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X-ray Crystal Structure of Aristolochene Synthase from Aspergillus terreus and Evolution of Templates for the Cyclization of Farnesyl Diphosphate,
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
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ChemInform Abstract: Enzymatic Formation of Sesquiterpenes
inferredcites →https://doi.org/10.1006/abbi.2000.1734openalex-snapshot
Aristolochene Synthase: Purification, Molecular Cloning, High-Level Expression in Escherichia coli, and Characterization of the Aspergillus terreus Cyclase
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The interpretation of protein structures: Estimation of static accessibility
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Encyclopedia of the terpenoids
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Sesquiterpene Biosynthesis: Cyclization Mechanisms
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Morphological aspects of oligomeric protein structures
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Elucidation of the deficiency in two yeast coenzyme Q mutants. Characterization of the structural gene encoding hexaprenyl pyrophosphate synthetase.
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[20] Processing of X-ray diffraction data collected in oscillation mode
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Managing and manipulating carbocations in biology: terpenoid cyclase structure and mechanism
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Isoprenoid biosynthesis: manifold chemistry catalyzed by similar enzymes
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Isoprenoid biosynthesis. Stereochemistry of the cyclization of allylic pyrophosphates
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Trichodiene Synthase. Identification of Active Site Residues by Site-Directed Mutagenesis
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Crystal Structure of Recombinant Farnesyl Diphosphate Synthase at 2.6-.ANG. Resolution
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X-ray Crystal Structures of D100E Trichodiene Synthase and Its Pyrophosphate Complex Reveal the Basis for Terpene Product Diversity,
inferredcites →https://doi.org/10.1021/bi034410mopenalex-snapshot
Evidence for Differential Folding of Farnesyl Pyrophosphate in the Active Site of Aristolochene Synthase: A Single-Point Mutation Converts Aristolochene Synthase into an (E)-β-Farnesene Synthase
inferredcites →https://doi.org/10.1021/bi050059oopenalex-snapshot
Molecular Recognition of the Substrate Diphosphate Group Governs Product Diversity in Trichodiene Synthase Mutants ,
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Trichodiene Synthase. Probing the Role of the Highly Conserved Aspartate-Rich Region by Site-Directed Mutagenesis
inferredcites →https://doi.org/10.1021/bi963018oopenalex-snapshot
Pre-Steady-State Kinetic Analysis of the Trichodiene Synthase Reaction Pathway
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Pre-Steady-State Study of Recombinant Sesquiterpene Cyclases
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Structural Biology and Chemistry of the Terpenoid Cyclases
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Aristolochene Synthase. Mechanism-Based Inhibition of a Terpenoid Cyclase
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Aristolochene biosynthesis. Stereochemistry of the deprotonation steps in the enzymatic cyclization of farnesyl pyrophosphate
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Aristolochene biosynthesis and enzymatic cyclization of farnesyl pyrophosphate
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Square-planar complexes of platinum(II) that luminesce in fluid solution
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Germacrene A Is a Product of the Aristolochene Synthase-Mediated Conversion of Farnesylpyrophosphate to Aristolochene
inferredcites →https://doi.org/10.1021/ja0499593openalex-snapshot
Aristolochene Synthase: Mechanistic Analysis of Active Site Residues by Site-Directed Mutagenesis
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Trichodiene Synthase. Enzymatic Formation of Multiple Sesquiterpenes by Alteration of the Cyclase Active Site
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Aristolochene Synthase. Elucidation of the Cryptic Germacrene A Synthase Activity Using the Anomalous Substrate Dihydrofarnesyl Diphosphate
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Computational Investigations of Carbenium Ion Reactions Relevant to Sterol Biosynthesis
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Designed divergent evolution of enzyme function
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Stabilisation of eudesmane cation by tryptophan 334 during aristolochene synthase catalysisElectronic Supplementary Information (ESI) available: GC profiles of co-injections of germacrene A from ASW334F and ASW334V with authentic germacrene A; mass spectra of germacrene A produced by ASW334V and…
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Structure of trichodiene synthase from Fusarium sporotrichioides provides mechanistic inferences on the terpene cyclization cascade
