalex-snapshot

Vicinal Difunctionalization of Alkenes through a Multicomponent Reaction with the Insertion of Sulfur Dioxide

inferredcites →https://doi.org/10.1002/chem.201705470openalex-snapshot

Radicals and Sulfur Dioxide: A Versatile Combination for the Construction of Sulfonyl‐Containing Molecules

inferredcites →https://doi.org/10.1002/chem.201900850openalex-snapshot

Direct Metal‐ and Reagent‐Free Sulfonylation of Phenols with Sodium Sulfinates by Electrosynthesis

inferredcites →https://doi.org/10.1002/chem.201901175openalex-snapshot

Visible Light‐Induced Sulfonylation/Arylation of Styrenes in a Double Radical Three‐Component Photoredox Reaction

inferredcites →https://doi.org/10.1002/chem.201902019openalex-snapshot

Sulfones as Chemical Chameleons: Versatile Synthetic Equivalents of Small‐Molecule Synthons

inferredcites →https://doi.org/10.1002/chem.201984862openalex-snapshot

Frontispiece: Sulfones as Chemical Chameleons: Versatile Synthetic Equivalents of Small‐Molecule Synthons

inferredcites →https://doi.org/10.1002/cjoc.201900505openalex-snapshot

Photoredox‐Catalyzed Functionalization of Alkenes with Thiourea Dioxide: Construction of Alkyl Sulfones or Sulfonamides

inferredcites →https://doi.org/10.1002/cssc.202101635openalex-snapshot

Recent Progress and Emerging Technologies towards a Sustainable Synthesis of Sulfones

inferredcites →https://doi.org/10.1002/ejoc.200400369openalex-snapshot

Total Synergistic Effect between Triflic Acid and Bismuth( III ) or Antimony( III ) Chlorides in Catalysis of the Methanesulfonylation of Arenes

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Borax‐Catalyzed and pH‐Controlled Selective Oxidation of Organic Sulfides by H 2 O 2 : An Environmentally Clean Protocol

inferredcites →https://doi.org/10.1002/ejoc.201000641openalex-snapshot

PhI(OAc)2/KI‐Mediated Reaction of Aryl Sulfinates with Alkenes, Alkynes, and α,β‐Unsaturated Carbonyl Compounds: Synthesis of Vinyl Sulfones and β‐Iodovinyl Sulfones

inferredcites →https://doi.org/10.1002/ejoc.201000826openalex-snapshot

Oxidation of Sulfides with a Silica‐Supported Peracid in Supercritical Carbon Dioxide under Flow Conditions: Tuning Chemoselectivity with Pressure

inferredcites →https://doi.org/10.1002/ejoc.201301101openalex-snapshot

Transition‐Metal‐Free Synthesis of (E)‐Vinyl Sulfones from Vinyl Halides in Water

inferredcites →https://doi.org/10.1002/ejoc.201403278openalex-snapshot

CuSO4·5H2O‐H‐Phosphonate‐Catalyzed Intermolecular C–S Bond Formation: Synthesis of (E)‐Vinyl Alkylsulfones from Alkynes and DMSO

inferredcites →https://doi.org/10.1002/ejoc.201601637openalex-snapshot

Photocatalytic Oxidation of Sulfinates to Vinyl Sulfones with Cyanamide‐Functionalised Carbon Nitride

inferredcites →https://doi.org/10.1002/ejoc.201700269openalex-snapshot

Electrooxidative Metal‐Free Dehydrogenative α‐Sulfonylation of 1H‐Indole with Sodium Sulfinates

inferredcites →https://doi.org/10.1002/ejoc.201701478openalex-snapshot

Nickel‐Catalyzed Synthesis of Diaryl Sulfones from Aryl Halides and Sodium Sulfinates

inferredcites →https://doi.org/10.1002/ejoc.201801128openalex-snapshot

Visible‐Light‐Induced 3‐Component Synthesis of Sulfonylated Oxindoles by Fixation of Sulfur Dioxide

inferredcites →https://doi.org/10.1002/ejoc.201900396openalex-snapshot

Photoinduced Sulfonylation Reactions through the Insertion of Sulfur Dioxide

inferredcites →https://doi.org/10.1002/ejoc.201901055openalex-snapshot

Palladium‐Catalyzed Direct ortho‐C–H Bond Sulfonylation and Halogenation of Phthalazine‐1,4‐diones

inferredcites →https://doi.org/10.1002/ejoc.202000403openalex-snapshot

Recent Advances in the Synthesis and Direct Application of Sulfinate Salts

inferredcites →https://doi.org/10.1002/ejoc.202001219openalex-snapshot

Three‐Component C–H Bond Sulfonylation of Imidazoheterocycles by Visible‐Light Organophotoredox Catalysis

inferredcites →https://doi.org/10.1002/hc.21401openalex-snapshot

One‐pot reactions for the synthesis of 5‐sulfonyl quinolines via domino N‐acylation and remote C‐H sulfonylation

inferredcites →https://doi.org/10.1007/s11144-012-0491-8openalex-snapshot

Oxidation of sulfides to sulfones with hydrogen peroxide in the presence of acetic acid and Amberlyst 15

inferredcites →https://doi.org/10.1007/s11164-018-3573-zopenalex-snapshot

Sulfonylation of C(sp3)–H bond for synthesis of 2-sulfolmethyl azaarenes catalyzed by TBAI in water

inferredcites →https://doi.org/10.1007/s13738-011-0062-3openalex-snapshot

Sulfonylation of aromatic compounds with methyl p-toluenesulfonate as a sulfonylating precursor

inferredcites →https://doi.org/10.1016/0040-4039(95)01095-yopenalex-snapshot

Copper-assisted displacement reaction of nonactivated lodoarenes with arenesulfinates. Convenient alternative synthesis of unsymmetrical diaryl sulfones

inferredcites →https://doi.org/10.1016/0040-4039(96)00548-5openalex-snapshot

An efficient oxidation of sulfides to sulfones using 2-methylpropanal and dioxygen

inferredcites →https://doi.org/10.1016/b978-0-08-012210-6.50106-xopenalex-snapshot

FRIEDEL-CRAFTS AND RELATED REACTIONS

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Recent Advances in the Synthesis of C–S Bonds via Metal-Catalyzed or -Mediated Functionalization of C–H Bonds

inferredcites →https://doi.org/10.1016/j.catcom.2006.10.028openalex-snapshot

Polystyrene and silica gel supported AlCl3 as highly chemoselective heterogeneous Lewis acid catalysts for Friedel–Crafts sulfonylation of aromatic compounds

inferredcites →https://doi.org/10.1016/j.cclet.2019.05.041openalex-snapshot

Metal-free visible-light-induced oxidative cyclization reaction of 1,6-enynes and arylsulfinic acids leading to sulfonylated benzofurans

inferredcites →https://doi.org/10.1016/j.cclet.2019.08.002openalex-snapshot

TsCl-promoted sulfonylation of quinoline N-oxides with sodium sulfinates in water

inferredcites →https://doi.org/10.1016/j.cclet.2020.08.037openalex-snapshot

Assembly of 3-sulfonated 2H-pyrrol-2-ones through the insertion of sulfur dioxide with allenoic amides

inferredcites →https://doi.org/10.1016/j.elecom.2019.106583openalex-snapshot

Electrochemical oxidations of thioethers: Modulation of oxidation potential using a hydrogen bonding network

inferredcites →https://doi.org/10.1016/j.jorganchem.2013.05.043openalex-snapshot

Imidazolium perrhenate ionic liquids as efficient catalysts for the selective oxidation of sulfides to sulfones

inferredcites →https://doi.org/10.1016/j.molcata.2003.10.066openalex-snapshot

Sulfonylation reactions of aromatics using FeCl3-based ionic liquids

inferredcites →https://doi.org/10.1016/j.tet.2013.01.071openalex-snapshot

Palladium-catalyzed alkenyl C–H bond sulfonylation reaction using organosulfonyl chlorides

inferredcites →https://doi.org/10.1016/j.tet.2015.02.048openalex-snapshot

An efficient electrochemical synthesis of vinyl sulfones from sodium sulfinates and olefins

inferredcites →https://doi.org/10.1016/j.tet.2015.04.117openalex-snapshot

Recent advances in sulfur- and phosphorous-centered radical reactions for the formation of S–C and P–C bonds

inferredcites →https://doi.org/10.1016/j.tet.2015.07.043openalex-snapshot

An efficient one-pot, three-component synthesis of vinyl sulfones via iodide-catalyzed radical alkenylation

inferredcites →https://doi.org/10.1016/j.tet.2017.10.022openalex-snapshot

Ammonium iodide-promoted unprecedented arylsulfonylation of quinone with sodium arylsulfinates

inferredcites →https://doi.org/10.1016/j.tet.2017.10.047openalex-snapshot

Electrosynthesis of vinyl sulfones from alkenes and sulfonyl hydrazides mediated by KI: Аn electrochemical mechanistic study

inferredcites →https://doi.org/10.1016/j.tetlet.2007.07.081openalex-snapshot

Rapid and mild sulfonylation of aromatic compounds with sulfonic acids via mixed anhydrides using Tf2O

inferredcites →https://doi.org/10.1016/j.tetlet.2008.04.051openalex-snapshot

Highly selective catalytic Friedel–Crafts sulfonylation of aromatic compounds using a FeCl3-based ionic liquid

inferredcites →https://doi.org/10.1016/j.tetlet.2009.06.078openalex-snapshot

An approach toward the synthesis of β-hydroxy sulfones on water

inferredcites →https://doi.org/10.1016/j.tetlet.2013.03.117openalex-snapshot

I2/TBHP-mediated reaction of sulfonylhydrazides with alkynes: synthesis of (E)-β-iodovinyl sulfones

inferredcites →https://doi.org/10.1016/j.tetlet.2014.03.078openalex-snapshot

Aerobic oxysulfonylation of alkynes in aqueous media: highly selective access to β-keto sulfones

inferredcites →https://doi.org/10.1016/j.tetlet.2014.11.089openalex-snapshot

Metal and solvent free selective oxidation of sulfides to sulfone using bifunctional ionic liquid [pmim]IO4

inferredcites →https://doi.org/10.1016/j.tetlet.2016.04.011openalex-snapshot

Copper-catalyzed C5-regioselective C H sulfonylation of 8-aminoquinoline amides with aryl sulfonyl chlorides

inferredcites →https://doi.org/10.1016/j.tetlet.2016.04.018openalex-snapshot

Molecular iodine mediated oxidative coupling of enol acetates with sodium sulfinates leading to β-keto sulfones

inferredcites →https://doi.org/10.1016/j.tetlet.2016.11.119openalex-snapshot

Green and mild laccase-catalyzed aerobic oxidative coupling of benzenediol derivatives with various sodium benzenesulfinates

inferredcites →https://doi.org/10.1016/j.tetlet.2018.03.023openalex-snapshot

Direct sulfonylation of pyrazolones with sodium sulfinates catalyzed by TBAI in water

inferredcites →https://doi.org/10.1016/j.tetlet.2018.11.059openalex-snapshot

Radical Heck-type reaction of styrenes with sulfonyl hydrazides on water at room temperature

inferredcites →https://doi.org/10.1016/j.tetlet.2019.02.021openalex-snapshot

Direct radical sulfonylation at α-C(sp3)-H of THF with sodium sulfinates in aqueous medium

inferredcites →https://doi.org/10.1016/s0022-5347(05)67032-2openalex-snapshot

BICALUTAMIDE MONOTHERAPY COMPARED WITH CASTRATION IN PATIENTS WITH NONMETASTATIC LOCALLY ADVANCED PROSTATE CANCER: 6.3 YEARS OF FOLLOWUP

inferredcites →https://doi.org/10.1016/s0040-4020(00)01005-xopenalex-snapshot

An efficient method for aromatic Friedel–Crafts alkylation, acylation, benzoylation, and sulfonylation reactions

inferredcites →https://doi.org/10.1016/s0040-4039(02)00598-1openalex-snapshot

Simple, economical and environmentally friendly sulfone synthesis

inferredcites →https://doi.org/10.1021/acs.chemrev.7b00397openalex-snapshot

Synthetic Organic Electrochemical Methods Since 2000: On the Verge of a Renaissance