inferredcites →https://doi.org/10.1073/pnas.232591099openalex-snapshot
Bornyl diphosphate synthase: Structure and strategy for carbocation manipulation by a terpenoid cyclase
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Sesquiterpene Synthases from Grand Fir (Abies grandis)
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Structural Basis for Bisphosphonate-mediated Inhibition of Isoprenoid Biosynthesis
inferredcites →https://doi.org/10.1074/jbc.m000433200openalex-snapshot
Crystal Structure Determination of Aristolochene Synthase from the Blue Cheese Mold, Penicillium roqueforti*
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Crystallography & NMR System: A New Software Suite for Macromolecular Structure Determination
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Biosynthesis of Plant Volatiles: Nature's Diversity and Ingenuity
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Structural Basis for Cyclic Terpene Biosynthesis by Tobacco 5-Epi-Aristolochene Synthase
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Crystal Structure of Pentalenene Synthase: Mechanistic Insights on Terpenoid Cyclization Reactions in Biology
inferredcites →https://doi.org/10.1126/science.277.5333.1824openalex-snapshot
Toroidal Structure of λ-Exonuclease
inferredcites →https://doi.org/10.1161/01.atv.0000158943.79580.9dopenalex-snapshot
Inorganic Pyrophosphate
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
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Aristolochene Synthase‐Catalyzed Cyclization of 2‐Fluorofarnesyl‐Diphosphate to 2‐Fluorogermacrene A
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Experimental and Theoretical Studies on Corvol Ether Biosynthesis
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Position‐Specific Mass Shift Analysis: A Systematic Method for Investigating the EI‐MS Fragmentation Mechanism of epi‐Isozizaene
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Single Point Mutation Abolishes Water Capture in Germacradien‐4‐ol Synthase
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QM/MM study of the taxadiene synthase mechanism
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Strategies for the Manipulation of Carbocations by Aristolochene Synthase
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Structural and mechanistic analysis of trichodiene synthase using site-directed mutagenesis: Probing the catalytic function of tyrosine-295 and the asparagine-225/serine-229/glutamate-233– Mg2+B motif
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De novo assembly of the Mylia taylorii transcriptome and identification of sesquiterpene synthases
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Electrostatically Guided Dynamics—The Root of Fidelity in a Promiscuous Terpene Synthase?
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Increasing Complexity of a Diterpene Synthase Reaction with a Single Residue Switch
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A Multiproduct Terpene Synthase from Medicago truncatula Generates Cadalane Sesquiterpenes via Two Different Mechanisms
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Intermediacy of Eudesmane Cation during Catalysis by Aristolochene Synthase
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Changes in Charge Distribution, Molecular Volume, Accessible Surface Area and Electronic Structure along the Reaction Coordinate for a Carbocationic Triple Shift Rearrangement of Relevance to Diterpene Biosynthesis
inferred← citeshttps://doi.org/10.1021/ol2000843openalex-snapshot
Inhibition of (+)-Aristolochene Synthase with Iminium Salts Resembling Eudesmane Cation
inferred← citeshttps://doi.org/10.1038/ja.2016.39openalex-snapshot
General base-general acid catalysis by terpenoid cyclases
inferred← citeshttps://doi.org/10.1038/s41467-020-17642-2openalex-snapshot
Discovery of the cryptic function of terpene cyclases as aromatic prenyltransferases
inferred← citeshttps://doi.org/10.1038/s42004-022-00765-6openalex-snapshot
Structure-guided product determination of the bacterial type II diterpene synthase Tpn2
inferred← citeshttps://doi.org/10.1039/b709562gopenalex-snapshot
Probing the reaction mechanism of aristolochene synthase with 12,13-difluorofarnesyl diphosphate
inferred← citeshttps://doi.org/10.1039/b804198aopenalex-snapshot
Stereochemistry of eudesmane cation formation during catalysis by aristolochene synthase from Penicillium roqueforti
inferred← citeshttps://doi.org/10.1039/c0cc02960bopenalex-snapshot
Electrostatic effects on (di)terpene synthase product outcome
inferred← citeshttps://doi.org/10.1039/c0ob00167hopenalex-snapshot
Quantum chemical dissection of the classic terpinyl/pinyl/bornyl/camphyl cation conundrum—the role of pyrophosphate in manipulating pathways to monoterpenes
inferred← citeshttps://doi.org/10.1039/c1np00006copenalex-snapshot
Biosynthesis via carbocations: Theoretical studies on terpene formation
inferred← citeshttps://doi.org/10.1039/c1np00060hopenalex-snapshot
Sesquiterpene synthases: Passive catalysts or active players?