inferredcites →https://doi.org/10.1021/acs.chemrev.8b00507openalex-snapshot

3d Transition Metals for C–H Activation

inferredcites →https://doi.org/10.1021/acs.joc.0c02679openalex-snapshot

Oxidant- and Catalyst-Free Synthesis of Sulfonated Benzothiophenes via Electrooxidative Tandem Cyclization

inferredcites →https://doi.org/10.1021/acs.joc.5b02509openalex-snapshot

Copper-Catalyzed Regioselective C–H Sulfonylation of 8-Aminoquinolines

inferredcites →https://doi.org/10.1021/acs.joc.5b02810openalex-snapshot

Iodine-catalyzed Sulfonylation of Arylacetylenic Acids and Arylacetylenes with Sodium Sulfinates: Synthesis of Arylacetylenic Sulfones

inferredcites →https://doi.org/10.1021/acs.joc.6b00661openalex-snapshot

Electrosynthesis of (E)-Vinyl Sulfones Directly from Cinnamic Acids and Sodium Sulfinates via Decarboxylative Sulfono Functionalization

inferredcites →https://doi.org/10.1021/acs.joc.6b01449openalex-snapshot

Photoredox Catalysis in Organic Chemistry

inferredcites →https://doi.org/10.1021/acs.joc.7b00994openalex-snapshot

Metal-free Oxidative Coupling of Aromatic Alkenes with Thiols Leading to ( E )-Vinyl Sulfones

inferredcites →https://doi.org/10.1021/acs.joc.7b01371openalex-snapshot

One-Pot Synthesis of β-Hydroxysulfones and Its Application in the Preparation of Anticancer Drug Bicalutamide

inferredcites →https://doi.org/10.1021/acs.joc.7b01741openalex-snapshot

Electrochemical Decarboxylative Sulfonylation of Cinnamic Acids with Aromatic Sulfonylhydrazides to Vinyl Sulfones

inferredcites →https://doi.org/10.1021/acs.joc.8b03002openalex-snapshot

Synthesis of Sulfonylated Lactams by Copper-Mediated Aminosulfonylation of 2-Vinylbenzamides with Sodium Sulfinates

inferredcites →https://doi.org/10.1021/acs.joc.9b01400openalex-snapshot

Aerobic Copper-Catalyzed Synthesis of ( E )-Vinyl Sulfones by Direct C–S Bond Oxidative Coupling

inferredcites →https://doi.org/10.1021/acs.joc.9b02302openalex-snapshot

I2–DMSO–H2O: A Metal-Free Combination System for the Oxidative Addition of Alkynes to Access (E)-α-Iodo-β-methylsulfonylalkenes

inferredcites →https://doi.org/10.1021/acs.joc.9b02779openalex-snapshot

Functionalization of Alkynes and Alkenes Using a Cascade Reaction Approach: Synthesis of β-Keto Sulfones under Metal-free Conditions

inferredcites →https://doi.org/10.1021/acs.joc.9b02954openalex-snapshot

Cu-Catalyzed Direct C7 Sulfonylation of Indolines with Arylsulfonyl Chlorides

inferredcites →https://doi.org/10.1021/acs.joc.9b03330openalex-snapshot

Regioselective C–H Sulfonylation of 2H-Indazoles by Electrosynthesis

inferredcites →https://doi.org/10.1021/acs.orglett.0c01730openalex-snapshot

Photoredox Generation of Sulfonyl Radicals and Coupling with Electron Deficient Olefins

inferredcites →https://doi.org/10.1021/acs.orglett.0c02144openalex-snapshot

Electrochemical Radical–Radical Cross-Coupling Approach between Sodium Sulfinates and 2H-Indazoles to 3-Sulfonylated 2H-Indazoles

inferredcites →https://doi.org/10.1021/acs.orglett.0c02341openalex-snapshot

Electrochemically Enabled Sulfonylation of Alkynes with Sodium Sulfinates

inferredcites →https://doi.org/10.1021/acs.orglett.0c02400openalex-snapshot

Directing-Group-Assisted C(sp2)–H Arylsulfonylation from Sulfur Dioxide

inferredcites →https://doi.org/10.1021/acs.orglett.5b01037openalex-snapshot

A Direct Metal-Free Decarboxylative Sulfono Functionalization (DSF) of Cinnamic Acids to α,β-Unsaturated Phenyl Sulfones

inferredcites →https://doi.org/10.1021/acs.orglett.5b01198openalex-snapshot

Copper(II)-Catalyzed Direct Sulfonylation of C(sp2)–H Bonds with Sodium Sulfinates

inferredcites →https://doi.org/10.1021/acs.orglett.5b01634openalex-snapshot

Pd(II)-Catalyzed Direct Sulfonylation of Unactivated C(sp3)–H Bonds with Sodium Sulfinates

inferredcites →https://doi.org/10.1021/acs.orglett.5b03114openalex-snapshot

Copper(I)-Catalyzed Sulfonylation of 8-Aminoquinoline Amides with Sulfonyl Chlorides in Air

inferredcites →https://doi.org/10.1021/acs.orglett.6b00734openalex-snapshot

Synthesis of β-Hydroxysulfones from Sulfonyl Chlorides and Alkenes Utilizing Visible Light Photocatalytic Sequences

inferredcites →https://doi.org/10.1021/acs.orglett.6b02289openalex-snapshot

Cu-Catalyzed Deoxygenative C2-Sulfonylation Reaction of Quinoline N-Oxides with Sodium Sulfinate

inferredcites →https://doi.org/10.1021/acs.orglett.7b02439openalex-snapshot

Ruthenium-Catalyzed ortho/meta-Selective Dual C–H Bonds Functionalizations of Arenes

inferredcites →https://doi.org/10.1021/acs.orglett.7b03195openalex-snapshot

Synthesis of Tetrahydropyridine Derivatives through a Reaction of 1,6-Enynes, Sulfur Dioxide, and Aryldiazonium Tetrafluoroborates

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Temperature Controlled Selective C–S or C–C Bond Formation: Photocatalytic Sulfonylation versus Arylation of Unactivated Heterocycles Utilizing Aryl Sulfonyl Chlorides

inferredcites →https://doi.org/10.1021/acs.orglett.8b03718openalex-snapshot

Copper(II)-Catalyzed Reaction of 2,3-Allenoic Acids, Sulfur Dioxide, and Aryldiazonium Tetrafluoroborates: Route to 4-Sulfonylated Furan-2(5H)-ones

inferredcites →https://doi.org/10.1021/acs.orglett.9b01041openalex-snapshot

Regioselective Intermolecular Sulfur–Oxygen Difunctionalization (Phenoxysulfonylation) of Alkynes: One-Pot Construction of ( Z )-β-Phenoxy Vinylsulfones

inferredcites →https://doi.org/10.1021/acs.orglett.9b03192openalex-snapshot

Switchable Synthesis of Aryl Sulfones and Sulfoxides through Solvent-Promoted Oxidation of Sulfides with O 2 /Air

inferredcites →https://doi.org/10.1021/acs.orglett.9b03636openalex-snapshot

Hydrosulfonylation of Unactivated Alkenes by Visible Light Photoredox Catalysis

inferredcites →https://doi.org/10.1021/acs.orglett.9b04221openalex-snapshot

Electrochemical Synthesis of β-Ketosulfones from Switchable Starting Materials

inferredcites →https://doi.org/10.1021/acscatal.0c05690openalex-snapshot

Recent Advances in the Catalytic Synthesis of Arylsulfonyl Compounds

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Effective Utilization of in Situ Generated Hydroperoxide by a Co–SiO2@Ti–Si Core–Shell Catalyst in the Oxidation Reactions

inferredcites →https://doi.org/10.1021/acscatal.8b03302openalex-snapshot

Electrochemical Oxidative Alkoxysulfonylation of Alkenes Using Sulfonyl Hydrazines and Alcohols with Hydrogen Evolution

inferredcites →https://doi.org/10.1021/acscatal.8b04188openalex-snapshot

Visible-Light-Mediated Regioselective Chlorosulfonylation of Alkenes and Alkynes: Introducing the Cu(II) Complex [Cu(dap)Cl2] to Photochemical ATRA Reactions

inferredcites →https://doi.org/10.1021/acscatal.9b00037openalex-snapshot

MOF-Derived Subnanometer Cobalt Catalyst for Selective C–H Oxidative Sulfonylation of Tetrahydroquinoxalines with Sodium Sulfinates

inferredcites →https://doi.org/10.1021/acsomega.8b02966openalex-snapshot

Metal-Free Synthesis of Functionalized Tetrasubstituted Alkenes by Three-Component Reaction of Alkynes, Iodine, and Sodium Sulfinates

inferredcites →https://doi.org/10.1021/acsomega.9b02442openalex-snapshot

Electrochemical Alkoxysulfonylation Difunctionalization of Styrene Derivatives Using Sodium Sulfinates as Sulfonyl Sources

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Metal-Free Sulfonylation of 3,4-Dihalo-2(5H)-furanones (X = Cl, Br) with Sodium Sulfinates under Air Atmosphere in Aqueous Media via a Radical Pathway

inferredcites →https://doi.org/10.1021/acssuschemeng.8b04339openalex-snapshot

Waste-Minimized Protocol for the Synthesis of Sulfonylated N-Heteroaromatics in Water

inferredcites →https://doi.org/10.1021/acssuschemeng.8b06566openalex-snapshot

Amino Acid-Catalyzed Direct Synthesis of β-Keto Sulfones via Aerobic Difunctionalization of Terminal Alkynes in an Aqueous Medium

inferredcites →https://doi.org/10.1021/ar800164nopenalex-snapshot

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

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Evolving Organic Synthesis Fostered by the Pluripotent Phenylsulfone Moiety

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Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

inferredcites →https://doi.org/10.1021/ja00783a041openalex-snapshot

Aromatic substitution. XXXI. Friedel-Crafts sulfonylation of benzene and toluene with alkyl- and arylsulfonyl halides and anhydrides

inferredcites →https://doi.org/10.1021/ja208286bopenalex-snapshot

Ruthenium-Catalyzed Meta Sulfonation of 2-Phenylpyridines

inferredcites →https://doi.org/10.1021/ja900200gopenalex-snapshot

Palladium-Catalyzed C−H Bond Functionalization with Arylsulfonyl Chlorides

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Nonsteroidal antiandrogens. Synthesis and structure-activity relationships of 3-substituted derivatives of 2-hydroxypropionanilides

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Acylation and Related Reactions under Microwaves. 4. Sulfonylation Reactions of Aromatics

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Bridged Polycyclic Compounds. XXV. Free-Radical Addition of Benzenesulfonyl Halides to Norbornadiene1

inferredcites →https://doi.org/10.1021/jo01284a075openalex-snapshot

Synthesis of aryl sulfones

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Friedel−Crafts Sulfonylation in 1-Butyl-3-methylimidazolium Chloroaluminate Ionic Liquids

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Sulfonylation of Five-Membered Heterocycles via an SNAr Reaction

inferredcites →https://doi.org/10.1021/jo402831kopenalex-snapshot

RegioselectiveC2 Sulfonylation of Indoles Mediated by Molecular Iodine

inferredcites →https://doi.org/10.1021/jo5010845openalex-snapshot

Copper-Catalyzed Aerobic Decarboxylative Sulfonylation of Cinnamic Acids with Sodium Sulfinates: Stereospecific Synthesis of ( E )-Alkenyl Sulfones

inferredcites →https://doi.org/10.1021/jo501314yopenalex-snapshot

Copper-Catalyzed Decarboxylative Sulfonylation of α,β-Unsaturated Carboxylic Acids

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Unsymmetrical Diaryl Sulfones through Palladium-Catalyzed Coupling of Aryl Iodides and Arenesulfinates

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A Practical, One-Pot Synthesis of Sulfonylated Pyridines

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Metal-Free Synthesis of Diaryl Sulfones from Arylsulfinic Acid Salts and Diaryliodonium Salts

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Sulfonylation of Quinoline N -Oxides with Aryl Sulfonyl Chlorides via Copper-Catalyzed C–H Bonds Activation