inferred← citeshttps://doi.org/10.1039/c1ob06184dopenalex-snapshot
Templating effects in aristolochene synthase catalysis: elimination versus cyclisation
inferred← citeshttps://doi.org/10.1039/c2cc17588fopenalex-snapshot
The role of aristolochene synthase in diphosphate activation
inferred← citeshttps://doi.org/10.1039/c2np00078dopenalex-snapshot
Electrophilic and nucleophilic enzymatic cascade reactions in biosynthesis
inferred← citeshttps://doi.org/10.1039/c2np20059gopenalex-snapshot
Terpenoid synthase structures: a so far incomplete view of complex catalysis
inferred← citeshttps://doi.org/10.1039/c3sc53293copenalex-snapshot
Predicting pathways for terpene formation from first principles – routes to known and new sesquiterpenes
inferred← citeshttps://doi.org/10.1039/c5ob01998bopenalex-snapshot
A method for investigating the stereochemical course of terpene cyclisations
inferred← citeshttps://doi.org/10.1039/c6cc08164aopenalex-snapshot
Enzymatic synthesis of natural (+)-aristolochene from a non-natural substrate
inferred← citeshttps://doi.org/10.1039/c9np00051hopenalex-snapshot
Terpene synthases in disguise: enzymology, structure, and opportunities of non-canonical terpene synthases
inferred← citeshttps://doi.org/10.1039/d1cy01913aopenalex-snapshot
Insights into the enzymatic catalytic mechanism of bCinS: the importance of protein conformational change
inferred← citeshttps://doi.org/10.1039/d2cy01617fopenalex-snapshot
Rational reprogramming of the sesquiterpene synthase BcBOT2 yields new terpenes with presilphiperfolane skeleton
inferred← citeshttps://doi.org/10.1039/d3gc01770bopenalex-snapshot
Repurposing the cellulase workhorse Trichoderma reesei as a ROBUST chassis for efficient terpene production
inferred← citeshttps://doi.org/10.1073/pnas.1519680113openalex-snapshot
Identification of amino acid networks governing catalysis in the closed complex of class I terpene synthases
inferred← citeshttps://doi.org/10.1074/jbc.m109.064683openalex-snapshot
Crystal Structure of Albaflavenone Monooxygenase Containing a Moonlighting Terpene Synthase Active Site
inferred← citeshttps://doi.org/10.1074/jbc.m110.165845openalex-snapshot
Cloning and Characterization of an Armillaria gallica cDNA Encoding Protoilludene Synthase, Which Catalyzes the First Committed Step in the Synthesis of Antimicrobial Melleolides
inferred← citeshttps://doi.org/10.1074/jbc.m111.337592openalex-snapshot
Insights into Diterpene Cyclization from Structure of Bifunctional Abietadiene Synthase from Abies grandis
inferred← citeshttps://doi.org/10.1074/jbc.m114.636159openalex-snapshot
Identification of a Fungal 1,8-Cineole Synthase from Hypoxylon sp. with Specificity Determinants in Common with the Plant Synthases
inferred← citeshttps://doi.org/10.1074/jbc.m800659200openalex-snapshot
X-ray Crystallographic Studies of Substrate Binding to Aristolochene Synthase Suggest a Metal Ion Binding Sequence for Catalysis
inferred← citeshttps://doi.org/10.1074/jbc.m802682200openalex-snapshot
Protonation of a Neutral (S)-β-Bisabolene Intermediate Is Involved in (S)-β-Macrocarpene Formation by the Maize Sesquiterpene Synthases TPS6 and TPS11
inferred← citeshttps://doi.org/10.1074/jbc.m807140200openalex-snapshot
Defining the Potassium Binding Region in an Apple Terpene Synthase
inferred← citeshttps://doi.org/10.1107/s1399004714005513openalex-snapshot
The first structure of a bacterial diterpene cyclase: CotB2
inferred← citeshttps://doi.org/10.1107/s2053230x14003100openalex-snapshot