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Iodine-Catalyzed Regioselective 2-Sulfonylation of Indoles with Sodium Sulfinates

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DABSO-Based, Three-Component, One-Pot Sulfone Synthesis

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Friedel–Crafts sulfonylation of aromatics catalysed by solid acids: An eco-friendly route for sulfone synthesis

inferredcites →https://doi.org/10.1039/b104603aopenalex-snapshot

Nafion-H catalysed sulfonylation of aromatics with arene/alkenesulfonic acids for the preparation of sulfones

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Study of regioselective methanesulfonylation of simple aromatics with methanesulfonic anhydride in the presence of zeolite catalysts

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Green and chemoselective oxidation of sulfides with sodium perborate and sodium percarbonate: nucleophilic and electrophilic character of the oxidation system

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Practical oxidation of sulfides to sulfones by H2O2 catalysed by titanium catalyst

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Solvent-free chemoselective oxidation of thioethers and thiophenes by mechanical milling

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Catalyst-free approach for solvent-dependent selective oxidation of organic sulfides with oxone

inferredcites →https://doi.org/10.1039/c2gc16664jopenalex-snapshot

A one-pot regioselective synthetic route to vinyl sulfones from terminal epoxides in aqueous media

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Aqueous heterogeneous oxygenation of hydrocarbons and sulfides catalyzed by recoverable magnetite nanoparticles coated with copper(ii) phthalocyanine

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Highly atom-economic, catalyst- and solvent-free oxidation of sulfides into sulfones using 30% aqueous H2O2

inferredcites →https://doi.org/10.1039/c3cy00719gopenalex-snapshot

Efficient and convenient oxidation of sulfides to sulfones using H 2 O 2 catalyzed by V 2 O 5 in ionic liquid [C 12 mim][HSO 4 ]

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Merrifield resin supported peroxomolybdenum(vi) compounds: recoverable heterogeneous catalysts for the efficient, selective and mild oxidation of organic sulfides with H2O2

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A molybdenum based metallomicellar catalyst for controlled and selective sulfoxidation reactions in aqueous medium

inferredcites →https://doi.org/10.1039/c3qo00075copenalex-snapshot

NBS-promoted halosulfonylation of terminal alkynes: highly regio- and stereoselective synthesis of (E)-β-halo vinylsulfones

inferredcites →https://doi.org/10.1039/c3ra47863gopenalex-snapshot

Molecular-iodine-catalyzed aerobic oxidative synthesis of β-hydroxy sulfones from alkenes

inferredcites →https://doi.org/10.1039/c4cc07606kopenalex-snapshot

Ammonium iodide-induced sulfonylation of alkenes with DMSO and water toward the synthesis of vinyl methyl sulfones

inferredcites →https://doi.org/10.1039/c4cc08117jopenalex-snapshot

Direct and metal-free arylsulfonylation of alkynes with sulfonylhydrazides for the construction of 3-sulfonated coumarins

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What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Rhodesain Inhibitors on the Edge of Reversibility-Irreversibility

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Oxidative Cascade Sulfonylation/Cyclisation of N‐Propargylindoles with Hantzsch Esters via Sulfur Dioxide Insertion

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Visible Light‐Driven Eosin Y‐Catalyzed Suzuki‐Type Sulfonylation

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Hybrid Catalysts in Photoredox Arylation of Sodium Arylsulfinates

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Copper‐Catalyzed Direct C−H Bond Oxidative Sulfonylation of β‐Alkyl Cyanoalkenes with Sodium Sulfinates

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Advances in Vinyl Sulfone Catalyzed Synthesis: Methods, Mechanisms and Perspectives

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Thermal vs. Visible‐Light Photoredox‐Catalyzed Cascade Radical Cyclization Involving SO 2 Fixation to Access 6‐Alkylsulfonylmethyl Phenanthridines

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Light‐Induced Three‐Component Synthesis of Sulfur‐Containing Compounds: A Concise Overview

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Diversification of Aryl Sulfonyl Compounds through Ligand‐Controlledmeta‐ andpara‐C−H Borylation

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Rapid and Scalable Halosulfonylation of Strain‐Release Reagents**

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Preparation of Degradable Polymers Containing Tunable Ratios of Dithioacetals and Disulfides via Mixed Mode Polymerization

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Diversification of Aryl Sulfonyl Compounds through Ligand‐Controlledmeta‐ andpara‐C−H Borylation

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Rapid and Scalable Halosulfonylation of Strain‐Release Reagents**

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Preparation of Degradable Polymers Containing Tunable Ratios of Dithioacetals and Disulfides via Mixed Mode Polymerization

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Visible Light‐Induced Arylsulfonylation/Cyclization Reactions for the Synthesis of Thiochromane 1,1‐dioxide

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Visible‐Light Induced Fixation of SO 2 into Organic Molecules with Polypyridine Chromium(III) Complexes

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Catalyst‐Free Visible Light‐Driven Hydrosulfonylation of Alkenes and Alkynes with Sulfonyl Chlorides in Water

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Graphite‐Catalyzed Synthesis of Sulfones in Aqueous Medium

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Synthesis of Sulfone Containing‐Spirocycles, ‐Pentafulvene Dyes and Their Photophysical Properties

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Photocatalyst‐Free, Visible Light‐Induced Hydroalkylation of Vinyl Sulfones with Alcohols

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Modular Assembly of Cyclic Sulfones via Radical Annulation with Unactivated Olefins

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Hypervalent Iodine‐Mediated Synthesis of Sulfones Using Organozinc Pivalates and Sulfinate Salts

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Brønsted Acid–Driven C6‐Selective Sulfonylation of Coumarins Promoted by Cu(OTf) 2 : Synthesis of Coumarin–Sulfone Scaffolds

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Expeditious Photosensitized Oxidation Reaction of Sulfides Toward the Selective Preparation of Sulfoxides and Sulfones

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Metal‐Free Direct Oxysulfonylation of Styrenes with N ‐Hydroxy Aryl Sulfonamides to Access β‐Ketosulfones

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CO2-promoted photoredox-catalyzed cascade cyclization of N-propargylindoles with sulfinates

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Mn(OAc)3 promoted radical cyclization of vinyl isocyanides: Synthesis of isoquinoline-1-sulfonates and derivatives