Crystallization and preliminary X-ray diffraction analysis of the diterpene cyclooctatin synthase (CYC) fromStreptomycessp. LZ35
inferred← citeshttps://doi.org/10.1111/j.1365-2958.2009.06717.xopenalex-snapshot
Diversity of sesquiterpene synthases in the basidiomycete Coprinus cinereus
inferred← citeshttps://doi.org/10.1128/aem.00036-18openalex-snapshot
Sesquiterpene Synthase–3-Hydroxy-3-Methylglutaryl Coenzyme A Synthase Fusion Protein Responsible for Hirsutene Biosynthesis in Stereum hirsutum
inferred← citeshttps://doi.org/10.1128/aem.01811-10openalex-snapshot
Selectivity of Fungal Sesquiterpene Synthases: Role of the Active Site's H-1α Loop in Catalysis
inferred← citeshttps://doi.org/10.1128/jb.00759-08openalex-snapshot
Identification of Sesquiterpene Synthases from Nostoc punctiforme PCC 73102 and Nostoc sp. Strain PCC 7120
inferred← citeshttps://doi.org/10.1146/annurev.biochem.76.061005.092322openalex-snapshot
Glycosyltransferases: Structures, Functions, and Mechanisms
inferred← citeshttps://doi.org/10.11575/prism/26983openalex-snapshot
Molecular cloning and characterization of sesquiterpene synthases from valeriana officinalis
inferred← citeshttps://doi.org/10.1186/s40643-021-00421-2openalex-snapshot
Mining methods and typical structural mechanisms of terpene cyclases
inferred← citeshttps://doi.org/10.1351/pac-con-09-09-37openalex-snapshot
Trinuclear metal clusters in catalysis by terpenoid synthases
inferred← citeshttps://doi.org/10.1351/pac-con-12-11-22openalex-snapshot
Inherent dynamical preferences in carbocation rearrangements leading to terpene natural products
inferred← citeshttps://doi.org/10.1351/pac200880081791openalex-snapshot
Chemical wizardry? The generation of diversity in terpenoid biosynthesis
inferred← citeshttps://doi.org/10.1371/journal.pone.0062446openalex-snapshot
Tetramerization Reinforces the Dimer Interface of MnSOD
inferred← citeshttps://doi.org/10.1515/hsz-2017-0171openalex-snapshot
Eremophilane-type sesquiterpenes from fungi and their medicinal potential
inferred← citeshttps://doi.org/10.31274/etd-180810-3614openalex-snapshot
Structure and function of class I diterpene synthase
inferred← citeshttps://doi.org/10.3389/fgene.2020.00421openalex-snapshot
Comparative (Within Species) Genomics of the Vitis vinifera L. Terpene Synthase Family to Explore the Impact of Genotypic Variation Using Phased Diploid Genomes
inferred← citeshttps://doi.org/10.3389/fpls.2019.00177openalex-snapshot
Linking Terpene Synthases to Sesquiterpene Metabolism in Grapevine Flowers
inferred← citeshttps://doi.org/10.3390/md11041399openalex-snapshot
Four New Chloro-Eremophilane Sesquiterpenes from an Antarctic Deep-Sea Derived Fungus, Penicillium sp. PR19N-1
inferred← citeshttps://doi.org/10.3390/microorganisms8101603openalex-snapshot
Combined Comparative Genomics and Gene Expression Analyses Provide Insights into the Terpene Synthases Inventory in Trichoderma
inferred← citeshttps://doi.org/10.3762/bjoc.15.228openalex-snapshot
Current understanding and biotechnological application of the bacterial diterpene synthase CotB2
inferred← citeshttps://doi.org/10.3762/bjoc.9.37openalex-snapshot
Caryolene-forming carbocation rearrangements
inferred← citeshttps://doi.org/10.70675/53d60d87za0a6z43a9z820ez54a3f1e78a4eopenalex-snapshot
Biodiversité, bioactivité et biosynthèse des composés terpéniques volatils des lavandes ailées, Lavandula stoechas sensu lato, un complexe d'espèces méditerranéennes d'intérêt pharmacologique
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