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Homolytic Aromatic Sulfonation with K2S2O5 Promoted by a Combination of Mn(OAc)3·2H2O and HFIP

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Catalyst-Free Electrochemical Sulfonylation of Organoboronic Acids

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Unified Radical Sulfonylative-Annulation of 1,6-Enynols with Sodium Sulfinates: A Modular Synthesis of 2,3-Disubstituted Benzoheteroles

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Mn(OAc)3-Promoted Sulfonation–ipso-Cyclization Cascade via the SO3– Radical: The Synthesis of Spirocyclic Sulfonates

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Reagentless Chemistry “On-Water”: An Atom-Efficient and “Green” Route to Cyclic and Acyclic β-Amino Sulfones via aza-Michael Addition Using Microwave Irradiation

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Glyoxylic Acid Monohydrate-Promoted Formation of the C–SO2 Bond Starting from Maleimides/Quinones and Sodium Sulfinates

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Visible-Light Induced Radical Addition–Elimination Reaction for Constructing Allylic Sulfones from Sulfonyl Chlorides and Allyl Bromides

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Sequential Ring Opening/In Situ SO 2 -Capture/Alkynylation of Cyclopropanols with Alkynyl Triflones Initiated by Energy Transfer

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Visible Light-Induced Photocatalyst-Free Diastereoselective Iodosulfonylation of Cyclopropenes in Water

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Vicinal Thiosulfonylation of ortho -(Alkynyl)benzyl Thiosulfonates/Sulfurothioates for Direct Synthesis of Sulfonyl-Derived Isothiochromenes

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Sustainable Sulfonylation and Sulfenylation of Indoles with Thiols through Hexamolybdate/H 2 O 2 -Mediated Oxidative Dehydrogenation Coupling

inferred← citeshttps://doi.org/10.1021/acs.joc.5c00077openalex-snapshot

Access to Methylidene-Azaspiro[4.5]decatrienones via Radical-Promoted Domino Thio-Functionalization/Dearomative Ipso-Annulation

inferred← citeshttps://doi.org/10.1021/acs.joc.5c00288openalex-snapshot

Photocatalytic Radical Cascade Cyclization of N-(o-Cyanobiaryl)acrylamides with Sulfonyl Chlorides

inferred← citeshttps://doi.org/10.1021/acs.joc.5c01278openalex-snapshot

Thermally Generated Cation Pool Enabled Condition-Controlled Synthesis of γ-Ketosulfones and β-Morpholinoketones from Methyl Ketone by α-Csp3-H Methylenation

inferred← citeshttps://doi.org/10.1021/acs.joc.5c01427openalex-snapshot

Substrate-Directed Annulative-Sulfonylation/Desulfonylation Cascade Using ( E )-β-Iodovinyl Sulfones: A Diverse Approach for the Synthesis of Imidazo[1,2- a ]pyridines with Sulfone Motifs

inferred← citeshttps://doi.org/10.1021/acs.joc.5c02543openalex-snapshot

The Visible-Light-Triggered Catalytic Triarylamine EDA Complex Enabled Synthesis of Sulfonylated Quinolines, Pyrroloindoles, and Chromenes by Radical Sulfonylation-Cyclization of Substituted Alkynes with Sulfonyl Chlorides

inferred← citeshttps://doi.org/10.1021/acs.joc.5c02712openalex-snapshot

Visible-Light Photoredox-Catalyzed Radical Addition/Cyclization of Imidazoles with Alkenes: Access to Polycyclic Imidazoles Bearing Alkylsulfonyl or Exocyclic Olefin Units

inferred← citeshttps://doi.org/10.1021/acs.joc.6c00164openalex-snapshot

Radical Cascade Sulfonylation/Cyclization of 1-Acryloyl-2-cyanoindoles/2-Cyano- N -arylacrylamides with Aryldiazonium Tetrafluoroborates via the Insertion of Sulfur Dioxide

inferred← citeshttps://doi.org/10.1021/acs.joc.6c00351openalex-snapshot

HFIP-Induced Formation of O -Aryl Oxyallyl Cation and Nucleophilic Addition with Sodium Sulfinate Salt

inferred← citeshttps://doi.org/10.1021/acs.joc.6c00917openalex-snapshot

4-Fluorophenyl Tagging as a Diagnostic Tool for Monitoring Sulfur Oxidation States via 19F NMR

inferred← citeshttps://doi.org/10.1021/acs.orglett.2c01260openalex-snapshot

Hydrosulfonylation of Alkenes with Sulfonyl Imines via Ir/Cu Dual Photoredox Catalysis

inferred← citeshttps://doi.org/10.1021/acs.orglett.2c01657openalex-snapshot

A Bi(OTf) 3 -Promoted Hydrosulfonylation of Alkenes with Sulfonyl Hydrazides: An Approach to Branched Sulfones

inferred← citeshttps://doi.org/10.1021/acs.orglett.2c03430openalex-snapshot

Highly Reactive Palladium-Catalyzed and Acetonitrile-Mediated Three-Component Reactions for Arylsulfone Synthesis

inferred← citeshttps://doi.org/10.1021/acs.orglett.2c03510openalex-snapshot

Mn(OAc) 3 -Promoted Sulfonation-Cyclization Cascade via the SO 3 – Radical: The Synthesis of Heterocyclic Sulfonates

inferred← citeshttps://doi.org/10.1021/acs.orglett.3c00441openalex-snapshot

Copper-Catalyzed Sulfonylation/Cyclization of Pent-4-ynamides toward Sulfonyl-Functionalized Pyrrol-2-ones

inferred← citeshttps://doi.org/10.1021/acs.orglett.3c02066openalex-snapshot

Pd-Catalyzed Multicomponent Cross-Coupling of Allyl Esters with Alkyl Bromides and Potassium Metabisulfite: Access to Allylic Sulfones

inferred← citeshttps://doi.org/10.1021/acs.orglett.4c03724openalex-snapshot

Au(I)/Au(III)-Catalyzed Sulfonylation of Aryl Iodides for the Synthesis of Various Functionalized Aryl Sulfones

inferred← citeshttps://doi.org/10.1021/acs.orglett.4c03733openalex-snapshot

Aminosulfonylation of Rhodium Carbene via Ylide Formation and 1,4-Sulfonyl Rearrangement

inferred← citeshttps://doi.org/10.1021/acs.orglett.5c01346openalex-snapshot

Energy-Transfer-Enabled Truce–Smiles Rearrangement Using Sulfonamides as Sulfonyl Radical Precursors

inferred← citeshttps://doi.org/10.1021/acs.orglett.5c04490openalex-snapshot

Assembly of α-Aryl Sulfones and Allyl Sulfones and Their Amide Analogues via Copper-Catalyzed Coupling Reactions

inferred← citeshttps://doi.org/10.1021/acs.orglett.6c00146openalex-snapshot

Regioselective C2-Sulfonylation of Indoles and Pyrroles via SO 2 Insertions

inferred← citeshttps://doi.org/10.1021/acs.orglett.6c01416openalex-snapshot

Mechanoredox Enables Sulfonylation of Alkenes in a Heterogeneous System

inferred← citeshttps://doi.org/10.1021/acsami.5c09484openalex-snapshot

Node-Solution Microenvironment Governs the Selectivity of Thioanisole Oxidation within Catalytic Zr-Based Metal–Organic Framework

inferred← citeshttps://doi.org/10.1021/acscatal.5c07507openalex-snapshot

Sulfonylation of Anilines through Photocatalytic Activation of N -Hydroxymethylphthalimide Sulfones

inferred← citeshttps://doi.org/10.1021/acscatal.6c02259openalex-snapshot

Photocatalyzed Decarboxylative Dual Functional Group Transposition Using Bifunctional Radical Precursors

inferred← citeshttps://doi.org/10.1021/acsnano.3c01634openalex-snapshot

Triboelectric Nanogenerators-Based Therapeutic Electrical Stimulation on Skin: from Fundamentals to Advanced Applications

inferred← citeshttps://doi.org/10.1021/jacs.3c11225openalex-snapshot

A General Platform for Visible Light Sulfonylation Reactions Enabled by Catalytic Triarylamine EDA Complexes

inferred← citeshttps://doi.org/10.1021/jacs.3c11809openalex-snapshot

Metal–Organic Frameworks as a Tunable Platform to Deconvolute Stereoelectronic Effects on the Catalytic Activity of Thioanisole Oxidation

inferred← citeshttps://doi.org/10.1039/d1qo01850gopenalex-snapshot

Visible-light mediated cross-coupling of aryl halides with sodium sulfinates via carbonyl-photoredox/nickel dual catalysis

inferred← citeshttps://doi.org/10.1039/d2ra06784fopenalex-snapshot

Metal-free hydrosulfonylation of α,β-unsaturated ketones: synthesis and application of γ-keto sulfones

inferred← citeshttps://doi.org/10.1039/d2re00190jopenalex-snapshot

PhSe(O)OH/Al(NO 3 ) 3 -Catalyzed selectivity controllable oxidation of sulphide owing to the synergistic effect of Se, Al 3+ and nitrate

inferred← citeshttps://doi.org/10.1039/d2re00280aopenalex-snapshot

A continuous flow investigation of sulfonyl chloride synthesis using N -chloroamides: optimization, kinetics and mechanism

inferred← citeshttps://doi.org/10.1039/d3cc02740fopenalex-snapshot

Photoredox catalysis in alkene and alkyne alkylsulfonylations: the construction of Markovnikov selective α-sulfones

inferred← citeshttps://doi.org/10.1039/d3dt02352dopenalex-snapshot

Tuning the morphology to enhance the catalytic activity of α-Ag 2 WO 4 through V-doping

inferred← citeshttps://doi.org/10.1039/d3ma00823aopenalex-snapshot

A magnetic Fe@PANI catalyst for the selective oxidation of sulphide under mild and green conditions

inferred← citeshttps://doi.org/10.1039/d3ob00557gopenalex-snapshot

Visible-light promoted cascade cyanoalkylsulfonylation/ ipso -cyclization of N -arylpropiolamides toward sulfonated spiro[4,5]trienones via SO 2 insertion

inferred← citeshttps://doi.org/10.1039/d3ra08685bopenalex-snapshot

I 2 /DMSO-mediated oxidative C–C and C–heteroatom bond formation: a sustainable approach to chemical synthesis

inferred← citeshttps://doi.org/10.1039/d3sc00182bopenalex-snapshot

Inexpensive and bench stable diarylmethylium tetrafluoroborates as organocatalysts in the light mediated hydrosulfonylation of unactivated alkenes

inferred← citeshttps://doi.org/10.1039/d4ee04820bopenalex-snapshot

Fluorine-free electrolytes in batteries: principles, strategies, and advances

inferred← citeshttps://doi.org/10.1039/d4qo00370eopenalex-snapshot

Visible light-induced sulfonylation with sulfinates as closed-shell radical acceptors

inferred← citeshttps://doi.org/10.1039/d4qo01499eopenalex-snapshot

Manganese( iii ) acetate in organic synthesis: a review of the past decade

inferred← citeshttps://doi.org/10.1039/d5cc01285fopenalex-snapshot

Visible-light-induced radical 1,3-hydrosulfonylation of allylketones with sulfonyl chlorides

inferred← citeshttps://doi.org/10.1039/d5cy00212eopenalex-snapshot

Selective oxidation of sulfides catalysed by WO 3 supported on chitosan-derived carbon

inferred← citeshttps://doi.org/10.1039/d5gc00057bopenalex-snapshot

CO 2 -Promoted photoredox-catalyzed hydrosulfonylation of alkenes with sulfinates

inferred← citeshttps://doi.org/10.1039/d5im00103jopenalex-snapshot

Advances in coupling catalytic selective oxidation reactions with in situ synthesis of hydrogen peroxide

inferred← citeshttps://doi.org/10.1039/d5ob00402kopenalex-snapshot

Construction of multi-functionalized carbon chains by Ni-catalyzed carbosulfonylation of butadiene

inferred← citeshttps://doi.org/10.1039/d5ob00799bopenalex-snapshot

Selective hydrogen isotope exchange on sulfonamides, sulfilimides and sulfoximines by electrochemically generated bases

inferred← citeshttps://doi.org/10.1039/d5ob01408eopenalex-snapshot

Palladium-catalyzed asymmetric propargylic sulfonylation of propargyl esters with sulfonyl hydrazides

inferred← citeshttps://doi.org/10.1039/d5ob01550bopenalex-snapshot

Aza-oxyallyl cation-mediated synthesis of α-sulfonyl hydroxamic acid derivatives from α-halo hydroxamates and sodium sulfinates

inferred← citeshttps://doi.org/10.1039/d6gc01807fopenalex-snapshot

Iron photocatalysis unlocks ozone's power for ultrafast sulfide-to-sulfone oxidation in continuous flow

inferred← citeshttps://doi.org/10.1039/d6ob00670aopenalex-snapshot

Electrophilic alkene sulfenylation with sulfinate esters

inferred← citeshttps://doi.org/10.1039/d6qo01046fopenalex-snapshot

Divergent reactivity of triflones: competing epoxidation and olefination pathways with formaldehyde

inferred← citeshttps://doi.org/10.1055/a-1996-8054openalex-snapshot

Electrochemical Synthesis of 3-Sulfonylindoles via Annulation of o-Alkynylanilines with Sodium Sulfinates

inferred← citeshttps://doi.org/10.1055/a-2004-1006openalex-snapshot

Facile Synthesis of Diaryl Sulfones through Arylsulfonylation of Arynes and Thiosulfonates

inferred← citeshttps://doi.org/10.1055/a-2059-3168openalex-snapshot

Synthesis of 2-Sulfonylthiazoles via Heteroaryl C–H Sulfonylation of Thiazole N-Oxides

inferred← citeshttps://doi.org/10.1055/a-2096-4349openalex-snapshot

Progress in S–X Bond Formation by Halogen-Mediated Electrochemical Reactions

inferred← citeshttps://doi.org/10.1055/a-2295-8639openalex-snapshot

Denitrative Sulfonylation of Nitroarenes with Sodium Sulfinates

inferred← citeshttps://doi.org/10.1055/a-2531-6862openalex-snapshot

Sodium Hypochlorite Pentahydrate as an Environmentally Benign Oxidizing Agent: Effective Synthesis of Carboxylic Acids from Primary Alcohols and Sulfones from Sulfides

inferred← citeshttps://doi.org/10.1055/a-2545-7313openalex-snapshot

Alkylation of Arylsulfonyl Cyanides To Form Alkyl Sulfones

inferred← citeshttps://doi.org/10.1055/a-2932-0679openalex-snapshot

Base-Mediated Convenient Synthesis of 4-Sulfonyl-1,2,3-NH-Triazoles and (Z)-β-Amidovinyl Sulfones using (E)-β-Iodovinyl Sulfones

inferred← citeshttps://doi.org/10.1055/s-0042-1751424openalex-snapshot

Visible-Light-Mediated Regioselective Chlorosulfonylation of Acrylamides

inferred← citeshttps://doi.org/10.1080/10426507.2021.2016758openalex-snapshot

Synthesis of sulfone derivatives via palladium-catalyzed cross-coupling of benzyl trimethylammonium triflates and sulfonyl hydrazides

inferred← citeshttps://doi.org/10.1080/17415993.2023.2278602openalex-snapshot

Methods for hydrosulfonylation of alkenes

inferred← citeshttps://doi.org/10.1080/17415993.2026.2632783openalex-snapshot

Sulfone synthesis in the coupling era: a decade update

inferred← citeshttps://doi.org/10.1134/s1070428025604686openalex-snapshot

Chemodivergent Photocatalytic Reaction of Sodium Benzenesulfinate and 2-Iodopyridine

inferred← citeshttps://doi.org/10.1134/s1990793125701258openalex-snapshot

Quinizarin—an Effective Photocatalyst for Oxidation of Organic Sulfides in a Supercritical Carbon Dioxide Medium

inferred← citeshttps://doi.org/10.1177/17475198241234629openalex-snapshot

Design, synthesis, and insecticidal activities of the novel sulfur-containing meta-amide compounds as potential pesticides

inferred← citeshttps://doi.org/10.21203/rs.3.rs-7453669/v1openalex-snapshot

Characterization of a novel polyfunctional “metalloglyco-protein/polypeptide-organochlorine” bioflocculant containing saturated nitro compounds, sulfones, polysulfides, phosphorus chlorine compounds, magnesium oxide, and metal chlorides, produced from Pseudomonas aeruginosa strain F29, isolated…

inferred← citeshttps://doi.org/10.2174/0115680266313243240624071549openalex-snapshot

Recent Developments on the Synthesis of Oxygen- and Sulfur-containing Heterocycles and their Derivatives under Visible Light Induced Reactions

inferred← citeshttps://doi.org/10.2174/0115701794347153241107110324openalex-snapshot

Metal- and Photocatalyst-Free Sulfonylcyanation of [1.1.1]Propellane with Sulfonyl Cyanide

inferred← citeshttps://doi.org/10.2174/1570180819666220812144409openalex-snapshot

Sulfones of Pyridinyloxy-Substituted Imidazo[2,1-b][1,3]thiazines: Synthesis, Anti-Inflammatory Activity Evaluation In Vivo and Docking Studies

inferred← citeshttps://doi.org/10.26434/chemrxiv-2023-kmb19openalex-snapshot

Arenes / (Hetero)Arenes CH Functionalization Under Synergistic Conditions: Electrochemistry, Photoelectrochemistry & Flow Technology

inferred← citeshttps://doi.org/10.3390/catal13030520openalex-snapshot

Lighting Up the Organochalcogen Synthesis: A Concise Update of Recent Photocatalyzed Approaches

inferred← citeshttps://doi.org/10.3390/molecules28114436openalex-snapshot

Photoinduced Photocatalyst-Free Cascade Cyclization of Alkynes with Sodium Sulfinates for the Synthesis of Benzothiophenes and Thioflavones

inferred← citeshttps://doi.org/10.3390/molecules29245868openalex-snapshot

Recent Advances in the Synthesis of Cyclic Sulfone Compounds with Potential Biological Activity

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